• Title/Summary/Keyword: Bond Stress

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A Molecular Dynamics Simulation Study on Hygroelastic behavior of Thermosetting Epoxy (열경화성 에폭시 기지의 흡습탄성 거동에 관한 분자동역학 전산모사)

  • Kwon, Sunyong;Lee, Man Young;Yang, Seunghwa
    • Composites Research
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    • v.30 no.6
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    • pp.371-378
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    • 2017
  • In this study, hygroelastic behavior of thermosetting epoxy is predicted by molecular dynamics simulations. Since consistent exposures to humid environments lead to macroscopic degradation of polymer composite, computational simulation study of the hygroscopically aged epoxy cell is essential for long-time durability. Therefore, we modeled amorphous epoxy molecular unit cell structures at a crosslinking ratio of 30, 90% and with the moisture weight fraction of 0, 4 wt% respectively. Diglycidyl ether of bisphenol F (EPON862) and triethylenetetramine (TETA) are chosen as resin and curing agent respectively. Incorporating equilibrium and non-equilibrium ensemble simulation with a classical interatomic potential, various hygroelastic properties including diffusion coefficient of water, coefficient of moisture expansion (CME), stress-strain curve and elastic modulus are predicted. To establish the structural property relationship of pure epoxy, free volume and internal non-bond potential energy of epoxy are examined.

Effects of the Treated Chemicals on the Flexual and Physical Properties of Fire Retardant Treated Particleboards (내화처리(耐火處理) 파티클 보오드의 휨강도(强度)와 물리적(物理的) 성질(性質)에 미치는 약제(藥劑)의 영향(影響))

  • Lee, Phil-Woo;Kwon, Jin-Heon
    • Journal of the Korean Wood Science and Technology
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    • v.11 no.3
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    • pp.39-48
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    • 1983
  • This research was performed to investigate the manufacturing possibility of the particleboard treated with commercial fire retardant chemicals. Laboratory test boards at this investigation were made from particles treated by soaking into 5, 10, 15, and 20 percent concentration solutions of ammonium sulfate and Minalith before resin was applied. According to the results, MOR (modulus of repture) and MOE (modulus of elasticity) in flexure exceeded type 100 (100 kgf/$cm^2$, $1.5{\times}10^4\;kgf/cm^2$) of the Korean Industrial Standard (KS F 3104). Except for 15 and 20 percent chemicals concentrations of Minalith, every internal bond stress values met type 100 (1.5 kgf/$cm^2$) of KS F 3104. However thickness swelling values of fire retardant treated particleboards were not reached in the Standard (12%).

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Flexural Capacity of Encased Composite Beam with Hollow Core PC Slabs (매입형 합성보의 휨 성능 평가 -속 빈 프리캐스트 콘크리트 슬래브와 비대칭 H형강 철골보-)

  • Heo, Byung Wook;Bae, Kyu Woong;Moon, Tae Sup
    • Journal of Korean Society of Steel Construction
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    • v.16 no.5 s.72
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    • pp.587-598
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    • 2004
  • In this study, an experiment was conducted on the Slim Floor system, using a hollow core PC slab, which could reduce the over-all depth of a composite beam. The Slim Floor system is a method used in steel frame multi-story building construction, in which the structural depth of each floor is minimized after incorporating the steel floor beams within the depth of the concrete floor slab. This experimental study focused on the flexural behavior of the partially connected Slim Floor system with asymmetric steel beams encased in hollow core PC slabs. Ten full-scale specimens were constructed and tested in this study, with different steel beam heights, hollow core PC slabs, slab widths, and PC slab bearings. Observations made in line with the experiments indicated that the degree of shear connection without additional shear connection was 0.48-0.98 times more than that of the full shear connection, due to inherent mechanical and chemical bond stress.

