• 제목/요약/키워드: C. minima

검색결과 68건 처리시간 0.023초

Ba-Ferrite 단결정의 자기적 및 열적 현상에 관한 미시적 연구 (Microscopic Studies of the Magnetic and Thermal Properties in Ba-ferrite Single Crystal)

  • 서정철;최정완
    • 한국자기학회지
    • /
    • 제19권4호
    • /
    • pp.152-155
    • /
    • 2009
  • Ba-ferrite 단결정을 제조하여 자기적 성질을 $M\"{o}ssbauer$ 분광법으로 연구하였다. 단결정 시료를 c-축 방향으로 얇게 절단하고 그 면에 감마선을 조사한 결과 Fe 이온의 스핀방향이 c-축과 일치하였고 시료 전체에 걸쳐 단일 결정체임을 확인하였다. 특히 감마선이 스핀과 나란한 경우 $M\"{o}ssbauer$ 흡수선 중에서 결정 내에 존재하는 Fe의 5개 자리 중에서 단지 4개 자리에서만 공명흡수선이 존재하였고 2b 자리에서는 전혀 공명흡수가 일어나지 않았다. 2b 자리에서의 공명흡수가 일어나지 않는 이유는 대칭성이 있는 2개의 우물 형 위치에너지의 중심 사이를 Fe 이온이 매우 빠른 속도로 c-축을 따라 진동하는 것으로 설명할 수 있다.

풀러렌-물 클러스터의 상호작용에 대한 양자 역학적 이론 연구 (Quantum Mechanical Investigations for the Interactions between Fullerene and Encapsulated Waters)

  • 김성현;신창호;김지선;강소영;김승준
    • 대한화학회지
    • /
    • 제59권1호
    • /
    • pp.9-17
    • /
    • 2015
  • 풀러렌(fullerene)의 내부에 캡슐화될 수 있는 물 분자의 수와 물 분자들이 증가함에 따라 풀러렌의 안정적인 구조에 미치는 영향을 조사하기 위해 밀도 범함수 이론(density functional theory, DFT)을 이용하여 풀러렌-물 클러스터$(H_2O)_n@C_{60}$, (n=1-10)의 구조 변화에 따른 열역학적 안정성 및 결합에너지를 계산하였다. 각각의 구조들에 대해서 여러 이론 수준에서 최적화하였으며 진동주파수를 계산하여 가장 안정한 구조를 조사하고 IR 스펙트럼을 예측하였다. 또한 풀러렌 내의 물 분자 수가 증가함에 따른 수소결합의 세기 변화를 순수한 물 클러스터$(H_2O)_n$, (n=1-6)의 수소결합과 비교 분석하였다.

BaO 과잉량에 따른 BaTiO3의 전기전도도 (Electrical Conductivity Revisited in Excess BaO into BaTiO3)

  • 여홍구;국민호;김명호;송태권;배동식;박태곤;이순일
    • 한국세라믹학회지
    • /
    • 제42권5호
    • /
    • pp.308-313
    • /
    • 2005
  • In this study the electrical conductivity of excess BaO in $BaTiO_3$ was measured to investigate the relationship between defects and solubility in the temperature range of $900^{\circ}C$ to $1300^{\circ}C$ under various oxygen partial pressure. First of all, quenched $BaTiO_3$ powders of various Ba/Ti ratios were analysed by X-ray diffraction to confirm whether second phase is formed or not. As the results, we observed the solubility of BaO in the temperature range of $1200^{\circ}C$ to $1400^{\circ}C$, and it was also found that the conductivity minima move to lower $PO_2$ with increasing excess BaO within solubility limit.

