• Title/Summary/Keyword: C:N

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Characteristics and Thermal Stabilities of W-B-C-N Diffusion Barrier by Using the Incorporation of Boron Impurities (Boron 불순물에 의한 W-B-C-N 확산방지막의 특성 및 열적 안정성 연구)

  • Kim, Soo-In;Lee, Chang-Woo
    • Journal of the Korean Magnetics Society
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    • v.18 no.1
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    • pp.32-35
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    • 2008
  • Thermally stable diffusion barrier of tungsten carbon nitride(W-C-N) and of tungsten boron carbon nitride(W-B-C-N) thin films have studied to investigate the impurity behaviors of boron and nitrogen. In this paper we newly deposited tungsten boron carbon nitride(W-B-C-N) thin film for various $W_2B$ target power on silicon substrate. The impurities of the 100nm-thick W-C-N and W-B-C-N thin films provide stuffing effect for preventing the inter-diffusion between W-C-N or W-B-C-N thin films and silicon during the high temperature($700^{\circ}C{\sim}1000^{\circ}C$) annealing process.

Hydrated Form of 4-N,N-Dimethylamino-4'-N'-Methyl-Stilbazolium Tosylate, $C_{16}H_{19}N_2(C_7H_7SO_3{\cdot}H_2O)$ (4-N,N-Dimethylamino-4'-N'- Mothy1-stilbazolium tosylate의 수화물)

  • Hong Hyung-Ki;Yoon Choon Sup;Suh Il-Hwan;Lee Jin-Ho;Choi Sung-San;Oh Mi-Ran;Marder Seth R.
    • Korean Journal of Crystallography
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    • v.8 no.1
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    • pp.1-5
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    • 1997
  • The crystal structure of the title compound consists of discrete 4-N,N-dimethylamino-4'-N'-methyl-stilbazolium, $C_{16}H_{19}N_2$, and tosylate, $C_7H_7SO_3$, dimer. The 4-N,N-dimethylamino-4'-N'-methyl-stilbazolium molecule has a trans conformation at the central C=C double bond: the dihedral angle between the phenyl and the pyridyl rings is $5.7(2)^{\circ}$ and the whole molecule is planar within $0.138(8){\AA}$. Tosylate molecules display hydrogen-bonded dimers with the O-H...O distances of 2.855(9) and $2.899(8){\AA}$, respectively. The shortest intermolecular contact is the distance $3.10(1){\AA}$ between O(3) and C(16).

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Hydrocarbon Gas Permeation Characteristics of PTMSP/LDH Composite Membranes (PTMSP/LDH 복합막의 탄화수소 기체투과 특성)

  • Jeong, Yeon-Eim;Lee, Hyun-Kyung
    • Membrane Journal
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    • v.24 no.6
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    • pp.423-430
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    • 2014
  • PTMSP/LDH composite membranes were prepared by adding 0, 1, 3, and 5 wt% LDH contents to PTMSP. The gas permeability and selectivity for $H_2$, $N_2$, $CH_4$, $C_3H_8$, $n-C_4H_{10}$ were investigated as a function of LDH content. As LDH content of PTMSP/LDH composite membranes increased to 5 wt%, the gas permeability for $H_2$ and $N_2$ gradually decreased, while $n-C_4H_{10}$ permeability rapidly increased. The gas permeability for $CH_4$ and $C_3H_8$ was found to decrease for the membranes with LDH content range of 0~3 wt%, however increase in the range of 3~5 wt%. As LDH content of PTMSP/LDH composite membranes increased to 5 wt%, the selectivity of membranes gradually increased for $H_2$, $N_2$, $CH_4$, $C_3H_8$, $n-C_4H_{10}$ over $H_2$, $N_2$. However the selectivity for $C_3H_8$ and $n-C_4H_{10}$ over $CH_4$ increased in the range of LDH content 0~3 wt% but decreased in the range of 3~5 wt%. The $CH_4$ and $n-C_4H_{10}$ selectivity over $H_2$ and $N_2$ increased as $CH_4$ and $n-C_4H_{10}$ permeability increased. The $n-C_4H_{10}$ selectivity over $CH_4$ increased with increasing $n-C_4H_{10}$ permeability up to 182,000 barrer and decreased above 182,000 barrer of $n-C_4H_{10}$ permeability. The $C_3H_8$ selectivity over $H_2$ and $N_2$ was found to decrease as the $C_3H_8$ permeability increased from 46,000 to 50,000 barrer, but to increase with increasing permeability from 50,000 to 52,300 barrer and decrease again with increasing permeability from 52,300 to 60,000 barrer. The $C_3H_8$ selectivity over $CH_4$ was found to decrease with increasing $C_3H_8$ permeability up to 52,300 barrer but increase above 52,300 barrer.

A Study on the Friction and Wear Characteristics of C-N Coated Spur Gear (C-N코팅 스퍼기어의 마찰 . 마모 특성에 관한 연구)

  • 노룡;류성기
    • Tribology and Lubricants
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    • v.20 no.5
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    • pp.272-277
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    • 2004
  • This study deals with the friction and wear characteristics of C-N coated spur gear. The PSII apparatus was built and a SCM415 test piece and test gear with steel substrate was treated with carbon nitrogen by this apparatus. The composition and structure of the surface layer were analyzed and compared with that of PVD coated TiN layer. It was found that both of friction coefficient of C-N coating and TiN coating decreased with increasing load, however, C-N coating showed relatively lower friction coefficient than that of TiN coating. We was investigated the effect of C-N coating on hardness, friction and wear. The TiN coated gear showed a more serious friction phenomena than that of C-N coated gear. It was considered that coating of TiN, which was conducted at a vacuum chamber at about 500$^{\circ}C$, results in a tempering of base material that causes microstructural change, which in turn resulted in decreasing of hardness. The C-N coated gear and pinion had higher wear resistance that of TiN coated gear and pinion. C-N coating significantly improved the friction and wear resistance of the gear.

