• Journal of the Korean Ceramic Society
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• v.46 no.2
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• pp.146-154
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• 2009

It is necessary to minimize the thickness of Ni inner electrode layer and to improve the coverage of inner electrode, for the purpose of developing the ultra high-capacity multi layered ceramic capacitor (MLCC). Thus, low temperature sintering of dielectric $BaTiO_3$ ceramic should be precedently investigated. In this work, the relationship between dielectric properties of MLCC and batch condition such as mixing and milling methods was investigated in the $BaTiO_3$(BT)-Dy-Mg-Ba system with borosilicate glass as a sintering agent. In addition, several chip properties of MLCC manufactured by low temperature sintering were compared with conventionally manufactured MLCC. It was found that low temperature sintered MLCC showed better DC-bias property and lower aging rate. It was also confirmed that the thickness of Ni inner electrode layer became thinner and the coverage of inner electrode was improved through low temperature sintering.

• Journal of the Microelectronics and Packaging Society
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• v.8 no.3
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• pp.31-36
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• 2001

Dielectric material which is suitably designed for the application of the high-temperature electrostatic chucks(HTESCS) has been developed. Electrical resistivities and dielectric constants of the dielectric layer satisfy the demands for the proper operation of HTESC, and coefficient of thermal expansion(CTE) of the dielectric material matches well that of the bottom insulator so that it secures stable structure. In order to minimize particle contaminations, borosilicate glass(BSG) is selected as a bonding layer between dielectric layer and bottom insulator, and silver is used as a electrode. BSG is solidly bonded between upper dielectric and bottom insulator, and no diffusions or reactions are observed among silver electrode, dielectric, and glass layers. The chucking characteristics of the fabricated HTESC are found to be superior to those of the commercialized one.

• Journal of the Korean Ceramic Society
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• v.50 no.6
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• pp.416-422
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• 2013

Cullet-loess tile bodies are successfully fabricated using cullet, loess, hollow microspheres, and sintering additives (borosilicate glass frit, boric acid, or fumed silica) as starting materials. The effects of the additive composition and sintering temperature on the sintered density and flexural strength of the cullet-loess tile bodies are investigated. The sintered density of the cullet-loess tile bodies increases with an increase in the sintering temperature as a result of the enhanced densification of pore walls through the viscous flow of a liquid phase formed from the glass frit and sintering additives. The flexural strength of the cullet-loess tile bodies increases with increases in the sintering temperature and the cullet content in the starting composition. A maximal flexural strength of 40 MPa is obtained in cullet-loess tile bodies sintered with glass frit at $800^{\circ}C$ in air.

• Proceedings of the KIEE Conference
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• 2000.07c
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• pp.1791-1793
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• 2000

본 연구에서는 다결정 실리콘 박막 트랜지스터(poly-Si TFTs)에서의 소오스 및 드레인 영역 형성을 위해 PSG (phosphosilicate glass)와 BSG (borosilicate glass) 박막을 도핑 물질(dopant)로 하여 저온에서 엑시머 레이저(eximer laser)로 활성화하는 공정을 제안한다. 이 실험을 통해 소스 가스인 $PH_3$와 $SiH_4$의 유량비, 레이저 에너지 밀도와 레이저 조사 횟수를 변화시키면서 면저항(sheet resistance)과 불순물의 확산 깊이(diffusion depth)를 성공적으로 조절하였다. 불순물의 확산 깊이와 표면 농도는 레이저 에너지 밀도와 조사 횟수를 증가시킴에 따라 증가하였으며 그 결과 최소 면저항 값은 인(P)의 경우 450$\Omega/\square$을 얻었고 붕소(B)의 경우 1100$\Omega/\square$을 얻었다. 이러한 실험결과는 제안된 방법을 통해 poly-Si TFTs 에서 소오스, 드레인 영역의 도핑 공정을 수행할 수 있음을 보여준다.

• Journal of the Korean Ceramic Society
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• v.31 no.4
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• pp.427-435
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• 1994

Cu-metallized low firing temperature substrates were synthesized by cofiring green sheet of cordierite-based glass with Cu. By Sol-Gel method, Cu powder was coated with borosilicate gel which should act as a glass frit in Cu paste during cofiring. Theoretical weight ratios of Glass/Cu were controlled to be 2.5, 5, 10 and 15% by varying alkoxide concentrations. Average particle size of coated Cu was 0.629~0.674 ${\mu}{\textrm}{m}$ in comparison to that of as-received Cu(0.596 ${\mu}{\textrm}{m}$), which increased with alkoxide concentration but did not increase above certain concentration. The weight ratios of coated layer were 2.11~5.37%. The properties of Cu-metallized low firing temperature substrate, cofired at 90$0^{\circ}C$ for 1h under H2/N2 atmosphere, were as follows; sheet resistance was 13~43 m{{{{ OMEGA }}/$\square$, adhesion strength was 1.0~2.1 kgf/$\textrm{mm}^2$. From the observations of SEM photographs, the gel coated on Cu performed excellently as a glass frit.

