• Journal of Adhesion and Interface
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• v.21 no.3
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• pp.81-85
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• 2020

Shaving dust is a collagen fiber that is the leather waste occurred for thickness adjustment during the natural leather manufacturing process, and causes problems such as an environmental contamination because of a chromium (Cr) contained when it comes to reclaiming process. Various studies applying the shaving dust are currently being conducted in many countries across the world with an initiative by the EU. Of those applications, the bonded leather is being highlighted as a substitute for natural leather. Since the bonded leather, however, uses latex as a binder, accordingly it entails a high weight and a poor ventilation, which are deemed as disadvantages due to its dense internal tissues compared to other synthetic leathers. To address such disadvantages, this study employed the thermally expandable micro sphere to improve its air permeability and light weight by alleviating the internal structure. This is a study on the manufacturing of light bonded leather using the shaving dusts. In the study, the shaving dusts were forced to foam under 100~120℃ considering the heat resistance of collagen fiber after applying the thermally expandable micro sphere, and then the tendency was analyzed. In the analysis results, the most excellent foaming rate was exhibited when the shaving dusts were treated under 120℃ for 8 minutes and the variation of internal structure according to a foaming was observed through SEM analysis for the cross-section of the bonded leather.

• Clean Technology
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• v.10 no.1
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• pp.19-25
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• 2004

The leather was fixed with various colors through the dyeing process in leather manufacturing. During the dyeing process, the amount of 30~50% dyestuff which were not bonded with leather drained with waste water. These dyestuff raise lots of environmental problems, so technology for improving the fixing effect, levelling effect and penentration effect with the use of small amount of dyestuff has been required. Also, insufficient color fastness level 2~3 grade for common natural leather needs to be improved at the same time. Accordingly, the use of ultrasound(us) in dyeing process has decreased the amount of dyestuff and obtained the smooth permeability effect. So, we could find that the reduction of amount of dyestuff in wastewater led to decrease in environmental trouble caused by leather waste water with severe contamination degree and improved fastness up to 0.5 grades.

• Journal of Adhesion and Interface
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• v.11 no.1
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• pp.26-34
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• 2010

We synthesized polyurethane adhesive having thermal characteristic could be debonded by heat treatment and made a dismantlable polyurethane adhesive including thermally expansive bead. We used dynamic mechanical thermal analyzer (DMA) to confirm thermal characteristic and investigated bond strength, dismantlement property of dismantlable polyurethane adhesive by content of thermally expansive bead, heating trigger and treatment conditions. The dismantlable polyurethane adhesive could be expanded by hot-air or microwave treatment and the dismantlement of the specimens became easier as the weight fraction of the thermally expansive bead increased. At the dismantlable polyurethane adhesive, the content of thermally expansive bead 40% was suitable for both bond strength and dismantlement, in case of using hot-air treatment as trigger for dismantlement, bonded joints were separated easily at $160^{\circ}C$ for 30 min and in case of using microwave as trigger, bonded joints were separated easily by irradiating microwave for 4 min.

• 제어로봇시스템학회:학술대회논문집
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• 2001.10a
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• pp.131.3-131
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• 2001

A 2-dimensional scanner have been generally used for an office, but 3-dimensional one was seldom used in industry. A footwear bonding process has been operated manually by the skilled operators, but it is needed to be operated automatically. So we developed an automatic outsole profile scanner, which consists of PC, CCD camera, laser beam diode and moving mechanism, to scan automatically the 3-dimensional profile of outsole inner face to be bonded. Here the developed algorithm makes 2D image into 3D outsole profile. This profile will be used enough to bond automatically the outsole to something like leather or clothes.

• Journal of the Korean Society of Costume
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• v.63 no.7
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• pp.79-93
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• 2013

In the Korean literature, records of systematic gold thread manufacturing such as gold foil(金 箔匠), gold foil bonded with fabrics(付金匠), gold foil bonded with paper materials(金箋紙匠), refining gold(鍊金匠), cutting gold(裁金匠), and making gold thread(絲金匠) can be easily found. We can infer from these literatures that the Korean people used to make gold threads. However, is not existent the gold thread making technique. Thus, a research was done using 67 pieces of gold thread artifacts used in textiles craft of Korea, China and Japan. The purpose of this research was to identify the characteristics of the Korean gold thread by studying the artifacts' form classification, gold foil, glue and the base. First, gold thread is divided into flat gold thread and wrapped gold thread. Wrapped gold thread was made in more various methods such as with a paper on the flat gold thread, metal thread and wrapped gold thread with gold foil on top. Compared to the flat gold thread, wrapped gold thread uses a thread that has a thinner and wider. Through this analysis, even making of the base of the gold threads was different according to the type. Secondly, we looked into the characteristics of materials according to form structure of the gold thread. After analysis of experiment results, we could know that to attach Korean gold thread, glue and the mixture of materials such as Red soil(朱土) was also added. The kinds of the base of gold threads were identified as paper, leather and intestines. Among those materials, for paper, Korea's Dakji, China's Sangpiji(桑皮紙) and Jukji(竹紙) and Japan's Anpiji(雁皮紙) seemed to have all been used, so because of the difference among countries, we can prove that Korea has also produced gold thread. By looking at the research, the base of gold threads and making features hugely vary according to the area.

• Macromolecular Research
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• v.17 no.8
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• pp.616-622
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• 2009

In-depth understanding of the influence of hot pressing and melt processing on the properties of thermoplastic polyurethane (TPU) is critical for effective mechanical recycling of TPU scraps. Therefore, this study focused on the effects of hot pressing and melt mixing on molecular weight (MW), polydispersity index (PDI), melt index (MI), characteristic IR peaks, hardness, thermal degradation and mechanical properties of TPU. The original TPU pellet (o-TPU) showed two broad peaks at lower and higher MW regions. However, four TPU film samples, TPU-0 prepared only by hot pressing of o-TPU pellet and TPU-1, TPU-2 and TPU-3 obtained by hot pressing of melt mixed TPUs (where the numbers indicate the run number of melt mixing), exhibited only a single peak at higher MW region. The TPU-0 film sample had the highest $M_n$ and the lowest PDI and hardness. The TPU-1 film sample had the highest $M_w$ and tensile modulus. As the run number of melt mixing increased, the peak-intensity of hydrogen bonded C=O stretching increased, however, the free C=O peak intensity, tensile strength/elongation at break and average MW decreased. All the samples showed two stage degradations. The degradation temperatures of TPU-0 sample (359 $^{\circ}C$ and 394 $^{\circ}C$)were higher than those of o-TPU (342 $^{\circ}C$ and 391 $^{\circ}C$). While all the melt mixed samples degraded at almost the same temperature (365 $^{\circ}C$ and 381 $^{\circ}C$). The first round of hot pressing and melt mixing was found to be the critical condition which led to the significant changes of $M_n$/$M_w$/PDI, MI, mechanical property and thermal degradation of TPU.