봄철 양평지역(楊平地域)의 지형(地形) 및 고도(高度)에 따른 일최저기온(日最低氣溫)의 분포(分布) (Topoclimatological interpretation of the daily air temperature minima at 17 locations crossing over Yangpyeong basin in 1986 spring)

  • 강안석;윤진일;정영상;노부테루 타니
    • 한국토양비료학회지
    • /
    • 제19권4호
    • /
    • pp.339-344
    • /
    • 1986
  • 농작물(農作物)에 대(對)한 서리의 피해(被害)는 재배지(栽培地)의 지형적(地形的) 특성(特性)과 밀접(密接)한 관계(關係)가 있으며, 일최저기온(日最低氣溫)의 평면적(平面的)인 분포(分布)는 야간복사냉각조건(夜間輻射冷却條件)과 냉기중력이동조건(冷氣重力移動條件)의 지역적(地域的)인 차이(差異)에 의(依)해 특징(特徵)지워진다. 과원지대(果園地帶)의 지형적조건(地形的條件)과 봄철 최저기온형성간(最低氣溫形成間)의 관계(關係)를 구명(究明)하기 위(爲)하여 1986년(年) 4월(月) 29일(日)부터 5월(月) 2일(日)까지 경기도(京畿道) 양평군(楊平郡) 남한강(南漢江) 유역의 과수원지대(果樹園地帶)에서 최저기온(最低氣溫)의 분포상태(分布狀態)를 조사(調査)하였다. 최근(最近) 수년간(數年間) 빈번한 동상해(凍霜害)로 인(因)해 과수재배(果樹栽培)가 중지(中止)된 지역(地域)을 관통(貫通)하는 직선거리(直線距離) 8.5km의 경로(經路) A에 대(對)하여 17개(個)의 고정관측점(固定觀測點)을 설치(設置)하였으며 피해(被害)를 거의 받지않아 현재(現在), 재배중(裁培中)인 지대(地帶)를 통과(通過)하는 직선거리(直線距離) 2.5km의 경로(經路) B에 대(對)해서는 일출직전(日出直前) 1시간여(時間餘)에 걸쳐 이동관측(移動觀測)을 수행(遂行)하였다. 관측(觀測)은 흐린 날과 갠 날로 나누어 실시(實施)하였다. 맑고 바람이 잔잔했던 (풍속(風速)<0.5 m/sec) 4월(月) 30일(日) 아침의 최저기온(最低氣溫)은 대체(大體)로 해발온도(海拔溫度)가 높을수록, 높게 나타났으며(강변(江邊), 마을지역제외(地域除外)), 흐리고 바람이 다소(多少) 강(强)했던 (풍속(風速) 1.5~2.5 m/sec) 5월(月) 1일(日) 아침에는 지형조건(地形條件)이나 해발고도(海拔高度)에 따른 최저기온변화(最低氣溫變化)가 거의 없었다. 피해(被害)가 경미(輕微)한 대흥리과수원(大興里果樹園)은 맑은 날 아침 최저기온(最低氣溫)이 주변저지대(周邊低地帶)에 비(比)하여 $1^{\circ}C$ 높았으나, 폐원(廢園)된 병산리일대(屛山里一帶)는 극최저기온(極最低氣溫)이 나타나는 중간지대(中間地帶)임이 확인(確認)되었다.

  • PDF

Theoretical Approach for the Equilibrium Structures and Relative Energies of C7H7+ Isomers and the Transition States between o-, m-, and p-Tolyl Cations

  • Shin, Chang-Ho;Park, Kyung-Chun;Kim, Seung-Joon;Kim, Byung-Joo
    • Bulletin of the Korean Chemical Society
    • /
    • 제23권2호
    • /
    • pp.337-345
    • /
    • 2002
  • The equilibrium structures for the ground and transition states of $C_7H_7^+$ isomers have been investigated using sophisticated ab initio quantum mechanical techniques with various basis sets. The structures of tropyrium and benzyl cations have been fully optimized at the DZP CCSD(T) levels of theory. And the structures of o-, m-and p-tolyl cations are optimized fully up to the DZ CCSD(T) levels of theory. The geometries for the transition states between three isomers of tolyl cations have been optimized up to DZP CISD level of theory. The SCF harmonic vibrational frequencies for tropylium, benzyl, and three isomers of tolyl cations are all real numbers, which confirm the potential minima and each unique imaginary vibrational frequencies for TS1 and TS2 confirm the true transition states. The relative energy of the benzyl cation with respect to the tropyrium cation is predicted to be 28.5 kJ/mol and is in good agreement with the previous theoretical predictions. The 0 K heats of formation, ${\Delta}H^{\circ}_{f0}$, have been predicted to be 890, 1095, 1101, and 1110 kJ/mol for tropylium, ortho-, meta-, and para-tolyl cations by taking the experimental value of 919 kJ/mol for the benzyl cation as the base level. The relative stability between tolyl cations is in the order of ortho

