• Korean Journal of Materials Research
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• v.8 no.6
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• pp.505-512
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• 1998

In this study, two-layer thermal barrier coatings composed of plasma sprayed 0.3mm $ZrO_2(8wt% Y_2o_3)$ ceramic coating layer and O.lmm $NiCrAlCoY_20_3$ bond coating layer on AISI 316 were investigated microstructure of the coating, oxidation of the metallic bond coating and adhesive strength to evaluate the durability of coating layer after cyclic and isothermal test at 90$0^{\circ}C$. And quantitative phase analysis of $ZrO_2(8wt% Y_2o_3)$ ceramic coating was performed as a function of thermal exposure time using XRD technique. The results showed that the amount of m - 2rO, phase in the coating was slightly increased with increasing thermal exposure time at 90$0^{\circ}C$. The c/a ratio of t' - $ZrO_2$ in the as-sprayed coating was 1.0099 and slightly increased to 1.0115 after 100 hours heat treatment. It was believed that $Y_2O_3$ in high yttria tetragonaJ(t') was transformed to low yttria tetragonaJ(t) by $Y_2O_3$ diffusion with increasing thermal exposure time. The adhesive strength was gradually decreased as thermal exposure time increased. After the isothermal test, the failure predominantly occured in ceramic coating layer. On the other hand. the specimens after cyclic thermal test were mostly failed at bond coating/ceramic coating interface. The failure was oeeured by decreasing the bond strength between bond coating and oxide scale which were formed by oxidation of the metallic elements within bond coating and by thermal stress due to thermal expansion mismatches between the oxide scale and ceramic coating.

• Korean Journal of Materials Research
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• v.15 no.6
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• pp.375-381
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• 2005

High temperature oxidation behavior of thermal barrier coating (TBC) system (IN738 substrate + NiCoCrAlY or NiAl bond coat with or without Pt + yttria stabilized zirconia) prepared by air plasma spray (APS) process has been studied in order to understand the effect of Pt addition to bond coat on the stability of TBC system. Specimens were oxidized in thermal cycling and isothermal oxidation test at $1100^{\circ}C$. The Pt addition in TBC system with NiCoCrAlY bond coat showed a longer life time compared to that without addition of Pt. Pt addition to TBC system is believed to help the formation of more stable thermally grown oxide, $Al_2O_3$, at the TBC/bond coat interface, leading to a longer lifetime of TBC system.

• Journal of the Korea Concrete Institute
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• v.25 no.1
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• pp.73-80
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• 2013

Polymer cement slurry (PCS) made from organic polymer dispersion and cement has good adhesion to steel, waterproofness and acid resistance due to being of polymer films formed in cement slurry. The purpose of this study is to evaluate the mix design conditions at early curing age of PCS-coating material effected on improvement in bond strength of coated rebar. The test pieces are prepared with two types of polymer dispersions such as St/BA and EVA, four polymer-cement ratios, two types of cement, four coating thicknesses and three curing ages, and tested for the bond strength test. From the test results, in general, bond strength of PCS-coated rebar is better than that of uncoated rebar and epoxy-coated rebar. It is also high bond strength at curing ages of 7-day or less, and coating thicknesses of $75{\mu}m$ and $100{\mu}m$. The maximum bond strength of PCS-coated rebar at curing age of 3-hour is almost same as that of curing age of 1-day and 7-day. The maximum bond strength of PCS-coated rebar with ultra high-early strength cement and St/BA at polymer-cement ratio of 80%, and coating thickness of $100{\mu}m$ is about 1.52 and 1.58 times respectively, the strength of uncoated rebar and epoxy-coated rebar. It is apparent that the curing age, coating thickness, type of polymer and cement are very important factors to improve the bond strength of PCS-coated rebar to cement concrete. We can have basic information that PCS-coated rebar with curing age at 3-hour and coating thickness of $100{\mu}m$ can replace epoxy-coated rebar.

