• 한국재료학회지
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• 제19권3호
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• pp.119-124
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• 2009

In the microelectronics packaging industry, the adhesion strength between Cu and polyimide and the thermal stability are very important factors, as they influence the performance and reliability of the device. The three different buffer layers of Cr, 50%Cr-50%Ni, and Ni were adopted in a Cu/buffer layer/polyimide system and compared in terms of their adhesion strength and thermal stability at a temperature of $300^{\circ}C$ for 24hrs. A 90-degree peel test and XPS analysis revealed that both the peel strength and thermal stability decreased in the order of the Cr, 50%Cr-50%Ni and Ni buffer layer. The XPS analysis revealed that Cu can diffuse through the thin Ni buffer layer ($200{\AA}$), resulting in a decrease in the adhesion strength when the Cu/buffer layer/polyimide multilayer is heat-treated at a temperature of $300^{\circ}C$ for 24hrs. In contrast, Cu did not diffuse through the Cr buffer layer under the same heat-treatment conditions.

• 토지주택연구
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• 제10권4호
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• pp.41-50
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• 2019

This study was started to study the buffer zone of Daejeon metropolitan city in order to study the policy and environment for the suitability evaluation of the use of green buffer zone. The target of the study was selected as the buffer zone of western buffer, which is frequently used in the Daejeon Metropolitan City, and a preliminary index was selected to evaluate the suitability of the green buffer zone. AHP analysis was conducted to increase the reliability of the preliminary indicators and the weight was analyzed by questionnaires to experts and practitioners. In addition, based on the existing statistical data, we rebuilt the green buffer zone and investigated the current condition, and compared and analyzed the green buffer zone and the places where they did not. The results are as follow. First, unlike the statute interpretation that construction can not be done in buffered green spaces, green buffer zones have been utilized in various ways. However, the lack of advanced citizen consciousness of the residents, the responsibility of the responsible person, and the problem of the management office alone are causing problems. Second, according to the results of AHP questionnaire analysis, functional and stability among the appropriateness indexes of green buffer zone utilization were evaluated highly. Park accessibility and utilization potential also weighed somewhat, and it was judged that the epochal trend was more important in the use of green buffer zones. Third, analysis of the status of Western green buffer zones in Daejeon showed that the utilization rate was more than half. This suggests the necessity of judging the appropriateness of the application of the green buffer zone effectively due to the change of the perception of the green buffer zone of the residents. Fourth, as a result of comparing and analyzing the site where the site is used and the site where it is not, it is found that it is used within a range that does not greatly affect each index. However, as the stability has decreased, we have decided that the utilization method is most damaging to the green zone, and we should strive to improve the stability in future. Finally, the analysis of a red clay road and a red clay road sites decreased from Class I of stability to Grade II. However, the fall figure showed a difference between the 13 % drop rate of the target location and the 5% decline rate of utilization. The difference was analyzed as the difference of width of a red clay road. This can be regarded as one of the ways of damaging the green zone to the minimum extent, which is a great advantage in selecting the future utilization plan.

• The Journal of Asian Finance, Economics and Business
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• 제9권3호
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• pp.347-354
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• 2022

This article examines the influence of Basel III reforms, risk management, and banking sector efficiency on banks' financial stability in emerging countries. The data for this study is collected from various sources. Based on the GDP classification of IMF, the top 22 countries were selected as the sample. The sampling frame includes all six regions of the world including 482 banks and 3022 observations in total. The empirical analysis is carried out by estimating the random effects models. It is found that the effects of capital buffer, liquidity, and risk management practices are significant on financial stability. It is also noticed that the capital buffer has a constructive and significant influence on financial stability. However, liquidity management shows a mixed impact, as in some countries, its impact is positive and significant while, in other countries, it is insignificant. Risk management practices have an overall positive influence on financial stability in the case of large economies. However, results are insignificant in the case of small economies. Bank-specific variables, namely profitability, size, and efficiency have a positive whereas, loan quality has a negative impact on financial stability in the emerging countries. GDP has a positive impact on financial stability whereas inflation and unemployment both have a negative effect on financial stability.