• Tribology and Lubricants
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• v.28 no.5
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• pp.212-217
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• 2012

A modified thermal noise method was proposed to measure the normal spring constants of the colloidal probes for an atomic force microscope. We used commercial tipless cantilevers (length 150, width 30, nominal k 7.4 N/m) and borosilicate spheres with a diameter of 20 to fabricate colloidal probes. The inverse optical lever sensitivity of both the tipless cantilever and colloidal probes were used to measure the normal spring constant of the colloidal probes. We confirmed the accuracy and usefulness of our method by comparing the measurement results with those obtained using the nanoforce calibrator (NFC), which reportedly has an uncertainty of 1.00%. The modified thermal method showed a good agreement (~10% difference) with the NFC, allowing us to conclude that the modified thermal method could be employed for the effective measurement of the normal spring constants of colloidal probes.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.19 no.3
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• pp.339-352
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• 2021

Legacy waste from the decommissioned A-1 nuclear power plant in the Slovak Republic is scheduled for immobilisation within a tailored alkali borosilicate glass formulation, as part of ongoing site cleanup. The aqueous durability and characterisation of a simulant glass wasteform for Chrompik III legacy waste, was investigated, including dissolution experiments up to 112 days (90℃, ASTM Type 1 water). The wasteform was an amorphous, light green glassy product, with no observed phase separation or crystalline inclusions. Aqueous leach testing revealed a suitably durable product over the timescale investigated, comparing positively to other simulant nuclear waste glasses and vitreous products tested under similar conditions. Iron and titanium rich precipitates were observed to form at the surface of monolithic samples during leaching, with the formation of an alkali deficient alteration layer behind these at later ages. Overall this glass appears to perform well, and in line with expectations for this chemistry, although longer-term testing would be required to predict overall durability. This work will contribute to developing confidence in the disposability of vitrified Chrompik legacy wastes.

• Nuclear Engineering and Technology
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• v.54 no.4
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• pp.1343-1354
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• 2022

Experiments were performed to measure the critical heat flux (CHF) on a vertical surface abutting a coarse packed bed of spherical particles. This geometry is representative of a CANDU reactor calandria tubesheet facing the end shield cavity during the in-vessel retention (IVR) phase of a severe accident. Deionized light water was used as the working fluid. Low carbon steel shielding balls with diameters ranging from 6.4 to 12.7 mm were used, allowing for the development of an empirical correlation of CHF as a function of shielding ball diameter. Previously published data is used to develop a more comprehensive empirical correlation accounting for the impacts of both shielding ball diameter and heating surface height. Tests using borosilicate shielding balls demonstrated that the dependence of CHF on shielding ball thermal conductivity is insignificant. The deposition of iron oxide particles transported from shielding balls to the heating surface is verified to increase CHF non-trivially. The results presented in this paper improve the state of the knowledge base permitting quantitative prediction of CHF in the CANDU end shield, refining our ability to assess the feasibility of IVR. The findings clarify the mechanisms governing CHF in this scenario, permitting identification of potential future research directions.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.22 no.2
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• pp.173-183
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• 2024

Vitrification, one of the most promising solidification processes for various materials, has been applied to radioactive waste to improve its disposal stability and reduce its volume. Because the thermal decomposition of dry active waste (DAW) significantly reduces its volume, the volume reduction factor of DAW vitrification is high. The KHNP developed the optimal glass composition for the vitrification of DAW. Since vitrification offers a high-volume reduction ratio, it is expected that disposal costs could be greatly reduced by the use of such technology. The DG-2 glass composition was developed to vitrify DAW. During the maintenance of nuclear power plants, metals containing paper, clothes, and wood are generated. ZrO₂ and HfO₂ are generally considered to be network-formers in borosilicate-based glasses. In this study, a feasibility study of vitrification for DAW that contains metal particulates is conducted to understand the applicability of this process under various conditions. The physicochemical properties are characterized to assess the applicability of candidate glass compositions.

• Tribology and Lubricants
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• v.21 no.5
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• pp.209-215
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• 2005

Nano/micro friction with the contact area was studied on Si-wafer (100) and diamond-like carbon (DLC) film. Borosilicate balls of radii $0.32{\mu}m,\;0.5{\mu}m,\;1.25{\mu}m\;and\;2.5{\mu}m$ mounted on the top of AFM tip (NPS) were used for nano-scale contact and Soda Lime glass balls of radii 0.25mm, 0.5mm, 1mm were used for micro-scale contact. At nano-scale, the friction between ball and surface was measured with the applied normal load using an atomic force microscope (AFM), and at micro scale it was measured using ball-on flat type micro-tribotester. All the experiments were conducted at controlled conditions of temperature $(24\pm1^{\circ}C)$ and humidity $(45\pm5\%)$. Friction was measured as a function of applied normal load in the range of 0-160nN at nano scale and in the range of $1000{\mu}N,\; 1500{\mu}N,\;3000{\mu}N\;and\;4800{\mu}N$ at micro scale. Results showed that the friction at nano scale increased with the applied normal load and ball size for both kinds of samples. Similar behavior of friction with the applied normal load and ball size was observed for Si-wafer at micro scale. However, for DLC friction decreased with the ball size. This difference of in behavior of friction in DLC nano- and microscale was attribute to the difference in the operating mechanisms. The evidence of the operating mechanisms at micro-scale were observed using scanning electron microscope (SEM). At micro-scale, solid-solid adhesion was dominant in Silicon-wafer, while plowing in DLC. Contrary to the nano scale that shows almost a wear-less situation, wear was prominent at micro-scale. At nano- and micro-scale, effect of contact area on the friction was discussed with the different applied normal load and ball size.