• Journal of the Korean Chemical Society
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• v.19 no.3
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• pp.179-185
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• 1975

A new mechanism is proposed for aromatic substitution, involving the formation of pseudo molecular complexes at the transition state. It accounts for the addition reactions of aromatic compounds with double bond reagents such as ozone, somium tetraoxide and carbene as well as all of the features of electrophilic substitution reactions. The pseudo molecular complex has been proved to be formed by quantum-chemical considerations using the simple Huckel method.

• Journal of the Korean Society for Nondestructive Testing
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• v.21 no.2
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• pp.163-168
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• 2001

Due to aging, adhesively bonded and riveted aircraft lap joints can contain distends, cracks around rivet holes, fatigue induced flaws, and corrosion. It is required for the safety of aircraft to inspect these defects through the whole region of mint in rapid speed. Bond quality or adhesively bonded and riveted aluminum lap splice joints is investigated using non-contact remote ultrasonic nondestructive evaluation (NDE). Non-contact ultrasonic tests are performed using laser generation and air-coupled transducer detection. A Q-switched Nd:YAG laser and a periodic transmission mask are used to generate a selected Lamb mode. The Lamb wave is generated on one side of the lap splice joint, propagates along the plate, interacts with the joint and is detected on the other side by a micromachined air-coupled capacitance transducer. Analysis of recorded signals allows to evaluate the condition of the bond.

• Journal of the Korea Concrete Institute
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• v.18 no.4 s.94
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• pp.543-552
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• 2006

The current design for crack width control in concrete bridges is incomplete in analytical models. As one of the important serviceability limit states, the crack width be considered with the quantitative prediction of the initiation and propagation of corrosion and corrosion-induced cracking. A serviceability limit state of cracking can be affected by the combined effects of bond, slip, cracking, and corrosion of the reinforcing elements. Considering life span of concrete bridges, an improved prediction of crack width affected by time-dependent general corrosion has been proposed for the crack control design. The developed corrosion models and crack width prediction equation can be used for the design and the maintenance of prestressed and non-prestressed reinforcements by varying time, w/c, cover depth, and geometries of the sections. It can also be used as the rational criteria for the maintenance of existing concrete bridges and the prediction of remaining life of concrete structures.

• Journal of the Korea Concrete Institute
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• v.28 no.6
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• pp.723-731
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• 2016

In pretensioned concrete members, a certain bond length from the end of the member is required to secure the effective prestress in the strands, which is defined as the transfer length. However, due to the complex bond mechanism between strands and concrete, most transfer length models based on the deterministic approach have uncertainties and do not provide accurate estimations. Therefore, in this study, Adaptive Neuro-Fuzzy Inference System (ANFIS), a Neuro-Fuzzy System, is introduced to reduce the uncertainties and to estimate the transfer length more accurately in pretensioned concrete member. A total of 253 transfer length test results have been collected from literatures to train ANFIS, and the trained ANFIS algorithm estimated the transfer length very accurately. In addition, a design equation was proposed to calculate the transfer length based on parametric studies and dimensional analyses. Consequently, the proposed equation provided accurate results on the transfer length which are comparable to the ANFIS analysis results.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.1
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• pp.59-65
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• 2018

RC(Reinforced Concrete) structures are exposed to various exterior conditions, and the performances of both chloride resistance and freezing/thawing action are evaluated for those exposed to corrosive environment-sea shore. Recently developed FRP Hybrid Bars which is coated with glass fiber and epoxy with core steel has an engineering advantage of higher Elasticity than FRP rod. In this work, corrosion resistance, weight loss, and bond strength are evaluated for the FRP Hybrid Bar tested through freezing/thawing action for 300cycles. The double coated FRP Hybrid Bar shows the least weight loss without defection due to freezing/thawing action. Bond strength in FRP Hybrid Bar increases to 120% of normal steel through torturity effect with Si-coating. Bond strength in normal steel shows 0.86~0.89times in 3-day corrosion acceleration and 0.35~0.38times in 5-day corrosion acceleration, however, that in FRP Hybrid Bar shows little changes in bond strength before and after freezing/thawing action.

