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Kinetic and multi-parameter isotherm studies of picric acid removal from aqueous solutions by carboxylated multi-walled carbon nanotubes in the presence and absence of ultrasound

  • Gholitabar, Soheila;Tahermansouri, Hasan
    • Carbon letters
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    • v.22
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    • pp.14-24
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    • 2017
  • Carboxylated multi-wall carbon nanotubes (MWCNTs-COOH) have been used as efficient adsorbents for the removal of picric acid from aqueous solutions under stirring and ultrasound conditions. Batch experiments were conducted to study the influence of the different parameters such as pH, amount of adsorbents, contact time and concentration of picric acid on the adsorption process. The kinetic data were fitted with pseudo-first order, pseudo-second-order, Elovich and intra-particle diffusion models. The kinetic studies were well described by the pseudo-second-order kinetic model for both methods. In addition, the adsorption isotherms of picric acid from aqueous solutions on the MWCNTs were investigated using six two-parameter models (Langmuir, Freundlich, Tempkin, Halsey, Harkins-Jura, Fowler-Guggenheim), four three-parameter models (Redlich-Peterson, Khan, Radke-Prausnitz, and Toth), two four-parameter equations (Fritz-Schlunder and Baudu) and one five-parameter equation (Fritz-Schlunder). Three error analysis methods, correlation coefficient, chi-square test and average relative errors, were applied to determine the best fit isotherm. The error analysis showed that the models with more than two parameters better described the picric acid sorption data compared to the two-parameter models. In particular, the Baudu equation provided the best model for the picric acid sorption data for both methods.

Removal of Methylene Blue by Modified Carbon Prepared from the Sambucus Nigra L. plant

  • Manoochehri, Mahboobeh;Amooei, Khadijeh
    • Carbon letters
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    • v.14 no.1
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    • pp.27-33
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    • 2013
  • An increase in population initiating rapid industrialization was found to consequently increase the effluents and domestic wastewater into the aquatic ecosystem. In this research the potentialities of Sambucus nigra L. (SNL) plant in the remediation of water, contaminated with methylene blue (MB), a basic dye were investigated. SNL was chemically impregnated with $KHCO_3$. Operating variables studied were pH, amount of adsorbent and contact time. In general, pH did not have any significant effect on colour removal and the highest adsorption capacity was obtained in 0.035 g MB/g-activated carbon. The Langmuir, Freundlich, Temkin and Dubinin-Radushkevich adsorption models were applied to describe the equilibrium isotherms. The adsorption isotherm data were fitted to the Temkin isotherm. The mass transfer property of the sorption process was studied using Lagergren pseudo-first-order and chemisorption pseudo-second-order kinetic models. The sorption process obeyed the pseudo-second-order kinetic model. The surface area, pores volume and diameter were assessed by the Brunauer-Emmett-Teller and Barrett-Joyner-Halenda methods. The results were compared to those from activated carbon (Merck) and an actual sample. The results indicate that SNL can be employed as a natural and eco-friendly adsorbent material for the removal of dye MB from aqueous solutions.

Improved Differential Detection Scheme of Space-Time Trellis Coded MDPSK For MIMO (MIMO에서 시공간 부호화된 MDPSK의 성능을 향상시키기 위한 차동 검파 시스템)

  • Kim, Chong-Il;Lee, Ho-Jin;Yoo, Hang-Youal;Kim, Jin-Yong;Kim, Seung-Youal
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.10 no.10
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    • pp.1869-1876
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    • 2006
  • Recently, STC techniques have been considered to be candidate to support multimedia services in the next generation mobile radio communications and have been developed the many communications systems in order to achieve the high data rates. In this paper, we Nose the Trellis-Coded Differential Space Time Modulation system with multiple symbol detection. The Trellis-code performs the set partition with unitary group codes. The Viterbi decoder containing new branch metrics is introduced in order to improve the bit error rate (BER) in the differential detection of the unitary differential space time modulation. Also, we describe the Viterbi algorithm in order to use this branch metrics. Our study shows that such a Viterbi decoder improves BER performance without sacrificing bandwidth and power efficiency.