A Study on the Friction and Wear Characteristics of C-N Coated Spur Gear (C-N 코팅 스퍼기어의 마찰${\cdot}$마모 특성에 관한 연구)

  • Lu Long;Lyu Sung-ki
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.41-46
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    • 2004
  • This study deals with the friction and wear characteristics of C-N coated spur gear. The PSII apparatus was built and a SCM415 test piece and test gear with steel substrate was treated with carbon nitrogen by this apparatus. The composition and structure of the surface layer were analyzed and compared with that of PVD coated TiN layer. It was found that both of friction coefficients of C-N coating and TiN coaling decreased with increasing load, however, C-N coating showed relatively lower friction coefficient than that of TiN coating. We was investigated the effect of C-N coating on hardness, friction and wear. The TiN coated gear showed more serious friction phenomena than that of C-N coated gear. It was considered that coating of TiN, which was conducted at a vacuum chamber at about $500^{\circ}C$ results in a tempering of base material that causes microstructure change, which in turn resulted in decreasing of hardness. The C-N coated gear and pinion had higher wear resistance that of TiN coated gear and pinion. C-N coating significantly improved the friction and wear resistance of the gear.

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Wear Characteristics of Coated $Si_3N_4$-TiC Ceramic Tool (Coated $Si_3N_4$-TiC Ceramic 공구의 마모 특성)

  • 김동원;권오관;이준근;천성순
    • Tribology and Lubricants
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    • v.4 no.2
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    • pp.44-51
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    • 1988
  • Titanium carbide(TiC), Titanium nitride(TiN), and Titanium carbonnitride(Ti(C,N)) films were deposited on $Si_3N_4$-TiC composite cutting tools by chemical vapor deposition(CVD) using $TiCl_4-CH_4-H_2$, $TiCl_4-N_2-H_2$, and $TiCl_4-CH_4-N_2-H_2$ gas mixtures, respectively. The experimental results indicate that TiC coatings compared with TiN coatings on $Si_3N_4$ -TiC ceramic have an improved microstructural property, good thermal shock resistance, and good interfacial bonding. However TiN coatings compared with TiC coatings have a low friction coefficient with steel and good chemical stability. It is found by cutting test that coated insert compared with $Si_3N_4$-TiC ceramic have a superior flank and crater wear resistance. And multilayer coating compared with monolayer coating shows a improved wear resistance.

Synthesis of Fullerene Oxide by Fullerene ($C_{70}$) and Various Amino N-Oxides under Ultrasonic Irradiation (초음파 조건에서 여러가지 아민 N-옥시드와 풀러렌($C_{70}$)를 이용한 풀러렌 산화물의 합성)

  • Ko, Weon-Bae;Han, Ji-Yeon;Lim, Young-A;Shin, Won-Jic;Yu, Gu-Yong
    • Elastomers and Composites
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    • v.39 no.2
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    • pp.153-160
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    • 2004
  • Fullerene oxides were synthesized by fullerene ($C_{70}$) and several amine N-oxides such as 3-picoline N-oxide, pyridine N-oxide hydrate, quinoline N-oxide, and isoquinoline N-oxide under ultrasonic condition at $25{\sim}43^{\circ}C$. The reactivity of fullerene ($C_{70}$) with various amine N-oxides undo, ultrasonic irradiation showed the same in all of the proceeding experiments; 3-picoline N-oxide : pyridine N-oxide hydrate : quinoline N-oxide : isoquinoline N-oxide. The MALDI-TOF MS, UV-vis spectrophotometer and HPLC analysis confirmed that the products of fullerene oxidation are [$C_{70}(O)n$] (n=1).

영남지역 콩 생산.가공 특산단지 조성

  • Lim, Sea-Gyu;Shin, Seong-Hyu;Ha, Tae-Joung;Shin, Sang-Ouk;Choi, Dae-Sig;Park, Byeong-Myeong;Oh, Ki-Won;Kim, Jung-Tae;Park, Keum-Yong;Suh, Duck-Yong;Kim, Beom-Su;Kwon, Taeg-Ki
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2007.04a
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    • pp.78.2-78.2
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    • 2007
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Embedding Algorithm between Folded Hypercube and HFH Network (폴디드 하이퍼큐브와 HFH 네트워크 사이의 임베딩 알고리즘)

  • Kim, Jongseok;Lee, Hyeongok;Kim, Sung Won
    • KIPS Transactions on Computer and Communication Systems
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    • v.2 no.4
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    • pp.151-154
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    • 2013
  • In this paper, we will analyze embedding between Folded Hypercube and HFH. We will show Folded Hypercube $FQ_{2n}$ can be embedded into HFH($C_n,C_n$) with dilation 4, expansion $\frac{(C_n)^2}{2^{2n}}$ and HFH($C_d,C_d$) can be embedded into $FQ_{4d-2}$ with dilation O(d).