• 제목/요약/키워드: Bulk samples

검색결과 528건 처리시간 0.02초

A Comparison between Wet-only and Bulk Deposition at Two Forest Sites in Japan

  • Imamura, Naohiro;Iwai, Noriko;Tanaka, Nobuaki;Ohte, Nobuhito
    • Asian Journal of Atmospheric Environment
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    • 제12권1호
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    • pp.67-77
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    • 2018
  • To investigate the effects of forest and the surrounding natural and anthropogenic sources on the bulk depositions on forested land, this study examined differences in ion concentrations between wet-only and bulk samples at two forested sites in Japan. The surrounding natural and anthropogenic sources at each site were different; Shirasaka is in a rural area and Tanashi is an urban environment. The volume weighted (vw) mean concentrations of $K^+$ and $Ca^{2+}$ in the bulk samples were significantly (p<0.05) higher than those in the wet-only samples at both sites. The forest canopy and a nearby incineration plant were hypothesized to be the main sources of $K^+$ contaminants at Shirasaka and Tanashi, respectively. The transport of sea salt and urban dust may explain the presence of enriched $Ca^{2+}$ concentrations in the bulk samples at Shirasaka and Tanashi, respectively. The $NH_4{^+}$ concentrations in the Shirasaka bulk samples were significantly (p<0.05) lower than those in the wet-only samples. The vw mean $SO{_4}^{2-}$ and $NO_3{^-}$ concentrations in both sample types were not significantly different at either site. This study demonstrated that the ion concentration differences between wet-only and bulk samples were affected by nearby natural and anthropogenic sources even at forest sites, similar to previous findings for non-forested locations. However, the $K^+$ concentration differences between wet-only and bulk samples may be higher owing to forest sources, even in the absence of anthropogenic sources.

마산과 행암 지역으로 유입되는 다환방향족탄화수소(PAHs)의 대기 침적 플럭스 산정과 특성 (Estimation and Characteristics of Atmospheric Deposition Flux of Polycyclic Aromatic Hydrocarbons (PAHs) into the Masan and Haengam Areas of Korea)

  • 이수정;문효방;최민규
    • 한국환경과학회지
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    • 제15권2호
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    • pp.121-131
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    • 2006
  • Atmospheric bulk (wet and dry) samples were monthly collected in Masan and Heangam areas of Korea, to assess the deposition flux and seasonal variation of polycyclic aromatic hydrocarbons (PAHs). Deposition fluxes of PAHs in bulk samples were determined using gas chromatography coupled to mass spectrometer detector (GC/MSD). Particle deposition fluxes from Masan and Haengam areas varied from 13 to $87\;g/m^2/year$ and from 5 to $52\;g/m^2/year$, respectively. PAHs deposition fluxes in atmospheric bulk samples in Masan and Haengam areas ranged from 135 to $464\;{\mu}g/m^2/year$ and from 62.2 to $194\;{\mu}g/m^2/year$, respectively. Atmospheric deposition fluxes of particles and PAHs in this study were comparable to or slightly lower values than those from different locations in Korea and other countries. PAHs profiles of atmospheric deposition bulk samples showed slightly different from two sampling areas, however the predominant species of PAHs were similar. Indeno (1,2,3-c,d)pyrene, benzo(g,h,i)perylene, phenanthrene compounds were the most detected PAHs in deposition bulk samples. Carcinogenic PAHs occupied the contribution of approximately $30-40\%$ of the total PAHs deposition fluxes. The non-metric multi-dimensional scaling (MDS) was used, to assess the differentiation of PAHs source between two sampling areas. The result suggests that PAHs contamination sources were different according to the location and season surveyed. There was no an apparent relationship between the PAHs deposition flux against temperature and rainfall amount, even though summer season with the highest temperature and the largest amount of precipitation showed the lowest PAHs deposition flux. Benzo(e)pyrene/benzo(a)pyrene ratio indicated that the photo-degradation process was one of important factors to the seasonal variation of PAHs with the lower deposition fluxes.

고에너지 볼 밀링이 Skutterudite계 CoSb3의 열전 및 전하 전송 특성에 미치는 영향 (Effect of High-Energy Ball Milling on Thermoelectric Transport Properties in CoSb3 Skutterudite)

  • 남우현;맹은지;임영수;이순일;서원선;이정용
    • 한국전기전자재료학회논문지
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    • 제28권12호
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    • pp.852-856
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    • 2015
  • In this study, we investigate the effect of high-energy ball milling on thermoelectric transport properties in double-filled $CoSb_3$ skutterudite ($In_{0.2}Yb_{0.1}Co_4Sb_{12}$). $In_{0.2}Yb_{0.1}Co_4Sb_{12}$ powders are milled using high-energy ball milling for different periods of time (0, 5, 10, and 20 min), and the milled powders are consolidated into bulk samples by spark plasma sintering. Microstructure analysis shows that the high-energy ball milled bulk samples are composed of nano- and micro-grains. Because the filling fractions are reduced in the bulk samples due to the kinetic energy of the high-energy ball milling, the carrier concentration of the bulk samples decreases with the ball milling time. Furthermore, the mobility of the bulk samples also decreases with the ball milling time due to enhanced grain boundary scattering of electrons. Reduction of electrical conductivity by ball milling has a decisive effect on thermoelectric transport in the bulk samples, power factor decreases with the ball milling time.

