• 제목/요약/키워드: Bonding efficiency

검색결과 198건 처리시간 0.021초

Enantioselective Recognition of Amino Alcohols and Amino Acids by Chiral Binol-Based Aldehydes with Conjugated Rings at the Hydrogen Bonding Donor Sites

  • Kim, Ji-Young;Nandhakumar, Raju;Kim, Kwan-Mook
    • Bulletin of the Korean Chemical Society
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    • 제32권4호
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    • pp.1263-1267
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    • 2011
  • Novel binol-based uryl and guanidinium receptors having higher ring conjugation at the periphery of the hydrogen bonding donor sites have been synthesized and utilized to study the enantioselective recognition of 1,2-aminoalcohols and chirality conversion of natural amino acids via imine bond formation. There is a remarkable decrease in the stereoselectivites as the conjugation increases at the periphery of hydrogen bonding donor sites. The guanidinium-based receptors show more selectivity towards the amino alcohol than that of the uryl based ones due to its charge reinforced hydrogen bonds. The conversion efficiency of L-amino acids to Damino acids by the uryl-based receptors is higher than that of the guanidinium-based ones.

진공확산접합을 이용한 형상적응형 냉각채널을 가진 화장품 용기용 사출금형의 제작 및 시험사출 (Fabrication and Testing of Injection Mold for Cosmetic Container with Conformal Cooling Channels Using Vacuum Diffusion Bonding)

  • 유만준;박종천
    • 한국기계가공학회지
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    • 제19권3호
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    • pp.92-98
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    • 2020
  • In this study, an injection mold with conformal cooling channels was designed and manufactured for use in the production of a thick plastic cosmetic container that required high gloss surfaces. A cooling analysis verified the design of the conformal cooling channel for the cosmetic container, and also showed that the cooling efficiency was superior to that of the straight cooling channel. Slide cores designed with the conformal cooling channel were manufactured using the Layers Parting method and vacuum diffusion bonding. Subsequent test injection and quality inspection showed no problem in the appearance and dimensional accuracy of the produced product. The cycle time for product production was about 110 seconds, sufficient for mass production.

염료감응 태양전지용 고성능 탄소 상대전극 제작 (Fabrication of High-performance Carbon Counter Electrode for Dye-sensitized Solar Cells)

  • 장연익;이승용;김동환;박종구
    • 한국분말재료학회지
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    • 제14권1호
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    • pp.44-49
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    • 2007
  • In the fabrication of dye-sensitized solar cells (DSSCs), carbon counter electrode has been tested for replacing the platinum counter electrode which has two drawbacks: limited surface area and high material cost. Poor mechanical stability of carbon layer due to weak bonding strength to electrically conductive TCO (transparent conducting oxide) glass substrate is a crucial barrier for practical application of carbon counter electrode. In the present study a carbon counter electrode with high conversion efficiency, comparable to Pt counter electrode, could be fabricated by adaption of a bonding layer between particulate carbon material and TCO substrate.

Field Emission Display의 고진공 실장에 관한 연구 (Study on Vacuum Packaging of Field Emission Display)

  • 이덕중;주병권;장진;오명환
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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    • pp.103-106
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    • 1999
  • In this paper, we suggest the FED packaging technology that have 4mm thickness, using sodalime glass-to-sodalime glass electrostatic bonding. It based on conventional silicon-glass bonding. The silicon film was deposited an around the exhausting hole on FED backside panel. And then, the silicon film of panel was successfully bonded with capping(bare) glass in vacuum environment and the FED panel was vacuum-sealed. In this method, we could achieve more 153 times increased conductance and 200 times increased vacuum efficiency than conventional tube packaging method. The vacuum level in panel, by SRG test, was maintained about low 10$_{-4}$ Torr during above two months And, the light emission was observed to 0.7-inch tubeless packaged FED. Then anode current was 34 $\mu$ A. Emission stability was constantly measured for 10 days.

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Reaction Kinetics and Dependence of Energy Efficiency in the Dilute Trichloroethylene Removal by Non-thermal Plasma Process combined with Manganese Dioxide

  • Han, Sang-Bo;Oda, Tetsuji;Park, Jae-Youn;Koh, Hee-Seok;Park, Sang-Hyun;Lee, Hyun-Woo
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.552-553
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    • 2005
  • In order to improve energy efficiency in the dilute trichloroethylene removal using the nonthermal plasma process, the barrier discharge treatment combined with manganese dioxide was experimentally studied. Reaction kinetics in this process was studied on the basis of final byproducts distribution. Decomposition efficiency was improved to about 99% at the specific energy 40J/L with passing through manganese dioxide. C=C $\pi$ bond cleavage in TCE gave DCAC (single bond, C-C) through oxidation reaction during the barrier discharge plasma treatment. Those DCAC were broken easily in the subsequent catalytic reaction due to the weak bonding energy about 3 ~ 4 eV compared with the double bonding energy in TCE molecules. Oxidation byproducts of DCAC and TCAA from TCE decomposition are generated from the barrier discharge plasma treatment and catalytic surface chemical reaction, respectively. Complete oxidation of TCE into $CO_X$ is required to about 400J/L.

