• Title/Summary/Keyword: C:N ratio

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Simultaneous Catalytic Reduction of NO and N2O over Pd-Rh Supported Mixed Metal Oxide Honeycomb Catalysts - Use of H2 or CO as a Reductant (혼합금속산화물에 담지된 Pd-Rh의 허니컴 촉매에서 NO와 N2O의 동시 환원 - H2 또는 CO 환원제의 사용)

  • Lee, Seung Jae;Moon, Seung Hyun
    • Korean Chemical Engineering Research
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    • v.47 no.1
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    • pp.96-104
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    • 2009
  • In order to lower a reaction temperature with high conversions for simultaneous catalytic reduction of NO and $N_2O$ over Pd-Rh supported mixed metal oxide honeycomb catalysts, $H_2$ or CO was utilized as a reductant. When using the reductants, the effects of reaction conditions were examined in NO and $N_2O$ conversions, where reaction temperatures, concentrations of the reductants and oxygen and the concentration ratio of $N_2O$ to NO were varied. In using $H_2$ reductant, larger than 50% of NO and $N_2O$ conversions was observed at the temperatures below $200^{\circ}C$ in absence of $O_2$. In using CO reductant, NO and $N_2O$ conversions increased from the temperatures higher than $200^{\circ}C$ and $300^{\circ}C$, respectively. However, in use of both reductants, NO and $N_2O$ conversions decreased with increasing oxygen concentration. As a result, $H_2$ reductant could reduce simultaneously NO and $N_2O$ at relatively lower reaction temperature than CO. Also, NO and $N_2O$ conversions were less influenced by using $H_2$ reductant than CO one. Concentration ratio between NO and $N_2O$ did not affect their conversions regardless the type of reductants. Pretreatment of the catalyst in $H_2$ was more effective in simultaneous reduction of NO and $N_2O$ at low reaction temperature than that in $O_2$.

Effects of Dietary Fatty Acid and Protein Sources on Serum Protein Profiles and Liver Functional Enzyme Activities in Rats with DMBA-Induced Mammary Tumors

  • Lee, Eun-Kyung;Kim, Hyun-Sook;Lee, Sang-Sun
    • Nutritional Sciences
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    • v.5 no.2
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    • pp.53-59
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    • 2002
  • This study was conducted to examine the effects of dietary sources of fatty acids and protein on serum protein profiles, hepatic functional enzyme activities, mammary tumor incidence and tumor weight in 7, 12-dimethylbenz($\alpha$)anthracene (DMBA)-treated rats. The sources of dietary fatty acids were 18n6 (rich in linoleic acid), 18n3 (rich in linolenic acid) and 22n3 (rich in DHA) : sources of dietary protein were casein (C) and soy protein isolate (S). mammary tumors (MTs) were chemically induced by DMBA (9 mg/100 g body weight) which was gastrically intubated at 7 weeks of age. Each experimental diet was given for the following 25 weeks. Casein-fed rats (group C) exhibited significantly higher levels of weight gain and FER (food efficiency ratio) than did group S. Group C showed higher levels of serum protein and globulin, and higher albumin/globulin (A/G) ratios than group S. Liver functional enzyme activities (GOT, GPT, ALP, LDH, $\gamma$-GT) and LDH/GOT ratios were not influenced by dietary protein. GPT activity was lower in the group given 18n3, and ALP activity was lower in the group given 18n6. The incidence and total number of MTs appeared to be lower in the group given 22n3 than in the group given 18n3 or 18n6, even though the average weight of MTs was highest in the group given 22n3, The average weight of MTs was higher in the C group than in the S group. MT incidence had a positive correlation with LDH activity and LDH/GOT ratio. The average weight of MTs had a negative correlation with serum albumin levels and A/G ratios, and a positive correlation with ALP activity. This research suggests that the measurement of serum protein profiles and liver functional enzyme activities may be utilized to monitor the development of mammary tumors.