Validation of Bulk Analysis with Simulated Swipe Samples Containing Ultra-Trace Amounts of Uranium and Plutonium Using MC-ICP-MS

  • Lim, Sang Ho;Han, Sun-Ho;Park, Jong-Ho;Park, Ranhee;Lee, Min Young;Park, Jinkyu;Lee, Chi-Gyu;Song, Kyuseok
    • Mass Spectrometry Letters
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    • 제6권3호
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    • pp.75-79
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    • 2015
  • Suitable analytical procedures for the bulk analysis of ultra-trace amounts of uranium and plutonium have been developed using multi-collector inductively coupled mass spectrometry (MC-ICP-MS). The quantification and determination of the isotopic ratios of uranium and plutonium in three simulated swipe samples, a swipe blank, and a process blank were performed to validate the analytical performance. The analytical results for the simulated swipe samples were in good agreement with the certified values, based on the measurement quality goals for the analysis of bulk environmental samples recommended by the International Atomic Energy Agency (IAEA)

Electron Transport Mechanisms in Ag Schottky Contacts Fabricated on O-polar and Nonpolar m-plane Bulk ZnO

  • Kim, Hogyoung
    • Transactions on Electrical and Electronic Materials
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    • 제16권5호
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    • pp.285-289
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    • 2015
  • We prepared silver Schottky contacts to O-polar and nonpolar m-plane bulk ZnO wafers. Then, by considering various transport models, we performed a comparative analysis of the current transport properties of Ag/bulk ZnO Schottky diodes, which were measured at 300, 200, and 100 K. The fitting of the forward bias current-voltage (I-V) characteristics revealed that the tunneling current is dominant as the transport component in both the samples. Compared to thermionic emission (TE), a stronger contribution of tunneling current was observed at low temperature. The reverse bias I-V characteristics were well fitted with the thermionic field emission (TFE) in both the samples. The presence of acceptor-like adsorbates, such as O2 and H2O, modulated the surface conductive state of ZnO, thereby affecting the tunneling effect. The degree of activation/passivation of acceptor-like adsorbates might be different in both the samples owing to their different surface morphologies and surface defects (e.g., oxygen vacancies).

원유내 체세포수 측정을 위한 Fossomatic과 Coulter Counter 방법의 비교 (Comparison of Fossomatic and Coulter Counter Methods for Somatic Cell Count in Raw Milk)

  • 이정구;손봉환;이정길;고홍범
    • 한국동물위생학회지
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    • 제16권1호
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    • pp.1-10
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    • 1993
  • Samples of bulk herd milk, foremilk, last milk (stripping) and individual cow sample were collected and their somatic cell number were counted with Fossomatic counter (FCC), Coulter counter(CC), direct microscopic somatic cell count(DMSCC) and Califormia mastitis test (CMT), The results were compared and summarized as follows : 1. Mean somatic cell counts of 120 bulk herd milk samples obtained by DMSCC, FCC and CC were 433,203, 481,213 and 676,245 respectively. 2. Mean somatic cell counts of 116 foremilk samples obtained by DMSCC, FCC and CC were 515,035, 611,845 and 725,051 respectively 3. Mean somatic cell counts of 87 last milk samples obtained by DMSCC, FCC and CC were 718,506, 839,874 and 1,041,160 respectively. 4. Mean somatic cell counts of 57 individual cow samples obtained by DMSCC, FCC and CC were 449,258, 491,018 and 521,315 respectively. 5. Mean somatic cell counts of all samples increased with the increasing CMT score, and the cell counts were higher by CC than by FCC. 6. The correlation coefficients between the somatic cell counts by CMT and CC were 0.926 in bulk herd milk, 0.707 in foremilk 0.688 in last milk and 0.675 in individual cow sample, respectively 7. The correlation coefficients between the somatic cell counts by CMT and FCC were 0. 945 in bulk herd milk, 0.705 in foremilk 0.694 in last milk and 0.727 in individual cow sample, respectively. 8. The correlation coefficients between the somatic cell counts by CC and FCC were 0.978 in bulk herd milk, 0.997 in foremilk 0.983 in last milk and 0.985 in individual cow sample, respectively.

