• Title/Summary/Keyword: Butadiene

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Influence of Molding Conditions on Environmental Stress Cracking Resistance of Injection Molded Part (사출성형품의 공정 조건에 따른 내환경응력균열 특성에 관한 연구)

  • Choi, D.S.;Kim, H.S.
    • Transactions of Materials Processing
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    • v.20 no.2
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    • pp.173-178
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    • 2011
  • Environmental Stress Cracking(ESC) is one of the most common causes of unexpected brittle failure of thermoplastic polymers. The exposure of polymers to liquid chemicals tends to accelerate the crazing process, initiating crazes at stresses that are much lower than the stress causing crazing in air. In this study, ESC of acrylonitirile butadiene styrene(ABS) was investigated as a function of the molding conditions such as injection velocity, packing pressure, and melt temperature. A constant strain was applied to the injection molded specimens through a 1.26% strain jig and a mixture of toluene and isopropyl alcohol was used as the liquid chemical. In order to examine the effects of the molding conditions on ESC, an experimental design method was adopted and it was found that the injection velocity was the dominant factor. In addition, predictions from numerical analyses were compared with the experimental results. It was found that the residual stress in the injection molded part was associated with the environmental stress cracking resistance (ESCR).

Study on the noise reduction occurred to rotation in duct (덕트 회전체에서 발생하는 소음저감에 대한 연구)

  • Park, Hong-Ul;Kim, You-Jae;Park, Sung-Kwan
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2006.11a
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    • pp.875-879
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    • 2006
  • Noise reduction has become a major issue of the duct air-conditioners. This paper describes the reduction of noise and vibration of rotational slim duct system. The design of slim duct system is the most important point of noise reduction in terms of the motor of 2f line noise, resonance noise between forced frequency and natural frequency of Sirocco fan, unbalance noise of motor axis and the noise induced refrigerant. The noise of duct system is mainly measured from diffuser and bottom of duct. The optimal design was implemented after measuring the effect of noise and vibration in each part which is composed of duct system. In this paper, experimental results show that the main elements in air-conditioner duct design. These elements are anti-vibration rubber of motor, axis length of motor, rubber coupler, materials of sirocco fan and control method of motor which are the most vital factors in reducing noise.

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Studies on the Inflammability and Heat Resistance of Conveyer Rubber Belts (콘베어 고무벨트의 난연성(難燃性) 및 내열성(耐熱性)에 관(關)한 연구(硏究))

  • Oh, Pyoung-Je
    • Elastomers and Composites
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    • v.16 no.4
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    • pp.211-216
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    • 1981
  • A series of conveyer rubber belts has been made by blending natural rubber(NR), styrene butadiene rubber(SBR), chloroprene rubber(CR) and additives on nylon cords, and their respective flammability has been investigated. It has been observed that: 1. By adding an antiflame agent to the belt, in addition to 70% chlorinated paraffine and antimony oxide($Sb_{2}O_{3}$), the inflammability is improved remarkably to O - 2 seconds due to the synergistic effect, while a sample without antiflame B fails to pass the KS M 6678 test. 2. Physical properties, such as tensile strength, elongation at break and adhesion strength, of the sample belts have been studies by varying ratios of NR/CR from 20 to 100, and it has been observed that the higher ratios have the better physical properties.

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Effects of Silica Fume Content and Polymer-Binder Ratio on Properties of Ultrarapid-Hardening Polymer-Modified Mortars

  • Choi, Jong Yun;Joo, Myung-Ki;Lho, Byeong Cheol
    • International Journal of Concrete Structures and Materials
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    • v.10 no.2
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    • pp.249-256
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    • 2016
  • This paper deals with the effects of silica fume content and polymer-binder ratio on the properties of ultrarapid-hardening polymer-modified mortar using silica fume and ethylene-vinyl acetate redispersible polymer powder instead of styrene-butadiene rubber latex to shorten the hardening time. The ultrarapid-hardening polymer-modified mortar was prepared with various silica fume contents and polymer-binder ratios, and tested flexural strength, compressive strength, water absorption, carbonation depth and chloride ion penetration depth. As results, the flexural, compressive and adhesion strengths of the ultrarapid-hardening polymer-modified mortar tended to increase as increasing polymer-binder ratio, and reached the maximums at 4 % of silica fume content. The water absorption, carbonation and chloride ion penetration resistance were improved according to silica fume content and polymer-binder ratio.

The Relationship between Microstructure and Freezing Thawing Resistance of Polymer-Cement Mortars (폴리머-시멘트 모르타르의 미세구조 동결융합 저항성의 관계)

  • ;;田英治(Eiji Kamada)
    • Journal of the Korean Ceramic Society
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    • v.31 no.9
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    • pp.949-956
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    • 1994
  • In order to investigate the relationship between pore size distribution and freezing-thawing resistance of mortars, polymer-cement mortars were prepared by using styrene-butadiene rubber latex, ethylene-vinyl acetate emulsion and polyacrylic ester emulsion with various polymer-cement ratios at constant flow. From the results of the test, polymer-cement mortars had a good pore size distribution for freezing-thawing resistance compared with unmodified mortars because of having a small pore volume in the pore radius range of 103~104 $\AA$ affecting on the frost damage. And the freezing-thawing resistance of polymer-cement mortars was improved with increasing polymer-cement ratio.

