• Title/Summary/Keyword: Burn-off

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Variation of Pore Structure of Coal-based Activated Carbon with Burn-off of Steam Activation (수증기 활성화법으로 제조된 석탄계 활성탄의 Burn-off에 따른 세공구조의 변화)

  • Lee, Song-Woo;Moon, Jang-Cheon;Lee, Chang-Han;Choi, Dong-Hoon;Ryu, Dong-Chun;Song, Seung-Koo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.12
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    • pp.2141-2148
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    • 2000
  • This study is to investigate changes of pore structure with different burn-off degree of steam activated carbons manufactured from domestic anthracite. The activated carbons were characterized by adsorption of nitrogen at 77 K. Steam activation substantially enhanced the porosity of the activated carbons. Burn-off increased linearly according to increasing activation time, and total pore volume and BET surface area increased with burn-off. Activation at $800^{\circ}C$ increased more micropore volume than that at $950^{\circ}C$. Activated carbons manufactured at high temperature had less microporosity than that at lower temperature, but had more developed macroporosity. The steam activation produced an enlargement of pore below $100{\AA}$ diameter in the activated carbons. Furthermore, the porosity in the $6{\sim}40{\AA}$ pore diameters range increased considerably with the degree of burn-off.

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Modeling and Characterization of Steam-Activated Carbons Developed from Cotton Stalks

  • Youssef, A.M.;Hassan, A.F.;Safan, M.
    • Carbon letters
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    • v.14 no.1
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    • pp.14-21
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    • 2013
  • Physically and chemically activated carbons (ACs) exhibited high adsorption capacities for organic and inorganic pollutants compared with other adsorbents due to their expanded surface areas and wide pore volume distribution. In this work, seven steam-ACs with different burn-off have been prepared from cotton stalks. The textural properties of these sorbents were determined using nitrogen adsorption at $-196^{\circ}C$. The chemistry of the surface of the present sorbents was characterized by determining the surface functional C-O groups using Fourier transform infrared spectroscopy, surface pH, $pH_{pzc}$, and Boehm's acid-base neutralization method. The textural properties and the morphology of the sorbent surface depend on the percentage of burn-off. The surface acidity and surface basicity are related to the burn-off percentage. A theoretical model was developed to find a mathematical expression that relates the % burn-off to ash content, surface area, and mean pore radius. Also, the chemistry of the carbon surface is related to the % burn-off. A mathematical expression was proposed where % burn-off was taken as an independent factor and the other variable as a dependent factor. This expression allows the choice of the value of % burn-off with required steam-AC properties.

Burn-in Considering a Trade-Off of Yield and Reliability (수율과 신뢰도의 상충효과를 고려한 번인)

  • Kim, Kyung-Mee
    • IE interfaces
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    • v.20 no.1
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    • pp.87-93
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    • 2007
  • Burn-in is an engineering method for screening out products containing reliability defects which would cause early failures in field operation. Previously, various burn-in models have been proposed mainly focused on the trade-off of shop repair cost and warranty cost ignoring manufacturing yield. From the view point of a manufacturer, however, burn-in decreases warranty cost at the expense of yield reduction. In this paper, we provide a general model quantifying a trade-off between product yield and reliability, in which any defect distribution from previous yield models can be used. A profit function is expressed in burn-in environments for determining an optimal burn-in time. Finally, the method is illustrated with gate oxide failures which is an important reliability concerns for VLSI CMOS circuits.

Activation of Carbon Fiber in $\textrm{CO}_2$ Gas(l)-Activation process of carbon fiber- ($\textrm{CO}_2$ gas를 이용한 탄소섬유의 활성화(I)-탄소섬유의 활성화 과정)

  • No, Jae-Seung;Seo, Dong-Su
    • Korean Journal of Materials Research
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    • v.8 no.2
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    • pp.114-119
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    • 1998
  • 등방성 피치계 탄소섬유를 Co$_{2}$gas중에서 등온산화시켜 활성탄소섬유를 제조하였다. 산화된 섬유의 비표면적은 BET장치를 이용하여 측정하였다. Burn-off가 증가하여도 반응속도는 크게 감소하지 않았으며, 80$0^{\circ}C$와 90$0^{\circ}C$에서 산화된 섬유의 비표면적은 40%-60%의 burn-off에서 급격히 증가하다가 60%이상에서 감소하였다. 110$0^{\circ}C$에서 산화된 시편은 40%이상 burn-off되어도 비표면적은 크게 증가하지 않고 60%를 지나서도 계속해서 표면적이 증가하는 현상을 나타내었다. 100$0^{\circ}C$에서 60.4%의 burn-off가 일어난 산화섬유의 비표면적은 3,614$m^2$/g로 가장 큰 값이 얻어졌다. 등방성 탄소섬유는 미세한 흑연결정립들이 무질서한 배향을 하고 있으며, 미세기공벽으로 작용할 수 있는 결정립층이 많기 때문에 활성탄소섬유 제조를 위한 원료로 적합하다고 판단된다.

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OPTIMAL BURN-IN FOR MULTIOBJECTIVES (다목적 경우의 최적 Burn-In 방법)

  • KIM, KUINAM J.
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.19 no.40
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    • pp.99-105
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    • 1996
  • 최적 Burn-In 방법은 신뢰성이나 평균수명을 극대화하고 위험율과 Cost를 극소화 하는 것이다. 기존의 연구는 하나의 목적을 대상으로 Burn-In 방법에 대하여 연구하였으나 상호 상충되는 목표에 대해 의사 결정을 하는 복잡하고 어려운 상황을 고려하여야 한다. 그러므로 둘 이상의 목표에 대한 최적의 Burn-In 방법에 대하여 연구되어야 한다. 본 논문에서는 이를 위해 Surrogate Worth Trade Off 기법을 사용하여 실제 최적의 Burn-In 방법을 구하고자 하는 경우에 대하여 연구하였다.