Investigation of Maximum Strength and Effective Bonding Length at the Interface Between Structure and GFRP Material Under Freeze-thaw Cycles and Applied Different Bonding Materials (동결융해 및 부착재료 변화에 따른 GFRP-구조물 경계면의 최대 부착강도 및 유효부착길이 평가)

  • Choi, Hyun Kyu;Jung, Woo Young;Ahn, Mi Kyoung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.2
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    • pp.107-115
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    • 2011
  • This research studies the behavior of the FRP-concrete interface subjected to two environmental substances. Frist is to investigate the behavior by the application of different bonding materials at the interface between FRP and concrete, second is to understand a long-term performance at the interface by Freeze-thaw actions. The parameters considered in this research are the maximum bonding strength and the effective bonding length at the FRP-concrete interface. In the first experimental phase, three types of specimens are fabricated and tested considering the number of applied bonding materials and the Freeze-thaw tests are performed to evaluate the behavior of the interface in the cycle range of 0 to 300 cycles. Finally, it is known that there is a 5~7% difference of the effective bonding length between applied bonding materials and the values for the maximum stress and the effective length under Freeze-thaw action are varied randomly as the freeze-thaw cycle is increased even though initial reduction of their capacities are occurred.

A Study on the high Temperature Properties of the Graded Thermal Barrier Coatings by APS and PAS (APS법으로 제조된 열장벽 피막과 PAS법으로 제조된 열장벽 성형체의 고온 물성에 관한 연구)

  • 강현욱;권현옥;한주철;송요승;홍상희;허성강;김선화
    • Journal of Surface Science and Engineering
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    • v.32 no.2
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    • pp.144-156
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    • 1999
  • Thermal Barrier Coating with Functional Gradient Materials (FGM-TBC) can play an important role to protect the parts from harmful environments in high temperatures such as oxidation, corrosion, and wear and to improve the efficiency of aircraft engine by lowering the surface temperature on turbine blade. FGM-TBC can increase the life spans of product and improve the operating properties. Therfore, in this study the evaluations of mechanical and thermal properties of FGM-TBC such as fatigue, oxidation and wear-resistance at high temperatures have been conducted. The samples of both the TBC with 2, 3, 5 layers (YSZ/NiCrAlY) to be produced by Air Plasma Spray method (APS) and the bulk TBC with 6 layers to be produced by Plasma Assisted Sintering method (PAS) were used. Furthermore, residual stress, bond strength, and thermal conductivity were evaluated. The average thickness of the APS was 500$\mu\textrm{m}$ to 600$\mu\textrm{m}$ and the average thickness of the PAS was 3mm. The hardness number of the top layer of APS was 750 Hv to 810Hv and that of PAS was 950 Hv to 1440Hv. The $ZrO_2$ coating layer of APS was composed of tetragonal structure after spraying as the result of XRD analysis. As shown in the results of the high temperature wear test, the 3 layer coating of APS had the best wear resistance at $800^{\circ}C$ and the 5 layer coating of APS had the best wear resistance at $600^{\circ}C$. But, these coatings had the tendency of the low-temperature softening at $300^{\circ}C$. The main mechanism of wear was the adhesive wear and the friction coefficient of coatings was increased as increasing the test temperatures. A s results of thermal conductivity test, the ${\Delta}T$ of the APS coating was increased as number of layer and the range of thermal conductivity of the PAS was $800^{\circ}C$ to $1000^{\circ}C$.

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Effect of Aspect Ratio on Direct Tensile Response of Strain Hardening Cement Composites with PET and PVA Fiber (PET 및 PVA섬유를 사용한 변형경화형 시멘트 복합체의 직접인장거동에서 섬유 형상비의 영향)

  • Jeon, Esther;Yun, Hyun-Do;Park, Wan-Shin;Kim, Yong-Chul;Kim, Yun-Su
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.913-916
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    • 2008
  • Direct tensile response of strain hardening cement composites(SHCC) depends primarily on the material's tensile response, which is a water cement ratio, direct function of fiber and matrix characteristics, the bond between them, and the fiber volume fraction. This paper discusses effect of aspect ratio of the direct tensile response of SHCC with PET and PVA fibers. The main variables considered include the aspect ratio of PET fibers(Aspect ratio, ${\ell}/d_f$ : 150, 300, 600). For the same mixture proportion, PET1.5+PVA0.5-300 and PET1.5+PVA 0.5-600(Aspect ratio 300, 600) showed better overall behavior(Pseudo strain-hardening, Multiple cracking) than specimens with PET1.5+PVA0.5-150(Aspect ratio 150). Tensile strain of PET1.5+PVA0.5-300 and PET1.5+PVA 0.5-600 at ultimate tensile stress were 0.5, 2.0% respectively.