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확산접합된 페라이트/마르텐사이트강의 미세조직 및 기계적 특성에 미치는 열처리 효과 (Effects of the Heat Treatment on the Microstructure and Mechanical Properties of the Diffusion-Bonded Ferritic/Martensitic Steel)

  • 사인진;김성환;홍성훈;장창희
    • 한국압력기기공학회 논문집
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    • 제11권1호
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    • pp.12-19
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    • 2015
  • As a measure of improving the mechanical properties of a diffusion bonded joint of a ferritic/martensitic steel (FMS), the post-bonding heat treatment (PBHT) is applied. In the temperature range of normalizing condition ($950-1,050^{\circ}C$), diffusion bonding is employed with compressive stress (6 MPa). Due to the martensite structure distributed in the matrix, Vicker's hardness values of the as-bonded are much higher than those of the as-received. Through the PBHT for 1 h at $720^{\circ}C$, hardness values are recovered to as low as those of the as-received condition. Also, tensile properties of PBHT are similar to those of the as-received at up to the test temperature of $550^{\circ}C$, when the diffusion bonding is carried out over $1,000^{\circ}C$. Based on the creep-rupture testing performed at $650^{\circ}C$ in air environment, the joint efficiency of the PBHTed specimens is about 80% in, which is higher than that of the as-bonded specimens.

이종재료의 결합방법에 따른 모자형 단면부재의 충돌실험 (Crushing Test of the Double Hat-shaped Members of Dissimilar Materials by Seining Methods)

  • 이명한;박영배;김헌영;오수익
    • 한국자동차공학회논문집
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    • 제13권4호
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    • pp.129-134
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    • 2005
  • There is a strong industrial demand for the development of light-weight vehicle to improve fuel efficiency and dynamic performance. The effective method of achieving the weight reduction is to use low-density materials such as aluminum and magnesium. In applying these materials to the vehicle, it is often required to join dissimilar materials such as aluminum and steel. However, conventional joining method, namely resistance spot welding cannot be used in joining dissimilar materials. Self·piercing rivet(SPR) and adhesive bonding is a good alternative to resistance spot welding. In this study, the impact test of double hat-shaped member made by resistance spot welding, SPR and adhesive bonding was performed. As a result, various parameters of crashworthiness were analyzed and evaluated. Also, the applicability of SPR and adhesive bonding as an alternative to resistance spot welding was suggested.

2.14-GHz 대역 고효율 Class-F 전력 증폭기 개발 (Development of a 2.14-GHz High Efficiency Class-F Power Amplifier)

  • 김정준;문정환;김장헌;김일두;전명수;김범만
    • 한국전자파학회논문지
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    • 제18권8호
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    • pp.873-879
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    • 2007
  • 본 논문에서는 Freescale사의 Si-LDMOSFET 4-W 소자를 이용하여 고효율 class-F 전력 증폭기를 구현하였다. Class-F 전력 증폭기를 구현하는데 있어서 모든 하모닉 성분들에 대해 원하는 임피던스를 갖도록 조정하기는 불가능하기 때문에 2차와3차 하모닉 성분만을 조율하여 회로의 간결함과 동시에 상대적으로 높은 효율을 얻을 수 있었다. 또한, 본 논문에 설계된 증폭기는 보다 정확하게 하모닉 성분을 조율하기 위해, LDMOSFET의 대신 호 등가 모델에서 가장 큰 영향을 미치는 drain-source capacitance(Cds)와 bonding inductance(Lb)를 추출하여 하모닉 조율 회로를 설계하였다 제작된 고효율 class-F 전력 증폭기의 측정 결과 drain-efficiency(DE) 65.1%, power-added-efficiency(PAE) 60.3%의 효율을 얻을 수 있었다.

완전자동화된 단속적 재료 공급식 가변적층 쾌속조형공정 밀 장치 개발에 관한 연구 (Investigation Into the Development Of Automatic VLM-ST (VLM-STA) Process and Its Apparatus)

  • 양동열;안동규;이상호;김효찬;박승교
    • 한국정밀공학회지
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    • 제21권4호
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    • pp.109-119
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    • 2004
  • Rapid prototyping (RP) technologies have been widely used to reduce the lead-time and development cost of new products. $VLM-_{ST}$ process has been developed to overcome the currently developed RP technologies such as a large building time, a high building cost, an additional post-processing and a large apparatus cost. $VLM-_{ST}$ process requires an additional human interaction due to the manual stacking and bonding. Hence, building time, building cost and the part quality are dependent on the skill of labor. A novel RP process, fully automated $VLM-_{ST}$ process ($VLM-_{ST}$), has been developed to improve building efficiency of the process and the human dependency of the part. The objective of this work is to propose a $VLM-_{ST}$ process and to develop an apparatus for implementation of the process. $VLM-_{ST}$ process and its apparatus have various technical novelties such as two step cutting using a rotating table, an automatic stacking method using two pilot holes and two reference shapes, a concept of automatic unit shape layer (AUSL), and an automatic bonding using the bonding roller and building magazine. In order to examine the efficiency and the applicability of the proposed process, various three-dimensional shapes, such as a piston, a human head shape and a human bust shape, were fabricated on the apparatus.

열간 금형펀치 제작을 위한 이종재 마찰용접과 고온크리프 실시간 예측 및 AE에 의한 품질평가(Ⅰ) -마찰용접과 AE (Friction Welding of Dissimilar Hot Die Punch Materials and Its Creep Prediction and Quality Evaluation by AE(I) - FRW and AE+)

  • 박일동;오세규;김지수
    • 한국해양공학회지
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    • 제13권3호통권33호
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    • pp.77-82
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    • 1999
  • The compleete joining method for dissimilar hot die punch materials and its real-time evaluation method are not available at present. Brazing method has been used for joining them, but it is known that the welded joint by the brazing has the lower bonding efficiency and reliability than the diffusion welding. The friction wleding with a diffusion mechanism in bonding was applied in this study. So, this work was carried out to determine the optimal friction welding conditions and to analyze mechanical properties of friction welded joints of hot die punch materials (STD61 for the blade part of hot die punch) to alloy steel (SCM440 for the shank park of hot die punch) such as plunger. In addition, acoustic emission test was carried out during friction welding to evaluate the weld quality.

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