• The Journal of Korean Academy of Prosthodontics
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• v.36 no.1
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• pp.26-49
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• 1998

The purpose of this study was to confirm the formation of hybrid layer and resin tags in dentin tissue and the possibility of bonding between luting cements used for the prosthesis and the resinous surface coated with resin bonding agents to prevent the dentin hypersensitivity after abutment preparation. Some resin bonding agents, which may have the possibility of bonding with polyacrylic acid as a liquid ingredient of polycarboxylate and glass ionomer cements, were selected. All-Blond desensitizer containing NTG-GMA and BPDM, Scotch-Bond Multipurpose plus containing HEMA, and XR-bond containing organophosphate were selected as a coating agent. Dental cements were zinc phosphate, polycarboxylate, and glass ionomer cement. After the exposed dentin surface of premolars was ethced with 10% phosphoric acid and coated with resin bonding agents, the morphology of treated surfaces and the resin tags and hybrid layers on sectioned surfaces were observed by SEM. Shear bond strength between the resin bonding agents and 3 kinds of cements was measured 24 hours after bonding. On the debonded surfaces of the shear bond strength tested specimens, the cement tags and the bonding sites between the resin materials and cements were examined by SEM. Following conclusions were drawn : 1. Coating of dentin with resin bonding agents had no effect on the shear bond strength of zinc phosphate cement. 2. Both of polycarboxylate and glass ionomer cements showed the increased shear bond strength by the dentinal coating with Scotch-Bond Multipurpose plus containing HEMA. However, in the case of dentinal coating with some agents containing NTG-GMA and BPDM or organophosphate, polycarboxylate cement exhibited the lowered shear bond strength, and glass ionomer cement showed the unchanged shear bond strength. 3. Complete obstructions of dentinal tubules were observed on the dentin coated with All-Bond desensitizer or XR-bond, but distinct shape of the orifices of dentinal tubules was observed consistently on the dentin coated with Scotch-Bond Multipurpose plus. 4. The hybrid layer was thickest on the dentin coated with All-Bond desensitizer, and the length of resin tags was longest on the dentin coated with Scotch-Bond Multipurpose plus. 3. On the debonded specimens which had been bonded with polycarboxylate cement or glass ionomer cement after coating with Scotch-Bond Multipurpose plus, the cement tags and the bonding sites between the resinous surface and the cements could be examined.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• v.y2005m4
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• pp.106-111
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• 2005

Failure mechanisms were investigated for the two layer thermal barrier coatings consisting of NiCrAlY bond coat and $ZrO_2-8wt.\% Y_{2}O_3$ ceramic coating during cyclic oxidation. $Al_{2}O_3$ developed at the ceramic coating/bond coat interface first, followed by the Cr/Ni rich oxides such as $NiCr_{2}O_4 and Ni(Al,Cr)_{2}O_4$ during cyclic oxidation It was observed that the spalling of ceramic coatings took place primarily within the NiCrAlY bond coat oxidation products or at the interface between the bond coat oxidation products and zirconia based ceramic coating or the bond coat. It was also observed that the fracture within these oxidation products occurred with the formation of $Ni(Cr,Al)_{2}O_4$ spinel or Cr/Ni rich oxides. It was therefore concluded that the formation of these oxides was a life-limiting event for the thermal barrier coatings.

• The Korean Journal of Ceramics
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• v.4 no.4
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• pp.340-344
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• 1998

Failure mechanisms were investigated for the two layer thermal barrier coatings consisting of NiCrAlY bond coat and $ZrO_2$-8wt.% $Y_2O_3$ ceramic coating during cyclic oxidation. $Al_2O_3$ developed at the ceramic coating/bond coat interface first, followed by the Cr/Ni rich oxides such as $NiCr_2O_4$ and $Ni(Al, Cr)_2O_4$ during cyclic oxidation. It was observed that the spalling of ceramic coatings took place primarily within the NiCrAlY bond coat oxidation products or at the interface between the bond coat oxidation products and zirconia based ceramic coating or the bond coat. It was also observed that the fracture within these oxidation products occurred with the formation of $Ni(Cr, Al)_2O_4$ spinel or Cr/Ni rich oxides. It was therefore concluded that the formation of these oxides was a life-limiting event for the thermal barrier coatings.

