• 제목/요약/키워드: By-product gypsum

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마이크로파 가열에 의한 부산석고(副産石膏)의 건조 특성 (Drying of By-product Gypsum by Microwave Heating)

  • 김형석;채영배;정수복;장영남
    • 한국광물학회지
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    • 제21권2호
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    • pp.193-200
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    • 2008
  • 배연탈황석고 및 인산부산석고에 함유된 부착수분을 마이크로파에 의한 직접 내부 가열 방법으로 증발시켜 건조하고자 하였다. 700 W, 1,000 W, 1,700 W의 출력인 마그네트론에서 발생된 2.45 GHz의 마이크로파로 배연탈황석고와 인산부산석고를 가열한 결과, 마이크로파 출력의 세기를 700 W에서 1,700 W로 높임에 따라 부착수의 증발시간이 10분에서 3분으로 단축되었고, 이수석고는 베타형 반수석고로 변질되었다. 그러나 베타형 반수석고는 무수석고로 변질되지 않았다.

Quality of Recycled Fine Aggregate using Neutral Reaction with Sulfuric Acid and Low Speed Wet Abrader

  • Kim, Ha-Seog;Lee, Kyung-Hyun;Kim, Jin-Man
    • 한국건축시공학회지
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    • 제12권5호
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    • pp.490-502
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    • 2012
  • The use of recycled aggregate, even for low-performance concrete, has been very limited because recycled aggregate, which contains a large amount of old mortar, is very low in quality. To produce a high-quality recycled aggregate, removing the paste that adheres to the recycled aggregate is very important. We have conducted research on a complex abrasion method, which removes the component of cement paste from recycled fine aggregate by using both a low-speed wet abrasion crusher as a mechanical process and neutralization as chemical processes, and well as research on the optimal manufacturing condition of recycled fine aggregates. Subsequently, we evaluated the quality of recycled fine aggregate manufactured using these methods, and tested the specimen made by this aggregate. As a result, it was found that recycled fine aggregates produced by considering the aforementioned optimal abrasion condition with the use of sulfuric acid as reactant showed excellent quality, recording a dry density of 2.4 and an absorption ratio of 2.94. Furthermore, it was discovered that gypsum, which is a reaction product occurring in the process, did not significantly affect the quality of aggregates. Furthermore, the test of mortar using this aggregate, when gypsum was included as a reaction product, showed no obvious retarding effect. However, the test sample containing gypsum recorded a long-term strength of 25.7MPa, whereas the test sample that did not contain gypsum posted a long-term strength of 29.4MPa. Thus, it is thought to be necessary to conduct additional research into the soundness and durability because it showed a clear reduction of strength.

다양한 석고제품으로 제작한 석고 모형의 정확성의 평가: 3차원 이미지의 컴퓨터 지원 분석 (Three-dimensional evaluation of stone models made of various gypsum products)

  • 김욱태
    • 대한치과기공학회지
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    • 제42권4호
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    • pp.321-325
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    • 2020
  • Purpose: This study is to evaluate the accuracy of gypsum replica models made from various gypsum products. Methods: One main model was made of stainless steel by CNC milling process. Molds were formed from the main model, and the gypsum replica models were made using 8 types of type IV gypsum, 10 pieces each. The main model was digitized by a contact scanner (Incise; Renishaw) and the gypsum replicas were digitized by an optical scanner (E4; 3Shape A/S). The difference between the main model and the gypsum replicas were measured by inspection software (3D Systems). One-way ANOVA was performed to evaluate the statistical significance of differences between groups. In addition, the independent sample T test was performed to determine the difference between the conventional and scannable stone group (n=10, α=0.05). Results: The root mean square of the stone models were 7.24 ㎛ to 10.78 ㎛, and statistical significance was found between the two groups (SR, FR) and the other 6 groups (IS, SG, CA, CS, ER, EBG) (p<0.05). The accuracy of the gypsum replicas was 9.04 ㎛ and 7.62 ㎛ in the conventional and scannable stone group, respectively. There was statistical significance between the two groups (p<0.01). Conclusion: In the limited results of this study, the product with low setting expansion and the scannable showed high accuracy. Therefore, in order to obtain a stable and accurate scan model, it is more effective in terms of accuracy to use a scannable stone with a low setting expansion.