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Force-based Coupling of Peridynamics and Classical Elasticity Models (페리다이나믹과 탄성체 모델의 연성기법 개발)

  • Ha, Youn Doh;Byun, Taeuk;Cho, Seonho
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.27 no.2
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    • pp.87-94
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    • 2014
  • In solid mechanics, the peridynamics theory has provided a suitable framework for material failure and damage propagation simulation. Peridynamics is computationally expensive since it is required to solve enormous nonlocal interactions based upon integro-differential equations. Thus, multiscale coupling methods with other local models are of interest for efficient and accurate implementations of peridynamics. In this study, peridynamic models are restricted to regions where discontinuities or stress concentrations are present. In the domains characterized by smooth displacements, classical local models can be employed. We introduce a recently developed blending scheme to concurrently couple bond-based peridynamic models and the Navier equation of classical elasticity. We demonstrate numerically that the proposed blended model is suitable for point loads and static fracture, suggesting an alternative framework for cases where peridynamic models are too expensive, while classical local models are not accurate enough.

Analysis for Nonlinear Behavior of Concrete Panel Considering Steel Bar Buckling (철근 좌굴을 고려한 콘크리트 패널의 비선형 거동에 대한 해석)

  • Lee, Sang-Sup;Park, Keum-Sung;Bae, Kyu-Woong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.6
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    • pp.130-137
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    • 2018
  • Many constitutive models for concrete have been developed to predict the nonlinear behavior of concrete members considerably. The constitutive model for reinforcing bar that include the tension stiffening effect due to the bond characteristics between steel bars and concrete is being studied but the bilinear model is generally used. It was found that the buckling of the longitudinal reinforcing bars is controlled the nonlinear behavior of hybrid precast concrete panel, which is being developed for core wall. In this study, the constitutive models that can consider the embedding and buckling effects of reinforcing bar are investigated and a new model combing these constitutive models is proposed. In order to verify the proposed model, the analysis results are compared with experimental results of the concrete wall and hybrid precast concrete panel. The analysis of embedding-effect-only modeling predicted that the deformation increases continually without the decrease in the load carrying capacity. However, the analysis results of proposed model showed good agreement with some experimental results, thus verifying the proposed computational model.

Influence of the Fluorine-doping Concentration on Nanocrystalline ZnO Thin Films Deposited by Sol-gel Process

  • Yoon, Hyunsik;Kim, Ikhyun;Kang, Daeho;Kim, Soaram;Kim, Jin Soo;Son, Jeong-Sik;Leem, Jae-Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.204.2-204.2
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    • 2013
  • Wide band gap II-VI semiconductors have attracted the interest of many research groups during the past few years due to the possibility of their applications in light-emitting diodes and laser diodes. Among the II-VI semiconductors, ZnO is an important optoelectronic device material for use in the violet and blue regions because of its wide direct band gap (Eg ~3.37 eV) and large exciton binding energy (60 meV). F-doped ZnO (FZO) and undoped ZnO thin films were grown onto quartz substrate by the sol-gel spin-coating method. The doping level in the solution, designated by F/Zn atomic ratio of was varied from 0 to 5 in 1 steps. To investigate the effects of the structure and optical properties of FZO thin films were investigated using X-ray diffraction (XRD), UV-visible spectroscopy, and photoluminescence (PL). In the XRD, the residual stress, FWHM, bond length, and average grain size were changed with increasing the doping concentration. For the PL spectra, the high INBE/IDLE ratio of the FZO thin films doping concentration at 1 at.% than the other samples.

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Mode III Fracture Toughness of Single Layer Graphene Sheet Using Molecular Mechanics (분자역학을 사용한 단층 그래핀 시트의 모드 III 파괴인성)

  • Nguyen, Minh-Ky;Yum, Young-Jin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.2
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    • pp.121-127
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    • 2014
  • An atomistic-based finite bond element model for predicting the tearing mode (mode III) fracture of a single-layer graphene sheet (SLGS) is developed. The model uses the modified Morse potential for predicting the maximum strain relationship of graphene sheets. The mode III fracture of graphene under out-of-plane shear loading is investigated with extensive molecular mechanics simulations. Molecular mechanics is used for describing the displacements of atoms in the area near a crack tip, and linear elastic fracture mechanics is used outside this area. This work shows that the molecular mechanics method can provide a reliable and yet simple method for determining not only the shear properties of SLGS but also its mode III fracture toughness in the armchair and the zigzag directions; the determined mode III fracture toughness values of SLGS are $0.86MPa{\sqrt{m}}$ and $0.93MPa{\sqrt{m}}$, respectively.