• 제목/요약/키워드: C-flux

검색결과 1,782건 처리시간 0.033초

가교된 PVA 막을 이용한 MTBE/methanol 혼합물의 증기투과(Vapor Permeation)분리 (Vapor Permeation Separation of MTBE-Methanol Mixtures Using Cross-linked PVA Membranes)

  • 김연국;임지원
    • 멤브레인
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    • 제10권3호
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    • pp.148-154
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    • 2000
  • 본 연구에서는 sulfur-succinic acid의 가교제를 이용한 가교된 폴리비닐알코올(poly(vinyl alcohol), PVA) 가교막을 이용하여 MTBE-methanol 혼합액에 대하여 조업온도, 가교제의 조성에 따른 증기투과 공정의 투과 특성을 조사 하였다. 팽윤 실험을 통해 PVA/SSA 가교막에 대하여 가교제 조성에 따른 막의 구조와 PVA의 하이드록실기(-OH), SSA의 설폰기(-$SO_3$H)와 용매와의 수소결합의 두 가지 인자가 상호 보완적으로 작용하고 있음을 알 수 있었다. 투과 특성에 있어 SSA의 설폰기가 중요한 인자로 작용하였다. 예를 들면 7% SSA 막에 대해서는 수소결합의 효과보다는 가교도의 효과가 투과 특성에 중요한 요인으로 작용하며 5% SSA에 대해서는 수소결합의 효과가 중요하게 작용하였다. 증기투과 공정에 있어 막과 직접 접촉하는 증기상이 액상에 비하여 methanol의 농도가 낮아 PVA의 하이드록실기와 methanol과의 수소결합 확률이 감소함에 따라 투과 특성에 영향을 미친다. 결과적으로 7% SSA 막에 대하여 MTBE/mthanol=80/20 혼합액에 대하여 공급액의 온도 3$0^{\circ}C$에서 선택도 2187, 투과도 4.84g/$m^2$hr를 보여 주었다.

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잔디밭에서 계절 변화에 따른 이산화탄소 플럭스 변동 (Response of Soil CO2 Fluxes to Seasonal Variations in a Grassplot)

  • 김박사;권병혁;강동환
    • 한국환경과학회지
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    • 제23권6호
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    • pp.1131-1142
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    • 2014
  • In this study, the variations of the carbon dioxide fluxes were investigated with soil temperatures in the grassplot and seasonal variations of carbon dioxide concentrations and fluxes were analysed. Soil temperatures, carbon dioxide concentrations and fluxes were measured on the grassplot in Pukyong National University. Field measurements were carried out 25 times from March in 2010 to March in 2011 with nine points on the grassplot. Seasonal variations of carbon dioxide concentrations and fluxes showed an inverse relation. In summer, carbon dioxide concentrations are lower and carbon dioxide fluxes are higher. In winter, carbon dioxide concentrations are higher and carbon dioxide fluxes are lower. On the grassplot, carbon dioxide emission rate increase when the soil temperature is more than $20^{\circ}C$ and the emission rate decrease when the soil temperatures are less than $10^{\circ}C$. When the accumulated rainfall for five days before measurement day is 20~100 mm, it is showed that the more rainfall, the more carbon dioxide emissions. Carbon dioxide emission rate from the grassplot to the upper atmosphere was increased or decreased by the factors such as soil temperature, growth and wither of grass and rainfall. The results of this study showed that the emission of carbon dioxide in the grassplot is dominantly controlled by seasonal factors (especially soil temperature and rainfall).