Advanced wastewater treatment capacity and growth of Chlorella vulgaris by nitrogen and phosphorus concentrations (N, P 농도에 따른 Chlorella vulgaris의 성장 및 하수고도처리능 평가)

  • Han, Su-Hyun;Lee, Yunhee;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.1
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    • pp.77-82
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    • 2013
  • The growth and removal capacity of nitrogen and phosphorus of Chlorella vulgaris were evaluated in artificial wastewater with different nitrogen and phosphorus concentrations as element growing components for microalgae growth. The nitrogen concentration was varied in 9, 15, 30 and 60 mg-N/L with fixed phosphorus concentration of 3 mg-P/L. The growth and phosphorus removal capacity of C. vulgaris were high at initial nitrogen concentration of 15 and 30 mg-N/L, and the corresponding N/P ratios calculated were 5 and 10. In the case of varying in 1.5, 3, 6 and 10 mg-P/L of phosphorus concentration with fixed nitrogen concentration of 30 mg-N/L, the growth and removal capacity of nitrogen and phosphorus were excellent with phosphorus concentration of 3 and 6 mg-P/L. The corresponding N/P ratios were shown as 10 and 5. Therefore, the appropriate N/P ratio was concluded between 5 and 10 for wastewater treatment using C. vulgaris.

The initial mass loss rates and the changes in carbon/nitrogen ratio of dead woods for the three dominant tree species in tropical rainforests of Brunei Darussalam (브루나이 열대우림 내 주요 3개 수종 고사목의 초기 질량 감소율과 탄질율 변화)

  • Roh, Yujin;Jang, Minju;Son, Yowhan
    • Korean Journal of Environmental Biology
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    • v.39 no.2
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    • pp.218-224
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    • 2021
  • This study was conducted to determine the mass-loss rates and the changes in carbon/nitrogen (C/N) ratio of dead woods, which were of following species: Dryobalanops aromatic, D. rappa, and Cratoxylum arborescens. These were dominant tree species in mixed Dipterocarp forests (MDF) and peat swamp forests (PSF) in Brunei Darussalam. In May, 2019, 48 dead wood samples (15 cm×4.8 cm×5 cm) were placed in MDF and PSF sites, and all the samples were collected after 16 months. The effects of species on mass loss were statistically significant (p<0.05); however, no difference was observed in the mass loss obtained from the two forest types (p>0.05). The initial density (g·cm-3) of the dead woods D. aromatic, D. rappa, and C. arborescens, was 0.64±0.02, 0.60±0.00, and 0.44±0.01, respectively. Also the annual mass loss rate (%) was estimated to be 6.37, 8.17, and 18.53 for D. aromatic, D. rappa, and C. arborescens, respectively. The proportion of dead woods in decay class III was only 25% of C. arborescens samples, which were attacked by wood-feeding invertebrates, such as termites. The C/N ratio decreased significantly in D. aromatic and D. rappa, but the decreasing trend of C/N ratio was not statistically significant in C. arborescens. The results indicate that physical traits of dead woods, such as density, could be one of the main factors causing the decomposition of dead woods initially, as invertebrates such as termites are one of the key decomposers of dead wood in tropical rainforests. In the samples of C. arborescens, which was attacked by invertebrates, nitrogen immobilization occurred to lesser extent as compared to that observed in D. aromatic and D. rappa.

Preparation of Alginate/Poly(N-isopropylacrylamide) Hydrogels Using Gamma-ray Irradiation Grafting

  • Lee, Young-Moo;Lee, Sang-Bong;Seo, Sung-Mi;Lim, Youn-Mook;Cho, Seong-Kwan;Nho, Young-Chang
    • Macromolecular Research
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    • v.12 no.3
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    • pp.269-275
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    • 2004
  • To graft N-isopropylacrylamide (NIPAAm) onto alginate, varying dosages of ${\gamma}$-rays were irradiated onto alginate films in deionized water and methanol media, which are non-solvents of alginate. We investigated the hydrogels graft ratio, mechanical strength, swelling kinetics and ratio, and behavior with respect to drug release. The graft yield of NIPAAm increased upon increasing the irradiation dose. The use of the aqueous solution increased the graft yield relative to that obtained in methanol. The mechanical strength of the grafted hydrogels increased after grafting with NIPAAm. In a study of the swelling kinetics, we found that all hydrogels reached an equilibrium swollen state within 3 h. The equilibrium swelling ratio of the hydrogels decreased upon increasing the irradiation dose. The swelling ratio of the hydrogels decreased dramatically between 30 and 35$^{\circ}C$ because phase separation of NIPAAm occurred at 32$^{\circ}C$. The swelling process, with respect to the temperature change, was repeatable. An NIPAAm-grafted alginate containing a drug sustained its release rate until 3 h after an initial high drug release caused by a burst effect.