하천에서 중금속 아연(Zn) 유입이 부착규조의 종조성과 형태 변이에 미치는 영향 (Influence of Heavy Metal (Zn) Inflow on Species Composition and Morphological Abnormalities of Epilithic Diatom in the River)

  • 신라영;류희성;이정호
    • 한국물환경학회지
    • /
    • 제33권4호
    • /
    • pp.424-433
    • /
    • 2017
  • The purpose of this study is to understand the changes on species composition of the epilithic diatoms and the appearance of morphological abnormalities in the upper region of the Nakdong River where heavy metal inflow is observed. The samples were collected once a week for a month of September 2016 from selecting 7 sampling stations. The heavy metals of cadmium (Cd) and arsenic (As) were not detected during the survey period, but zinc (Zn) was detected in st.4 - st.6 with the range of $0.015{\sim}0.188mg\;L^{-1}$. Metal sensitive species such as Achnanthes convergens, Cocconeis placentula, Cocconeis placentula var. euglypta, Cocconeis placentula var. lineata showed high dominance in st.1 - st.3, st.7. However, metal tolerant species such as Nitzschia palea, Achnanthes minutissima showed high dominance in st.4 - st.6. It is concluded that heavy metal inflow directly affects the changes in species composition of epilithic diatoms. As a result of CCA, the characteristics of the sampling sites were divided into 3 groups. Group 1 was represented the non-detected Zn sites with C. placentula, C. placentula var. euglypta, C. placentula var. lineata. Group 2 was showed the detected Zn sites with Navicula minima and Nitzschia palea. Group 3 was included st.3 - st.7 on 4th week that was stabilized the community structure. Total 8 taxa of abnormal frustules observed. This occurrence of abnormal frustules reflected the temporal and quantitative indicators of heavy metal pollution, in particular, it was confirmed that genus Fragilaria, which has a high abnormality according to heavy metal pollution, can be used as an indicator species.

생물학적 후각 시스템을 모방한 대규모 가스 센서 어레이에서 코사인 유사도와 퍼지 클러스터링을 이용한 중복도 제거 방법 (The Redundancy Reduction Using Fuzzy C-means Clustering and Cosine Similarity on a Very Large Gas Sensor Array for Mimicking Biological Olfaction)

  • 김정도;김정주;박성대;변형기;;임승주
    • 센서학회지
    • /
    • 제21권1호
    • /
    • pp.59-67
    • /
    • 2012
  • It was reported that the latest sensor technology allow an 65536 conductive polymer sensor array to be made with broad but overlapping selectivity to different families of chemicals emulating the characteristics found in biological olfaction. However, the supernumerary redundancy always accompanies great error and risk as well as an inordinate amount of computation time and local minima in signal processing, e.g. neural networks. In this paper, we propose a new method to reduce the number of sensor for analysis by reducing redundancy between sensors and by removing unstable sensors using the cosine similarity method and to decide on representative sensor using FCM(Fuzzy C-Means) algorithm. The representative sensors can be just used in analyzing. And, we introduce DWT(Discrete Wavelet Transform) for data compression in the time domain as preprocessing. Throughout experimental trials, we have done a comparative analysis between gas sensor data with and without reduced redundancy. The possibility and superiority of the proposed methods are confirmed through experiments.

