• Title/Summary/Keyword: C:N ratio

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Synthesis of $\beta$-Sialon from Wando Pyrophyllite (2) (완도 납석으로부터 $\beta$-Sialon의 합성 (2))

  • 이홍림;장병국;이형복
    • Journal of the Korean Ceramic Society
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    • v.22 no.5
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    • pp.35-42
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    • 1985
  • $eta$-Sialon powders were prepared by reduction-nitridation from mixture of Wando pyrophyllite and graphite as a reducing agent at 135$0^{\circ}C$ in 80% $N_2$-20% $H_2$ atmosphere. As the reaction products $Si_2ON_2$, $\beta$-$Si_3N_4$ a--$Si_3N_4$ and $\beta$-SiC were observed. Additive agents of MgO, CaO, $Y_2O_3$ were used for promoting the reduction and nitridiation aeaction. The present study was conducted to investigate the effects of silica-carbon ratio ($SiO_2$/C=weight ratio), raction time gas flow rate pellet size and powder packing on synthesis of $\beta$-Sialon from Wando pyropyllite.

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Effect of DHEA Administration on PUFA/SFA Ratio and Lipid Peroxide in Rat Liver Microsome (DHEA 투여로 인한 쥐 간 소포체분획에서의 PUFA/SFA 비율과 지질과산화의 감소 효과)

  • Kwak Chune Shil;Kim Mee Yeon
    • Journal of Nutrition and Health
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    • v.38 no.4
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    • pp.297-306
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    • 2005
  • It is known that dehydroepiandrosterone (DHEA) shows a dual effect, prooxidant or antioxidant, depending on the do-sage or physiological status of animals. The purpose of this study was to determine the effects of DHEA administration at low dose on lipid peroxidation, protein carbonylation and fatty acid composition in liver. Sprague Dawley male rats were fed either com oil diet containing $15\%$ com oil or fish oil diet containing $2\%$ corn oil + $13\%$ sardine oil, with or without $0.2\%$ DHEA for 9 weeks. Atherogenic index and hepatic triglyceride and cholesterol levels were significantly reduced by DHEA administration in rats fed with fish oil diet. Hepatic lipid peroxide product (TBARS) and protein carbonyl levels were significantly higher in rats fed with fish oil diet than in rats fed with corn oil diet. However, DHEA administration significantly reduced the hepatic thiobarbituric acid-reactive substance (TBARS) and conjugated diene levels in rats fed with fish oil diet. Contents of C16 : 0, C16 : 1, C20 : 5 and C22 : 6 in hepatic microsome were higher in rats fed with fish oil diet than in rats fed with corn oil diet, and contents of C18 : 2 and C20 : 4 were lower than in rats fed with com oil diet. DHEA administration significantly increased C16 : 0 and C18 : 3 contents and reduced C18 : 2 content in rats fed with com oil diet, while it increased C16 : 0 and C18 : 1 and reduced C20 : 5 and C22 : 6 in rats fed with fish oil diet. On overall, DHEA administration increased saturated fatty acid (SFA) and reduced polyunsaturated fatty acid (PUFA) in hepatic microsome, thereby PUFA/SFA ratio was significantly (p < 0.0001) reduced without the change of n-3/n-6 ratio. Taken together, low dose of DHEA administration lowered PUFA/SFA ratio in hepatic microsomal membranes and also showed antioxidative effect especially in fish oil-induced highly oxidative stress condition through blocking increases of C20 : 5 and C22 : 6 contents.

Optimization of culture condition for the gellan production by Pseudomonas elodea ATCC 31461 (Pseudomonas elodea ATCC 31461에 의한 gellan 생산의 최적 배양조건)

  • Lim, Sung-Mi;Wu, Jian-Rong;Lee, Jin-Woo;Kim, Sung-Koo
    • Journal of Life Science
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    • v.13 no.5
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    • pp.705-711
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    • 2003
  • The gellan was produced by Pseudomonas elodea under aerobic condition. In this study, the effects of inoculum size, carbon sources and concentration, nitrogen source, and C/N ratio on the cell growth and the production of gellan were evaluated. The maximum growth of P. elodea and gellan production was obtained at 5% (v/v) of inoculum size and glucose showed best results among 9 carbon sources tested. The maximum specific yield of 2.22 and productivity of $0.03 g/\ell$h were obtained at 1.0% (w/v) of glucose. The maximum gellan production was obtained at medium without ammonium nitrate. This indicates that nitrogen limitation is essential for the production of gellan. The highest cell and gellan production were obtained at 20 of C/N ratio.