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Removal of Pesticide (Oxamyl) from Water using Activated Carbons Developed from Apricot Stones

  • El-Nabarawy, Th.;Sayed Ahmed, S.A.;Youssef, A.M.
    • Carbon letters
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    • v.8 no.4
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    • pp.299-306
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    • 2007
  • Four stream- activated carbons were prepared by carbonizing apricot stones at $600^{\circ}C$ followed by gasification with steam at $950^{\circ}C$ to burn-off's=17, 32, 49 and 65%. The textural parameters of these activated carbons were determined from nitrogen adsorption results at 77 K. The total pore volume and the mean pore radius increased with the increase of % burn-off whereas the surface area increased with the increase of burn- off from 17 to 32 and further to 49%. Further increase of burn-off to 65% was associated with a considerable decrease in surface area as a result of pronounced pore widening due to pore erosion. The surface pH values of the carbons investigated range between 7.1 and 8.2. The adsorption of oxamyl onto the activated carbon followed pseudo-second order kinetics and the equilibrium adsorption isotherms fitted Langmuir adsorption model. The adsorption of oxamyl proved to be of the physical type and took place in non-micropores. The amount of oxamyl adsorbed expressed as $q_m$ depends to a large extent to the surface area located in non-micropores $S^{\propto}\;_n$, where a straight line relationship passing through the origin was obtained.

Preparation of PAN-based Activated Carbon Fibers by Physical Activation (물리적 활성화에 의한 PAN계 활성탄소섬유의 제조)

  • 임연수;김기원;정승훈;김기덕;정윤중
    • Journal of the Korean Ceramic Society
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    • v.36 no.10
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    • pp.1016-1021
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    • 1999
  • In this study activated carbon fibers were prepared from PAN-based carbon fibers by physical activation with steam or carbon dioxide. The variations in specific surface area amount of iodine adsorption and pore size distribution of the activated carbon fibers after the activation process were discussed. in steam activation BET surface area of about 1019 m2/g was obtained after 77% burn-off while carbn dioxide activation produced ACF with 694m2/g of BET surface area after 52% burn-off. However carbon dioxide activation produced at a similar degree of activation higher micropore volume(0.37 cc/g) and amount of iodine adsorption (1589mg/g) than steam activation. Nitrogen adsorption isotherms for (PAN based activated carbon fibers that prepared by physical activation were of type I in the Brunauer-Deming-Deming-Teller classification

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Activation of Pitch-based Carbon Fiber on $\textrm{CO}_2$ Gas(ll) -Microporosity of Activated Carbon Fiber ($\textrm{CO}_2$ gas를 이용한 탄소섬유의 활성화(ll)-활성탄소섬유의 미세공특성)

  • No, Jae-Seung;Seo, Dong-Su
    • Korean Journal of Materials Research
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    • v.8 no.2
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    • pp.120-125
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    • 1998
  • CO$_{2}$gas중에서 산화된 활성탄소섬유를 77K에서 질소흡착에 의해 흡착등온곡선을 구하였다. 미세공부피와 외부표면적은 t-법으로 구하였으며, 평균기공크기와 기공분포는 Dubinin-Astakhov법으로 구하여 기공발당과정을 고찰하였다. 산화반응 초기(약 40% burn-off까지)에 섬유내부에 발달하는 미세공은 burn-off가 40%를 넘으면 서서히 큰 미세공으로 성장하며, burn-off가 약 60%이상되면 미세기공은 확대 또는 합체되어 점차 중기공으로 성장하는 것으로 관찰되었다. 또한 고온산화반응으로 발달한 기공은 저온에서 생성된 기공보다 크다.

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Decontamination Performance Assessment for the Plasma Arc Vitrification pilot plant on the basis of Trial Burn Results(I) - Decontamination Characteristics for Hazardous Metal, Radioactive surrogate and Radioactive Tracer in Off-gas (시험연소결과에 근거한 플라즈바 아크방식 유리화 시험 설비의 제염성능 평가(I) - 배기가스중의 유해중금속, 방사성핵종 모의물질 및 방사성핵종 제염특성 -)

  • Chae, Gyung-Sun;Park, Youn-Hwan;Min, Byong-Yun;Chang, Jae-Ock;Park, Jun-Yong;Jeong, Weon-Ik;Moon, Byung-Sik
    • Journal of Radiation Protection and Research
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    • v.25 no.2
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    • pp.99-107
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    • 2000
  • Through the results of off-gas analysis at 3 sampling points in Plasma Arc Melting vitrification pilot plant, it was evaluated the partitioning of spiked materials in off-gas and the decontamination characteristic of off-gas treatment system. Spiked materials are hazard_us heavy metals(Pb, Cd, Hg), radioactive surrogate(Co, Cs) and radioactive materials($^{60}Co,\;^{137}Cs$). Through the Trial burn tests, Decontamination factor of spiked materials in off-gas treatment system is calculated.

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Hardware Burn-in and Software Testing (하드웨어 번인과 소프트웨어 시험)

  • 유영관;이종무
    • Proceedings of the Safety Management and Science Conference
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    • 2001.05a
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    • pp.77-81
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    • 2001
  • Burn-in is a test procedure to find and eliminate the inherent initial failure of a product during or at the final stage of production process. Software testing is the validation and verification process which is used to cut off the faults from a software. The two have the common function and objective of "debugging". This article summarizes some significant models on the optimal hardware and software burn-in time, and provides the relevant paper lists. The need for the development of the unified burn-in policy of a hardware-software system is addressed.addressed.

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