• Title/Summary/Keyword: Building Morphology

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Synthesis and Characterization of MoS2/Graphene-TiO2 Ternary Photocatalysts for High-Efficiency Hydrogen Production under Visible Light

  • Zhang, Feng-Jun;Kong, Cui;Li, Xuan;Sun, Xian-Yang;Xie, Wen-Jie;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.56 no.3
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    • pp.284-290
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    • 2019
  • Ternary MoS2/graphene (G)-TiO2 photocatalysts were prepared by a simple hydrothermal method. The morphology, phase structure, band gap, and catalytic properties of the prepared samples were investigated by X-ray diffraction, Raman spectroscopy, scanning electron microscopy, UV-vis spectrophotometry, and Brunauer-Emmett-Teller surface area measurement. The H2 production efficiency of the prepared catalysts was tested in methanol-water mixture under visible light. MoS2/G-TiO2 exhibited the highest activity for photocatalytic H2 production. For 5 wt.% and 1 wt.% MoS2 and graphene (5MT-1G), the production rate of H2 was as high as 1989 µmol-1h-1. The catalyst 5MT-1G showed H2 production activity that was ~ 11.3, 5.6, and 4.1 times higher than those of pure TiO2, 1GT, and 5MT, respectively. The unique structure and morphology of the MoS2/G-TiO2 photocatalyst contributed to its improved hydrogen production efficiency under visible light.

Bedform Distribution and Sand Transport Trend on a Subtidal Sand Ridge in a Macrotidal Bay, West Coast of Korea

  • Park, Soo-Chul;Yoo, Dong-geun
    • Journal of the korean society of oceanography
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    • v.32 no.4
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    • pp.181-190
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    • 1997
  • A large subtidal sand ridge (Jungang Satoe) in Asan Bay, on the west coast of Korea, was studied in order to understand the morphology and sediment transport trend in a macrotidal setting, by means of analyzing sediment samples, current data, side-scan sonographs and seismic profiles. The ridge is about 15 km long and 2-5 km wide, with a relief of about 15 m. It is elongated in the flow direction of flood (SE) and ebb (NW) tidal currents, but asymmetrical in cross section. The western and southwestern side of the ridge is characterized by relatively gentle slopes averaging 0.4$^{\circ}$, whereas on the northeastern side, relatively steep slopes were mapped with 1.6$^{\circ}$ slope angles. Tidal currents associated with the ridge are very strong; maximum surface velo-cities range from neap values of 50 cm/s to spring values of 130 cm/s. The shear velocities during flood and ebb are strong enough to erode and transport sands on the ridge. Sand waves and megaripples (dunes) are the most common bedforms produced by the tidal currents, which show regional differences in shape and size on the ridge. The distribution pattern of these bedforms in-dicates that the flood tidal currents are dominant on the offshore (northwest) side of the ridge, whereas the onsho.e (southeast) side of the ridge is ebb-dominated. The sand transport path as inferred from bedform orientations is directed toward the ridge crest on the flanks, whereas on the crest, it is near-longitudinal to the ridge axis. The convergent, upslope movement of sands on the ridge flanks appears to be important in sand ridge building and maintenance. A significant ridge migration toward the northeast can be suspected on the basis of the ridge morphology, which may cause offshore hazards for navigation.

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Morphological Transformation of Building Blocks of Apartment Complexes in Busan (부산 아파트 단지의 주동 평면형태의 변화 특성에 관한 연구)

  • Lee, Sangjin;Park, SoHyun
    • Journal of the Architectural Institute of Korea Planning & Design
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    • v.35 no.8
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    • pp.3-14
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    • 2019
  • The research is to track the morphological transformation of residential towers of apartment complexes in Busan. Though apartment is one of the most important components in Korean society, it has not drawn enough attention from academia as well as the public, especially regarding its shape. In result, its morphological change has barely been recognized. Instead, negative, but superficial, evaluation has become dominant tendency to deal with the shape of apartment tower. There are numerous 'partial' evidences to inform the morphological change of apartment plan type, and understanding the change is critical since morphological resultant reflects culture, politics, economy of a society. The research has been done on the 261 apartment complexes built through 2016 in Busan. The analysis shows that $I^0$ type, to represent 'typical boring architectural shape' of Korean apartments, has been dominant until the year 2000. However, its portion has become drastically decreased since the mid-2000. Composite plan type, the geometrical precedents of which had never been existent, emerged in the mid-2000, and this phenomenon may symbolize the change of morphology of apartment. When tower plan types are grouped together according to geometrical shape, three types, I-type, L-type and Y-type, take the most of residential towers, explaining 97% of the total. As expected, I-type is the most dominant, but its influence has decreased as time passes. Y-type might become one of the most important type in the period V. L-type has become the leading type in the Period VI to exceed I-type by 12 percent.