• Proceedings of the Korea Concrete Institute Conference
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• 1996.10a
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• pp.122-126
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• 1996

In recent years, plenty of problems in the large-scaled bridges, piers…have been reported to the public due to the severe environment factors. The use of Epoxy-Coated reinforcement against salt and sulfate corrosion is considered as a reasonable solution and tested to study the bond performance between the thickness of coating and bond stresses. The results are that the strength of bond was decreased by 10 to 13 percent in the case of 100$\mu\textrm{m}$ of coating thickness and by 15 to 25 percent in the case of 200$\mu\textrm{m}$ to 300$\mu\textrm{m}$ and significantly fell down when the thickness was above 300$\mu\textrm{m}$. Accordingly, a 200$\mu\textrm{m}$ coating-thickness to the reinforcement is suggested to maintain the acceptable bond mechanism and goes well with the ASTM(item NO.A775) and those of Korean Concrete Institute.

• Korean Journal of Metals and Materials
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• v.48 no.10
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• pp.901-906
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• 2010

The first stage blade of a gas turbine was operated under a severe environment which included both $1300^{\circ}C$ hot gas and thermal stress. To obtain high efficiency, a thermal barrier coating (TBC) and an internal cooling system were used to increase the firing temperature. The TBC consists of multi-layer coatings of a ceramic outer layer (top coating) and a metallic inner layer (bond coat) between the ceramic and the substrate. The top and bond coating layer respectively act as a thermal barrier against hot gas and a buffer against the thermal stress caused by the difference in the thermal expansion coefficient between the ceramic and the substrate. Particularly, the bondcoating layer improves the resistance against oxidation and corrosion. An inter-diffusion layer is generated between the bond coat and the substrate due to the exposure at a high temperature and the diffusion phenomenon. A thickness measurement result showed that the bond coat of the suction side was thicker than that of the pressure side. The thickest inter-diffusion zone was noted at SS1 (Suction Side point 1). A chemical composition analysis of the bond coat showed aluminum depletion around the inter-diffusion layer. In this study, we evaluated the properties of the bond coat and the degradation of the coating layer used on a $1300^{\circ}C$-class gas turbine blade. Moreover, the operation temperature of the blade was estimated using the Arrhenius equation and this was compared with the result of a thermal analysis.

• Journal of Dental Rehabilitation and Applied Science
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• v.29 no.1
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• pp.69-79
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• 2013

The aim of this study was to evaluate the effect of surface conditioning on the shear bond strength of zirconium-oxide ceramic to resin cement. A total of 120 disk-shaped zirconium-oxide ceramic blocks(3-TZP, Kyoritsu, Tokyo, Japan) were treated as follows: (1) no treatment; (2) sandblasting with 110 ${\mu}m$ aluminum-oxide(Al2O3); (3) particles tribochemical silica coating(RocatecTM, 3M ESPE). Then zirconium-oxide ceramic blocks were divided into six groups(10 for each group) and bonded with resin cement(Rely X U-200, 3M ESPE). (1) No treatment / No treatment (2) No treatment / Sandblasting with 110 ${\mu}m$ aluminum-oxide particles (3) No treatment / Silica coating (4) Sandblasting with 110 ${\mu}m$ aluminum-oxide particles / Sandblasting with 110 ${\mu}m$ aluminum-oxide particles (5) Sandblasting with 110 ${\mu}m$ aluminum-oxide particles / Silica coating (6) Silica coating / Silica coating. Each group was tested in shear bond strengths by UTM. Data analysis included one-way analysis of variance(ANOVA) and the Tukey Honestly Significant Difference test (P=0.05). Group that bonded two silica coated specimen showed a highest bond strength(P<0.05). Two silica coated surface conditioning group and air-abrasion and silica coated surface conditioning group showed significantly difference with other groups(P<0.05). Other groups had no significantly difference each other. Within the limitation of this study, Surface conditioning with Rocatec treatment to each side of specimen provided the highest bond strength.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.293-296
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• 2006

Normally, using coating material could result in different performance according to the various changes of environments or operation conditions. For these reasons, there are decreasing tendency for the durability, beauty and scenery of structures as the separation or exfoliation occurred after operation. Especially we must find out not only bond strength characteristics of coating material under temperature conditions but also bond strength reduction under heating-cooling repeat test because Korea has four distinct seasons. In this paper, the deformation and bond strength characteristics of coating material have been investigated. and we suggest some preliminary data of coating material for its best performance under various temperature condition.