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Characteristics of Fe-Ni Nanopowders Prepared by Electrical Explosion of Wire in Water and Ethanol

  • Bac, L.H.;Kim, B.K.;Kim, J.S.;Kim, J.C.
    • Journal of Magnetics
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    • 제16권4호
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    • pp.435-439
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    • 2011
  • In this work, we prepared Fe-Ni alloy nanopowders by wire electrical explosion in deionized water and ethanol. Particles size and morphology of the as-synthesized nanoparticles prepared in water and ethanol were observed by transmission electron microscopy. In both cases, the as-synthesized nanoparticles were in nearly spherical shape and their size distribution was broad. The particles prepared in the water were in core-shell structure due to the oxidation of Fe element. X-ray diffraction was used to analyze the phase of the nanopowders. It showed that the nanopowders prepared in water had ${\gamma}$-Fe-Ni solid solution and FeO phase. The samples obtained in ethanol were in two phases of Fe-Ni solid solution, ${\gamma}$-Fe-Ni and ${\alpha}$-Fe-Ni. Bulk samples were made from the as-synthesized nanopowders by spark plasma sintering at $1000^{\circ}C$ for 10 min. Structure of the bulk sample was observed by scanning electron microscope. Magnetic properties of the as-synthesized nanopowders and the bulk samples were investigated by vibrating sample magnetometer. The hysteresis loop of the assynthesized nanopowders and the sintered bulk samples revealed a ferromagnetic characteristic.

국내 석면 고형시료 중 석면의 종류 및 함유량에 관한 연구 (A Study on Types and Contents of Asbestos in Bulk Samples)

  • 최호춘;안선희;홍좌령;전봉환;이용필;박정일
    • 한국산업보건학회지
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    • 제21권4호
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    • pp.201-208
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    • 2011
  • Objectives: According to the compliance of the asbestos-related regulation, every building has to be inspected for asbestos presence before its abatement work. This study was performed for identifying the types and contents of asbestos in building bulk samples. Materials and Methods: Bulk samples were collected during the asbestos inspection in 2010. We grouped the bulk samples into the regulated asbestos containing materials(RACM), presumed asbestos containing materials(PACM), and construction products. Additionally, the types of asbestos in all bulk samples were identified by polarization microscopy(PLM). Results: The RACMs were from building, house, pipe and facility. The RACMs were found mainly building (72.1%) and house (93.7%). The contents of chrysotile in building, house and facility were 66.9% (1-90%), 89.7% (2-90%) and 11.0% (2-90%), respectively. PACMs were surfacing material, thermal system insulation (TSI), and miscellaneous material. The miscellaneous materials that showed a high detection rate (79.2%) were ceiling, roofing and wall materials. Among them, the roofing materials had high chrysotile content(9.7%, 2-21%), followed by wall (8.7%, 2-21%) and ceiling (3.4%, 1-17%). In the construction products, asbestos was found mainly in slate (92.6%, 2-21%), including chrysotile. The slate had high asbestos content (9.7%, 2-21%), followed by cement flat board (8.7%, 2-19%) and textile (3.4%, 1-17%) Conclusions: Utilizing these results, it would be contributed to construct a useful ACM database and prevent from asbestos exposure to workers in the asbestos abatement and maintenance works.

과냉각 액상구간에서 압축.인장시 Cu기 비정질 합금의 결정화 거동 (Crystallization behavior of Cu-base bulk metallic glass in supercooled liquid region during compression and tension)

  • 박은수;김상현;허무영;김휘준;배정찬
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2008년도 추계학술대회 논문집
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    • pp.215-217
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    • 2008
  • Crystallization behavior of the bulk metallic glass (BMG) during compression and tension was studied in the supercooled liquid region (SLR). Rod samples of the BMG alloy were produced by consolidating gas atomized powders of $Cu_{54}Zr_{22}Ti_{18}Ni_6$ using spark plasma sintering. The crystallization behavior in these samples was examined by tackling changes in thermal property during heating the samples in DSC. The present BMG alloy was firstly decomposed and then crystallized during annealing in the SLR. The phase decomposition from the original amorphous phase was retarded by the compressive stress, while it was accelerated by the tensile stress.

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세종지역 사육 소의 큐열 항체 보유율 조사 (Prevalence of antibodies to Coxiella burnetii in cattle in Sejong)

  • 이태호;이성희;윤창희
    • 한국동물위생학회지
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    • 제42권4호
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    • pp.177-181
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    • 2019
  • Q fever is a zoonosis caused by Coxiella burnetti that is important not only for livestock but also for humans. This research aims to investigate infection rate of Q fever by examining the prevalence of antibody titers in cattle in Sejong City. From March to October 2018, 505 samples of Hanwoo serum and 47 samples of bulk-tank milk were collected and analyzed using ELISA. According to the result, 25 (53.2%) out of 47 bulk-tank milk samples were antibody positive and 28 (5.5%) out of 505 cows were antibody positive. The seroprevalence of C. burnetii increased with age (<1 y=0%, 1~2 y=4.1%, 3~5 y=7.5%, ≥6 y=9.6%) and was higher in females (6.5%) compared to males (0%).