석고 종류 및 혼입률에 따른 CAC 반응 특성 (Reaction Characteristics of the CAC with Various Gypsum Type and Mixing Ratio)

  • 최선미;김진만;구자술
    • 자원리싸이클링
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    • 제30권1호
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    • pp.83-91
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    • 2021
  • 조강 생산 시 발생되는 슬래그는 대부분 서냉 방식에 의해 처리되고 있다. 하지만 슬래그 중 일부는 속경성 광물을 포함하고 있음에도 불구하고, 서냉 방식에 의해 그 반응성을 상실하게 된다. 이에 본 연구에서는 제강환원슬래그를 SAT공법에 의하여 공기 급냉하여 선별 및 분급 후 분쇄한 CAC의 활용성 확대를 목적으로 석고 종류 및 혼입율에 따른 CAC의 특성에 관하여 고찰하였다. 그 결과, CAC는 3시간에서는 석고 용해도, 1일 이후에는 석고 함량비에 따라 특성이 나타나는 것을 확인하였다. 반수, 무수석고의 적정 혼입율은 30% 이내, 이수석고는 35% 이상인 것을 확인하였으며, 이수석고의 혼입율 및 특성 확인을 통하여 부산이수석고의 적용 가능성을 확인하였다.

SO3를 다량 함유한 폐석고보드 미분말을 첨가한 3성분계 무기결합재의 길이변화 특성 (The Length Change Characteristic of the Ternary System Inorganic Composites adding the Waste Gypsum Board Micro Powder containing SO3 the great quantity)

  • 김윤미;박종필;이상수;송하영
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2012년도 추계 학술논문 발표대회
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    • pp.65-66
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    • 2012
  • The cement used in the construction industry of the manufacturing process, large amounts of the greenhouse gas, CO2 and is currently being studied for cement substitutes that reduce greenhouse gas issue. Therefore, the this study as a replacement for cement industrial by-product of blast furnace slag, red mud, silica fume and alkali-activator, using only inorganic composites without high-temperature calcination process were manufactured. The waste gypsum board micro powder added to compensate for the shrinkage cracks, the compressive strength and flow, and length change characteristics were investigated. Consequently, The setting time was shortened as GB added And liquidity was reduced. GB 2%, 7 days curing the added strength of specimens was the highest. Came out, and change the length of the Plain least.

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제철 산업부산물인 석회석 슬러지의 배연탈황 공정 적용에 관한 연구 (A Study on the Application Limestone Sludge to the Flue Gas Desulfurization Process)

  • 서성관;추용식;심광보;이종규;송훈;윤영민
    • 한국세라믹학회지
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    • 제51권6호
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    • pp.575-583
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    • 2014
  • The flue gas desulfurization (FGD) process is currently the most effective process utilized to remove sulfur dioxide from stack gases of coal-fired plants. However, FGD systems use a lot of limestone as desulfurizing agent. In this study, we use limestone sludge, which is a by-product of the steel industry, to replace the desulfurizing agent of the FGD system. The limestone particle size is found to be unrelated to the desulfurizing rate; the gypsum purity, however, is related. Limestone sludge mixes with limestone slurry delivered at a constant rate in a desulfurizing agent with organic acid are expected to lead to a high desulfurization efficiency and high quality by-product (gypsum).

포토 폴리머의 직접 주조에 관한 연구 (A Study on the Direct Casting of Photo-polymer)

  • 김우순;김동현
    • 한국공작기계학회논문집
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    • 제15권6호
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    • pp.127-133
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    • 2006
  • Rapid prototyping technologies have been widely used to reduce the development cost of new products. Manufacturing industries are nowadays characterized by the flexibility and complexity of products. This to due to the rapid development of manufacturing technology and diverse needs of customers. In this paper, the best homing out and casting condition for getting casting product of resin pattern(photopolymer) have been examined experimentally. In generally, the burning out and casting conditions have effect on the casting products. Using the direct casting. we directly Producted the Jewelry. And in this paper, we used only gypsum. Many study of casting for resin have been used to dental investment. A dental investment is good for resin casting. but dental investment is too hard and not useful on the jewelry casting. Therefore we need to find the way of resin casting by gypsum.

