• 공업화학
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• 제26권4호
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• pp.432-438
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• 2015

본 연구에서는 활성탄소섬유(ACFs)에 함산소불화 표면처리를 수행하여 수용액상에 존재하는 저농도 $Cr^{6+}$ 이온의 흡착특성을 조사하였다. ACFs의 기공구조와 표면특성은 BET와 X선 광전자 분광기(XPS)를 통해 각각 확인하였다. ACFs의 함산소불화 처리는 ACFs의 표면에 중금속 흡착 능력에 영향을 미치는 C-O 결합의 비율을 크게 증가시켰으며, 그 결과 $Cr^{6+}$ 흡착이 10 min 이내에 빠르게 평형에 도달할 수 있었다. 또한 초기 $Cr^{6+}$ 농도 20 ppm에서 최대 $Cr^{6+}$ 제거효율은 미처리 ACFs와 비교하여 약 100% 증가하였다. 이러한 결과로부터 ACFs의 함산소불화 반응은 저농도 $Cr^{6+}$의 흡착을 위한 표면처리법으로 응용될 수 있을 것이다.

• Bulletin of the Korean Chemical Society
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• 제27권10호
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• pp.1623-1632
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• 2006

NiO supported on zirconia modified with $MoO_3$ for acid catalysis was prepared by drying powdered $Ni(OH)_2-Zr(OH)_4$ with ammonium heptamolybdate aqueous solution, followed by calcining in air at high temperature. The characterization of prepared catalysts was performed using FTIR, Raman, XRD, and DSC. $MoO_3$ equal to or less than 15 wt% was dispersed on the surface of catalyst as two-dimensional polymolybdate or monomolybdate, while for $MoO_3$ above 15 wt%, crystalline orthorhombic phase of $MoO_3$ was formed, showing that the critical dispersion capacity of $MoO_3$ on the surface of catalyst is 0.18 g/g NiO-$ZrO_2$ on the basis of XRD analysis. Acidity and catalytic activities for acid catalysis increased with the amount of dispersed $MoO_3$. The high acid strength and acidity was responsible for the Mo=O bond nature of the complex formed by the interaction between $MoO_3$ and $ZrO_2$. The catalytic activity for acid catalysis was correlated with the acidity of the catalysts measured by the ammonia chemisorption method.

• 콘크리트학회논문집
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• 제19권1호
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• pp.67-74
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• 2007

FRP 판을 콘크리트 구조물의 거푸집 및 보강재로 이용하기 위한 기본적인 실험을 수행하였다. FRP 판과 콘크리트가 합성 효과를 발휘하기 위해서는 두 재료간의 부착이 중요한 요인 중의 하나이다. 이러한 부착을 확보하기 위하여 FRP 판에 두 가지 크기의 골재를 일반적으로 건설 현장에서 많이 사용하는 에폭시를 이용하여 부착 하였다. 콘크리트 보는 FRP 판만으로 인장 보강하였고 추가적인 휨 및 전단 보강은 하지 않았다. 비교를 위해 한 비교 실험 시편은 FRP 판에 골재를 부착하지 않고, 다른 한 비교 실험 시편은 FRP 판 대신에 종래의 철근으로 보강하여 실험하였다. 모든 콘크리트 보의 실험은 보의 중앙에 집중하중을 파괴까지 재하하였다. 실험 결과는 현행 ACI 318(2005)과 ACI 440(2006)과 비교 분석하였다. 본 연구 결과 FRP 판을 콘크리트 구조물의 거푸집 대용 및 인장 보강재로 충분히 활용할 수 있는 가능성을 보여주었다.

• 대한토목학회논문집
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• 제32권6D호
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• pp.615-622
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• 2012

