• Title/Summary/Keyword: Boron addition

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Application and evaluation of boron nitride-assisted liquid silicon infiltration for preparing Cf/SiC composites

  • Kim, Jin-Hoon;Jeong, Eui-Gyung;Kim, Se-Young;Lee, Young-Seak
    • Carbon letters
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    • v.12 no.2
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    • pp.116-119
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    • 2011
  • C/SiC composites were prepared by boron nitride (BN)-assisted liquid silicon infiltration (LSI), and their anti-oxidation and mechanical properties were investigated. The microstructures, bulk densities, and porosities of the C/SiC composites demonstrated that the infiltration of liquid silicon into the composites improved them, because the layered-structure BN worked as a lubricant. Increasing the amount of BN improved the anti-oxidation of the prepared C/SiC composites. This synergistic effect was induced by the assistance of BN in the LSI. More thermally stable SiC was formed in the composite, and fewer pores were formed in the composite, which reduced inward oxygen diffusion. The mechanical strength of the composite increased up to the addition of 3% BN and decreased thereafter due to increased brittleness from the presence of more SiC in the composite. Based on the anti-oxidation and mechanical properties of the prepared composites, we concluded that improved anti-oxidation of C/SiC composites can be achieved through BN-assisted LSI, although there may be some degradation of the mechanical properties. The desired anti-oxidation and mechanical properties of the composite can be achieved by optimizing the BN-assisted LSI conditions.

Light-weight Design and Simulation of Automotive Rear Bumper Impact Beam Using Boron Steels (보론강을 이용한 리어 범퍼 임팩트빔의 경량 설계 및 해석)

  • Kim, Kee-Joo;Han, Chang-Pyung;Lim, Jong-Han;Lee, Young-Suk;Won, Si-Tae;Lee, Jae-Woong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.2
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    • pp.98-102
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    • 2012
  • Increasing the fuel economy has been an inevitable issue for the development of new cars, and one of the important measures to improve the fuel economy is to decrease the vehicle weight. In order to obtain this goal, the researches about lighter, stronger and the well impact absorbing bumper impact beam have been studied without sacrificing bumper safety. In this study, the overall weight reduction possibility of rear bumper impact beam could be examined based on the variation of frontal, offset and corner impact crash capability by substituting a ultra high strength steel material (boron steel ) having tensile strength of 1.5 GPa grade instead of conventional steels. In addition, the section variations (open section, closed section, open section with 5 stays) of the bumper impact beam structure were examined carefully. It could be reached that this analysis could be well established and be contributed for design guide and the optimum design conditions of the automotive rear bumper impact beam development.

Physics study for high-performance and very-low-boron APR1400 core with 24-month cycle length

  • Do, Manseok;Nguyen, Xuan Ha;Jang, Seongdong;Kim, Yonghee
    • Nuclear Engineering and Technology
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    • v.52 no.5
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    • pp.869-877
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    • 2020
  • A 24-month Advanced Power Reactor 1400 (APR1400) core with a very-low-boron (VLB) concentration has been investigated for an inherently safe and high-performance PWR in this work. To develop a high-performance APR1400 which is able to do the passive frequency control operation, VLB feature is essential. In this paper, the centrally-shielded burnable absorber (CSBA) is utilized for an efficient VLB operation in the 24-month cycle APR1400 core. This innovative design of the VLB APR1400 core includes the optimization of burnable absorber and loading pattern as well as axial cutback for a 24-month cycle operation. In addition to CSBA, an Er-doped guide thimble is also introduced for partial management of the excess reactivity and local peaking factor. To improve the neutron economy of the core, two alternative radial reflectors are adopted in this study, which are SS-304 and ZrO2. The core reactivity and power distributions for a 2-batch equilibrium cycle are analyzed and compared for each reflector design. Numerical results show that a VLB core can be successfully designed with 24-month cycle and the cycle length is improved significantly with the alternative reflectors. The neutronic analyses are performed using the Monte Carlo Serpent code and 3-D diffusion code COREDAX-2 with the ENDF/B-VII.1.

Three-D core multiphysics for simulating passively autonomous power maneuvering in soluble-boron-free SMR with helical steam generator

  • Abdelhameed, Ahmed Amin E.;Chaudri, Khurrum Saleem;Kim, Yonghee
    • Nuclear Engineering and Technology
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    • v.52 no.12
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    • pp.2699-2708
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    • 2020
  • Helical-coil steam generator (HCSG) technology is a major design candidate for small modular reactors due to its compactness and capability to produce superheated steam with high generation efficiency. In this paper, we investigate the feasibility of the passively autonomous power maneuvering by coupling the 3-D transient multi-physics of a soluble-boron-free (SBF) core with a time-dependent HCSG model. The predictor corrector quasi-static method was used to reduce the cost of the transient 3-D neutronic solution. In the numerical system simulations, the feedwater flow rate to the secondary of the HCSGs is adjusted to extract the demanded power from the primary loop. This varies the coolant temperature at the inlet of the SBF core, which governs the passively autonomous power maneuvering due to the strongly negative coolant reactivity feedback. Here, we simulate a 100-50-100 load-follow operation with a 5%/minute power ramping speed to investigate the feasibility of the passively autonomous load-follow in a 450 MWth SBF PWR. In addition, the passively autonomous frequency control operation is investigated. The various system models are coupled, and they are solved by an in-house Fortran-95 code. The results of this work demonstrate constant steam temperature in the secondary side and limited variation of the primary coolant temperature. Meanwhile, the variations of the core axial shape index and the core power peaking are sufficiently small.