• The korean journal of orthodontics
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• v.30 no.2 s.79
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• pp.215-222
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• 2000

The purpose of this study was to determine whether the application of chlorhexidine varnish affects the shear bond strength and failure pattern of orthodontic brackets or not. The experimental group consisted of 22 human premolars which extracted after chlorhexidine varnish application (4 times for 1 week interval) in vivo, and the control group consisted of 22 human premolars which extracted without any pre-treatment. After all teeth were etched with $37\%$ phosphoric acid gel, metal orthodontic brackets (Q-3002, RMO, USA) were bonded to each tooth using auto-polymerizing orthodontic resin (Ortho-One, Bisco, USA) with the same bonding procedure. The shear bond strength was measured with Instron universal testing machine (model 4466, Instron Ltd., England), and the failure pattern of each bracket was examined with Scanning Electron Microscope (SM 840A, JEOL, Japan). The data were analysed statistically with t-test. The results were as follows : 1. Application of chlorhexidine varnish had no significant effect on the shear bond strength of the orthodontic bracket. 2. There was no significant difference in the failure pattern of orthodontic bracket between the experimental group and the control group.

• Journal of the Korea Concrete Institute
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• v.21 no.6
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• pp.753-761
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• 2009

This paper presents the test results of total 24 beam-end specimens to investigate the effect of high-strength concrete and cover thickness on the development resistance capacity in tensile lap splice length regions. Based on bond characteristics that an increase in concrete strength results in higher bond stress and shortening of the transfer length, cracking behavior that thin cover thickness induced a splitting crack easily and brittle crack propagation, current design code that development length provisions as uniform bond stress assumption was investigated apply as it. The results showed that as higher strength concrete was employed, not only development resistance capacity was influenced by cover thickness, but also more sufficient safety factor reserved shorter than the lap splice length provision in current design code. From experimental research results, high-strength concrete development length was not inverse ratio of $\sqrt{f_{ck}}$ but directly inverse of $f_{ck}$, and it is also said that there is a certain limit length of the embedded steel over which the assumption of uniform bond stress distribution is valid specially for high-strength concrete not having a same embed length such as normal-strength concrete in current design criteria hypothesis.

• Journal of the korean academy of Pediatric Dentistry
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• v.28 no.3
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• pp.522-529
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• 2001

This study seeks to know the effect of fluoride topical application on the shear bond strength between enamel and fissure sealant. On group 1,2,3,4, Teethmate A(unfilled sealant) and on group 5,6,7,8 Ultraseal XT(filled sealant) were used. Group 1 and 5 were not pre-treated with fluoride and group 2 and 6 were pre-treated with 1.23% APF for 4minutes. Group 3 and 7 were pretreated with 2.0% NaF for 4 minutes. and group 4 and 8 were pumiced with abrasive containing fluoride for 10 seconds. Prepared specimens were acid etched for 30 seconds using 35% phosphoric acid, and then sealant was cured to the specimen using a 3mm diameter by 2mm height mold. They went through thermocycling. Its shear bond strength was measured, and then acid etched both groups that were pretreated with fluoride and that were not pretreated with fluoride. Then we examined the surface of the specimen with EM and came up with these results. In groups using unfilled sealant(group 1,2,3.4) there were no significant differences between oops pretreated with fluoride and groups not pretreated with fluoride. In groups using filled sealant(group 5,6,7,8), groups 6 and 7(treated with 1.23% APF 2.0% NaF respectively) showed significantly lower shear bond strength, compared to group 5 (not pretreated with fluoride) and group 8 (pumiced with abrasive containing fluoride) (p<0.05).

• Journal of the Korea Institute of Building Construction
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• v.18 no.2
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• pp.99-107
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• 2018

The objective of the present study is to propose a reliable shape of supplementary V-ties in the section jacketing approach for seismic strengthening of reinforced concrete columns. A total of 24 pull-out specimens were prepared. The test parameters selected with regard to bond strength of V-ties were the shape of V-ties, embedment length of V-tie legs, and compressive strength of concrete. The measured bond strength of V-ties with different shapes were compared with that of the conventional V-ties and predictions using CEB-FIP equation. Ultimately, V-ties with pressed end-details at their legs could be recommended for the supplementary lateral reinforcement of strengthening columns with jacketing thickness less than the embedment length [= max (75mm, $6d_b$)] of conventional V-ties, where $d_b$ is the diameter of the reinforcing bar used for V-ties.

• Journal of the Korea Concrete Institute
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• v.18 no.1 s.91
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• pp.91-100
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• 2006

This paper presents an analytical model for evaluation of crack widths in structural concrete members. The model is mathematically derived from the actual bond stress-slip relationships between the reinforcement and the surrounding concrete, and the relationships summarized in CEB-FIP Model Code 1990 are employed in this study together with the assumption of a linear slip distribution along the interface at the stabilized cracking stage. With these, the actual strains of the steel and the concrete are integrated respectively along the embedment length between the adjacent cracks so as to obtain the difference in the axial elongation. The model is applied to the test specimens available in literatures, and the predicted values are shown to be in good agreement with the experimentally measured data.