• Title/Summary/Keyword: C-S-H phase

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Effects of H$_2$BO$_3$ on the Hydration of $C_4$A$_3$S Blended Rapid Hardign Cement (CSA계 혼합 시멘트 수화에 미치는 Boric Acid 의 영향)

  • Yoo, K.S.;Lee, K.H.;Kim, N.H.;Lee, Y.S.;Hun, K.H.;Lee, J.W.;Yim, Going
    • Journal of the Korean Ceramic Society
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    • v.35 no.6
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    • pp.583-593
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    • 1998
  • The study was carried on the influence of {{{{ { {H }_{3 }BO }_{3 } }} for hydration of blended rapid hardening cement which was composed of {{{{ {{C }`_{4 } ^{ }A }_{3 } }} Adding {{{{ { {H }_{3 }BO }_{3 } }} to the mortar of blended rapid hardening cement delayed the setting time and increased the flow of the mortar. When {{{{ { {H }_{3 }BO }_{3 } }} added to the blended rapid hardening cement mono-sulfate was produced rather than ettringite and the existing time of monosulfate also prolonged. After hours monosulfate was converted to ettringite through being producted like gels. This monosulfate phase in-fluences on the setting time and flow of fresh mortar.

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Effect of Starting Materials on the Characteristics of (La1-xSrx)Mn1+yO3−δ Powder Synthesized by GNP (GNP법에 의해 합성한 (La1-xSrx)Mn1+yO3−δ 분말의 출발물질에 따른 특성)

  • Lee, Mi-Jai;Kim, Sei-Ki;Jee, Mi-Jung;Choi, Byung-Hyun;Park, Sang-Sun;Lee, Kyung-Hee
    • Journal of the Korean Ceramic Society
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    • v.44 no.1 s.296
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    • pp.52-57
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    • 2007
  • We synthesized $(La_{1-x}Sr_x)MnO_3$ as a cathode for SOFC by glycine nitrate process (GNP) and knew the different properties of $(La_{1-x}Sr_x)MnO_3$ by using nitrate solution and oxide solution as a starting material. In case of using nitrate solution as a starting material, main crystal phase peak of $LaMnO_3$ increased as Sr content added up and a peak of $Sr_2MnO_4\;and\;La_2O_3$ was showed as a secondary phase. We added Mn excess to control a crystal phase. In this case, the electrical conductivity had a high value 210.3 S/cm at $700^{\circ}C$. On the other side, when we used oxide solution as a starting material, we found main crystal phase of $LaMnO_3$ to increase as Sr content added up and a peak of $La_2O_3$ as a secondary phase. Similary, we added Mn excess to control a crystal phase in this case. We knew $(La,Sr)MnO_3$ powder to sinter well and the electrical conductivity of the sintered body at $1200^{\circ}C$ for 4 h was 152.7 S/cm at $700^{\circ}C$. The sintered $(La,Sr)MnO_3$ powder at $1000^{\circ}C$ for 4 h got the deoxidization peak, depending on the temperature and in case of using nitrate solution as a starting material, the deoxidization peak was showed at $450^{\circ}C$ which is lower than used a oxide solution as a starting material. As a result, when $(La,Sr)MnO_3$ powder was synthesized to add Mn excess and to use nitrate solution as a starting material, we found it to have the higher deoxidization property and considered it as a cathode for SOFC properly. And we found it to have different electrical conductivity the synthesized $(La,Sr)MnO_3$ powder by using different starting materials like nitrate solution and oxide solution which influence a sintering density and crystal phase.

Synthesis of Ferroelectric Liquid Crystals Obtained from Optically Active l-isoleusine (광학활성 이소로이신을 출발물질로 한 강유전성 액정물질의 합성)

  • Jeong, N.H.;Kikuchi, H.;Kajiyama, T.
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.3
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    • pp.51-60
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    • 1996
  • A new one series of chiral schiff's base containing benzylidene aniline moieties was synthesized and characterized by IR, $^1H$ NMR. elementary analysis, and polarized optical microscopy(POM). The yield of these synthetic compounds was in the range of $62{\sim}67^{\circ}C$. The results showed that most of the synthetic compounds were monotropic liquid crystal and exhibited chiral smectic C($Sc^{\ast}$) liquid crystal phases, and the range of phase transition temperature was to $71.4^{\circ}C$ from $45.0^{\circ}C$.

Influence of Candide parapsilosis on the Changes in Various Components of Korea Red Ginseng Extract (Candida payapsilosis가 홍삼엑기스의 성분 변화에 미치는 영향)

  • 양재원;노길봉
    • Journal of Ginseng Research
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    • v.13 no.1
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    • pp.60-65
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    • 1989
  • The Quality characteristics of pH, ginsenosides, fatty acid, phenolic compounds were studied for their changes during growth of Candia parapsilosis. The yeast growth not only scarcely affected the total amount of saponins and ginsenosidvs of recd ginseng tail root extract, but also was not affected by the saponin C. pnrapsilosis did not utilize the ginsenosides as a carbon source. Glucose, fructose and free sugars were utilized in the initial phase of growth, whereas sucrose and maltose were used as the growth continued and completely redured after 43 hours of incubation. Unsaturated fatty acids were significantly reduced with cell growth, showing a relationship between unsaturated fatty acid content and the yeast growth, whereas the amount of saturate[1 tatty acids in red ginseng extract was not affected by the yeast growth. Generally, there were no changes in major organic acids and phenolic compounds (vanillie acid , m-coumaric acid) except the 50% reduction in maltol and ferulic acid in the ginseng extract. The amounts of amlno acids were gradually decreased, but that of arginine was remarkably reduced.