Characterization of Quorum-Sensing Signaling Molecules Produced by Burkholderia cepacia G4

  • Park, Jun-Ho;Hwang, In-Gyu;Kim, Jin-Wan;Lee, Soo-O;Conway, B.;Peter Greenberg, E.;Lee, Kyoung
    • Journal of Microbiology and Biotechnology
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    • v.11 no.5
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    • pp.804-811
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    • 2001
  • In many Gram-negative bacteria, autoinducers, such as N-acyl-L-homoserine lactone(acyl-HSL) and its derivative molecules, mediate the cell-density-dependnet expression of certain operons. The current study identified the autoinducers produced by Burkholderia cepacia G4, a trichloroethylene-degrading lagoon isolate, using TLC bioassays with Agrobacterium tumefaciens NT1(pDCI141E33) and Chromobacterium violaceum CVO26, and a GC-MS analysis. The ${R_f}\;and\;{R_t}$ values and mass spectra were compared with those of synthetic compounds. Based on the analyses, it was confirmed that G4 produces N-hexanoyl (C6)-, N-octanoyl (C8)-, N-decanoyl (C10)-, N-dodecanoyl (C12)-HSL, and an unknown active species. The integration of the GC peak areas exhibited a ratio of C8-HSL:C10-HSL:C12-HSL at 3:17:1 with C6-HSL and C10-HSL production at trace and micromolar levels, respectively, in the culture supernatants. Nutants partially defective in producing acyl-HSLs were also partially defective in the biosynthesis of an antibiotic substance. These results indicate that the autoinducer-dependent gene regulation in G4 is dissimilar to the clinical B. cepacia strains isolated from patients with cystic fibrosis.

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Evaluation of Oxic Denitrification in A2O Fixed Biofilm System through Mass Balance (물질수지를 이용한 A2O 고정생물막법에서의 호기탈질평가)

  • Yoon, Cho-Hee;Park, Seung-Hwan;Lee, Sang-Hoon;Kim, Seung-Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.2
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    • pp.231-239
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    • 2000
  • This study was investigated to estimate optimal conditions and biological oxic denitrification to treat wastewater with low C/N ratio and high strength total inorganic nitrogen (TIN) concentration by using $A_2O$ fixed biofilm system. The lab-scale experimental system packed with media, which were composed of polyvinylidene chloride fiber (oxic basin) and ceramic ball (anaerobic and anoxic basin), was used. This system was operated with various influent alkalinities at the C/N(TOC/TIN) ratio of 0.5. The study results showed that TOC were removed over 96.0% at all operation conditions. The removal efficiencies over 93.5% for $NH_4{^+}-N$ and 81.8% for TIN were obtained at the alkalinity of about 1210mg/L(Run 5). Among the removal of TIN, 64.9% was occurred by biological denitrification at an oxic basin. It was confirmed through mass balance of alkalinity and nitrogen that the amount of alkalinity produced during biological denitrification at oxic basin was 2.49~3.46 mg Alkalinity/mg $NO_2{^-}-N$, ${\Delta}TOC/{\Delta}DEN$ of 0.34 (Run 5) was obtained at an oxic basin, which was less than the theoretical value of 1.22.

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Study on the fatty acid profile of phospholipid and neutral lipid in Hanwoo beef and their relationship to genetic variation

