• The Journal of Advanced Prosthodontics
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• 제5권2호
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• pp.126-132
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• 2013

PURPOSE. Post surface conditioning is necessary to expose the glass fibers to enable bonding between fiber post and resin cement. The purpose of the present study was to evaluate the effect of different surface conditioning on tensile bond strength (TBS) of a glass fiber reinforced post to resin cement. MATERIALS AND METHODS. In this in vitro study, 40 extracted single canal central incisors were endodontically treated and post spaces were prepared. The teeth were divided into four groups according to the methods of post surface treatment (n=10): 1) Silanization after etching with 20% $H_2O_2$, 2) Silanization after airborne-particle abrasion, 3) Silanization, and 4) No conditioning (Control). Adhesive resin cement (Panavia F 2.0) was used for cementation of the fiber posts to the root canal dentin. Three slices of 3 mm thick were obtained from each root. A universal testing machine was used with a cross-head speed of 1 mm/minute for performing the push-out tests. Two-way ANOVA and Tukey post hoc tests were used for analyzing data (${\alpha}$=0.05). RESULTS. It is revealed that different surface treatments and root dentin regions had significant effects on TBS, but the interaction between surface treatments and root canal regions had no significant effect on TBS. There was significant difference among $H_2O_2$ + Silane Group and other three groups. CONCLUSION. There were significant differences among the mean TBS values of different surface treatments. Application of hydrogen peroxide before silanization increased the bond strength between resin cements and fiber posts. The mean TBS mean values was significantly greater in the coronal region of root canal than the middle and apical thirds.

• 구강회복응용과학지
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• 제16권2호
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• pp.123-132
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• 2000

The field of maxillofacial prosthetics is concerned with the prosthetic reconstruction of missing head and neck tissue. Currently, facial prostheses are usually applied in cases of defects caused by the surgical removal of tumors or congenital defects. While silicone has been most widely used for the reconstruction of missing maxillofacial defects, it does not have ideal physical properties. Therefore, bonding a thin polyurethane sheet to silicone prostheses was recommended. In this case skin adhesives were used for the retention of maxillofacial prostheses. But retention of devices has always been problematic. The contributions of implants can be made to solve these problems. Implants have reduced the need for adhesive use, simplifying cleaning procedures and thus extending the life of the prostheses. For implant-retained prostheses, retentive matrix is necessary to hold attachments and/or magnets. The retentive matrix is usually fabricated with autopolymerizing acrylic resin or visible light- polymerized resin. The purpose of this study was to compare the adhesion-in-peel force of silicone adhesive to autopolymerizing acrylic resin and polyurethane sheet with two different surface textures : pumice polish only or retention groove, and three surface primers : Dow corning 1205 primer or Dow corning S-2260 primer or FactorII A-304 primer, and two polymerization methods : room temperature or dry heat oven. The t-peel bond strength of specimens was determined as described in ASTM Standard D1876-72. The results were statistically analyzed using the ANOVA test, multiple range test and t-test The results were as follows. 1. The t-peel bond strength of A-304 primer was the highest and statistically higher than that of S-2260(p<0.05). 2. The t-peel bond strength of specimens with retention groove was statistically higher than that of specimens polished with pumice(p<0.05). 3. The t-peel bond strength of specimens polymerized in dry heat oven was statistically higher than that of specimens in room temperature(p<0.01).

• Restorative Dentistry and Endodontics
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• 제26권1호
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• pp.41-50
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• 2001