Screen of Green Manure Crops for Cultivation on Agricultural Land with Spring Season in the Central Regions of Korea

  • Cho, Hyeon-Suk;Seo, Myung-Chul;Kim, Jun-Hwan;Sang, Wan-gyu;Shin, Pyeong;Lee, Geon Hwi
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.6
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    • pp.689-696
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    • 2015
  • The green manure crops are returned to soil when the plants are still green. The green manure crops play a role in reducing chemical fertilizers, improvement of soil fertility, reduction of soil erosion, weed control, and landscapes effect. Typical green manure crops are barley green manure, hairy vetch, chines milk vetch and clovers. We sowed 49 species of green manure crops in upland soil to increase the usage of green manure crops. We searched the effectiveness of green manure yield, C/N ratio, soil mulching, and landscape effect. The green manure crops that have $5tonha^{-1}$ or more of green manure yield (fresh weight) were 6 gramineous crops, 4 leguminous crops, and 3 others. Green manures yield in a short growth period was higher in gramineous crops than leguminous crops. Among the green manure crops, 3 gramineous crops, 12 leguminous crops, and 3 others were under 25 in C/N ratio. Seven gramineous crops, 8 leguminous crops, and 5 others were over 50% of soil covering rate. Green manure crops that have beautiful flowers were in total 16 kinds, such as 4 gramineous crops, 6 leguminous crops, and 6 others. In result, based on green manure yield and C/N ratio, excellent species in the green manure crops were 4 species (triticale, 2 kinds of hairy vetch, and lupin). Green manure crops that were effective at soil mulching were 20 species, like hairy vetch, oats, sorghum, phacelia, buckwheat, etc. Buckwheat, crotalaria, mustard plant, phacelia, and etc. could be available for landscape crops.

Effects of Operational Condition on N2O Production from Biological Nitrogen Removal Process (생물학적 질소제거시 운전조건의 변화가 N2O 발생에 미치는 영향)

  • Jang, Hyun-Sup;Kim, Tae-Hyeong;Lee, Myoung-Joo;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.5
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    • pp.547-555
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    • 2009
  • The objectives of this research were focused on the effects of various operating parameters on nitrous oxide emission such as C/N ratio, ammonia concentration and HRT in the hybrid and suspension reactors. With the decreasing of C/N ratios, $N_2O$ emission rates in the both processes were increased because organic carbon source for denitrification was depleted. In case of biofilm reactor operated using medium, $N_2O$ release from the nitrification was not affected by the variation of ammonia concentration. But in the suspension reactor, $N_2O$ production from the nitrification was rapidly increased with the increase of ammonia. Nitrite accumulation caused by undesirable nitrification conditions could be a important reason for the increase in the $N_2O$ production from the aerobic reactor. And rapid increase in $N_2O$ production was reflected by the decrease of HRT, similar to the results observed in the results of ammonia loading changes. So it could be said that it is very important to put in consideration both its optimum conditions for wastewater treatment efficiency and suitable conditions for $N_2O$ diminish, simultaneously, in order to development an eco-friendly and advanced wastewater treatment, especially in BNR process.

Fatigue Crack Growth Equation considered the Effect of Stress Ratio (응력비의 영향을 고려한 표면피로균열의 균열성장식)

  • 강용구;김대석
    • Journal of Ocean Engineering and Technology
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    • v.12 no.1
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    • pp.39-49
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    • 1998
  • In this work, fatigue tests by axial loading were carried out to investigate the effect of stress ratio on the growth behaviors of surface fatigue crack for SM45C steel and Al 2024-T4 alloy. The growth behaviors of surface crack have been monitored during fatigue process by measuring system attached CCTV and monitor. When the growth rates of surface crack were investigate by the concept of LEFM based on Newman-Raju's .DELTA.K, the dependence of stress ratio appears both SM45C steel and Al 2024-T4 alloy. Therefore, modified stress intensity factor range, .DELTA.K' [=(1+R)/sup n/.DELTA.K] are intorduced to eliminate the dependence of stress ratio. Using .DELTA.K', it is found that the dependence of stress ratio disappears both SM45C steel and Al 2024-T4 alloy.

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Experimental Study on the Cold Storage of Spherical Capsules in the Cylindrical Tank (원통형 축냉조내 구형캡슐들의 축냉에 관한 실험 연구)

  • ;;Jung, Gab Yong
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.10
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    • pp.2647-2656
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    • 1995
  • The present work was performed to axially and radially investigate the local cold storage performance in the cylindrical tank with the spherical capsules inserted n-Tetradecane as a new cold storage material. The local cold storage performance of the capsules in the tank was experimentally investigated for the inlet temperature of -7, -5, -3, 0.deg. C, for the flow rate of 0.95, 1.89, 2.84, 6.00 l/min, and for the diameter ratio of 4.9, 9.0, 13.1. The local cold storage performance in the case of using water applied for the commercial ice-ball system was axially investigated by changing the flow rate only with the inlet temperature of -7.deg. C and the diameter ratio of 9.0 in order to compare with the performance in the case of using n-Tetradecane. For the case of using n-Tetradecane, the difference of cold storage period between the first and the seventh story was increased as the inlet temperature was increased and the flow rate was decreased. The capsules at the center of the tank showed the supercooling and the increased cold storage period compared with the capsules at the wall of the tank due to the small porosity and insufficient cold storage performance at the center of the tank as the diameter ratio is increased. The case using water showed worse cold storage performance due to comparatively large supercooling than the case using n-Tetradecane.