Vegetation filtering techniques for LiDAR data of levees using combined filters with morphology and color (형태와 색상의 복합형 필터를 이용한 제방 LiDAR 측량 데이터의 식생 영상 제거 기법 연구)

  • Park, Heeseong;Lee, Du Han
    • Journal of Korea Water Resources Association
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    • v.56 no.2
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    • pp.139-150
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    • 2023
  • Terretial LiDAR surveying is highly useful for maintenance of civil facilities as it can easily detect the temporal deformation of structures or topography. However, for river facilities such as levess, it is difficult to detect the deformation of the topography or structure under vegetations due to the influence of vegetation. Vegetation filters can be divided into color filters and morphological filters. In this study, combined filters with color and morphology are developed to improve the accuracy of vegetation filters. 8 color filters, 6 morphological filters, and 4 combined filters are applied to the vegetation removal on the embankment slope, and their accuracy and calculation time are compared. Color filters show a short calculation time, but the accuracy was low in the vegetation area. Morphological filters show high accuracy in the vegetation area, but low accuracy in places with severe local topographical changes such as heavy rocks. Combined filters also show a tendency similar to morphological filters, but in the case of ExGGM, the accuracy is excellent in both the vegetation and rock area. Considering the accuracy and calculation time, the combined filter ExGGM is suitable for general cases, and the shape filter GrMIn or the complex filter ExGISL is suitable for cases where the local topographical change is not severe.

Hydrological Characteristics of the Naeseong Stream before the Operation of Yeongju Dam, Korea (영주댐 운영 전 내성천의 수문 특성)

  • Kim, Donggu;Lee, Chanjoo
    • Ecology and Resilient Infrastructure
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    • v.4 no.1
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    • pp.3-11
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    • 2017
  • In this study, change in vegetation on bars was analyzed using the data on hydrology and river morphology with on-site photographic monitoring data for the sites of interest of the Naeseong Stream during the period from March 2013 to July 2016 when the impoundment of Yeongju Dam began. The effect of flow condition on burial and removal of vegetation covered on bar surfaces was elucidated by comparison of on-site photographic monitoring data with continuous water level plotted with on the cross-section profile. In 2014 burial happened due to late flood, while July flood caused burial and removal in 2016. On the contrary vegetation increased in 2015 due to low flow without flood. Results of this study showing natural changes in vegetation will be reference to changes which is expected to be caused by dam impoundment.

Self Healing System for Concrete Surface Crack using Polymer based Coating Agent Incorporating Microencapsulated Healing Agent (마이크로캡슐을 함유한 폴리머 코팅제의 콘크리트 표면균열 자기치유시스템)

  • Shin, Ki-Su;Ryu, Byung-Chul;Wang, Xiao-Yong;Park, Ki-Bong
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.6
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    • pp.579-587
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    • 2015
  • In this paper, microencapsulated healing agent was embedded in the polymer matrix to obtain self healing properties. Microencapsulation of methacrylate using polyurea-formaldehyde as a shell material and studied the effect of agitation rate on capsule characteristics such as size, shell thickness, and surface morphology. The formation of microcapsules was confirmed by FTIR and TGA, and capsule characteristics were studied by optical microscopy and SEM. The self-healing effect was evaluated using permeability measurements and further confirmed by surface analytical tools including optical microscope. According to the experimental results, the microencapsulated healing system has the self-heaing ability for artificial cracks.

Improvement in Water Resistance of Desulfurized Gypsum by Novel Modification of Silicone Oil Paraffin Composite Emulsion-based Waterproofing Agent

  • Cao, Jing-Yu;Li, Jin-Peng;Jiang, Ya-Mei;Wang, Su-Lei;Ding, Yi;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.56 no.6
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    • pp.558-565
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    • 2019
  • In this study, dimethyl silicone oil and liquid paraffin were combined and subsequently emulsified; the resulting mixture was innovatively incorporated into desulfurized gypsum to resolve its drawback of a poor water resistance. The waterproof mechanism of the composite emulsion and liquid paraffin emulsion with mass fractions of 1%, 2%, 3%, and 4% were investigated. The effect of the desulfurized gypsum on the waterproof performance and basic mechanical properties were also investigated. The configuration of the composite waterproofing agent was characterized by FTIR and 1HNMR. The results showed that, compared with the traditional liquid paraffin emulsion-based waterproofing agent, the softening coefficient of the silicone oil paraffin composite emulsion-based water-repellent agent was increased by 60% and attained a value of 0.89. Combined with the waterproof mechanism and microscope morphology analysis of gypsum hydration products, the improvement in the water resistance of water resistance was primarily attributed to the formation of a silicone hydrophobic membrane between the crystals of the gypsum block; this ensured that water could not penetrate the crystal.