The purpose of this study was to examine the influences of camphoroquinone on the properties of five experimental composites. The contents of camphoroquinone were varied as 0.2%, 0.3%, 0.4%, 0.5%, and 0.6%, with silanized filler 75% and tertiary amine 0.2%. Five kinds of experimental composites were prepared, and diametral tensile strength, shear bond strength, depth of cure and yellowish discoloration were tested as a measurement. Specimen numbers of 10 were applied to all test items and experimental groups. Specimens for testing the diametral tensile strengths with internal diameter of 6mm in diameter and 3mm in height were filled with 5 experimental composites which were crushed with 1mm/min cross-head speed on Instron universal testing machine (Model No. 4467). Shear bond strength was measured on specimens attached to bovine teeth enamel etched with 37% phosphoric acid. Depth of cure was measured by the measurement of height of specimens which were removed the un-polymerized portion with acetone. Yellowness measurements were made by chromometer(Minolta Co. Japan) using L$^*$a$^*$b$^*$ values. ANOVA and Multiple range tests were used analyzed data with confidence level at 95%. The mean value of the shear bond strengths ranged from 31.03MPa to 39.49MPa. Following results were obtained ; 1. Diametral tensile strength was highest in experimental group 3, then was not affected by the contents of camphoroquinone ($r^2$=0.0422). 2. Composite resins containing 0.4% camphoroquinone showed the highest shear bond strength, but there was no statistical significance (p=0.3718). 3. Camphoroquinone reduces the depth of cure in the composite resins (p=0.0004, $r^2$=0.9483). 4. Camphoroquinone made the composites yellowish ($r^2$=0.9815). These results mean that increased content of camphoroquinone reduces the depth of cure, and that camphoroquinone make composites yellowish.

• 대한치과보철학회지
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• 제51권1호
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• pp.20-26
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• 2013

연구 목적: 본 연구는 최근 심미수복에 주로 사용되는 CAD/CAM 세라믹 인레이와 각종 레진 시멘트간의 결합강도를 알아보고자 하였다. 연구 재료 및 방법: 원기둥 모양의 세라믹 블록(높이: 5 mm, 직경: 3 mm)을 Cerec3로 제작하고, 총 90개의 우식이 없는 대구치의 상아질 표면에 세 종류의 레진 시멘트(Unicem$^{(R)}$, Biscem$^{(R)}$, Variolink II$^{(R)}$)를 사용하여 각각 제조업체의 지시에 따라 접착했다. 90개의 시편을 레진 시멘트의 종류에 따라 3개의 군으로 나누고, 각 군의 절반은 $5-55^{\circ}C$, 5,000 cycle 조건 하에서 thermocycling을 시행하였고, 다른 절반은 시행하지 않았다. 모든 시편은 결합강도를 측정하기 전에 $37^{\circ}C$ 생리 식염수에 24시간 동안 보관되었다. 전단결합강도는 만능시험기를 이용하여 0.5 mm/min의 cross head speed로 측정하였다. 결과 값은 t-test 및 one-way ANOVA를 사용하여 통계 분석하였다. 결과: Unicem$^{(R)}$ 군의 전단결합강도가 thermocycling 후에 약간 감소했으나 3 개의 군 중 가장 높은 결합 강도를 보였다. Unicem$^{(R)}$ 및 Valiolink II$^{(R)}$ 군의 전단결합강도가 thermocycling에 영향을 받았지만 Biscem$^{(R)}$은 영향을 받지 않았다(P<.05). Thermocyling 전에는 3개의 군 간의 결합강도에 유의한 차이가 없었지만, thermocyling 후에는 Unicem$^{(R)}$과 Valiolink II$^{(R)}$ 군 간에 유의한 차이가 있었다(P<.05). 결론:CAD/CAM 세라믹 인레이 수복물을 치아에 접착할 때, etch-and-rinse 레진 시멘트인 Valiolink II$^{(R)}$ 대신self-adhesive 레진 시멘트인 Unicem$^{(R)}$과 Biscem$^{(R)}$을 사용해도 임상적으로 유용하다.

• 대한치과보철학회지
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• 제30권1호
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• pp.55-64
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• 1992

