• Title/Summary/Keyword: C rate

Search Result 19,598, Processing Time 0.039 seconds

Effect of Temperature on Removal of Ammonia in the Ceramic Biofilter Inoculated with Earthworm Casts (지렁이 분변토를 접종한 세라믹 바이오필터의 암모니아 제거에 미치는 온도의 영향)

  • Cho, Kyung-Suk
    • Journal of Environmental Impact Assessment
    • /
    • v.9 no.1
    • /
    • pp.39-46
    • /
    • 2000
  • Removal of ammonia using the porous ceramic biofilter inoculated with earthworm casts was characterized. By assuming a plug air flow in the biofilter and applying the Michaelis-Menten equation, the maximum removal rate of $NH_3$ was $280.7g-N{\cdot}m^{-3}{\cdot}h^{-1}$($18.0g-N{\cdot}kg^{-1}{\cdot}d^{-1}$) at $30^{\circ}C$. $NH_3$ removal rate was increased as temperature increases from $15^{\circ}C$ to $35^{\circ}C$. The maximum removal rate was $285.8g-N{\cdot}m^{-3}{\cdot}h^{-1}$($18.8g-N{\cdot}kg^{-1}{\cdot}d^{-1}$) at $35^{\circ}C$. At $15^{\circ}C$, the $NH_3$ removal rate was $122.8g-N{\cdot}m^{-3}{\cdot}h^{-1}$($8.1g-N{\cdot}kg^{-1}{\cdot}d^{-1}$). When 210 ppm $NH_3$ was supplied to the biofilter at space velocity of $220h^{-1}$, the removal efficiency of $NH_3$ at 15, 25, 30 and $35^{\circ}C$ was 80, 90, 95, and 96%, respectively. The removal rate of the ceramic biofilter was 3 to 15 times higher than other biofilters comparing the removal efficiency of $NH_3$ per unit volume of carrier. This result indicates that earthworm casts and porous ceramics are very good inoculum source and carrier, respectively, for the $NH_3$-degrading biofilter.

  • PDF

The Solvolysis of Benzoyl Chloride in Water-Acetone Mixtures Under High Pressure

  • Jee, Jong-Gi;Ree, Taik-Yue
    • Bulletin of the Korean Chemical Society
    • /
    • v.8 no.1
    • /
    • pp.31-39
    • /
    • 1987
  • By using a complete rate constant($k_e$) which treats a solvent (water) as a reactant, and a conventional rate constant($k_c$), which ignores the solvent in describing the rate, the parameters ${\Delta}V^{\neq}_s,\;{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ were introduced. These quantities represent the volume change, the enthalpy change, and the entropy change accompanying the electrostriction which occurs when solvent molecules condense on the activated complex. The authors measured the rates of the solvolysis of benzoyl chloride in water-acetone mixtures at $15^{\circ}$ to $30^{\circ}C$ and 1 bar to 2500 bars. Applying the authors' theory to the experimental results, the parameters, ${\Delta}V^{\neq}_s,\;{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ were evaluated, and it was found that they are all negative, indicating that water dipoles condense on the activated complex. They also proposed the following equations: ${\Delta}H^{\neq}_c\;=\;{\Delta}H^{\neq}_e\;+\;{\Delta}H^{\neq}_s\;and\; {\Delta}S^{\neq}_c\;=\;{\Delta}S^{\neq}_e\;+{\Delta}S^{\neq}_s\;,\;where\;{\Delta}H^{\neq}_c\;and\;{\Delta}H^{\neq}_c\;and\;{\Delta}S^{\neq}_s $are the activation enthalpy change and the activation entropy change for the conventional reaction rate, respectively, and ${\Delta}H^{\neq}_e$ and ${\Delta}S^{\neq}_e$ are the corresponding quantities for the complete reaction rate. The authors proposed that for the $SN_1$ type, all the quantities, ${\Delta}V^{\neq}_s,\;{\Delta}S^{\neq}_s\;,{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ are comparatively large, and for the $SN_2$ type, these quantities are smaller than for the $SN_1$ type, and occasionally the case ${\Delta}S^{\neq}_e$ < 0 occurs. Using these criteria, the authors concluded that at high temperature, high pressure and for a high water content solvent, the SN_1$ type mechanism predominates whereas in the reversed case the $SN_2$M type predominates.

Augmented QSBC(Quantum Short-Block Code)-QURC(Quantum Unity-Rate Code)(II) with Pauli X,Y,Z error detection (파울리 X,Y,Z 오류검출 기능을 갖는 증강된 QSBC(Quantum Short-Block Code)-QURC(Quantum Unity-Rate Code)(II))

  • Dong-Young Park;Sang-Min Suh;Baek-Ki Kim
    • The Journal of the Korea institute of electronic communication sciences
    • /
    • v.18 no.3
    • /
    • pp.495-508
    • /
    • 2023
  • This paper proposes a method to find out the type and location information of Pauli X, Y, Z errors generated in quantum channels using only the quantum information processing part of the multiple-rate quantum turbo short-block code without external help from the classical information processing part. In order to obtain the location information of the Pauli X,Y error, n-auxiliary qubits and n-CNOT gates were inserted into the C[n,k,2] QSBC-QURC encoder. As a result, the maximum coding rate is limited to about 1/2 as the trade-off characteristics. The location information of the Pauli Z error for C[n,k,2] QSBC-QURC was obtained through the Clifford-based stabilizer measurement. The proposed method inherits all other characteristics of C[n,k,2] QSBC-QURC except for the coding rate.

