• Title/Summary/Keyword: Bulk-fill

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Development of Standard Analysis Methods for Physical Properties on Korean bedsoil 1. Particle density and Bulk density (우리나라 상토의 물리적 표준분석법 설정 연구 1. 입자밀도 및 용적밀도)

  • Kim, Lee-Yul;Cho, Hee-Kee
    • Korean Journal of Soil Science and Fertilizer
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    • v.35 no.6
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    • pp.327-334
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    • 2002
  • Method of besoil analysis were difficult to be applied universally since the use and the source material of bedsoils are diverse from country to country. Korean Standard Methods for Bedsoil Analysis was developed to measure the particle and bulk density. Fifty-three samples for horticultural bedsoil and nine samples for paddy rice bedsoil in the current market were collected. Particle density was measured by electrical pyconometer with He gas, and bulk density by the sandbox method, free fall method, plunger compaction method, free fall and plunger method, and sample weight compaction method. While the use of glass pycnometer which measures particle density to fill blank space with water was inappropriate due to floating organic and calcined inorganic materials in the water, the electrical pycnometer with gas type was suitable considering speed and accuracy. For bulk density, the sandbox method recommended as European Standard Method was more reasonable in principle than other methods. However, this method requires expensive apparatus and intricate process. Plunger compaction method was proposed as standard method, since it had higher consistence with the sandbox method than other methods, as well as an advantage of easy and prompt measurement. Particle density of bedsoil ranged $1.48{\sim}2.67Mg\;m^{-3}$(mean $1.93Mg\;m^{-3}$) for horticultural bedsoil and $2.33{\sim}2.67Mg\;m^{-3}$ (mean $2.43Mg\;m^{-3}$) for paddy rice bedsoil by the electrical pycnometer with He gas. Bulk density of bedsoil ranged $0.11{\sim}0.40Mg\;m^{-3}$ (mean $0.22Mg\;m^{-3}$) for horticultural bedsoil and $0.84{\sim}1.26Mg\;m^{-3}$(mean $1.01Mg\;m^{-3}$) for paddy rice bedsoil by plunger compaction method.

Time-Variant Characteristics of Organic Thin Film Solar Cell Devices on Plastic Substrates (플라스틱 기판에 제작된 유기박막태양전지의 출력특성 경시변화)

  • No, Im-Jun;Lee, Sunwoo;Shin, Paik-Kyun
    • Journal of the Korean Vacuum Society
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    • v.22 no.4
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    • pp.211-217
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    • 2013
  • Two types of organic thin film solar cell devices with bulk hetero-junction (BHJ) structure were fabricated on plastic substrates using conjugated polymers of $PCDTBT:PC_{71}BM$ and $PTB7:PC_{71}BM$ blended as active channel layer. Time-variant characteristics of the organic thin film solar cell devices were investigated: short circuit current density ($J_{SC}$); open circuit voltage ($V_{OC}$); ; fill factor (FF); power conversion efficiency (PCE, ŋ). All the performance parameters were degraded by progress of the measurement time, while $V_{OC}$ showed the most drastic decrease with time. Possible factors to cause the time-variant alteration of performance parameters were discussed to be clarified.

Nanoscale Double Interfacial Layers for Improved Photovoltaic Effect of Polymer Solar Cells (이중 나노 계면층을 적용한 고효율 고분자 태양 전지 소자 연구)

  • Lee, Young-In;Park, Byoung-Choo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.1
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    • pp.70-75
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    • 2011
  • We introduced nanoscale interfacial layers between the PV layer and the cathode in poly (3-hexylthiophene):methanofullerene bulk-heterojunction polymer photovoltaic (PV) cells. The nanoscale double interfacial layers were made of ultrathin poly (oxyethylenetridecylether) surfactant and low-work-function alloy-metal of Al:Li layers. It was found that the nanoscale interfacial layers increase the photovoltaic performance, i.e., increasing short-circuit current density and fill factor with improved device stability. For PV cells with the nanoscale double interfacial layers, an increase in power conversion efficiency of $4.18{\pm}0.24%$ was achieved, compared to that of the control devices ($3.89{\pm}0.08%$) without the double interfacial layers.