This study investigated the effect of porcelain primer on bonding of coomposite resin to porcelain surface. In order to test the bond strength between porcelain and composite resin, porcelain cylinders were embedded in acrylic resin, and polished with 240grit silicone caqrbide paper. The specimens were divided into twelve groups. All specimens were treated with three porcelain primers and bonded with five composite resins. All test groups were stored in $37^{\circ}C$ distilled water for 48hours. Shear bond strengths were measured with Instron(Model 4201) at a cross-head speed of 1mm/min. The obtained results were as follows : 1. Scotchprime/Silux II group and BISCO Porcelain Primer/Bisfill group showed significant higher bond strengths than Clearfil Porcelain Primer/photo Clearfil Bright group(p<0.05). And there was no significant differences in bond strengths between Scotchprime/Silux II group and BISCO Porcelain Primer/Bisfill group(p>0.05). 2. When composite resins were used with Scotchprime, the bond strengths were decresed Silux II$(16.68{\pm}3.35MPa)$, Bisfil$(16.23{\pm}4.54MPa)$, Poly-Fill$(14.74{\pm}4.08MPa)$, Photo Clearfil Bright$(13.75{\pm}2.89MPa)$ and Pekalux$(14.74{\pm}4.08MPa)$ in order, but there was no statistical significance(p>0.05). 3. When composite resins were used with BISCO Porcelain Primer, the bond strength were decreased Bisfil$(16.17{\pm}1.60MPa)$, Silux II$(12.13{\pm}2.37MPa)$, Poly-Fill$(10.78{\pm}1.99MPa)$, Photo Cleafil Bright $(9.91{\pm}4.59MPa)$ and Pekalux$(7.36{\pm}2.16MPa)$ in order, but there was no statistical significance(p>0.05). 4. Silux II, Photo Clearfil Bright and Poly-Fill used with Scotchprime showed significant higher bond strengths than BISCO Porcelain Primer(p>0.05).

• 대한치과보존학회:학술대회논문집
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• 대한치과보존학회 2001년도 추계학술대회(제116회) 및 13회 Workshop 제3회 한ㆍ일 치과보존학회 공동학술대회 초록집
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• pp.577-577
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• 2001

The lastest concepts in bonding are "total etch", in which both enamel and dentin are etched with an acid to remove the smear layers, and "wet dentin" in which the dentin is not blown dry but left moist before application of the bonding primer. Ideally, the application of a bonding agent to tooth structure should be insensitive to minor contamination from oral fluids. Clinically contaminations such as saliva, gingival fluid, blood and handpiece lubricant are often encountered by dentists during preparation of a restoration. The aim of this study was to evaluate the effect of contamination by hem-ostatic agents on shear bond strength of compomer restorations. One hundred and ten extracted human maxillary and mandibular molar teeth were collected. The teeth were cleaned from soft tissue remnant and debris and stored in physiologic solution until they were used. Small flat area on dentin of the buccal surface were wet ground serially with 400, 800 and 1200 abrasive paper on automatic polishing machine. The teeth were randomly divided into 11 groups. Each group was conditioned as follows: Group 1 : Dentin surface was not etched and not contaminated by hemostatic agents. Group2 : Dentin surface was not etched but was contaminated by Astringedent (Ultradent product Inc., Utah, U.S.A.). Group3 : Dentin surface was not etched but was contaminated by Bosmin (Jeil Phann, Korea.). Group4 : Dentin surface was not etched but was contaminated by Epri-dent (Epr Industries, NJ, U.S.A.). Group5: Dentin surface was etched and not contaminated by hemostatic agents. Group 6 : Dentin surface was etched and contaminated by Astringedent. Group7 : Dentin surface was etched and contaminated by Bosmin. Group8 : Dentin surface was etched and contaminated by Epri-dent. Group9 : Dentin surface was contaminated by Astringedent. The contaminated surface was rinsed by water and dried by compressed air. Group10 : Dentin surface was contaminated by Bosmin. The contaminated surface was rinsed by water aud dried by compresfed air. Group 11 : Dentin surface was contaminated by Epri-dent. The contaminated surface was rinsed by water and dried by compresfed air. After surface conditioning, F2000 was applicated on the conditoned dentin surface. The teeth were thermocycled in distilled water at $5^{\circ}C\;and\;55^{\circ}C$ for 1000 cycles. The samples were placed on the binder with the bonded compomer-dentin interface parallel to the lmife-edge shearing rod of the Universal testing machine(Zwick 020, Germany) running at a cross head speed of 1.0mmimin. There were no significant differences in shear bond strength between groups 1 and group 3 and 4, but group 2 showed significant decrease in shear bond strength compared with group 1. There were no significant differences in shear bond strength between group 5 and group 7 and 8, but group 6 showed significant decrease in shear bond strength compared with group 5. There were no significant differences in shear bond strength between group 5 and group 9, 10 and 11.