Analysis of the fracture surface morphology of concrete by the method of vertical sections

  • Konkol, Janusz;Prokopski, Grzegorz
    • Computers and Concrete
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    • v.1 no.4
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    • pp.389-400
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    • 2004
  • The examinations carried out have confirmed a relationship existing between the character of fracture surfaces and the composition and structure of (basalt and gravel) concretes. For both concretes investigated, a very good correlation was obtained between the profile line development factor, $R_L$, and the fracture surface development factor, $R_S$. With the increase in the $R_L$ parameter, the fracture surface development factor $R_S$ also increased. Agreement between the proposed relationship of $R_S=f(R_L)$ and the proposal given by Coster and Chermant (1983) was obtained. Stereological examinations carried out along with fractographic examinations made it possible to obtain a statistical model for the determination of $R_L$ (or $R_S$) based on the volume of air voids in concrete, $V_{air}$, the specific surface of air pores, $S_V_{air}$ the specific surface of coarse aggregate, $S_{Vagg.}$, and the volume of mortar, $V_m$. An effect of coarse aggregate type on the obtained values of the profile line development factor, $R_L$, as well as on the relationship $R_S=f(R_L)$ was observed. The increment in the fracture surface development factor $R_S$ with increasing $R_L$ parameter was larger in basalt concretes than in gravel concretes, which was a consequence of the level of complexity of fractures formed, resulting chiefly from the shape of coarse aggregate grains.

Comparative Analysis of Filtering Techniques for Vegetation Points Removal from Photogrammetric Point Clouds at the Stream Levee (하천 제방의 영상 점군에서 식생 점 제거 필터링 기법 비교 분석)

  • Park, Heeseong;Lee, Du Han
    • Ecology and Resilient Infrastructure
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    • v.8 no.4
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    • pp.233-244
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    • 2021
  • This study investigated the application of terrestrial light detection and ranging (LiDAR) to inspect the defects of the vegetated levee. The accuracy of vegetation filtering techniques was compared by applying filtering techniques on photogrammetric point clouds of a vegetated levee generated by terrestrial LiDAR. Representative 10 vegetation filters such as CIVE, ExG, ExGR, ExR, MExG, NGRDI, VEG, VVI, ATIN, and ISL were applied to point cloud data of the Imjin River levee. The accuracy order of the 10 techniques based on the results was ISL, ATIN, ExR, NGRDI, ExGR, ExG, MExG, VVI, VEG, and CIVE. Color filters show certain limitations in the classification of vegetation and ground and classify grass flower image as ground. Morphological filters show a high accuracy of the classification, but they classify rocks as vegetation. Overall, morphological filters are superior to color filters; however, they take 10 times more computation time. For the improvement of the vegetation removal, combined filters of color and morphology should be studied.

Low Cost Alcoholic Breath Sensor Based on SnO2 Modified with CNTs and Graphene

  • Morsy, M.;Yahia, I. S.;Zahran, H.Y.;Ibrahim, M.
    • Journal of the Korean Physical Society
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    • v.73 no.10
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    • pp.1437-1443
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    • 2018
  • In this work, $SnO_2$ modified with reduced graphene oxide (rGO) and carbon nanotubes (CNTs) separately and combined sensitized by using the co-precipitation method and their sensing behavior toward ethanol vapor at room temperature were investigated. An interdigitated electrode (IDE) gold substrate is very expensive compared to a fluorine doped tin oxide (FTO) substrate; hence, we used the latter to reduce the fabrication cost. The structure and the morphology of the studied materials were characterized by using differential thermal analyses (DTA) and thermogravimetric analysis (TGA), transmission electron microscope (TEM), X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, Brunauer-Emmett-Teller surface area and Barrett-Joyner-Halenda (BJH) pore size measurements. The studied composites were subjected to ethanol in its gas phase at concentrations from 10 to 200 ppm. The present composites showed high-performance sensitivity for many reasons: the incorporation of $SnO_2$ and CNTs which prevents the agglomeration of rGO sheets, the formation of a 3D mesopourus structure and an increase in the surface area. The decoration with rGO and CNTs led to more active sites, such as vacancies, which increased the adsorption of ethanol gas. In addition, the mesopore structure and the nano size of the $SnO_2$ particles allowed an efficient diffusion of gases to the active sites. Based on these results, the present composites should be considered as efficient and low-cost sensors for alcohol.