The Effect of Al Powder as an Additive on the Sintering of $Al2_O_3$ (I. In air, $1350~1550^{\cire}C$) (첨가된 알루미늄 분말의 산화가 알루미나 소결에 미치는 영향(I. 공기중, $1350~1550^{\cire}C$에서))

  • 박정현;안주삼;김해두
    • Journal of the Korean Ceramic Society
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    • v.20 no.1
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    • pp.49-54
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    • 1983
  • The main object of this study is to investigate the effect of Al powder as an additive on the sintering of calcined alumina comparing with that of calcined alumina alone. The degree of Al oxidation is calculated by measuring the weight increase during the firing Water absorption bulk density and compressive strength of the $Al_2O_3+Al$ system at each temperature are compared with those of $Al_2O_4$ alone. The $Al_2O_3+Al$ system shows better physical propeties than Al2O3 alone and it seems by the SEM observation that the fine oxidized Al particles(fine $Al_2O_3$ particles submicron unit) fill the interstices of the original $Al_2O_3$ par-ticles and thus result in the well-close-packed arrangement of the particles.

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Resistance to Airflow of Grain as Affected by Grain Moisture Content (곡물(穀物)의 함수율(含水率) 변화(變化)에 따른 송풍저항(送風抵抗)에 관(關)한 연구(硏究))

  • Kim, M.S.;Kim, S.R.
    • Journal of Biosystems Engineering
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    • v.11 no.2
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    • pp.55-65
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    • 1986
  • The resistance to the passage of airflow through various agricultural products is an important consideration in the design of an aeration or drying system. The amount of resistance to airflow varied widely from one kind of grain to another, and depended upon airflow rate, surface texture and shape of the particles, the size and configuration of voids, and foreign and fine material in the grain bed. The airflow rate was the major factor considered on this kind of study in the early stages. But these days, the studies on the resistance to airflow of grain affected by grain moisture content and foreign and fine material have been widely carried out. However the foreign an fine material in the grain bed could not be a major factor on the study in Korea because there were only a few grain process procedure after harvesting it. The objectives of this study were to investigate the effect of moisture content and airflow rate on airflow resistance to grain, and to develop a model to predict the static pressure drop across the grain bed as a function of moisture content and airflow rate. The rough rice varieties, Akibare, Milyang 15 (Japonica types), Samkwang, Backyang (Indica types)and covered barley variety, Olbori, which were harvested in 1985 were used in the experiment after cleaning them. Resistances to airflow of grain were investigated at four levels of moisture content (13-25%, wb.) for ten different airflow rates($0.01-0.15m^3/sm^2$). The results of this study are summarized as follows; 1. Theaverage bulk densities were $585.3kg/m^3$ for rough rice and $691.6kg/m^3$ for barley at the loose fill, and were $648.8kg/m^3$ for rough rice and $758.2kg/m^3$ for barley at the packed fill. The pressure drops at the packed fill beds were approximately 1.4 to 1.8 times higher than those at the loose fill beds. 2. The pressure drops across grain beds deceased with the increase of moisture content and increased with airflow rate. The decreasing rates of pressure drop across grain beds according to the moisture contents at the lower airflow rates were higher than those at the higher airflow rates, and the increasing rates of pressure drop according to the airflow rates at the lower moisture contents were higher those at higher moisture contents. 3. The pressure drop across barley bed were much higher than rough rice beds and the pressure drops across Japonica type rough rice beds were a little higher than Indica type. 4. The mathematical models to predict the pressure drop across grain beds as a function of moisture content and airflow rate were developed from these experiments.