가압수열 수용액중에서 인산석고로부터 $\alpha$형 반수석고의 생성에 미치는 염류의 영향 (Effects of Salts on the Formation of $\alpha$-Calcium Sulfate Hemihydrated from by-Product Gypsum of Phosphoric Acid Process at Hydrothermal Condition)

  • 이구종;최상흘
    • 한국세라믹학회지
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    • 제24권4호
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    • pp.343-348
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    • 1987
  • The effects of salts such as aluminum sulfate as inorganic salt(2-4%), and sodium salts of citrate, tartrate, succinate, potassium tartrate and gelatin as organic salts(0.1%) on the formation of ${\alpha}$-calcium sulfate hemihydrate from by-product gypsum of phosphoric acid process under hydrothermal condition at 123$^{\circ}C$ and 133$^{\circ}C$ were investigated. Aluminum sulfate solution exhibited the catalystic effected on the crystallization of ${\alpha}$-calcium sulfate hemihydrate of which was assumed in the prismatic form, and organic salts solution exhibited little effect on the catalystic action to the crystallization, than inorganic salts. In the acidic solution with sulfuric acid(pH=2), needle like crystal of calcium sulfate hemihydrate was obtained. Hydrothermal process with aluminum sulfate solution also showed certain amounts of impurity removal such as phosphorus penataoxide from calcium sulfate hemihydrate.

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Effect of Phospho-gypsum on reduction of methane emission from rice paddy soil

  • Ali, Muhammad Aslam;Lee, Chang-Hoon;Kim, Pil-Joo
    • 한국환경농학회지
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    • 제26권2호
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    • pp.131-140
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    • 2007
  • Phospho-gypsum a primary waste by-product in phosphate fertilizer manufacturing industry and a potential source of electron acceptors, such as mainly of sulfate and a trace amount of iron and manganese oxides, was selected as soil amendment for reducing methane $(CH_4)$ emissions during rice cultivation. The selected amendment was added into potted soils at the rate of 0, 2, 10, and 20 Mg $ha^{-1}$ before rice transplanting. $CH_4$ flux from the potted soil with rice plant was measured along with soil Eh and floodwater pH during the rice cultivation period. $CH_4$ emission rates measured by closed chamber method decreased with increasing levels of phospho-gypsum application, but rice yield markedly increased up to 10 Mg $ha^{-1}$ of the amendment. At this amendment level, total $CH_4$ emissions were reduced by 24% along with 15% rice grain yield increment over the control. The decrease in total $CH_4$ emission may be attributed due to shifting of electron flow from methanogenesis to sulfate reduction under anaerobic soil conditions.

산업부산물을 이용한 저시멘트계 지반개량재의 강도 특성 (Strength Characteristics of Low Cement Ratio Soil Stabilizer Using Industrial By-products)

  • 조진우;이용수;유준;김세호
    • 한국지반공학회논문집
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    • 제22권4호
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    • pp.31-39
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    • 2006
  • 본 연구에서는 산업부산물을 이용한 저시멘트계 지반개량재의 강도특성을 고찰하였다. 저시멘트계 지반개량재는 시멘트의 일정부분을 대표적인 포졸란 물질인 고로슬래그, 플라이애쉬, 석고 등의 산업부산물과 활성제를 이용하여 대체함으로써 제조하였다. 일축압축강도 실험을 통하여 포졸란 물질의 반응성을 고찰하였으며 최적의 강도를 나타내는 구성조합을 도출하였다. 실험결과 시멘트의 사용량을 감소시키고 적절한 량의 산업부산물과 활성제를 첨가한 결과 강도가 증가하고 시료구조가 밀실화 되는 것을 확인할 수 있었다.