An experimental study on the characteristics of the swirl ratio distribution with an intake port geometry (흡기포트 형상에 따른 선회비 분포특성에 관한 실험적 연구)

  • Lee, Ji-Geun;Ju, Bong-Cheol;No, Byeong-Jun;Gang, Sin-Jae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.6
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    • pp.725-734
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    • 1997
  • The effect of helical intake port geometry on in-cylinder swirl flow characteristics was studied. Two helical intake ports were selected to change swirl ratio, mean flow coefficient with the variation of valve lifts, valve eccentricity ratios and axial distance. The measurements were made by using an impulse swirl meter. The port B modified to increase the swirl ratio( $R_{s}$) had the tendency of the increased non-dimensional rig swirl ( $N_{r}$) distribution in comparison with that of the port A. And the $N_{r}$ distribution was remarkably improved at low valve lifts. The modification of the geometry to increase the swirl ratio ( $R_{s}$) in helical intake port resulted in the decrease of the mean flow coefficient ( $C_{f(mean)}$) regardless of valve eccentricity ratio ( $N_{y}$). And also non-dimensional rig swirl ( $N_{r}$) in the high valve lift affected the calculation of swirl ratio considerably.onsiderably.

Biopolyrner Production of Zoogloea ramigera in Batch, Fed-Batch and Continuous Culture Processes (Zoogloea ramigera의 회분식, 유가배양, 연속배양에 의한 생물고분자 생산)

  • 안대희;정윤철
    • Microbiology and Biotechnology Letters
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    • v.20 no.2
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    • pp.196-202
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    • 1992
  • Zoogloea ramigera 115 was selected for the production of viscous microbial polysaccharide for bioflocculants usage. Batch, fed-batch, and continuous culture processes were examined with regard to the high biopolymer production. Several carbon sources were tested, including glucose, lactose, molasses, and cheese whey. The C/N ratio of 90 was most effective for biopolymer production from glucose, while the C/N ratios of 30 for lactose and 60 for both molasses and cheese whey substrate gave a maximum production. Fed batch culture proved more effective to increase final biopolymer concentration than batch culture. Continuous fermentation with two stages modifying C/N ratio increased the productivity. The production rates were a maximum at dilution rate of 0.048 $hr^{-1}$ for molasses and at 0.096 $hr^{-1}$for cheese whey.

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Formation of Ohmic Contacts on acceptor ion implanted 4H-SiC (이온 이온주입한 p-type 4H-SiC에의 오믹 접촉 형성)

  • Bahng, W.;Song, G.H.;Kim, H.W.;Seo, K.S.;Kim, S.C.;Kim, N.K.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.290-293
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    • 2003
  • Ohmic contact characteristics of Al ion implanted n-type SiC wafer were investigated. Al ions implanted with high dose to obtain the final concentration of $5{\times}10^{19}/cm^3$, then annealed at high temperature. Firstly, B ion ion implanted p-well region were formed which is needed for fabrication of SiC devices such as DIMOSFET and un diode. Secondly, Al implanted high dose region for ohmic contact were formed. After ion implantation, the samples were annealed at high temperature up to $1600^{\circ}C\;and\;1700^{\circ}C$ for 30 min in order to activate the implanted ions electrically. Both the inear TLM and circular TLM method were used for characterization. Ni/Ti metal layer was used for contact metal which is widely used in fabrication of ohmic contacts for n-type SiC. The metal layer was deposited by using RF sputtering and rapid thermal annealed at $950^{\circ}C$ for 90sec. Good ohmic contact characteristics could be obtained regardless of measuring methods. The measured specific contact resistivity for the samples annealed at $1600^{\circ}C\;and\;1700^{\circ}C$ were $1.8{\times}10^{-3}{\Omega}cm^2$, $5.6{\times}10^{-5}{\Omega}cm^2$, respectively. Using the same metal and same process of the ohmic contacts in n-type SiC, it is found possible to make a good ohmic contacts to p-type SiC. It is very helpful for fabricating a integrated SiC devices. In addition, we obtained that the ratio of the electrically activated ions to the implanted Al ions were 10% and 60% for the samples annealed at $1600^{\circ}C\;and\;1700^{\circ}C$, respectively.

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