• Journal of the Korea Concrete Institute
• /
• v.23 no.5
• /
• pp.675-682
• /
• 2011

Recently, in retrofit of RC structures using FRP (Fiber Reinforced Polymer), researches about Near-Surface-Mounted Rertofit (NSMR) method have been widely performed. In NSMR, FRP bar is normally inserted in the slit formed in the cover concrete and then bonded by using epoxy mortar. In this paper, the bond characteristic of NSMR using FRP plate instead of bar was studied experimentally. Fracture behavior is observed from bond test using the parameters of embedment length, shear key, and FRP plate layer. In addition, an equation to predict the splitting strength of NSMR using FRP is proposed using the test result. The results showed that when the longer embedment length and more layers of FRP are used, the higher bond strength is achieved. There was a good co-relationship between the test and calculated results using the proposed equation.

• Journal of the Korea Concrete Institute
• /
• v.22 no.6
• /
• pp.753-760
• /
• 2010

Ultra high performance concrete (UHPC), is characterized by its high compressive strength and advanced tensile behavior that is much superior to those of conventional concrete. In order to apply this new material in practice, the bond characteristics of UHPC were evaluated in this study. Pull-out tests between UHPC and deformed steel rebar were carried out according to the modified RILEM test method, and were verified by finite element analysis. From the test results showed that UHPC presents 5 to 10 times higher bond strength compared to normal strength concrete, this study suggested remarkably reduced development length and concrete cover comparing to existing specifications. The test results of 700 MPa high strength steel rebar demonstrated the applicability of high strength steel to UHPC. In addition, the transfer length measurements of seven-wire strand in UHPC specimens indicated that the transfer length limit set by the current design code is very conservative for UHPC.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2008.04a
• /
• pp.1085-1088
• /
• 2008

Splice of reinforcement is inevitable in reinforced concrete structures and, generally, lap splices are used. Lap length for tension splice is determined from development length in tension. The development length is calculated from an experimental model which was based on data of tests on anchorage and splice. Longitudinal reinforcements in flexural members are deformed and, therefore, prying action happens in spliced reinforcements unlike anchored reinforcements. The prying action induces tensile stress in cover concrete and this tensile stress plays the same role to a circumferential tensile stress caused by bond. Because splitting failure is assumed to occur when the summation of tensile stresses caused by the prying action and the bond is equal to the tensile strength of the concrete, the prying action reduces the bond strength of spliced reinforcements. A theoretical model for the prying action is developed and effects of the prying action on the bond strength are assessed. The tensile stress by the prying action is proportional to tensile strength and modulus of elasticity of reinforcements. In addition, the tensile stress is inversely proportional to spacing of reinforcements. Consequently, longer splice length is required for spliced reinforcements with small spacing in flexible members.

• Structural Engineering and Mechanics
• /
• v.72 no.3
• /
• pp.305-312
• /
• 2019

This paper investigates the effect of utilizing vacuum bagging process to enhance the bond behavior between fiber reinforced polymer (FRP) composites and concrete substrate. Sixty specimens were prepared and tested using double-shear bond test. The effect of various parameters such as vacuum, fiber type, and FRP sheet length and width on the bond strength were investigated. The experimental results revealed that utilizing vacuum leads to improve the bond behavior between FRP composites and concrete. Both the ultimate bond forces and the maximum displacements were enhanced when applying the vacuum which leads to reduction in the amount of FRP materials needed to achieve the required bond strength compared with the un-vacuumed specimens. The efficiency of the enhancement in bond behavior due to vacuum highly depends on the fiber type; using carbon fiber showed higher enhancement in the bond strength compared to the glass fiber when vacuum was applied. On the contrary, specimens with glass fiber showed higher enhancement in the maximum slippage compared to specimens with carbon fibers. Utilizing vacuum does not affect the debonding failure modes but lead to increase in the amount of attached concrete on the surface of the debonded FRP sheet.

