• Title/Summary/Keyword: Bond order

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Bonding Characteristics of Basalt Fiber Sheet as Strengthening Material for Railway Concrete Structures (Basalt 섬유쉬트의 철도시설 콘크리트구조물 보강재로서의 부착거동 연구)

  • Park, Cheol-Woo;Sim, Jong-Sung
    • Journal of the Korean Society for Railway
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    • v.12 no.5
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    • pp.641-648
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    • 2009
  • Concrete structures become more common in railway systems with an advancement of high speed train technologies. As the service life of concrete structures increases, structural strengthening for concrete structures may be necessary. There are several typical strengthening techniques using steel plate and fiber reinforced polymer (FRP) materials, which have their own inherent shortcomings. In order to enhance greater durability and resistance to fire and other environmental attacks, basalt fiber material attracts engineer's attention due to its characteristics. This study investigates bonding performance of basalt fiber sheet as a structural strengthening material. Experimental variables include bond width, length and number of layer. From the bonding tests, there were three different types of bonding failure modes: debonding, rupture and rip-off. Among the variables, bond width indicated more significant effect on bonding characteristics. In addition the bond length did not contribute to bond strength in proportion to the bond length. Hence this study evaluated effective bond length and effective bond strength. The effective bond strength was compared to those suggested by other researches which used different types of FRP strengthening materials such as carbon FRP.

An Experimental Study on the Bond Characteristic of GFRP Bars in PVA Fiber Reinforced Activated Hwangtoh Concrete (PVA 섬유보강 황토 콘크리트에 대한 GFRP 보강근의 부착성능에 관한 실험적 연구)

  • Park, Mi-Rae;Kim, Seung-Hun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.1
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    • pp.134-141
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    • 2017
  • Many studies have been conducted with respect to the materials to replace the cement in order to reduce the carbon dioxide emissions during the cement production. Activated hwangtoh as cement replacement material goes through calcination process of $850^{\circ}C$. PVA fibers and GFRP bars are used in order to compensate for the cracks of activated hwangtoh concrete(AHC). This paper presents an experimental study investigating the bond characteristic of GFRP bars in PVA fiber reinforced AHC under tensile loads. Experimental results showed that average bond strength factor of specimens with and without PVA fiber was 2.27~2.48 and was not significantly affected by the ratio of PVA fiber andactivated hwangtoh. In addition, as the bond length was increased, the bond strength was reduced.

An Experimental Study for Bond Stress between DFRCC and Carbon FRP Plank Used as a Permanent Formwork (영구거푸집으로 활용한 탄소섬유 FRP 판과 DFRCC 사이의 부착응력에 관한 실험적 연구)

  • Park, Chan-Young;Yoo, Seung-Woon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.6
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    • pp.1687-1694
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    • 2014
  • Recently FRP of carbon fibers is utilized as a repairing and reinforcing material for concrete structures. In this study, the bond performance between CFRP planks and ductile fiber reinforced cementitious composites was evaluated in order to develop a new system of concrete bridge deck to take advantage of the FRP planks of carbon fiber using as a permanent formwork. In order to strengthen the bonding between the FRP and cast-in-place concrete, an epoxy resin circulated in the market generally was fitted with a silica sand. The bond stress of ordinary concrete appeared in 2.11~5.43MPa and the bond stress of ductile fiber reinforced cementitious composites DC1 (RF4000) and DC2 (PP) respectively were 3.91~5.60MPa, 2.92~5.21MPa and the average bond stress of DC3 (RF4000+RSC15) and DC4 (PP+RSC15) were 4.80~5.58MPa, 5.57~5.89MPa.

Nucleophilic Displacement at Sulfur Center (III). Kinetic Studies on Halide Exchange Reactions of Dimethylsulfamoyl Chloride in Dry Acetone (유황의 친핵 치환반응 (제3보). 아세톤 용매속에서의 Dimethylsulfamoyl Chloride의 할라이드 교환반응에 관한 속도론적 연구)

  • Ikchoon Lee;Shi Choon Kim
    • Journal of the Korean Chemical Society
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    • v.17 no.6
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    • pp.406-410
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    • 1973
  • Kinetic study of halide exchange for dimethylsulfamoyl chloride in dry acetone by using radioisotopic halide ions has been carried out at two temperatures. The result of the order of nucleophilicity, as compared with benzenesulfonyl chloride, shows a similar tendency but reaction rate is slower, more than $10^{-2}$times, than benzenesulfonyl chloride. The activation parameter, ${\Delta}H^{\neq}\;and\;{\Delta}S^{\neq}$ decrease in sequence $Cl^-\;>\;Br^-\;>\;I^-$ in dimethylsulfamoyl chloride but it is the reverse order found for benzenesulfonyl chloride. The results are interpreted with bond-breaking, bond-formation, and electronic requirments, and in the light of HSAB Principle.