• 한국멀티미디어학회논문지
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• 제5권3호
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• pp.249-254
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• 2002

본 논문에서는 영상압축을 위한 버퍼제약에 의한 적응양자화 알고리즘에 대해서 논하고져 한다. 버퍼제약에 의한 알고리즘은 source coding과 더불어 그간 연구되다가, 최근에는 비트율 왜곡의 이름으로 연구가 더욱 진전돼 오고 있다. 여기에서 우리는 버퍼 occupancy의 값이 비트율 왜곡의 측정치에서 Lagrange multiplier 형식으로 통합되는 것을 제안한다. 여기서 제안하는 알고리즘이 Viterbi 알고리즘과는 반대로 최적치에는 약간 못미치는 성능을 보여주지만, 대신 계산의 복잡도가 매우 낮을 뿐 아니라, 버퍼 제어 알고리즘의 안정도를 Liapnov의 안정화이론을 이용해서 간단하게 설명 할 수 있다는 것이다.

• 마이크로전자및패키징학회지
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• 제28권3호
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• pp.17-24
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• 2021

페로브스카이트 태양전지는 용액공정으로 제작되어 공정 중 전구체 조성제어를 통해 밴드갭을 용이하게 조절할 수 있다. 탠덤 태양전지의 상부셀로 활용하여 실리콘 태양전지와 접합 시 30% 이상의 효율 달성이 가능하지만, 페로브스카이트 태양전지의 낮은 안정성이 상용화의 걸림돌로 작용하고 있다. 아이오딘 이온 및 전극 물질 확산이 주된 열화기구로 알려져 있어 장기 안정성을 확보하기 위해서는 이러한 이온 이동의 방지가 필요하다. 본 연구에서는 층간소재와 페로브스카이트 광활성층 사이의 이온이동에 의한 열화현상을 관찰하고, 이를 억제하기 위해 페로브스카이트 소재와 은전극 사이에 버퍼층을 도입하여 소자의 안정성을 확보하였다. 85℃에서 300시간 이상 보관 시 버퍼가 없는 소자는 페로브스카이트 층이 PbI₂ 및 델타상으로 변화하며 변색되었으며 AgI가 형성되는 것을 확인했다. LiF와 SnO₂ 버퍼 도입 시 이온이동 억제 효과를 통해 페로브스카이트 태양전지의 열안정성이 향상되었다. LiF버퍼층 적용 및 봉지를 한 소자는 85℃-85%RH damp heat 시험 200시간 후 효율감소가 발생하지 않았으며 추가로 AM 1.5G-1SUN 하에서 최대출력점을 추적하였을 때 200시간 후 초기 효율의 90% 이상 유지하는 것을 확인했다. 이 결과는 버퍼층 형성을 통한 층간 물질이동 억제가 장기안정성을 확보하기 위한 필요조건임을 보여준다.

• 대한화장품학회지
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• 제37권1호
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• pp.55-60
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• 2011

본 연구에서는 DOPC 리포좀의 안정성에 대한 염의 영향을 알아보기 위하여 증류수, phosphate buffer, 그리고 phosphate bufferd saline으로 리포좀을 제조하였다. 그리고 염의 추가에 따른 리포좀의 입자크기 및 제타전위 등 기본적인 물성 변화를 확인하였다. 그에 앞서 희석에 대한 영향을 알아보고자 리포좀을 각각 제조시 용매로 40배와 80배로 희석하였고 그 결과 같은 용매로 희석시킬 경우 40배 희석까지는 안정한 것을 확인하였다. 증류수로 제조한 리포좀을 증류수, phosphate buffer, 그리고 phosphate buffered saline으로 희석하였고, phosphate buffer로 제조한 리포좀은 phosphate buffer, 그리고 phosphate buffered saline으로 희석하여 염 농도 증가에 따른 리포좀의 입자크기 및 제타전위 변화를 확인하였다. 그 결과 리포좀 분산액 내에 존재하는 염의 양이 증가할수록 리포좀의 입자크기가 약간씩 작아지는 경향을 나타내었고, 제타전위 또한 염의 양이 증가할수록 0에 가까워지는 경향을 나타내었다. 결론적으로, 리포좀의 입자크기와 제타전위는 리포좀의 안정성을 판단할 수 있는 좋은 요소이며 또한 리포좀 제조시의 용매와 다른 조건의 염농도는 리포좀 입자의 안정성에 큰 영향을 줄 수 있다고 사료된다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2008년도 제39회 하계학술대회
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• pp.1224-1225
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• 2008

The results of the experiment that was conducted on the electron emission property and the long-term stability of the emission current in various carbon nanotubes (CNTs)-based field emitters with a CNT/catalyst/buffer/W-tip configuration are presented herein. CNT-based field emitters were fabricated by varying the (TiN, Al/Ni/TiN) buffer layer and the (Ni, Co) catalyst material. This study aimed to elucidate how the buffer layers and catalyst materials affect the structural properties of CNTs and the long-term stability of CNT emitters. Raman spectroscopy, field emission SEM, and high-resolution TEM were used to analyze the crystalline structure, surface morphologies, and nanostructures of all the grown CNTs. X-ray photoelectron spectroscopy (XPS) was used to monitor the chemical bonds of all the buffer layers and catalysts. Electron emission measurement and a long-term (up to 40h) stability test were carried out using a compactly designed field emission measurement system.