석분토와 바텀애쉬를 이용한 인공경량골재 제조 (Manufacturing of Artificial Lightweight Aggregate using Stone-Dust and Bottom Ash)

  • 윤섭;김정빈;정용;김양배
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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    • pp.381-384
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    • 2008
  • 부순골재 생산과정에서 발생하는 석분토와 화력발전소에서 발생하는 Bottom ash를 이용한 인공경량골재의 물리 화학적 특성을 분석하여 콘크리트용 인공경량골재의 사용여부를 검토하였는데, 그 결과는 다음과 같다. 석분토(이하 SD)와 Bottom ash(이하 BA)의 혼입비율에 따른 인공경량골재의 특성으로는 BA의 혼입비율이 커질수록 미연탄소와 $Fe_2O_3$의 함량 증가로 인해 소성 시 가스 발생량이 증가하여 밀도는 낮아지고 흡수율은 증가하는 것으로 나타났는데, 화학조성상 적절한 혼합비율은 SD : BA = 5:5 내외일 것으로 판단된다. Flux제 첨가에 따른 인공경량골재의 특성으로는 $Na_2SO_4$ 첨가율이 증가할수록 밀도는 낮아졌다. 이에 본 연구범위내에서는 SD: BA = 5:5, $Na_2SO_4$ 2%, $Fe_2O_3$ 1%, 소성 온도 $1,150^{\circ}C$, 소성시간 15분에서 밀도 $1.52g/cm^3$, 흡수율 7.3%의 인공경량골재를 개발할 수 있었다.

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Flat TR용 페라이트 코아의 고주파 동작 특성 (Study on operating characteristics of Ferrite cores for Flat TR in high frequency)

  • 한세원;조한구;류동욱;최광보
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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    • pp.1168-1171
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    • 2003
  • In contrast to a conventional transformer, the flat transformer is made using a number of small ferrite cores. Two cores for transformer and one core for inductor, which composed one module. Many modules can be connected together to form a flat matrix transformer. This structural arrangement eliminates the single hot spot problem in conventional transformers and permits high current density pertains at high frequency. In this study, the ferrite magnetic cores of Mn-Zn system for the Flat transformer were manufactured and the electrical and magnetic characteristics of its tested. The power loss of sample FO2(Mn-Zn ferrite) sintered at $1350^{\circ}C$ was $350kW/m^3$ in test conditions of 250kHz, 200mT and $100^{\circ}C$, which showed the good power loss property in high frequency. The power loss of FO2 samples has been studied as a function of magnetic flux density and frequency. Steinmetz exponent was 2.82 at 250kHz and 2.73 at 500kHz. These results illustrated the switching of power loss mechanism in ferrite core from hysteresis losses to eddy current losses or others.

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한반도 중규모 대류복합체의 발달특성에 관한 연구 (Characters of Mesoscale Convective Complex Development in Korean Peninsula)

  • 이순환;원효성
    • 한국지구과학회지
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    • 제26권7호
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    • pp.698-705
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    • 2005
  • 한반도 집중호우를 유발시키는 중규모대류복합체는 매우 복잡한 특성을 띠고 있다. 2004년 7월 14일 발생한 중 규모 대류복합체의 발달메커니즘을 분석한 결과, a) 대류복합체 생성 전에 강한 남서기류의 유입이 있었으며, b) 600hPa고도에서 강한 역전층이 나타났다. 역전층은 상층과 하층간의 상당온위의 차이를 유발하여 대기불안정을 더욱 강화시켰다. 그리고 c) 일반적인 중규모대류복합체 특징인 풍향의 쉬어보다는 풍속의 쉬어에 의해 대류계의 열역학 불안정이 강화되었다. 그리고 d) 흑산도 등 해안지방에 의해 유발되는 난류 및 대기불안정으로 인하여 중규모 대류복합체가 해안지방에서 발달한 것으로 보인다. 그러므로 지형에 의한 중규모 대류 복합체의 발달메커니즘 규명이 필요하다.