Role of modified activated carbon by H3PO4 or K2CO3 from natural adsorbent for removal of Pb(II) from aqueous solutions

  • Manoochehri, Mahboobeh;Khorsand, Ameneh;Hashemi, Elham
    • Carbon letters
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    • v.13 no.2
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    • pp.115-120
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    • 2012
  • Most heavy metals are well-known toxic and carcinogenic agents and when discharged into wastewater represent a serious threat to the human population and the fauna and flora of the receiving water bodies. The present study aims to develop a procedure for Pb(II) removal. The study was based on using powdered activated carbon, which was prepared from walnut shells generated as plant wastes and modified with potassium carbonate or phosphoric acid as chemical agents. The main parameters, such as effect of pH, effect of sorbent dosage, Pb(II) concentrations, and various contact times influence the sorption process. The experimental results were analyzed by using Langmuir, Freundlich, Tempkin and Dubinin-Radushkevich adsorption models. The kinetic study of Pb(II) on activated carbon from walnut shells was performed based on pseudo-first order and pseudo-second order equations. The data indicate that the adsorption kinetics follow the pseudo-second order rate. The procedure was successfully applied for Pb(II) removal from aqueous solutions.

SER Analysis of QAM with Space Diversity in Rayleigh Fading Channels

  • Kim, Chang-Joo;Kim, Young-Su;Jeong, Goo-Young;Mun, Jae-Kyung;Lee, Hyuck-Jae
    • ETRI Journal
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    • v.17 no.4
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    • pp.25-35
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    • 1996
  • This paper derives the symbol error probability for quadrature amplitude modulation(QAM) with L-fold space diversity in Rayleigh fading channels. Two combining techniques, maximal ratio combining(MRC) and selection combining(SC), are considered. The formula for MRC space diversity is obtained by averaging the symbol error probability of M-ary QAM in an additive white Gaussian noise(AWGN) channel over a chi-square distribution with 2L degrees of freedom. The obtained formula overcomes the limitations of the earlier work, which has been limited only to deriving the symbol error rate(SER) of QAM with two branch MRC space diversity. The formula for SC space diversity is obtained by averaging the symbol error probability of M-ary QAM in an AWGN channel over the distribution of the maximum signal-to noise ratio among all of the diversity channels for SC space diversity has been reported yet. Analytical results show that the probability of error decreases with the order of diversity gain per additional branch decreases as the number of branches becomes larger. On the other hand, the performance of 16 QAM with MRC becomes much better than that of SC as the number of branches becomes larger. By giving the order of diversity, L, and the number of signal points, M, we have been able to obtain the SER performance of QAM with general space diversity. These results can be used to determine the order of diversity to achieve the desired SER in land mobile communication system employing QAM modulation.

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Multiple Symbol Detection of Trellis coded Differential space-time modulation for OFDM (OFDM에서 트렐리스 부호화된 차동 시공간 변조의 다중 심벌 검파)

  • 유항열;한상필;김진용;김성열;김종일
    • Journal of the Institute of Convergence Signal Processing
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    • v.5 no.3
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    • pp.223-229
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    • 2004
  • Recently, OFDM and STC techniques have been considered to be candidate to support multimedia services in the next generation mobile radio communications and have been developed the many communications systems in order to achieve the high data rates. In this paper, we propose the Trellis-Coded Differential Space Time Modulation-OFDM system with multiple symbol detection. The Trellis-code performs the set partition with unitary group codes. The Viterbi decoder containing new branch metrics is introduced in order to improve the bit error rate (BER) in the differential detection of the unitary differential space time modulation. Also, we describe the Viterbi algorithm in order to use this branch metrics. Our study shows that such a Viterbl decoder improves BER performance without sacrificing bandwidth and power efficiency.

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Performance Improvement of Single Chip Multiprocessor using Concurrent Branch Execution (분기 동시 수행을 이용한 단일 칩 멀티프로세서의 성능 개선)

  • Lee, Seung-Ryul;Kim, Jun-Shik;Choi, Jae-Hyeok;Choi, Sang-Bang
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.44 no.2
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    • pp.61-71
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    • 2007
  • The instruction level parallelism, which has been used to improve the performance of processors, expose its limit. The change of a control flow by a branch miss prediction is one of the obstacles that restrict the instruction level parallelism. The single chip multiprocessors have been developed to utilize the thread level parallelism. However, we could not use the maximum performance of the single chip multiprocessor in case of executing the coded programs without considering the multi-thread. In order to overcome the two performance degradation factors, in this paper, we suggest the concurrent branch execution method that applies to the multi-path execution method at a single chip multiprocessor. We executes all two flows of the conditional branch using the idle core processor. Through this, we can improve the processor's efficiency with blocking the control flow termination by the branch instruction and reducing the idle time. We analyze the effects of concurrent branch execution proposed in this paper through the simulation. As a result of that, concurrent branch execution reduces about 20% of idle time and improves the maximum 10% of the branch prediction accuracy. We show that our scheme improves the overall performance of maximum 39% compared to the normal single chip multiprocessor and maximum 27% compared to the superscalar processor.