• Transactions on Electrical and Electronic Materials
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• 제8권6호
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• pp.260-264
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• 2007

We have studied stability in organic light-emitting diode depending on buffer layer and cathode. A transparent electrode of indium-tin-oxide(ITO) was used as an anode. An electron injection energy barrier into organic material is different depending on a work function of cathodes. Theoretically, the energy barriers for the electron injection are 1.2 eV, -0.1 eV, and 0.0 eV for Al, LiAl, and LiF/Al at 300 K, respectively. We considered the cases that holes are injected to organic light-emitting diode. The hole injection energy barrier is about 0.7 eV between ITO and TPD without buffer layer. For hole-injection buffer layers of CuPc and PEDOT:PSS, the hole injection energy barriers are 0.4 eV and 0.5 eV, respectively. When the buffer layer of CuPc and PEDOT:PSS is existed, we observed the effects of hole injection energy barrier, and a reduction of operating-voltage. However, in case of PVK buffer layer, the hole injection energy barrier becomes high(1.0 eV). Even though the operating voltage becomes high, the efficiency is improved. A device structure for optimal lifetime condition is ITO/PEDOT:PSS/TPD/$Alq_3$/LiAl at an initial luminance of $300cd/m^2$.

• Journal of Pharmaceutical Investigation
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• 제29권4호
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• pp.337-341
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• 1999

We have studied the stability and transdennal flux of prostaglandin $E_1\;(PGE_1)$ from various donor solutions through hairless mouse skin. Stability in HEPES buffer or in propylene glycol (PG) solution where enhancer (oleic acid (OA), propylene glycol monolaurate (PGML), transcutol (TC), ethanol (EtOH))s dissolved was investigated. $$PGE_1 was not stable in HEPES buffer. The concentration of $$PGE_1 decreased continuously for 7 days, and the degradation rate constant was $0.0028\;h^{-1}$, assuming first order reaction. The effect of current or penetration enhancer on the degradation was minimal. Percutaneous transport from HEPES buffer by passive or iontophoretic delivery without enhancer was close to nil. When OA or PGML was used together with PG, both passive and iontophoretic flux increased. PGML showed better enhancing effect than OA. Flux by cathodal delivery was about 2 times larger than that by passive delivery. Flux by anodal delivery was lower than that by passive delivery. TC and EtOH also increased the transdermal flux, but the effect was not as good as that observed when OA or PGML was used. These stability and flux data provide important information on how to formulate the patch, which will be the next step of this work, and on the polarity of current to use during iontophoresis.

• 방사성폐기물학회지
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• 제18권spc호
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• pp.21-36
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• 2020

With respect to spent nuclear fuels, disposal containers and bentonite buffer blocks in deep geological disposal systems are the primary engineered barrier elements that are required to isolate radioactive toxicity for a long period of time and delay the leakage of radio nuclides such that they do not affect human and natural environments. Therefore, the thermal stability of the bentonite buffer and structural integrity of the disposal container are essential factors for maintaining the safety of a deep geological disposal system. The most important requirement in the design of such a system involves ensuring that the temperature of the buffer does not exceed 100℃ because of the decay heat emitted from high-level wastes loaded in the disposal container. In addition, the disposal containers should maintain structural integrity under loads, such as hydraulic pressure, at an underground depth of 500 m and swelling pressure of the bentonite buffer. In this study, we analyzed the thermal stability and structural integrity in a deep geological disposal environment of the improved deep geological disposal systems for domestic light-water and heavy-water reactor types of spent nuclear fuels, which were considered to be subject to direct disposal. The results of the thermal stability and structural integrity assessments indicated that the improved disposal systems for each type of spent nuclear fuel satisfied the temperature limit requirement (< 100℃) of the disposal system, and the disposal containers were observed to maintain their integrity with a safety ratio of 2.0 or higher in the environment of deep disposal.