Effect of Precipitates on Hot Ductility Behavior of Steel Containing Ti and Nb (Ti-Nb 합금강에서 합금성분의 변화에 따른 석출물거동이 고온연성에 미치는 영향)

  • Han, Won Bae;Lee, Jong Ho;Kim, Hee-Soo;An, Hyeun Hwan;Lee, Seung Jae;Kim, Seong Woo;Seo, Seok Jong;Yoon, Chong Seung
    • Korean Journal of Metals and Materials
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    • v.50 no.4
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    • pp.285-292
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    • 2012
  • Hot ductility behavior of precipitation-hardened low-carbon iron alloys containing 0.02 wt% Ti and 0.05 wt% Nb was characterized by a hot tensile stress test. Carbon (0.05, 0.1, 0.25 wt%) and boron (0.002 wt%) contents were varied to study the effect of precipitates on the high-temperature embrittlement of the alloys in the temperature range of $600{\sim}800^{\circ}C$. Ductility loss was observed at $700^{\circ}C$ for the tested alloys. The cause of the ductility loss was mainly attributed to the carbides and ferrite films formed at the grain boundaries during deformation. Although the carbon content tended to raise the total fraction of Nb (C, N), the precipitates were formed mostly in the grain interior as the precipitation temperature was raised above the deformation temperature by the high carbon content. Hence, carbon in excess suppressed the hot ductility loss. Meanwhile, boron addition improved the hot ductility of the alloys. The improvement is likely due to the boron atoms capturing carbon atoms and thus retarding the carbide formation.

An Essay of the Reinforcing Effect of BNNT and CNT: A Perspective on Interfacial Properties (BNNT와 CNT의 강화효과에 대한 복합재 계면물성 관점의 고찰)

  • Seunghwa Yang
    • Composites Research
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    • v.37 no.3
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    • pp.155-161
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    • 2024
  • Boron nitride nanotubes and carbon nanotubes are the most representative one-dimensional nanostructures, and have received great attention as reinforcement for multifunctional composites for their excellent physical properties. The two nanotubes have similar excellent mechanical stiffness, strength, and heat conduction properties. Therefore, the reinforcing effect of these two nanotubes is greatly influenced by the properties of their interface with the polymer matrix. In this paper, recent comparative studies on the reinforcing effect of boron nitride nanotubes and carbon nanotubes through experimental pull-out test and in-silico simulation are summarized. In addition, the conflicting aspect of the two different nanotubes with structural defects in their side wall is discussed on the viscoelastic damping performance of nanocomposites.

Development and application analysis of high-energy neutron radiation shielding materials from tungsten boron polyethylene

  • Qiankun Shao;Qingjun Zhu;Yuling Wang;Shaobao Kuang;Jie Bao;Songlin Liu
    • Nuclear Engineering and Technology
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    • v.56 no.6
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    • pp.2153-2162
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    • 2024
  • The purpose of this study is to develop a high-energy neutron shielding material applied in proton therapy environment. Composite shielding material consisting of 10.00 wt% boron carbide particles (B4C), 13.64 wt% surface-modified cross-linked polyethylene (PE), and 76.36 wt% tungsten particles were fabricated by hot-pressure sintering method, where the optimal ratio of the composite is determined by the shielding effect under the neutron field generated in typical proton therapy environment. The results of Differential Scanning Calorimetry measurements (DSC) and tensile experiment show that the composite has good thermal and mechanical properties. In addition, the high energy-neutron shielding performance of the developed material was evaluated using cyclotron proton accelerator with 100 MeV proton. The simulation shows a 99.99% decrease in fast neutron injection after 44 cm shielding, and the experiment result show a 99.70% decrease. Finally, the shielding effect of replacing part of the shielding material of the proton therapy hall with the developed material was simulated, and the results showed that the total neutron injection decreased to 0.99‰ and the neutron dose reduced to 1.10‰ before the enhanced shielding. In summary, the developed material is expected to serve as a shielding enhancement material in the proton therapy environment.

A Study on Vacuum Sintering of M2 HSS Powder (M2 분말의 진공소결에 관한연구)

  • Choe, Yeong-Taek
    • 한국기계연구소 소보
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    • s.20
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    • pp.89-104
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    • 1990
  • This study was carried out to obtain the most optimum conition in vacuum sintering of M2 HSS powder, by analysis of sintering characteristics and fracture strength in several conditions. The conclusion deduced from this study are as follows; -Boron was more effective element than graphite; at this time, the optimum amount of addition was 0.05 wt% -The optimum condition of sintering temperature and time were 1190- $1200^{\circ}C$ and 1-1.25hr, respectively -Fracture strength of vacuum sintered and heat-treated specimen in the most optimum condition was 2-2.5KN/ $mm^2$

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Convenient Procedure for the Reduction of Carboxylic Acids via Acyloxyborohydrides

  • Cho, Byung-Tae;Yoon, Nung-Min
    • Bulletin of the Korean Chemical Society
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    • v.3 no.4
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    • pp.149-152
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    • 1982
  • A new convenient method for the reduction of carboxylic acids to the corresponding alcohols via acyloxyborohydrides was explored. Acyloxyborohydrides, prepared from the reaction of various carboxylic acids and sodium borohydride, underwent reduction to the corresponding alcohols readily by the addition of dimethyl sulfate or Lewis acids, such as boron trifluoride etherate and triphenyl borate, presumably through acyloxyboranes. By utilizing this procedure, aliphatic and aromatic acids are rapidly and quantitatively reduced to the corresponding alcohols in terahydrofuran either at room temperature (or at $65^{\circ}$). This procedure provides selective reduction of carboxylic acids in the presence of halogen, nitro, and heterocyclic rings such as furan and thiophene.