Survey of mastitis management and incidence of mastitis in high somatic cell count of bulk milk at dairy farms in the Gyeongnam (경남지역의 체세포수 문제 목장에서의 젖소 유방염 관리실태 및 발생양상 조사)

  • Kim, Seong-Eun;Hah, Do-Yun;Jang, Eun-Hee;Kwon, Hee-Nyung;Jo, Seong-Suk;Kwon, Young-Taek;Park, Dong-Yeop;Lee, Kuk-Cheon;Kim, Jong-Shu
    • Korean Journal of Veterinary Service
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    • v.34 no.4
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    • pp.379-388
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    • 2011
  • Survey of mastitis management and incidence of mastitis in the Gyeongnam was started in May to September 2009 to solve mastitis problem statistically valid data for use in estimating mastitis management, isolation and antimicrobial drug susceptibility in 30 dairy farms having over 350,000/ml somatic cell count. In investigation on recognition of farmer about bovine mastitis, the ratio of understanding of differences between infectious and environmental origin, understanding of correlation between superbacteria and using indiscriminate, necessity of pathogen identification, and necessity of antimicrobial sensitivity tests were 80.0%, 73.3%, 33.3%, and 53.3%, respectively. In survey of mastitis management type, regular california mastitis test (CMT), conducting CMT test and empirical self-treatment, when detecting suspected cows, were 30.0%, 40.0%, and 46.7%, respectively. Checking and cleaning pulsators biweekly, cleaning vacuum system and replacing liners every 3~6 month, and getting milking system checked by engineers showed 80.0%, 76.7%, and 76.7% in the questionnaires, respectively. In recognition of farmer about milking hygiene for prevention of bovine mastitis, using individual towels, separated milking (milking order of cows), and teat-dipping disinfection after milking exhibited 13.3%, 86.7%, and 93.3%, respectively. In conclusion, through the questionnaires and laboratory test, we suggest that recognition of farmer about management and incidence of mastitis was very low, thus systemic educational program and public relations about mastitis management were need for dairy farmers.

Experimental crack analyses of concrete-like CSCBD specimens using a higher order DDM

  • Haeri, Hadi
    • Computers and Concrete
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    • v.16 no.6
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    • pp.881-896
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    • 2015
  • A simultaneous analytical, experimental and numerical analysis of crack initiation, propagation and breaking process of the Central Straight through Crack Brazilian Disk (CSCBD) specimens under diametrical compression is carried out. Brazilian disc tests are being accomplished to evaluate the fracturing process based on stress intensity factors (SIFs). The effects of crack inclination angle and crack length on the fracturing processes have been investigated. The same experimental specimens have been numerically modeled by a higher order indirect boundary element method (HDDM). These numerical results are compared with the existing experimental results proving the accuracy and validity of the proposed numerical method.

Global Positioning System and Strengthening of Geodetic Network of Nepal

  • Adhikary, Krishna Raj;Mahara, Shree Prakash
    • Proceedings of the KSRS Conference
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    • 2003.11a
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    • pp.955-958
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    • 2003
  • Nepal is a country of mountains The higher order geodetic points were mostly established on the top of mountains and these points were used for the geodetic network extension. Lower order geodetic control networks were established at different times and used for the surveying and mapping activities of the country.. It has been found that the rate of convergence between north and south borders of Nepal to be 21${\pm}$2 mm each year and the rate translation of Kathmandu to 55${\pm}$3 mm/year to the plates. The most intense deformation in Nepal occurs along the belt of high mountains along its northern border res ulting in a strain contraction rate normal to the Himalayan Arc. This belt is approximately 40 km wide and extends into southern Tibet.( 13). Recently Survey Department of Nepal has lunched a program of strengthening the existing geodetic network of Nepal and re-observed the position of higher order geodetic points by using geodetic GPS receivers to evaluate their position and thus to define the precision of the control points once again. This paper describes the observation procedure and the adjustment results of the existing higher order control network of Nepal established in different time using different types of equipment and techniques; and highlights the observation procedure and the result obtained after the post processing of the GPS observation results. Attempt has been made to give the procedure and identify the methodology for the re observation of existing higher order geodetic points by using GPS receiver and post processing the observed data so that the existing higher order geodetic points are within the given accuracy standard.

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