온도에 따른 집광형 태양전지의 성능에 관한 실험적 연구 (An Experimental Study on the Performance of a Concentrating Photovoltaic Cell as a Function of Temperature)

  • 신재혁;이승신;김상민;부준홍
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2012년도 춘계학술발표대회 논문집
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    • pp.96-101
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    • 2012
  • An experimental study was conducted to investigate the performance of a concentrating photovoltaic cell (CPV) against temperature. It is know that a high efficiency of a CPV can be achieved only with proper cell temperature as well as high concentration ratio (CR). This study is concerned with appropriate cooling condition for a liquid-convection cooler for the best performance of a specific CPV. A series of experiments was conducted in a range of cell temperatures as a result of varying cooling conditions, while the concentration ratio was 390 and the solar irradiation flux was higher than 900 $W/m^2$ in outdoor environment. The CPV had a planar dimension of 10 by 10 mm. A Fresnel lens was used as a concentrator, of which the dimension was 221 mm(W) ${\times}$ 221 mm(L) ${\times}$ 3 mm(t) and the transmissivity was known to be 0.8. The cooler was attached to the bottom side of the CPV and had a contact area of 21 mm(W) ${\times}$ 26 mm(L), which was identical to the size of the base plate of the CPV. The coolant temperature was controlled by an isothermal bath and the flow rate was controlled and measured by a flowmeter. The experimental results showed that the average of power efficiency of the CPV decreased from 28.6 % to 24.7 % as the cell temperature increased from $36^{\circ}C$ to $97^{\circ}C$. An appropriate cooling method of a CPV might increase the power conversion efficiency by about 4% for the same concentration ratio. Discussion is included from the viewpoint of the combined efficiency in addition to the power efficiency.

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Isolation and Characterization of a Gene Encoding Hexokinase from Loquat (Eriobotrya japonica Lindl.)

  • Qin, Qiaoping;Zhang, Lanlan;Xu, Kai;Jiang, Li;Cheng, Longjun;Xu, Chuanmei;Cui, Yongyi
    • 원예과학기술지
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    • 제30권3호
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    • pp.243-249
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    • 2012
  • Hexokinase is the first enzyme in the hexose assimilation pathway; it acts as a sensor for plant sugar responses, and it is also important in determining the fruit sugar levels. The full-length cDNA of a hexokinase gene was isolated from loquat through reverse transcription polymerase chain reaction (RT-PCR) and rapid amplification of cDNA ends, which was designated as EjHXK1. EjHXK1 is 1,839 bp long and contains an entire open reading frame encoding 497 amino acids. The predicted protein of EjHXK1 shares 72%-81% similarity with other plant hexokinases. Phylogeny analysis indicated that EjHXK1 is closely related to maize and rice hexokinases. Transient expression of the 35S: EjHXK1-GFP fusion protein was observed on the cell membrane and cytoplasm. Real-time RT-PCR indicated that EjHXK1 is expressed in loquat leaves, stems, flowers, and fruits. EjHXK1 transcripts were higher during early fruit development, but decreases before maturation, which is consistent with hexokinase enzyme activity during fruit development and conducive for hexose accumulation in mature fruits. These results imply that EjHXK1 may play important roles in the regulation of sugar flux during fruit ripening.

MOD-TFA 공정에 의한 YBCO박막제조시 과잉 yttrium첨가 효과에 관한 연구 (Effects of Excess Yttrium Addition on YBCO Thin Films Prepared by TFA-MOD Process)

  • 이승이;송슬아;김병주;박진아;김호진;이희균;홍계원;장석헌;주진호;유재무
    • Progress in Superconductivity
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    • 제7권1호
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    • pp.87-91
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    • 2005
  • [ $YBa_{2}Cu_{3}O_{7-x}$ ] thin films were fabricated on $LaAlO_3$(100) substrate by TFA-MOD process. Yttrium-excess (0, 2.5, 5, 10, 15, 20 $at\%$) coating solution was prepared by adding extra amount of yttrium into a stoichiometric(Y:Ba:Cu=1:2:3) TFA precursor solution. Results are presented concerning the influence of excess yttrium additions on the microstructure development and superconducting properties of $YBa_{2}Cu_{3}O_{7-x}$ film. Large sized CuO particles was observed by SEM EDS investigation. The addition of excess yttrium affected little on $T_c$ of $YBa_{2}Cu_{3}O_{7-x}$ film. $J_c$ of YBCO film was enhanced with excess yttrium addition. Jc maximum of $2.21\;MA/cm^2$ (77 K, self field) appeared with the $15\;at\%$ addition of excess yttrium. With further yttrium addition up to $20\;at\%$, Jc decreased down to $0.9\;MA/cm^2$.

