• Analytical Science and Technology
• /
• v.5 no.4
• /
• pp.401-408
• /
• 1992

The ion-selectrodes based on calcium ferrite were prepared by mixing calcium oxide with ferric oxide on molar ratio of 0.6:1.4, 0.8:1.2, 1.0:1.0, respectively. The specimens were sintered at $1400^{\circ}C$ for 2hrs in $O_2$ and for 20min in $H_2$ atmosphere. The selectrode sintered in hydrogen atmosphere showed better responded potential and wider range of responded concentration than selectrode sintered in oxygen atmosphere. The ion-selectrodes base on calcium ferrite(0.6:1.4 molar ratio.) showed the highest potential to bivalent cations such as $Ca^{2+}$, $Ba^{2+}$, $Mg^{2+}$, $Zn^{2+}$ and halogen anions such as $I^-$, $Br^-$ in the range of $10^{-1}{\sim}10^{-7}M$. It showed good agreement with theoretical nernstian values.

• Journal of the Korean Ceramic Society
• /
• v.41 no.3
• /
• pp.253-258
• /
• 2004

Non-aggregated nanoscale $\alpha$-Al$_2$O$_3$ powders were prepared successfully by polyacrylamine (PAA) gel method. The method was very simple and polymer network inhibited the aggregate of $\alpha$-Al$_2$O$_3$ powders. In this investigation, nanoparticles of $\alpha$-Al$_2$O$_3$ with a diameter of about 8-15 nm were fabricated by calcining the gel precusors with various concentrations of aluminum sulfate, acrylamide and N,N'-methylene-bis-acrylamide (BIS) in air at 110$0^{\circ}C$ for 2 h. The molar ratio of aluminum sulfate to acrylamide did not have any influence on the size of particles. On the other hand, as the molar ratio of BIS to acrylamide increased, the size of nanoparticles decreased.

• Journal of the Korean Ceramic Society
• /
• v.37 no.12
• /
• pp.1159-1164
• /
• 2000

페롭스카이트 구조를 갖는 E $r_{1-x}$S $r_{x}$Cr $O_{3-y}$ 계에서 x=0.0, 0.05, 0.1, 0.2인 비화학양론적 화합물 고용체를 1573 K 대기압 하에서 제조하였다. X-선 회절분석을 통하여 제조된 모든 계들이 등방정계 단일상을 형성하였고, 또한 반지름이 큰 S $r^{2+}$를 doping 시켜줌에 따라 격자상수 및 환산부피가 증가됨을 알 수 있었으며, 단위 세포의 부피는 직선성을 보이며 증가하였다. TG-DTA에 따른 열분석 결과 Sr이 치환되지 않은 계에서는 상전이가 발생하는 반면, x값이 0.05 이상인 계들은 고온영역에 이르기까지 등방정계에서 마름모정계로의 상전이가 억제되었다. 전자현미경을 통하여 치환된 Sr의 몰비에 따른 시료들이 미세구조를 관찰하였고, d.c 전도도 측정을 통하여 다결정성 시료계들이 가지는 전도도의 온도 의존성으로부터 구한 활성화 에너지는 0.17 eV였다.다.

• Journal of Sensor Science and Technology
• /
• v.28 no.4
• /
• pp.256-261
• /
• 2019

In this study, mid-infrared transparent zinc sulfide (ZnS) ceramics were fabricated through hydrothermal synthesis with different molar ratios of S/Zn (S/Zn = 0.8, 1.0, 1.2, 1.4, and 1.6). The ZnS ceramics were sintered at a relatively low temperature of $850^{\circ}C$ to prevent the occurrence of the hexagonal phase featuring optical anisotropy. The phase composition, microstructure, and optical properties of the ZnS ceramics were subsequently investigated by employing X-ray diffraction, scanning electron microscopy, and Fouriertransform infrared spectroscopy. The results obtained indicate that the ZnS nanoparticles feature the cubic phase, without the hexagonal phase. Moreover, with increasing S, the crystallinity and particle size of the ZnS nanoparticles increased. The crystallinity and density of the ZnS ceramics improved when the molar ratio of S was higher than the molar ratio of Zn, thereby enhancing the transmittance. Furthermore, the ZnS ceramic with an S/Zn value of 1.2 was found to exhibit the highest transmittance of approximately 69% owing to the reduced occurrence of the hexagonal phase and a high density of 99.8%.

• Journal of the Korean Ceramic Society
• /
• v.28 no.5
• /
• pp.373-382
• /
• 1991

The effect of Ca/P mole ratio (Ca/P=1.60, 1.67, 1.75) in the initial solution on the mechanical properties of alumina added hydroxyapatite was investigated. Hydroxyapatite was synthesized by precipitation method using Ca(NO3)2$.$4H2O and (NH4)2HPO4 as starting materials and 5 wt% of ${\alpha}$-Al2O3 was added to precipitation solution. The powder was calcined at 800$^{\circ}C$ and sintered at 1,150∼1,400$^{\circ}C$ under water vapor atmosphere. With the increasing of Ca/P mole ration in the initial solution, the amount of tricalcium phosphate formed from the decomposition of hydroxyapatite reduced and the sinterability and mechanical properties were increased. The bending strength and Vickers hardness of the specimen sintered at 1,300$^{\circ}C$ with the Ca/P mole ratio of 1.75 in the initial solution were 230 MPa and 650 kg/$\textrm{mm}^2$, respectively. The improvement of mechanical properties was attributed to not only the effect of Ca/P mole ratio but also the strengthening of sintered body by Al substitution for P ions.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2005.05a
• /
• pp.85-88
• /
• 2005