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Numerical Prediction of Forced Convective Boiling Heat Transfer and Flow in Steam Generator Helical Coils (헬리컬 증기발생기 코일에서 강제대류 비등 열전달 및 유동의 수치 적 예측)

  • Jo J. C.;Kim H. J.;Kim W. S.;Yu S. O.
    • 한국전산유체공학회:학술대회논문집
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    • 2004.10a
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    • pp.127-130
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    • 2004
  • In this study, three-dimensional numerical calculations are peformed to simulate the flow and heat transfer in helically coiled tube steam generator employing a commercial CFD (Computational Fluid Dynamics) code. The problem considered herein includes the boiling phase change flow of tube side fluid and the single-phase counter-current flow of shell side hot fluid transferring heat to the tube side flow thru the tube wall. Detailed investigations are performed for both shell-side and tube-side flow fields in terms of density and volume fractions of each phase of fluids as well as for the tube wall heat transfer field in terms of heat transfer coefficients.

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Aluminide Coatings on IN713C by Chemical Vapor Depostion (화화증착법에 의한 알루미나이드 코팅층의 형성)

  • Sohn, H.S.;Hong, S.H.;Kim, M.I.
    • Journal of the Korean Society for Heat Treatment
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    • v.7 no.2
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    • pp.129-138
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    • 1994
  • The purpose of this study is to clarify the influence of the reaction temperature and $AlCl_3$ content on the aluminide coating formation on Ni-based superalloy IN713C in CVD process and to compare its throwing power with that of Pack Cementation process. Aluminide coating was formed by CVD in hot-wall stainless tube reactor from an $AlCl_3-H_2$ mixture in the temperature range $850{\sim}1050^{\circ}C$. At reaction temperature $850^{\circ}C$, the coating thickness and the content of aluminium at the surface were increased as $AlCl_3$ heating temperature was raised. At reaction temperature $1050^{\circ}C$, they were not influenced by the variation of $AlCl_3$ heating temperature. When $AlCl_3$ heating temperature was fixed $125^{\circ}C$, the phases of the coatings were varied from $Ni_2Al_3$ to Al-rich NiAl and to Ni-rich NiAl with the reaction temperature. Therefore, in this study the reaction temperature has been found to be a major factor in determining the phase formed in CVD process. The throwing power of CVD was superior to that of Pack Cementation.

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A study on the Energy Efficient C-Dump Converters for Switched Reluctance Motor Drives (SRM구동을 위한 Energy Efficient C-Dump 컨버터에 관한 연구)

  • Choi J.H.;Yoon Y.H.;Song B.S.;Won C.Y.;Kim G.S.;Choi S.W.
    • Proceedings of the KIPE Conference
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    • 2001.12a
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    • pp.105-108
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    • 2001
  • This paper compared a Modified C-dump converter and energy efficient converter topologies, derived from the conventional C-dump converter, for switched reluctance motor (SRM) drives. The proposed topologies overcome the limitations of the conventional C-dump converter, and could reduce the whole cost of the SRM drive. Also, the above converters have simple control requirements; and allow the motor phase current to freewheel during chopping mode. Specially, the voltage ratings of the dump capacitor and some of the switching devices in the proposed an Energy efficient C-dump converter is reduced to the supply voltage ($V_{dc}$) level compared to twice the supply voltage ($2V_{dc}$) in the conventional C-dump converter. Simulation and experimental results of the proposed converters are presented and verified.

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Isolation of Wild Killer Yeast from Traditional Meju and Production of Killer Toxin (재래식 메주로부터 야생 Killer 효모의 분리 및 Killer Toxin의 생산)

  • Lee, Jong-Su;Lee, Seong-Hun;Kim, Jae-Ho;Yu, Jin-Yeong
    • KSBB Journal
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    • v.14 no.4
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    • pp.434-439
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    • 1999
  • A wild yeast S-13 which has excellent killer toxin activity to gas-producing yeast of traditional Doenjang and Kochujang was selected among forty seven strains of Meju yeasts and identified as Hansenular capsulata S-13 by investigation of the morphological, cultural and physiological properties. The optimal conditions for the production of killer toxin were investigated. H. capsulata s-13 showed the higest killer toxin activities when it was cultured up to the late-log phase of 36 hr in YEPD medium (pH4.5) at $25^{\circ}C$ H. capsultara S-13 showed killer toxin activities to seven strains of industrial yeasts such as S. cerevisiae, C. veratilis and P. membranaefacieus.

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A Study on the Estimation Technique of Frequency in the Power System using FIR Filter (FIR 필터를 이용한 전력계통 주파수 추정기법에 관한 연구)

  • Nam, S.B.;Lee, H.G.;Park, C.W.;Shin, M.C.
    • Proceedings of the KIEE Conference
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    • 2001.07e
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    • pp.80-85
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    • 2001
  • Frequency is an important operating parameter of a power system. Frequency of a power system remains constant if sum of all the loads plus losses equals total generation in the system. However, the frequency starts to decrease if total generation is less than the sum of loads and tosses. On the other hand, the system frequency increases if total generation exceeds the sum of loads and losses. Electric power systems sustain transient frequency swings whenever the balance between generation and load does not no longer hold. To cope with this Constraints, it requires an accurate and high speedy frequency deviation estimation technique and suitable adjustment to obtain the power system energy balance. The fundamental frequency component of 3-phase signal is first extracted by using an algorithm based on FIR(finite duration impulse response) filter, a phase angle of a voltage. The rate change of the phase angle is used for estimation and speed in its process. Also, to confirm the validity of the proposed algorithm, the simulation results obtained by using EMTP(electro magnetic transients program) are shown.

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