수리형태학을 이용한 영상 분할 (Image Segmentation Using Mathematical Morphology)

  • 조선길;강현철
    • 한국통신학회논문지
    • /
    • 제30권11C호
    • /
    • pp.1076-1082
    • /
    • 2005
  • 최근 수리형태학적 접근 방법을 이용하여 영상을 분할하고자 하는 연구가 계속되고 있다. 그 중에서도 분수경계 알고리듬은 기존의 에지 기반의 영상 분할 방법과 영역기반의 영상분할 방법의 장점을 모두 가지고 있는 효과적인 영상 분할 기법 중에 하나이다. 분수경계 알고리듬의 기본적인 개념은 지형학적 해석에 기반을 두고 있으며 항상 영역의 외곽에 폐곡선을 형성한다. 그러나 잡영에 매우 민감하게 반응하여 수많은 영역으로 분할되는 과분할 현상을 초래한다. 따라서 본 논문에서는 중요하지 많은 국부 최소점과 국부 최대점을 모두 제거함으로써 과분할 현상을 줄이는 제한적 워터폴 알고리듬을 제안한다. 실험결과 제안한 제한적 워터폴 방법이 다른 과분할 억제 방법보다 평균분할 영역수와 외곽선 소실 측면에서 효과적으로 영상을 분할할 수 있었다.

ORBITAL PERIOD VARIATION AND MORPHOLOGICAL LIGHT CURVE STUDIES FOR THE W UMa BINARY BB PEGASI

  • Hanna, Magdy A.;Awadalla, Nabil S.
    • 천문학회지
    • /
    • 제44권3호
    • /
    • pp.97-108
    • /
    • 2011
  • The photometric light curves of the W-type W UMa eclipsing contact binary system BB Pegasi have been found to be extremely asymmetric over all the observed 63 years in all wavelengths UBVR. The light curves have been characterized by occultation primary minima. Hence, the morphology of these light curves has been studied in view of these different asymmetric degrees. The system shows a distinct O'Connell effect, as well as depth variation. A 22.96 years of stellar dark spots cycle has been determined for the system. Almost the same cycle (22.78 yr) has been found for the depth variation of MinI and MinII. We also present an analysis of mid-eclipse time measurements of BB Peg. The analysis indicates a period decrement of $5.62{\times}10^{-8}$ day/yr, which can be interpreted in terms of mass transfer at a rate of $-4.38{\times}10^{-8}M_{\odot}$/yr, from the more to the less massive component. The O - C diagram shows a damping sine wave covering two different cycles of 17.0 yr and 12.87 yr with amplitudes equal to 0.0071 and 0.0013 day, respectively. These unequal durations show a non-periodicity which may be explained as a result of magnetic activity cycling variations due to star spots. The obtained characteristics are consistent with similar chromospherically active stars, when applying the Applegate's (1992) mechanism.

STUDY OF PERIOD VARIATION OF THE ECLIPSING BINARY SYSTEM W DELPHINI

  • Hanna, Magdy A.
    • 천문학회지
    • /
    • 제39권4호
    • /
    • pp.129-138
    • /
    • 2006
  • A period study of the semi-detached eclipsing binary system W Delphini based on the extensive series of minimum timings covering more than a century(109 years) indicates a cyclic(O-C) variation of the system. This variation can be explained as due either to (1) stellar magnetic activity cycles of the cool subgiant G5 secondary component of the binary with a subsurface magnetic field equals to 3 kG, or (2) a long-term orbital period increases with a rate of $1.68{\times}10^{-8}$ day/cycle caused by a mass transfer rate of $4.9{\times}10^{-8}M_{\odot}yr^{-1}$ from the less to more massive component modulated by a light time effect due to a hypothetical third body with period of $53.4{\pm}1.06$ years. The former explanation is more recommended than the later one since the obtained third body mass value($M_3=1.58\;M_{\odot}$) is quite large but it can not manifest itself observationally and also it cannot be a white dwarf. In the contrary, from the magnetic activity point of view, the obtained characteristics are in good consistent when applying Applegate(1992) mechanism. However, further precise photometric and CCD observations for minima timings with brightness determinations are needed to confirm the present solution.