Transition State Characterization of the Low- to Physiological-Temperature Nondenaturational Conformational Change in Bovine Adenosine Deaminase by Slow Scan Rate Differential Scanning Calorimetry

  • Bodnar, Melissa A.;Britt, B. Mark
    • BMB Reports
    • /
    • v.39 no.2
    • /
    • pp.167-170
    • /
    • 2006
  • Bovine adenosine deaminase undergoes a nondenaturational conformational change at $29^{\circ}C$ upon heating which is characterized by a large increase in heat capacity. We have determined the transition state thermodynamics of the conformational change using a novel application of differential scanning calorimetry (DSC) which employs very slow scan rates. DSC scans at the conventional, and arbitrary, scan rate of $1^{\circ}C/min$ show no evidence of the transition. Scan rates from 0.030 to $0.20^{\circ}C/min$ reveal the transition indicating it is under kinetic control. The transition temperature $T_t$ and the transition temperature interval ${\Delta}T$ increase with scan rate. A first order rate constant $k_1$ is calculated at each $T_t$ from $k_1\;=\;r_{scan}/{\Delta}T$, where $r_{scan}$ is the scan rate, and an Arrhenius plot is constructed. Standard transition state analysis reveals an activation free energy ${\Delta}G^{\neq}$ of 88.1 kJ/mole and suggests that the conformational change has an unfolding quality that appears to be on the direct path to the physiological-temperature conformer.

Seasonal Variations in the Basal Metabolic Rate of Korean Airmen Volunteers (한국인 기초 신진대사량의 계절에 따른 변동)

  • Lee, Kae-Yol;Chee, Sun-Ho;Hong, Seung-Kil;Sung, Yang-Ho
    • The Korean Journal of Physiology
    • /
    • v.6 no.2
    • /
    • pp.23-30
    • /
    • 1972
  • Contrary to most of European and American investigators failed to find out the seasonal variations of basal metabolic rate in man, Japanese and Korean investigators reported the increase in winter, decrease in summer season. But the causes of variation were not found clearly. To find out whether metabolic acclimatization to climate could be arise or not in human being, the basal metabolic rate was determined monthly for a period of one year in Airmen volunteers who live in Seoul, with 9 l Collins spirometer. The results obtained were as follows: 1. The average ambient temperature was lowest in February $(-5.88^{\circ}C)$ and highest in July $(27.34^{\circ}C)$. 2. Basal metabolic rate was lowest in June and highest in December showing seasonal variations. Interestingly, the increase of basal metabolic rate followed after the drop of ambient temperature below $0^{\circ}C$ (December) and the decrease followed after the elevation of ambient temperature from optimum to hot (June) or cold to warm (March). 3, Mean skinfold thickness increased in spring, decreased in winter. 4. These findings indicate that the basal metabolic rate of Korean reveals the seasonal variation affected by ambient temperature highly.

  • PDF

Composting Characteristics of a Continuous Aerated Pilot-scale Reactor Vessel for Commercial Composting (상업용 퇴비화를 위한 연속 통기식 파이로트 규모 반응조의 퇴비화 특성)

  • 홍지형;최병민
    • Journal of Animal Environmental Science
    • /
    • v.4 no.2
    • /
    • pp.149-160
    • /
    • 1998
  • Hog manure slurry amended with sawdust was composted in pilot-scale reactor vessels using continuous aeration nuder different C/N ratios and pH conditions during composting high rate (decomposition) process. For each material two replicated piles were built and monitored over a period of three weeks. The compost piles had an initial volume of 0.18 ㎥. In this study we evaluated the temperature in compost O2 and CO2 evolution, aeration rate, NH3 concentration etc. and investigated the stability of compost during composting high rate process. According to measured results, while the maximum NH3 concentration during composting high rate process. According to measured results, while the maximum NH3 concentration during composting high rate was in the range of 213 to 412 ppm on 5th day which was near the optimum C/N(22∼24) and pH(7.5∼7.9). And then, the NH3 concentration reduced to between 22∼26 ppm by 13th day. The maximum NH3 concentration for the lower C/N(18∼19) and pH value of 6 reached 574∼1,063 ppm by the 16th through 11th days and the NH3 concentration during continuous aerated composting high rate process, it was more important to manage NH3 gas so that compost odor is reduced.