• Bulletin of the Korean Chemical Society
• /
• v.26 no.4
• /
• pp.553-557
• /
• 2005

The formation of striped phases of unsymmetric hexyl octadecyl disulfide ($CH_3(CH_2)_5SS(CH_2)_{17}CH_3$, HOD) and 1-hydroxyundecyl octadecyl disulfide ($CH_3(CH_2)_{17}SS(CH_2)_{11}$OH, HUOD) on Au(111) and graphite has been investigated by scanning tunneling microscopy (STM) to understand the self-assembly processes of dialkyl disulfides. STM imaging clearly shows the formation of striped phases having corrugation periodicities that are nearly consistent with the molecular length of alkanethiolate moieties formed after the S-S bond cleavage of dialkyl disulfide on a gold surface. On the other hand, self-assembled monolayers (SAMs) of dialkyl disulfides on a graphite surface displayed long-range, well-ordered monolayers with one striped pattern that shows periodicity as a function of molecular length via nondissociative adsorption. From a nonoscopic viewpoint, we have clearly demonstrated that dialkyl disulfide SAMs on gold form via S-S bond cleavage of disulfide.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2001.11a
• /
• pp.997-1002
• /
• 2001

Tensile strength of CFRP (Carbon Fiber Reinforced Polymer) is approximately 10 times higher than that steel reinforcement, but the design strength of CFRP is normally reduced by the bond failure between RC and CFRP. Many researches have been carried out, concerned with bond behavior between RC and CFRP to prevent the unpredicted bond failure of RC beam strengthened by CFRP, but the national design code for design bond strength of CFRP hasn't been constructed. In this study, 3 beams specimen strengthened by CFRP under the variable of bonded length were tested to derive the design bond strength of CFRP to the RC flexural members. Also 2 beams specimen strengthened by CFRP were tested to inspect the construction environment effects such as mixing error of epoxy resin and the amount of primer epoxy resin. From the test results, It is concluded that the maximum design bond strength of CFRP to RC flexural member is considered to be $\tau_{a}$=8kgf/$cm^{2}$.

• Bulletin of the Korean Chemical Society
• /
• v.23 no.12
• /
• pp.1811-1815
• /
• 2002

We have calculated energies and structures for the hydrogen bonded clusters between trimethyl phosphate and nitric acids. The hydrogen bond lengths between phosphoryl oxygen and the proton of nitric acid are short compared to normal hydrogen bonds, and the H-bond strengths are fairly strong. The hydrogen bond length becomes longer, and the strength becomes weaker, as more nitric acids are bound to the TMP. The average H-bond strengths for the $TMP-(HNO_3)_n$ complexes with n = 1, 2, and 3, are 9.6, 7.9 and 6.4kcal/mol at 300K respectively. Weak hydrogen bonds between nitrate oxygen and methyl proton might contribute to the stability of the clusters. Not only the BSSE but also the fragment relaxation energies should be considered to calculate hydrogen bond strengths for the complexes accurately.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2000.10b
• /
• pp.1019-1024
• /
• 2000

Carbon fiber sheet has been widely used for the strengthening of the concrete buildings structures due to its excellent physical properties such as high strength, lightness and high durability. Bond strength or behavior, on the other, hands, between carbon fiber sheet and concrete is very important in strengthening the concrete member using CFS. Also the bond failure mechanism between CFS and concrete should be fully verified and understood. This study is to investigate the bond strength of CFS to th concrete by the direct pull-out test and the tensile-shear test methods. From the tests, the average bond stress, $$\tau$_{y}$ and the effective bond length, $$\ell$_{ｕ}$ are acquired.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.9 no.1
• /
• pp.233-241
• /
• 2005

The paper is presented experimental study results on bond stress between profiled steel and concrete in Profiled SPC(Profiled Steel Plate Concrete) rectangular steel tubes through an experimental program in which 13 pull-out specimens were tested. Advantages and class of composite members and current problems of construction work are noted, past research of PSSC is described. An experimental study is described and evaluated. The bond capacity is interrelated with slip at the steel concrete interface. The factors influencing the mechanism of bond stress transfer were the cross section shape, length/diameter, diameter/thickness and environmental parameters (temperature, moisture). The results of experimental program indicated that the force transfer could be characterized into two regions The first region was governed by bond with no relative slip between the profiled steel and concrete. The second region occurs after the chemical debonding. Bond stress transfer in this region was governed by frictional resistance between profiled steel and concrete and cross section shapes. The important factors influencing the magnitude of frictional resistance are the profiled steel shapes, length/diameter and environmental parameters. (temperature, moisture)

• Bulletin of the Korean Chemical Society
• /
• v.12 no.2
• /
• pp.211-213
• /
• 1991

The ground state of the oxygen molecule is calculated by various methods of coupled cluster approaches and many body perturbation theory using a double zeta plus polarization basis set and the UHF reference state. All the methods employed are capable of describing the oxygen molecule near the equilibrium bond length and the separated atom, but do not correctly depict the breaking of the multiple bond. For this basis set, including more correlations does not necessarily improve the agreement with experiment for molecular properties such as bond lengths and dissociation energies.