• Restorative Dentistry and Endodontics
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• 제22권2호
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• pp.609-621
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• 1997

The purpose of this study was to evaluate the shear bond strength of three light-cured glass ionomer cements to blood contaminated bovine dentin. The materials used in this study were Fuji II LC, Dyract and Variglass VLC. The dentin conditioners were 10% polyacrylic acid, 10% maleic acid and 10% phosphoric acid. 180 lower anterior bovine teeth were selected in this study. The teeth were embedded in acrylic resin and were grounded with 320 to 600 grit silicon carbide paper to create a flat dentin surface. The teeth were divided into SIX groups. The experimental procedures in six groups were as follows; Group l(GF) : Samples bonded to dentin surface with Fuji II LC after 10% polyacrylic acid treatment. Group 2(BGF) : Samples bonded to dentin surface with Fuji II LC after 10% polyacrylic acid treatment and blood contamination. Group 3(MD) : Samples bonded to dentin surface with Dyract after 10% maleic acid treatment. Group 4(BMD) : Samples bonded to dentin surface with Dyract after 10% maleic acid treatment and blood contamination. Group 5(PV) : Samples bonded to dentin surface with Variglass VLC after 10% phosphoric acid treatment. Group 6(BPV) : Samples bonded-to dentin surface with Variglass VLC after 10% phosphoric acid treatment and blood contamination. Group 1,3 and 5 were classified into the control groups, while group 2,4 and 6 were classified into the experimental groups. Each group contained 30 samples. After 24 hours water storage at $37^{\circ}C$, all smples were subjected to a shear load to fracture at a cross head speed of 1.0 mm/min with Instron universal testing machine(No. 4467). Debonded surfaces were observed under Scanning Electron Microscope(Hitachi S-2300) at 20kvp. The data were evaluated statistically at the 95% confidence level with Student's t-test. The following results obtained; 1. Shear bond strengths were higher in the control groups(1,3,5 group) than in the experimental groups(2,4,6 group). 2. The shear bond strength of group 5(PV) was the highest in the control groups, and the group 5 was significantly higher than the group l(GF) on the shear bond strength. 3. The group 4(BMD) was the highest on the shear bond strength, and the group 2(BGF) was the lowest in the experimental groups. The group 4(BMD) and 6(BPV) showed a significant difference with the group 2 on the shear bond strength. 4. All the groups showed an adhesive-cohesive failure. except the group 2(BGF) showing adhesive failure.

• Asian-Australasian Journal of Animal Sciences
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• 제13권1호
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• pp.10-18
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• 2000

This paper describes the magnetic orientation of the intact and demembranated bull sperm treated by DTT or heparin in a 5,400 G static field. Semen samples collected from four bulls (Japanese Black) were mixed to the same sperm density. One percentage triton X-100 was used to extract the plasma membrane. The intact and demembranated sperm suspensions were treated with 20, 200, 2,000 mM DTT, 100, 1,000 or 10,000 units heparin solutions at $4{^{\circ}C}$ for 6 days. The decondensation of the sperm nuclei treated by DTT or heparin was examined by measuring the sperm head area at 1, 3, and 6 days. After measuring the area, each sperm sample was exposed to a 5,400 G static magnetic field generated by Nd-Fe-B permanent magnets for 24 hours at room temperature. Results showed that the decondensation of bull sperm nuclei was not induced by the heparin treatment, however, incomplete decondensation was induced by the DTT treatment. During the magnetic orientation, bull sperms treated by DTT or heparin had low percentages of long axis perpendicular to the magnetic lines of force. However, different aspects were obtained for long axis perpendicular orientations following treatment of DTT or heparin. Through the DTT treatment, the decline of long axis perpendicularly oriented percentages was due to the increase of long axis parallel orientation with the head of the flat plane perpendicular to the magnetic lines of force, whereas, using the heparin treatment, the decline of long axis perpendicular orientation was due to the increment of long axis parallel orientation with the head of the flat plane parallel to the magnetic lines of force. Also, percentages of the head of the flat plane perpendicular were decreased by the heparin treatment. These findings suggest that maintaining the structure of protamine in the chromatin is necessary for the sperm head to orient with its flat plane perpendicular, and maintaining the disulfide bond in the chromatin is necessary for the long axis of sperm to orient perpendicularly.