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Performance Characteristics of p-i-n type Organic Thin-film Photovoltaic Cell with Rubrene:CuPc Hole Transport Layer (Rubrene:CuPc 정공 수송층이 도입된 p-i-n형 유기 박막 태양전지의 성능 특성 연구)

  • Kang, Hak-su;Hwang, Jongwon;Kang, Yongsu;Lee, Hyehyun;Choe, Youngson
    • Korean Chemical Engineering Research
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    • v.48 no.5
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    • pp.654-659
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    • 2010
  • We have investigated the effect of rubrene-doped CuPc hole transport layer on the performance of p-i-n type bulk hetero-junction photovoltaic device with a structure of ITO/PEDOT:PSS/CuPc: rubrene/CuPc:C60(blending ratio 1:1)/C60/BCP/Al and have evaluated the current density-voltage(J-V) characteristics, short-circuit current($J_{sc}$), open-circuit voltage($V_{oc}$), fill factor(FF), and energy conversion efficiency(${\eta}_e$) of the device. By rubrene doping into CuPc hole transport layer, absorption intensity in absorption spectra decreased. However, the performance of p-i-n organic type bulk hetero-junction photovoltaic device fabricated with crystalline rubrene-doped CuPc was improved since rubrene shows higher bandgap and hole mobility compared to CuPc. Increased injection currents have effected on the performance improvement of the present device with energy conversion efficiency(${\eta}_e$) of 1.41%, which is still lower value compared to silicone solar cell and many efforts should be made to improve organic photovoltaic devices.

Performance Characteristics of p-i-n Type Organic Thin-film Photovoltaic Cell with CuPc: $F_4$-TCNQ Hole Transport Layer (CuPc: $F_4$-TCNQ 정공 수송층이 도입된 P-i-n형 유기 박막 태양전지의 성능 특성 연구)

  • Park, So-Hyun;Kang, Hak-Su;Senthilkumar, Natarajan;Park, Dae-Won;Choe, Young-Son
    • Polymer(Korea)
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    • v.33 no.3
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    • pp.191-197
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    • 2009
  • We have investigated the effect of strong p-type organic semiconductor $F_4$-TCNQ-doped CuPc hole transport layer on the performance of p-i-n type bulk heterojunction photovoltaic device with ITO/PEDOT:PSS/CuPc: $F_4$-TCNQ(5 wt%)/CuPc:C60(blending ratio l:l)/C60/BCP/LiF/Al, architecture fabricated via vacuum deposition process, and have evaluated the J-V characteristics, short-circuit current ($J_{sc}$), open-circuit voltage($V_{oc}$), fill factor(FF), and power conversion efficiency(${\eta}_e$) of the device. By doping $F_4$-TCNQ into CuPc hole transport layer, increased absorption intensity in absorption spectra, uniform dispersion of organic molecules in the layer, surface uniformity of the layer, and enhanced injection currents improved the current photovoltaic device with power conversion efficiency(${\eta}_e$) of 0.16%, which is still low value compared to silicone solar cell indicating that many efforts should be made to improve organic photovoltaic devices.

Reconstruction of the Recurrent Ischial Sore with Modified Gluteus Maximus Myocutaneous V-Y Advancement flap (변형된 대둔근 V-Y 전진 피판을 이용한 재발성 좌골부 욕창의 재건)

  • Lee, SeungRyul;Kim, Da-Arm;Oh, SangHa
    • Archives of Plastic Surgery
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    • v.36 no.6
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    • pp.714-719
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    • 2009
  • Purpose: Recurrent ischial pressure sore is troublesome for adequate soft tissue coverage, because usually its pocket has a very large deep space and adjacent donor tissue have been scarred in the previous surgery. However, the conventional reconstructive methods are very difficult to overcome them. Modified gluteus maximus myocutaneous V - Y advancement flap from buttock can be successfully used in these circumstances. Methods: From February 2007 to October 2008, modified gluteus maximus myocutaneous V - Y advancement flaps were perfomed in 10 paraplegic patients with recurrent ischial pressure sore. The myocutaneous flap based on the inferior gluteal artery was designed in V - shaped pattern toward the superolateral aspect of buttock and was elevated from adjacent tissue. Furthermore, when additional muscular bulk was required to obliterate dead space, the flap dissection was extended to the inferolateral aspect which can included the adequate amount of the gluteal muscle. After the advanced flap was located in sore pocket, donor defect was repaired primarily. Results: The patients' mean age was 46.9 and the average follow - up period was 12.4 months. The immediate postoperative course was uneventful. But, two patients were treated through readvancement of previous flap due to wound dehiscence or recurrence after 6 months. The long - term results were satisfied in proper soft tissue bulk and low recurrence rate. Conclusions: The modified gluteus maximus myocutaneous V - Y advancement flap may be a reliable method in reconstruction of recurrent ischial pressure sore, which were surrounded by scarred tissue because of its repetitive surgeries and were required to provide sufficient volume of soft tissue to fill the large pocket.