숏크리트는 현장에서 빠른 시공을 실시하여 굴착면을 침식으로부터 보호하고 암괴의 전단이동방지, 암괴의 붕괴방지, 개구절리의 봉합, 응력의 집중완화, 응력전달효과 등에 의하여 후속작업의 원활한 진행이 될 수 있도록 굴착면을 방지하여 지내력을 증대시키는 것이 주목적이다. 숏크리트공법으로는 건식과 습식의 두 가지방법이 있으며, 1997년 이후부터는 건식보다 습식 숏크리트가 많이 이용되고 있다. 그러나 작업 중 목적물에 부착되지 않고 반발되는 현상, 즉 리바운드가 많이 발생하며 이러한 많은 양의 리바운드는 숏크리트와 전체 공사비 원가에 중대한 영향을 미치게 된다. 특히 숏크리트는 재료비, 배합, 타설시간 증가, 재료의 취급과 계량장치에 소요되는 인력 및 버력제거를 위한 비용 증가 발생원인이 되고 있다. 이 연구에서는 국내현장에서 시행한 급결제 함유량에 따른 일반 습식 숏크리트 및 강섬유 습식 숏크리트공법의 시공실적을 분석하여 반발 양 및 강도의 실험적인 분석을 실시하였다. 또한 국내 건설공사에 실제 사용할 수 있는 효과적이고 합리적인 방법을 제시하였다.

• BMB Reports
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• 제31권4호
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• pp.370-376
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• 1998

Src-Homology 2 (SH2) domains have a capacity to bind phosphotyrosine-containing sequence context and play essential roles in various cellular signaling pathways. Due to the specific nature of the binding between SH2 domains and their counterpart proteins, inhibitors of SID domain binding have drawn extensive attention as a potential candidate for therapeutic agents. Here, we describe the binding assay system to screen for the ligands or blockers of the SH2 domains with an emphasis on the $p56^{lck}$ SH2 domain. In our assay system, SID domains expressed and purified as fusion proteins to Glutathione-S-transferase (GST) were covalently attached to 96-well microtitre plates through amide bond formation, which were subsequently allowed to bind the biotinylated phosphotyrosine (pY)containing synthetic pep tides. The binding of biotinylated pY peptides was detected by the horseradish peroxidase (HRP)-conjugated streptavidin. Using the various combinations of SH2 domain-pY peptides, we observed that: (1) The binding of pY-peptides to its counterpart SH2 domain is concentration-dependent and saturable; (2) The binding is highly specific for a particular combination of SH2 domain-pY peptide pair; and (3) The binding of Lck SH2-cognate pY-peptides is specifically competed by the nonbiotinylated peptides with expected relative affinity. These results indicate that the established assay system detects the SH2-pY peptide interaction with reproducible sensitivity and specificity and is suitable for screening the specific inhibitors of $p56^{lck}$ SH2 function.

• Steel and Composite Structures
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• 제36권2호
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• pp.187-196
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• 2020

Double skin composite wall system owns several structural merits in terms of high load-carrying capacity, large axial stiffness, and favorable ductility. A recently proposed form of truss connector was used to bond the steel plates to the concrete core to achieve good composite action. The structural behavior of rectangular high walls under compression and T-shaped high walls under eccentric compression has been investigated by the authors. Furthermore, the influences of the truss spacings, the wall width, and the faceplate thickness have been previously studied by the authors on short walls under uniform compression. This paper experimentally investigated the effect of width-to-thickness ratio on the compressive behavior of short walls. Compressive tests were conducted on three short specimens with different width-to-thickness ratios. Based on the test results, it is found that the composite wall shows high compressive resistance and good ductility. The walls fail by local buckling of steel plates and crushing of concrete core. It is also observed that width-to-thickness ratio has great influence on the compressive resistance, initial stiffness, and strain distribution across the section. Finally, the test results are compared with the predictions by modern codes.

• Geomechanics and Engineering
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• 제19권6호
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• pp.485-498
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• 2019

Pre-tensioned rock bolts can be classified into fully anchored, lengthening anchored and point anchored bolts based on the bond length of the resin or cement mortar inside the borehole. Bolts in varying anchoring methods may significantly affect the supporting effect of surrounding rock around a tunnel. However, thus far, the theoretical basis of selecting a proper anchoring method has not been thoroughly investigated. Based on this problem, 16 schemes were designed while incorporating the effects of anchoring length, pretension, bolt length, and spacing, and a systematic numerical experiment was performed in this paper. The distribution characteristics of the stress field in the surrounding rock, which corresponded to various anchoring scenarios, were obtained. Furthermore, an analytical approach for computing the active and passive strengthening index of the anchored surrounding rock is presented. A new fully anchoring method with pretension and matching technology are also provided. Then, an isolated loading model of the anchored surrounding rock was constructed. The physical simulation test for the bearing capacity of the model was performed with three schemes. Finally, the strengthening mechanism of varying anchoring methods was validated. The research findings in this paper may provide theoretical guidelines for the design and construction of bolting support in tunnels.