• 대한치과보철학회지
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• 제41권5호
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• pp.606-616
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• 2003

Purpose : The purpose of this study was to research the properties of some chemically cured methacrylate polymers such as MMA, HEMA, TEG-DMA, bis-GMA, GMA. Material and Method : 5 kinds of methacrylates were selected and added 2% tertiary amine and benzoyl peroxide to make a chemically curable polymer 25 micron crushed silicas which are treated with silane were selected as filler, they were added into methacrylate monomer until the consistency did not changed by the load of 500gram. All of the experimental resins were 5 kinds, and a serial test was done with 3 kinds of items including the filler contents, the tensile strength, and the bond strength. The number of specimen were 10 for each group. Filler contents were obtained by reducing the specimens to ashes at $600^{\circ}C$ for 1 hour. The specimens with the dimension of 6mm in diameter and 3mm thick were immersed in $37{\pm}1^{\circ}C$ distilled water for 24 hours before test, and tensile strength were measured with cross-head speed 1mm/min. Shear bond strength were mea sured on the specimens attached to bovine enamel etched with 37% phosphoric acid for 1 minute. Results : 1. Maximum filler incorporation was the highest as 75.5% on MMA, and the least as 53.4% on bis- GMA(p<0.0001). 2. The tensile stregth were MMA 141.3, GMA 154.3, TEG-DMA 157.4, bis-GMA 161.4 MPa, and HEMA showed the highest value, 226.9MPa(p = 0.0004). 3. The bond strength were GMA 10.1, TEG-DMA 11.7, HEMA 12.2, bis-GMA 13.3 MPa, and MMA showed the highest value, 15.3MPa, however statistical significances were not (p =0.3838), 4. TEG-DMA and HEMA were not different on the aspect of maximum filler contents and shear bond strength(p>0.05). Conclusion : HEMA can be used as an another diluent substituting TEG-DMA with the increased strength and with the constant bond strength and the constant filler contents.

• 대한치과보철학회지
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• 제32권1호
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• pp.1-8
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• 1994

근관 충전에 사용된 sealer가 포스트를 세멘트할때 사용되는 레진 세멘트에 어떠한 영향을 주는지 알아보기 위하여 절치 치근 86개를 사용하여 통상의 방법으로 근관확대한 후, 44개의 치근은 I, II, & III군의 Z.O.E. sealer, 42개의 치근은 IV, V, & VI군의 수산화칼슘 계통의 sealer인 Apexit를 사용하여 근관충전하였다. 근관충전 1일(I, IV군), 3일 (II, V군), 7일(III, VI군)이 경과된 후에 기성의 Para-post stainless steel post를 사용하여 a군에서는 Z.P.C.로, b군에서는 All-Bond & composite resin cement로 깊이 7mm가 되게 세멘트하여 군당 시편의 수가 7-8개 되도록 하여 12군으로 나누었다. 완전한 세멘트의 경화를 위하여 5일이 경과된 후 인스트론 만능시험기에 retention jig를 사용하여 거상하고 1mm/min의 cross-head speed로 인장력을 가하여 유지력을 측정하여 다음과 같은 결과를 얻었다. 1. Z.O.E. sealer사용 후 All-Bond & composite resin cement로 세멘트한 군에서 I b군이 $15.5{\pm}7.1kg$, II b군이 $21.6{\pm}5.4kg$, 그리고 III b군이 $20.1{\pm}8.1kg$으로 나타나 I b군이 매우 유지력이 낮았으나 통계학적 유의성은 없었다(p>0.05). 2. 수산화칼슘 계통의 sealer 사용 후 All-Bond & composite resin cement로 세멘트한 군에서 IV b군이 $19.0{\pm}6.7kg$, V b군이 $17.3{\pm}6.5kg$, 그리고 VI b군이 $18.9{\pm}7.9kg$으로 나타났으며 통계학적 유의성은 없었다(P>0.05). 3. 같은 sealer를 사용하고 같은 기간에서 Z.P.C.와 All-Bond & composite resin cement의 포스트 유지력 비교시 All-Bond & composite resin cement 군이 Z.P.C. 군보다 높게 나타났으나 통계학적 유의성은 없었다(P>0.05).