The stone powder sludge occurred at aggregate production process is classified the specified waste, so it is disposed by appropriate method. But the problems of the shortage of the disposal-site, the environment pollution, and the increase of disposal cost can be occurred in handling process, therefore the stone powder sludge is required the development of recycling technique. The stone powder sludge includes SiO2 of about $63\%$. This characteristic is important at the production of hardened specimens under condition of hydro-thermal reaction. In this study, we investigated the strength properties of concrete used stone powder sludge as siliceous material. The test results under condition of hydro-thermal reaction shows the two main facts. The first, the stone powder sludge is affected to fluidity because the surface of the stone powder sludge has characteristics of flakily and angularity. The second, weight content of the stone powder sludge, is not effective factor to the properties of strength.

• Membrane Journal
• /
• v.12 no.4
• /
• pp.247-254
• /
• 2002

In order to develop the ion exchange membranes which would be used in direct methanol fuel cell (DMFC), the polysulfone polymer was sulfonated using chlorosulfonic acid (CSA) and trimethylchlorosilane(TMCS). It has been characterized in terms of ion conductivities, methanol crossover, swelling degree and ion exchange capacities for the heat untreated and treated membranes at $150^{\circ}C.$ Typically, the methanol permeability and ion conductivity at the mole ratio of 1.4 between polysulfone repeating unit and sulfonating agents showed $2.87{\times}10^{-7}\; cm^2/s$(without heat treatment), $1.52{\times}10^{-7}\; cm^2/s$(with heat treatment) and $1.10{\times}10^{-2}\; S/cm$(without heat treatment), $0.87{\times}10^{-2}\;$ S/cm(with heat treatment), respectively. After the mole ration of 1.4 both values indicated mild increase.

• Korean Chemical Engineering Research
• /
• v.43 no.6
• /
• pp.683-690
• /
• 2005

The microwave carbonization of rice chaff was performed, and their kinetics were compared to those of conventional thermal carbonization. Thermal carbonization was carried out at $300-600^{\circ}C$ for 30 minutes. The weight loss and C/H mole ratio remarkably increased as increase of temperature, while there was no carbonization by microwave dielectric heating in spite of increasing incident power and irradiation time. However, microwave carbonization was successfully performed by addition of 6 wt％ of thermal carbonized rice chaff, it's C/H mole ratio is larger than 3.0, as a catalytic initiator to uncarbonized rice chaff, and the kinetics was depended on the incident power and irradiation time, resulting in the coincide with thermal carbonization to the Arrhenius equation. The activation energy of microwave carbonization was quite low as compared to that of thermal carbonization, while the kinetic constant was large. This is due to the internal volumetric heating characteristics of carbonized rice chaff by microwave. The effect of ash, and C/H mole ratio and amount of carbonized rice chaff were investigated on microwave carbonization.

• Analytical Science and Technology
• /
• v.36 no.3
• /
• pp.128-134
• /
• 2023

Centella asiatica (C. asiatica) extracts, including asiaticoside and madecassoside, are used in ointments to treat the wound and atopic dermatitis due to their antibacterial and skin-regenerating effects in Asia. Therefore, research on the cultivation and extraction efficiency of C. asiatica is being actively conducted to increase commercialization efficiency. In this study, various deep eutectic solvents (DESs) were prepared and used as the extraction solvents according to the mole ratio between the hydrogen bond acceptor (HBA) and hydrogen bond donor (HBD). And then, the extraction yields in distilled water (DW) and methanol (MeOH), commonly used extraction solvents for C. asiatica, were compared and analyzed by HPLC in the optimized operating condition. As a result, a mixture of DW and DES at a ratio of 3:7 showed about 1.4 times higher extraction efficiency than MeOH only. Conversely, the extraction efficiency in a mixture of MeOH and DES at a ratio of 3:7 was about 6 % lower than that in MeOH only.

• Proceedings of the KIEE Conference
• /
• 2001.11a
• /
• pp.100-102
• /
• 2001

In this paper, the piezoelectric and dielectric properties of $Pb(Zr_xTi_{1-x)O_3$ - $Pb(Co_{1/3}Nb_{1/3})O_3)$ piezoelectric ceramics have been investigated as a function of Zr/Ti mole ratio. From the results, when Zr/Ti mole ratio is 49/51, electromechanical coupling coefficient($k_p$), piezoelectric strain constant($d_{33}$) mechanical quality factor($Q_m$), and Permittivity(${{\varepsilon}_{33}}^T/{\varepsilon}_0$) is 64[%], 469[PC/N], 360 and 2000, respectively. Morphotropic Phase Boundary is Zr/Ti mole ratio(49/51) from XRD analysis. Also. From SEM observation, when sintering temperature is 1150[$^{\circ}C$], grain size is about $1{\sim}2[{\mu}m]$ and maximum sintering density is 7.85[$g/cm^3$].