Investigation of short-term stability in high efficiency polymer : nonfullerene solar cells via quick current-voltage cycling method

  • Lee, Sooyong;Seo, Jooyeok;Kim, Hwajeong;Song, Dong-Ik;Kim, Youngkyoo
    • Korean Journal of Chemical Engineering
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    • v.35 no.12
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    • pp.2496-2503
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    • 2018
  • The short-term stability of high efficiency polymer : nonfullerene solar cells was investigated by employing a quick (ten cycles) current density-voltage (J-V) cycling method. Polymer : nonfullerene solar cells with initial power conversion efficiency (PCE) of >10% were fabricated using bulk heterojunction (BHJ) films of poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)-benzo[1,2-b:4,5b']dithiophene))-alt-(5,5-(1',3'-di-2-thienyl-5,7'-bis(2-ethylhexyl)benzo[1',2'-c:4',5'-c']dithiophene-4,8-dione))] (PBDB-T) and 3,9-bis(2-methylene-((3-(1,1-dicyanomethylene)-6/7-methyl)-indanone))-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2',3'-d']-s-indaceno[1,2-b:5,6-b']dithiophene (IT-M). One set of the BHJ (PBDB-T : IT-M) films was thermally annealed at $160^{\circ}C$ for 30min, while another set was used without any thermal treatment after spin-coating. The quick J-V scan (cycling) measurement disclosed that the PCE decay was relatively slower for the annealed BHJ layers than the unannealed (as-cast) BHJ layers. As a result, after ten cycles, the annealed BHJ layers delivered higher PCE than the unannealed BHJ layers due to higher and more stable trend in fill factor. The present quick J-V cycling method is simple but expected to be useful for the prediction of short-term stability in organic solar cells.

Fabrication of large area OPV cells (대면적 유기 태양 전지의 제작)

  • Byun, Won-Bae;Shin, Won Suk;Ryu, Ka Yeon;Park, Hye Sung;Moon, Sang-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.69.2-69.2
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    • 2010
  • Recently, bulk hetero-junction cells have been extensively studied by many researchers. Most of these cells were fabricated by spin coater. However, the spin coating process is not favorable to the large-scaled industry because it is not compatible with roll-to-roll process. One of the alternative methods is Doctor blading. In this study, we fabricated large OPV cells having total area of $100cm^2$. The buffer layer was Poly-(3,4-ethylenedioxythiophene) : poly-(styrenesulfonate) aqueous dispersion (PEDOT:PSS) and the active material is poly (3-hexythiophene) (P3HT) and phenyl-C61-butyric acid methyl ester (PCBM) blend in the solvent of Chlorobenzene. All of the organic layers were coated by dragging the blade with a speed of 5~20 mm/s on the stage with a temperature of $50^{\circ}C$. As-bladed PEDOT:PSS layer was baked at $120^{\circ}C$ for 10 minutes to eliminate the water. The cell structure is patterned ITO substrate/PEDOT:PSS/P3HT:PCBM/LiF/Al. The topmost electrode, LiF/Al, was deposited by thermal evaporation. After depositing electrode, and the cell was annealed at $150^{\circ}C$ for 30 minutes. The measured ISC, VOC, fill factor, and PCE were 2.95 A, 5.86 V, 0.32, and 0.78%, respectively. PCE was quite low but the large active area could be obtained successfully.

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