• Steel and Composite Structures
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• 제33권6호
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• pp.793-803
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• 2019

Concrete-filled steel tubular (CFST) beam-columns are widely used owing to their good performance. They have high strength, ductility, large energy absorption capacity and low costs. Externally stiffened CFST beam-columns are not used widely due to insufficient design equations that consider all parameters affecting their behavior. Therefore, effect of various parameters (global, local slenderness ratio and adding hoop stiffeners) on the behavior of CFST columns is studied. An experimental study that includes twenty seven specimens is conducted to determine the effect of those parameters. Load capacities, vertical deflections, vertical strains and horizontal strains are all recorded for every specimen. Ratio between outer diameter (D) of pipes and thickness (t) is chosen to avoid local buckling according to different limits set by codes for the maximum D/t ratio. The study includes two loading methods on composite sections: steel only and steel with concrete. The case of loading on steel only, occurs in the connection zone, while the other load case occurs in steel beam connecting externally with the steel column wall. Two failure mechanisms of CFST columns are observed: yielding and global buckling. At early loading stages, steel wall in composite specimens dilated more than concrete so no full bond was achieved which weakened strength and stiffness of specimens. Adding stiffeners to the specimens increases the ultimate load by up to 25% due to redistribution of stresses between stiffener and steel column wall. Finally, design equations previously prepared are verified and found to be only applicable for medium and long columns.

• 부모자녀건강학회지
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• 제1권
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• pp.56-74
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• 1998

The language of the newborn, like that of adults, is one of gesture, posture, and expression(Lewis, 1980). Helping parents understand and respond to their newborn's cues will make caring for their baby more enjoyable and may well provide the foundation for a communicative bond that will last lifetime. Infant state provides a dynamic pattern reflecting the full behavioral repertoire of the healthy infant(Brazelton, 1973, 1984). States are organized in a predictable emporal sequence and provide a basic classification of conditions that occur over and over again(Wolff, 1987). They are recognized by characteristic behavioral patterns, physiological changes, and infants' level of responsiveness. Most inportantly, however, states provide caregivers a framework for observing and understanding infants' behavior. When parents know how to determine whether their infant is sleep, awake, or drowsy, and they know the implications, recognition of states has for both the infant's behavior and for their caregiving, then a lot of hings about taking care of a newborn become much easier and more rewarding. Most parents have the skills and desire to do what is best for their infant. The skills 7373parents bring to the interaction are: the ability to read their infant's cues: to stimulate the baby through touch, movement, talking, and looking at: and to respond in a contingent manner to the infant's signals. Among the crucial skills infants bring to the interaction are perceptual abilities: hearing and seeing, the capacity to look at another for a period of time, the ability to smile, be consoled, adapt their body to holding or movement, and be regular and predictable in responding. Research demonstrates that the absence of these skills by either partner adversely affects parent-infant interaction and later development. Observing early parent-infant interactions during the hospital stay is important in order to identify parent-infant pairs in need of continued monitoring(Barnard, et al., 1989).

• 태양에너지
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• 제17권1호
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• pp.3-15
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• 1997

본 연구는 R-12($CF_2Cl_2F$) 대체냉매인 R-134a($CF_3CH_2F$) 적용 태양열 열펌프시스템에 의하여 학교교실($20{\sim}25$평형)이나 학교 화장실($13{\sim}17$평형)의 난방에 관한 것으로서 대체냉매 적용할 때 시스템의 안정성과 성능에 관해 실험되어졌다. 학교교실 난방을 위한 방법 중에서 온풍난방을 택하여 실험하였는데 대체냉매 적용 실제와 모형시스템의 난방성능을 비교 해석하였다. 이 결과를 근거로 R-22($CHClF_2$)와 그 대체냉매들에 대한 성능을 예측하였다. 서울지방 봄 가을철, 겨울철의 외기 온도에서 실내온도가 $18{\sim}20^{\circ}C,\;23{\sim}25^{\circ}C$로 유지할 수 있도록 설계 제작되었다.