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Manufacturing of Packing Materials for 3D Printing and Evaluation of their Performances (3D 프린팅에 의한 충진물 제조 및 성능평가)

  • Lee, Hwa Young;Choi, Young Min;Hong, Yeon Ki
    • Journal of Institute of Convergence Technology
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    • v.5 no.2
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    • pp.33-36
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    • 2015
  • In this paper, the development history of random packings for several generations was briefly introduced. We demonstrate the application of 3D printing to the fabrication of Pall rings, directly using computer aided design (CAD) models. The CAD was used to design Pall rings with different number of blades. The models were then printed by using UV curing of acrylonitrile-butadiene-styrene (ABS) resins. The results show that 3D printing is a promising method for producing precisely controlled packing materials. It is also expected that 3D printing is helpful for the fundamental studies of highly efficient packing materials with complex geometrical shapes.

The Study of the Recycling Methode of Alloyed Recycling Plastics by Using the Compatibilizers (상용화제를 이용한 혼합 폐플라스틱의 재활용 방안)

  • Lee, Soo-Keun;Kim, Jai-Neung
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.10 no.1
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    • pp.37-46
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    • 2004
  • The aim of this study was to develop the recycling methode of alloyed recycling plastics. The compatibilizers have been used to improve the physical properties of recycling plastics. Eethylene propylene rubber(EPR), ethylene propylene diene monomer(EPDM), styrene ethylene butylene styrene block copolymer(SEBS), maleic anhydride modified styrene ethylene butylene styrene block copolymer(SEBS-MA) and styrene butadiene styrene block copolymer(SBS) were singled out as compatibilizers. In this study, the physical properties such as impact and tensile strength have improved above 20% by using the compatibilizers.

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Stress relaxation of ABS polymer melts. 1. Effect of weight fraction of rubber particle

  • Cho, Kwang-Soo;Park, Joong-Hwan;Kim, Sang-Yong;Youngdon Kwon
    • Korea-Australia Rheology Journal
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    • v.12 no.3_4
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    • pp.157-163
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    • 2000
  • We develop a simple model which can describe and explain abnormal stress relaxation of ABS melt for which stress dose not exponentially decay. The relaxation behavior of ABS melt consists of two distinct relaxation modes. One is the relaxation of the matrix phase similar to the case of homopolymer melt. The other is manifested by the collection of butadiene rubber particles, named as the cluster, where the particles are connected through the interaction between grafted SAN and matrix SAN. The second mode of the relaxation is characterized by the relaxation time, which is a function of the average size and the microscopic state of the cluster. Experimental results reveal that it can be represented as the product of the average size of the clusters by a function of internal variable that represents the fraction of strained SAN chains inside the cluster.

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Joining of Thermoplastics by the Ultrasonic Welding (초음파용접에 의한 열가소성 수지의 접합)

  • Park, Joon-Boo;Lee, Chul-Ku
    • Journal of the Korean Society for Precision Engineering
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    • v.9 no.1
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    • pp.118-125
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    • 1992
  • Joining of thermoplastics is an area of growing importance in the automotive, aerospace, electronics medical and other domestic appliance industries. While adhesive Bonding or mechanical fastening could be used to join thermoplastics, welding is very effective because of its speed and low cost. This study investgated the ultrasonic joining of thermoplastics. Four kinds of thermoplastics such as Acrylonitrile Butadiene Styrene, Polystyrene, Polyethylene and Polypropylene were used, ultilizing all possible joining combinations. In each combination of thermoplastics, the weldability of the joint was evaluated as a function of weld time, amplitude of vibration and pressure. It was generally found that joining of amorphous thermoplastics with semicrystalline thermopastics resulted in poor joints due to its different crystalline structure. Joining of the amorphous thermoplastics together and joining of the semicrystalline thermoplastics together produced the best joints owing to its same crystalline structure.

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Computational and Experimental Investigation on U-type Seal of Hydraulic Actuator (유압액추에이터용 U자형 시일의 해석 및 실험적 고찰)

  • Yoo, Myung-Ho;Kwon, Jong-Ho;Lee, Taek-Sung
    • Journal of the Korean Society for Precision Engineering
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    • v.23 no.12 s.189
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    • pp.80-87
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    • 2006
  • Seals are usually made from elastomer, a kind of rubber, and it has the non-linearity and hyper-elasticity. U-type seals are used to prevent the leakage of internal fluid sealed in hydraulic actuator because they have more excellent performance than O-rings or rectangular seals. As a core part of hydraulic actuator, U-type seal gives much effect on performance and reliability of actuator. This study considers an NBR U-type seal under high pressure of a hydraulic actuator, and provides its deformation, stress-strain characteristic and contact force using the non-linear finite element analysis. Analysis results are compared with the experimental ones performed by the self-developed testing equipment. Verification result shows that this study presents a good application process for the effective design of U-type seals under high operation pressure.