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EFFECT OF THERMOCYCLING ON BONDING OF COMPOSITE RESIN AFTER DENTIN SURFACE TREATMENTS (상아질 표면처리후 복합레진 수복시 온도변화가 결합에 미치는 영향)

  • Lee, Yong-Woo;Son, Ho-Hyun
    • Restorative Dentistry and Endodontics
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    • v.16 no.2
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    • pp.126-142
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    • 1991
  • The purpose of this study was to evaluate the effect of various dentin surface treatments on shear bond strength, microhardness and fracture mode before and after thermocycling. Recently extracted 75 human molars were used. The teeth were sagittal sectioned faciolingually to obtain 150 specimens. They were randomly divided into six groups. Mesial and distal dentinal surfaces of specimens were exposed by grinding and treated respectively with GC-DENTIN CONDITIONER. 10-3 solution of 4-Meta, Cleansar and Primer of GLUMA, Scotchprep of Scotchbond 2, DENTIN CONDITIONER and PRIMER A, B of ALL BOND according to the manufacturers directions. Specimens of one group were not treated. Adhesive agent of Scotchbond 2, were applied and cured on the treated dentin surfaces. After P-50 were cured on them, specimens were stored in 31c water for 24 hours before shear bond strength measurement Shear bond strength was measured in 10 specimens of each group. 10 specimens of each group were thermocycled in $20^{\circ}C$, $60^{\circ}C$,$20^{\circ}C$, $4^{\circ}C$, $20^{\circ}C$ water in order, for 30 seconds respectively, 100 times a day for 7 days. After thermocycling shear bond strength was measured. Microhardness was checked on treated dentin surface and fractured dentin surface in 10 specimens respectievly. Francture modes were observed with SEM The following results were obtained. 1. Before thermocycling. shear bond strengths in the specimens treated with DENTIN CONDITIONER and PRIMER A, B of ALL BOND were significantly higher than those in other specimens(P<0.01). 2. After thermocycling. shear bond strengths in the specimens treated with Cleanser and Primer of GLUMA, Scotchprep of Scotchbond 2 and DENTIN CONDITIONER and PRIMER A, B of AIL BOND were significantly higher than those in specimens not: treated, treated with GC-DENTIN CONDITIONER and 10-3 solution of 4-Meta(P<0.01). Shear bond strengths in the specimens treated with GC-DENTIN CONDITIONER and PRIMER A, B of ALL BOND were significantly higher than those in other specimens except those treated with Scotchprep of Srotchbond 2(P<0.01). 3. Shear bond strengths after thermocycling were reduced in the specimens not treated, treated with GC-DENTIN CONDITIONER and 10-3 solution of 4-Meta and were increased in the specimens treated with Cleanser and Primer of GLUMA, Scotchprep of Scotchbond 2, without significance, compared with those before thermocycling. In the specimens treated with DENTIN CONDITIONER and PRIMER A, B of ALL BOND, shear bond strengths after thermocycling were significantly increased, compared with those before thermocycling(P<0.01). 4. Microhardnesses in the fractured surfaces after shear bond strength measurement were significantly increased in the specimens treated with 10-3 solution of 4-Meta and significantly decreased in the specimens treated with DENTIN CONDITIONER and PRIMER A, B of ALL BOND, compared with those in the treated dentin surfaces(P<0.01). 5. In the specimens treated with Cleanser and Primer of GLUMA, Scotchprep of Scotchbond 2 and DENTIN CONDITIONER and PRIMER A, B of ALL BOND, cohesive fracture modes were observed more than adhesive fracture modes.

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The effect of preheat treatment on ceramic to metal bond strength (도재-금속의 결합 강도에 미치는 비금속 합금의 열처리 효과)

  • Kim, Chi-Young;Kim, Young-Gon; Cho, Hyun-Seol
    • Journal of Technologic Dentistry
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    • v.24 no.1
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    • pp.33-41
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    • 2002
  • In dental prosthetics, the application of metal-ceramic restorations has steadily increased since their introduction. This is due to excellent esthetics in combination with high mechanical stability. In order to optimum bond strength between metal and ceramics, controlled oxidation of metal substructure is essential factor. Beryllium containing and beryllium free Ni-Cr alloys for metal-ceramic restorations were evaluated for the metal-ceramic bond strength by changing heat treatment for oxide formation. A mechanical three-point bending test was employed to evaluate the interfacial bond strength of metal-ceramic. In each metal, plate type specimens were used for mechanical three-point bending test. With Ni-Cr alloys for metal ceramics, mechanical three-point bending test showed that double degassing was more available preheat treatment method than another. It was found that beryllium containing Ni-Cr alloys are more effective than beryllium-free for metal-ceramic bond strength.