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Identifying the VeLLOs in the Spitzer Gould's Belt Survey

  • Kim, Mi-Ryang;Lee, Chang-Won;Dunham, M.;Allen, L.;Myers, Philip C.;Evans, N.
    • 천문학회보
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    • 제35권2호
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    • pp.67.2-67.2
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    • 2010
  • We present results of searching for the Very Low Luminosity Objects (VeLLOs; internal luminosity : $L_{int}$ < $0.1(d/140pc)^2\;L\odot$) in the Gould's Belt clouds using observations from 3.6 to 70 micron by the Spitzer Space Telescope. The clouds are California, Chamaeleon I, III, Musca, Lupus V, VI, Scorpius, Serpens, Corona Australis, Cepheus, and IC 5146 having the properties of active low-mass star-forming such as the Taurus cloud. The observing sensitivity of the Spitzer data is estimated to be about $L_{int}\;\geq\;5\times10^{-3}(d/140pc)^2\;L\odot$, a factor of 20 better than that of the Infrared Astronomical Satellite (IRAS). The observing data were processed by the c2d Legacy pipeline. As the criteria to select the VeLLOs, we slightly modified previous ones by Dunham et al. The most important criterion is a flux density at 70 micron that is directly converted to the internal luminosity. Also, we used additional criteria to remove the contamination of evolved stars and extragalaxies which have colors or SEDs very similar to YSOs. We identified a total of 64 new embedded VeLLO candidates with $L_{int}$ < $0.1(d/140pc)^2\;L\odot$, consisting of 8 in California, 15 in Chamaeleon-Musca, 13 in Scorpius-Lupus, 20 in Serpens, 3 in Corona Australis, 3 in Cepheus, and 2 in IC 5146. The classification of the spectral index (${\alpha}$) fitted to the shape of the Ks-24 micron SEDs shows most of VeLLO candidates (89%) are in types of Class I and Flat spectrum. We plot various diagrams based on their 2MASS-Spitzer bands colors and magnitudes to discuss properties of the VeLLOs. This search will lead us new adventure toward a future systematic study of the VeLLOs.

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Sr1-xBaxAl2O4:Eu2+, Dy3+계 축광성 형광체의 합성과 그의 발광특성 (Synthesis and Photoluminescence of the Sr1-xBaxAl2O4:Eu2+, Dy3+ Long Phosphorescence Phosphor)

  • 박진우;김정식
    • 한국세라믹학회지
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    • 제43권6호
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    • pp.333-337
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    • 2006
  • In this study, the $Sr_{1-x}Ba_{x}Al_{2}O_{4}:Eu^{2+},Dy^{3+}$ phosphor were prepared by the solid-state reaction method and its photoluminescence properties were investigated. Starting powders of $SrCO_3,\;BaCO_3,\;and\;Al_{2}O_3$ were mixed with $Eu_{2}O_3$ as activator, $Dy_{2}O_3$ as co-activator and $B_{2}O_3$ as flux. Then, the mixed powders were heated at the temperature of $1100{\sim}1400^{\circ}C$ for 3 h under the reducing ambient atmosphere of $95%Ar+5%H_2$. The effect of Ba addition from 0.0 to 1.0 mol on photoluminescence was investigated. As the amount of Ba increased, the intensity of emission increased and the optimum long phosphorescence occurred at the amount of 0.1 mol Ba. The optimum sintering condition for long phosphorescent phosphor of $Sr_{1-x}Ba_{x}Al_{2}O_{4}:Eu^{2+},Dy^{3+}$($x=0{\sim}1.0mol$) was found at $1400^{\circ}C$. The excitation spectra showed a broad band of $250{\sim}450nm$ with maximum peak at 360 nm. The maximum peak intensity of emission spectra occurred at the range of $480{\sim}520nm$, depending on Ba content.