  • PDF

A Characteristic of Nitrogen and Phosphorus Removal in Anoxic/Oxic Basins combined with Iron Electrolysis (철 전기분해장치와 무산소/호기공정을 결합한 질소, 인제거 특성에 관한 연구)

  • Kim, Young-Gyu
    • Journal of Environmental Health Sciences
    • /
    • v.43 no.6
    • /
    • pp.525-531
    • /
    • 2017
  • Objectives: The purpose of this experiment is to better understand the nitrogen and phosphorus removal ratio according to operating conditions in an iron electrolysis system consisting of an anoxic basin, aerobic basin, and iron precipitation apparatus. Methods: Iron electrolysis consists of an iron precipitation reactor composed of iron plates in oxic and anoxic basins. We studied the interrelation coefficient between T-N and T-P removal rates and F/M ratio, and the C/N ratio and BOD removal rate. Results: The F/M ratio and the T-N and T-P removal rate per unit area have interrelation coefficients of 0.362 and 0.603, respectively. The removal rate per MLVSS and the T-N and T-P removal rate per unit area have respective interrelation coefficients of 0.49 and 0.59. Conclusions: The removal rate of T-N and T-P increased with the increasing F/M ratio in the influent, and they also linearly increased in proportion to the C/N ratio of influent and BOD removal rate of the reactor.

Cutting Chip Forms on the Cutting Condition and Tempering Temperatures of Lead-free Brass (무연황동의 절삭 칩 형태에 미치는 절삭조건과 템퍼링 온도의 영향)

  • Joo, Y.S.;Lee, S.B.;Kim, S.Y.;Joo, C.S.;Jung, B.H
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.25 no.1
    • /
    • pp.14-21
    • /
    • 2012
  • The effects of cutting condition and tempering temperature for the shape of cutting chip were investigated. For this purpose, a lead-free brass containing 1wt.% of Bi extruded at $750^{\circ}C$ in straight turning was used in this study. The cutting chip preferred was mainly found to be loose form of arc chips with curling discontinuity, and these were formed by shear fracture. However, some of fragmental element chip were found to be mixed when tempering temperature was as high as $500^{\circ}C$. The form and size of chip was more affected by feed rate than by tempering temperature and cutting rate. In addition, the cutting surface was observed to be formed more rough in the case of high feed rate and low cutting rate compared to low feed rate and high cutting rate.

Effects of temperature on the biomass yield and the chemical composition of pseudomonas cells in continuous culture (Pseudomonas sp.의 연속배양에 있어서의 세포의 수율 및 화학적 조성에 미치는 영향)

  • 김창진;이영록
    • Korean Journal of Microbiology
    • /
    • v.21 no.3
    • /
    • pp.163-169
    • /
    • 1983
  • Effects of temperature on the gorwth characteristics and the chemical composition of pseudomonas cells grown under glucose-or methanol-utilizing continuous culture were studied. In a glucose-utilizing continuous culture, optimum dilution rate, agitation, pH, and temperature, for the higher biomass yield were $0.45hr^-$, 7000rpm, pH 7.5, and $30^{\circ}C$, respectively. But in a methanol-utilizing continuous culture, they were $0.125hr^-$, 600rpm, pH 8, and $30^{\circ}C$, respectively. In methanol-utilizing continuous culture, the maximum production rate of the cells was 1.48g, dry wt./1/hr at a dilution rate of $0.45hr^-$, and the cell yield was 0.46g. dry wt./g. glucose. In the methanol-utilizaing continuous culture, the maximum production rate of the cells was 0.33 7g. dry wt./1/hr. at a dilution rate of $0.125hr^-$ and the cell yield was 0.44g dry cell/g. methanol. The contents of protein of the cells increase with the increase ingrowing temperature (from 15 to $30^{\circ}C$), more or less, while the contents of RNA nad carbohydrate of the cells decreased. However, DNA contents of cells growth under the various temperature ranges didn't change. As the temeprature of cultivation rises at a constant dilution rate, the efficiency of RNA in protein synthesis was increased, showing the decreases in the ratio of RNA to protein.

  • PDF

Dynamic Constitutive Equations of Auto-Body Steel Sheets with the Variation of Temperature (I) - Dynamic Material Characteristics with the Variation of Temperature - (차체용 강판의 온도에 따른 동적 구성방정식에 관한 연구 (I) - 온도에 따른 동적 물성 특성 -)

  • Lee, Hee-Jong;Song, Jung-Han;Park, Sung-Ho;Huh, Hoon
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.31 no.2 s.257
    • /
    • pp.174-181
    • /
    • 2007
  • This paper is concerned with the thermo-mechanical behavior of steel sheet for an auto-body including temperature dependent strain rate sensitivity. In order to identify the temperature-dependent strain rate sensitivity of SPRC35R, SPRC45E and TRIP60, uniaxial tensile tests are performed with the variation of the strain rates from 0.001/sec to 200/sec and the variation of environmental temperatures from $-40^{\circ}C$ to $200^{\circ}C$. The thermo-mechanical response at the quasi-static state is obtained from the static tensile test and that at the intermediate strain rate is obtained from the high speed tensile test. Experimental results show that the variation of the flow stress and fracture elongation becomes sensitive to the temperature as the strain rate increases. It is observed that the dynamic strain aging occurs with TRIP60 at the temperature above $150^{\circ}C$. Results also indicate that the flow stress and tincture elongation of SPRC35R are more dependent on the changes of strain rates and temperature than those of SPRC45E and TRIP60.