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Effect of Pt on the High Temperature Stability of NiCoCrAlY or NiAl Bond Coat in the Thermal Barrier Coating System (NiCoCrAlY 및 NiAl bond coat를 사용한 Thermal Barrier Coating의 고온안정성에 미치는 Pt의 영향)

  • Ku Seongmo;Kim Gil Moo
    • Korean Journal of Materials Research
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    • v.15 no.6
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    • pp.375-381
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    • 2005
  • High temperature oxidation behavior of thermal barrier coating (TBC) system (IN738 substrate + NiCoCrAlY or NiAl bond coat with or without Pt + yttria stabilized zirconia) prepared by air plasma spray (APS) process has been studied in order to understand the effect of Pt addition to bond coat on the stability of TBC system. Specimens were oxidized in thermal cycling and isothermal oxidation test at $1100^{\circ}C$. The Pt addition in TBC system with NiCoCrAlY bond coat showed a longer life time compared to that without addition of Pt. Pt addition to TBC system is believed to help the formation of more stable thermally grown oxide, $Al_2O_3$, at the TBC/bond coat interface, leading to a longer lifetime of TBC system.

Bond behaviors of shape steel embedded in recycled aggregate concrete and recycled aggregate concrete filled in steel tubes

  • Chen, Zongping;Xu, Jinjun;Liang, Ying;Su, Yisheng
    • Steel and Composite Structures
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    • v.17 no.6
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    • pp.929-949
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    • 2014
  • Thirty one push-out tests were carried out in order to investigate the bond behavior between shape steel, steel tube (named steels) and recycled aggregate concrete (RAC), including 11 steel reinforced recycled aggregate concrete (SRRAC) columns, 10 recycled aggregate concrete-filled circular steel tube (RACFCST) columns and 10 recycled aggregate concrete-filled square steel tube (RACFSST) columns. Eleven recycled coarse aggregate (RCA) replacement ratios (i.e., 0%, 10%, 20%, 30%, 40%, 50%, 60%, 70%, 80%, 90% and 100%) were considered for SRRAC specimens, while five RCA replacement ratios (i.e., 0%, 25%, 50%, 75% and 100%), concrete type and length-diameter ratio for recycled aggregate concrete-filled steel tube (RACFST) specimens were designed in this paper. Based on the test results, the influences of all variable parameters on the bond strength between steels and RAC were investigated. It was found that the load-slip curves at the loading end appeared the initial slip earlier than the curves at the free end. In addition, eight practical bond strength models were applied to make checking computations for all the specimens. The theoretical analytical model for interfacial bond shear transmission length in each type of steel-RAC composite columns was established through the mechanical derivation, which can be used to design and evaluate the performance of anchorage zones in steel-RAC composite structures.

Effects of cooling rate on Microstructure and Bond Strength in WC-Co/Cu/SM45C steel joint (WC-Co/Cu/SM45C강접합에 미세조직 및 접합강도에 미치는 냉각속도의 영향)

  • 정승부;양훈모
    • Journal of Welding and Joining
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    • v.17 no.2
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    • pp.104-111
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    • 1999
  • The interfacial microstructure and bond strength were examined for WC-Co/Cu/SM45C steel join using a nickel-plated copper in vacuum at 1323K for 0.6ks∼3.6ks. After bonding, microstructure in bonding interface was observed by OM(Optical Microscopy), SEM(Scanning Electron Microscopy) and EPMA(Eelectron Probe Micro Analyzer). The oil cooling was carried out at 353K, the cooling rate in air and furnace was 22K/s and 4.4K/s. respectively. It was found that dendritic widths increased with the content of cobalt and bonding times at 1323K. As a whole, bond strength values at the same bonding condition decreased in this order: WC-13wt.%Co/SM45Csteel. WC-8wt.%Co/SM45Csteel and WC-4wt.%Co/SM45Csteel. The bond strength of WC-13wt.%Co/S45C steel joint in oil cooling was 273MPa. This value was greatly higher than those of 125MPa in furnace cooling and 93MPa in air cooling at 1323K for 0.6ks. The bond strength values were found to be closely associated with the content of cobalt in WC-Co and cooling rate.

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An Experimental Study on the Effect of Concrete Surface Treatment Methods on the Bond Strength of Metal Spray Coating (콘크리트 표면처리 방법이 콘크리트 표면 금속용사 피막의 부착강도에 미치는 영향에 관한 실험적 연구)

  • Park, Jin-Ho;Kim, Sang-Yeol;Lee, Han-Seung
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.36 no.1
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    • pp.147-154
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    • 2020
  • The exterior finishing of reinforced concrete buildings is one of the important factors to prevent durability and prevent natural environment or disaster such as temperature, snow, wind, rain from the outside as well as external design of buildings. Finishing methods can be divided into wet and dry methods. The wet method using paint is relatively easy to construct, but it requires repair and reinforcement every 1 to 5 years and requires a lot of LCC for maintenance. Finishing method using panel has good durability, but it is difficult to install and expensive. Therefore, in this paper, we evaluate the bond strength for the application of the metal spray method in order to overcome the problems of existing methods. Experimental results show that the sandblast + surface roughness agent(S-R(Y)) has a roughness of 41.16 ㎛ and the bond strength is about 3.19 MPa, which is the highest bond strength. In addition, the grinding + surface roughness agent(G-R(Y)) application showed roughness of about 36.59 ㎛ and secured the bond strength performance of 2.94 MPa.