  • Beak, Seok-Hyeon;Lee, Yoonseok;Lee, Eun Bi;Kim, Kyoung Hoon;Kim, Jong Geun;Bok, Jin Duck;Kang, Sang-Kee
    • Journal of Animal Science and Technology
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    • v.61 no.2
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    • pp.69-76
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    • 2019
  • Maize which has very high omega-6 fatty acid content has been used as a main feed grain for Hanwoo beef production to increase marbling, and thus omega-6 to omega-3 fatty acids ratio in Hanwoo beef is expected to be biased. To elucidate the current status of omega fatty acids ratio in Hanwoo beef, fatty acid profiles of neutral lipid and phospholipid fraction were analyzed separately using 55 Hanwoo steers' longissimus dorsi muscle slaughtered at Pyeongchang, Korea from Oct. to Nov. 2015. In addition, an association study was conducted to evaluate associations between single nucleotide polymorphism (SNP) markers from references and omega fatty acid profiles in phospholipid of Hanwoo beef samples using analysis of variance (ANOVA). In neutral lipid fraction, composition of saturated and monounsaturated fatty acids was higher and polyunsaturated fatty acids was lower compared to those in phospholipid fraction. The mean n-6/n-3 ratios of Hanwoo were $56.059{\pm}16.180$ and $26.811{\pm}6.668$ in phospholipid and neutral lipid, respectively. There were three SNPs showing statistically significant associations with omega fatty acid content. GA type of rs41919985 in fatty acid synthase (FASN) was significantly associated with the highest amount of C20:5 n-3 (p = 0.031). CC type of rs41729173 in fatty acid-binding protein 4 (FABP4) was significantly associated with the lowest amount of C22:2n-6 (p = 0.047). AG type of rs42187261 in FADS1 was significantly linked to the lowest concentration of C20:4 n-6 (p = 0.044). The total n-6/n-3 ratio of the steer which has all four SNP types in above loci (27.905) was much lower than the mean value of the total n-6/n-3 ratio in phospholipid of the 55 Hanwoo steers ($56.059{\pm}16.180$). It was found that phospholipid and neutral lipid of Hanwoo have very high n-6/n-3 ratios compared to the reported data from different cow breeds. Four SNPs in genes related with fatty acid metabolism showed significant associations with the fatty acid profile of phospholipid and may have potential as SNP markers to select Hanwoo steers in terms of n-6/n-3 balance in the future.

Physico-chemical Characteristics and Utilization of Raw Materials for Mushroom Substrates (버섯 병재배 배지재료의 이화학성과 활용)

  • Cheong, Jong-Chun;Jhune, Chang-Sung;Lee, Chan-Jung;Oh, Jin-A
    • The Korean Journal of Mycology
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    • v.38 no.2
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    • pp.136-141
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    • 2010
  • To provide a basic information on the chemical concentrations of different raw materials used in mushroom cultivation, the raw materials were collected from 13 Flammulina velutipes, 14 Pleurotus eryngii, and 8 P. ostreatus farms and analyzed to calculate moisture contents, pH, total carbon(T-C), total nitrate(T-N), total phosphate(T-P) and 13 different cations. In our results, the C : N ratios of cotton seed meal, beet pulp, and corn-cob were 6~17, 12~29 and 56~127, respectively. Depending on the companies which process these materials, the range of C:N ratio of soybean curd residue was approximately either 8~9 or 14~17 with wider range of C : N ratio of the raw materials imported from other countries without the detection of heavy metals. In this study, the formula was provided to calculate the composition of mixed media for mushroom cultivation based on the ingredient chart of different raw materials.

A Study on Calculation of Protection Ratio for Interference Analysis in Fixed Radio Relay Networks (고정 무선중계 망의 간섭 분석을 위한 보호비 계산에 대한 연구)

  • Suh Kyoung-Whoan;Lee Joohwan
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.43 no.1 s.343
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    • pp.133-142
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    • 2006
  • This paper suggests an efficient method of protection ratio(PR) calculation and shows some results of point-to-point radio relay system for frequency coordination. The proposed PR can be expressed as a function of C/N of modulation scheme, noise-to-interference ratio(N/I), multiple interference allowance, fade margins of multi-Path and rain attenuation and net filter discrimination. And PR calculation is performed in view of fade margin, modulation scheme, distance, and interference for actual point-to-point radio relay frequency. According to results for 6.2 GHz, 64-QAM and 60 km at BER 10-6, fade margin and co-channel Protection ratio reveal 41.1dB and 74.9 dB, respectively The merit of presented method provides a systematic and easy calculation by means of PR correction factor related with various parameters and can apply the same concept to frequency coordination of millimeter wave radio relay system.