• Title/Summary/Keyword: Boiling Point

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Analysis of Illegally Mixed Used Lube Oil in Bunker C (폐윤활유 불법혼입 C중유 물성 분석)

  • Lim, Young-Kwan;Lee, Jae-Min;Kim, Wan-Sik;Lee, Jeong-Min
    • Tribology and Lubricants
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    • v.34 no.5
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    • pp.191-196
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    • 2018
  • Bunker C is used in heavy-lift ships, furnaces, and boilers for generating heat, and power. Bunker C has only four regulations for quality standards and is rarely inspected in Korea. For these reasons, other oils such as used lubricant oil are commonly blended with Bunker C. This illegal mixture of fuel can damage the boilers, engines and affect the environment adversely. In this study, we investigate the fuel properties and perform atomic analysis of illegal Bunker C blended with used lube oil. The test results show that higher quantities of used lube oil in Bunker C have higher flash points, total acid numbers, copper corruption, solid contamination, and metal components. Further, increasing quantities of used lube oil in Bunker C cause lower viscosity, sulfur, and V content. However, adequate sample (approximately 1 L) is needed to evaluate presence of adulterants in Bunker C, we attempted the SIMDIST analysis. In the SIMDIST chromatogram, the used engine oils are detected for longer retention times than Bunker C owing to the high boiling point. We also quantitatively analyzed the lube oil content using SIMDIST.

Analysis of Fragrance Volatiles of Korean Rosa hybrida Using Gas Chromatography-Mass Spectrometry

  • Cho, Yong-Sik;Cho, In-Hee;Park, Hong-Ju;Chun, Hye-Kyung
    • Journal of Applied Biological Chemistry
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    • v.49 no.4
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    • pp.180-185
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    • 2006
  • Two different extraction procedures, SDE and SPME, were employed to determine a comprehensive and efficient fragrance profile of Korean Rosa hybrida. Both extraction methods could compensate for each other, covering compounds with diverse boiling point, polarities, and chemical properties. A total of 46 compounds were identified in Mi-hyang. The identified compounds were composed of 17 alcohols, 14 carbonyls, 7 aliphatic hydrocarbons, 2 terpene hydrocarbons, 4 benzenes, 1 ester, and 1 miscellaneous compound. Quantitatively, carbonyls($12.96{\sim}21.79%$ in essential oils of SDE and $2.89{\sim}8.44%$ in SPME headspace) and alcohols($7.98{\sim}11.73%$ in essential oils of SDE and $3.39{\sim}17.35%$ in SPME headspace) were dominant in Mi-hyang's volatiles.

A Study on the Stability of Carpet by Thermal Decomposition (열분해에 의한 카펫의 안정성에 관한 연구)

  • Park, Keun-Ho;Lee, Ki-Cheol
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.2
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    • pp.147-152
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    • 2006
  • The accidents occurred by unstable material which is easily exploded or burnt up were caused by heat and collision under the condition of relatively low temperature without oxygen, have been reported frequently. However, the amount of the unstable material is getting higher by development of fine ceramic research area even though its dangerous characteristic is disregarded. This research studied a heat stability and measured boiling point of various carpet material. Carpet has been used in home as well as general indoor usage. Now a day, carpet material which is hardly burnt has been on commercial, but its detailed unstable conditions is not mentioned. This research reports the measurement of the initial temperature of generation heat and heat-radiation change on differential scanning calorimeter (DSC). The DSC data of nylon bulked continuous filament (N-BCF) yam 100%, nylon (NY), poly propylene (PP), and a new material named polytrimethylene terephthalate (PTT) are studied and researched about the effect of them using TGA, furnace, and direct-burning experiment.

Growth and electrical properties of Pb(Zr, Ti)$O_3$ thin films by sol-gel method (솔-젤 법을 이용한 Pb(Zr, Ti)$O_3$ 박막의 성장 및 전기적 특성에 관한 연구)

  • 김봉주;전성진;이재찬;유지범
    • Journal of the Korean Vacuum Society
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    • v.8 no.4A
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    • pp.425-431
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    • 1999
  • $Pb(Zr_{0.52}, Ti_{0.48})O_3$ (PZT) thick films as an actuating material with conducting oxides, $(La_{0.5}Sr_{0.5}) CoO_3$ (LSCO), have been fabricated by sol-gel method for Optical Micro-Electro-Mechanical System (MEMS) devices, in which PZT/LSCO/SiO2 structures were used. In order to improve the adhesion to LSCO solution in order to enhance the wetting behavior of a water-based LSCO precursor solution and further to improve the adhesion between LSCO and $SiO_2$ layers. PZT films were made using 1-3 propanediol based precursor solution which has a high viscosity and a boiling point appropriate for thick film fabrication. In the precursor solution, Ti-propoxied and Zr-propoxied are partially substituted with acetylacetone to achieve the solution stability while maintaining reactivity. Crack free PZT films (0.8~1$\mu\textrm{m}$) have been successfully fabricated at crystallization temperatures above $700^{\circ}C$. Dielectric constants and dielectric losses of the PZT films were 900~1200and 2~5%, respectively. Piezoelectric constant $d_{33}$ of the PZT films constrained by a substrate were 200pm/V at 100kV/cm.

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An Experimental Study on the Analysis of Liquid/Vapor Phase in GDI Spray (직접 분사식 연료 분무에서의 기.액상 분리 계측에 관한 연구)

  • Jang, S.H.;Kim, J.H.;Park, K.S.;Jin, S.H.;Kim, G.S.
    • Journal of ILASS-Korea
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    • v.5 no.4
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    • pp.57-65
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    • 2000
  • For this research an extension of the LIF technique that the LIEF(Laser Induced Exciplex Fluorescence) technique has been used LIEF technique is the unique method to allows the visualization of fuel vapor phase and liquid phase individually by capturing each signals of them. In this work performed that the basic procedure for advanced LIEF technique using TEA and benzene as dopants md high power KrF excimer laser to excite the dopants. Iso-octane is used as the fuel because it does not absorb light at the laser wavelength. The boiling point of benzene and TEA are $81^{\circ}C\;and89^{\circ}C$, respectively, in comparison to $99^{\circ}C$ for iso-octane. It is observed that the behavior and distribution of high pressed fuel injection from various test condition. The injection pressure is set as 3MPa. and 5MPa. And the ambient pressure of test chamber is atmospheric pressure and 1MPa, the ambient temperature of chamber is room temperature, $300^{\circ}C\;and\;500^{\circ}C$ to imitate the condition of GDI engine cylinder.

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Experimental Study of Thermo-electric material using Lithium-Ammonia$(Li(NH_3)_n)$ Solution (리튬-암모니아 $(Li(NH_3)_n)$ 용액을 이용한 열전기적 특성 실험)

  • Park, Han-Woo;Kim, Ji-Beom;Jeon, Joon-Hyeon
    • Korean Chemical Engineering Research
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    • v.49 no.2
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    • pp.263-270
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    • 2011
  • The aim of this paper is, through the experiment of Lithium-Ammonia solutions $(Li(NH_3)_n)$, to analyze and verify a thermoelectric-conversion property at near Ammonia-boiling point ($-40^{\circ}C$). The experiment results show that the solutions with 0.58 MPM~1.87 MPM generate thermoelectric power at temperature difference $({\Delta}T=0{\sim}15^{\circ}C)$ where Current is constantly proportional to Voltage. This paper provides a new insight into the development of a thermoelectric material.

A Heat Exchanging Characteristics of Organic Rankine Cycle for Waste Heat Recovery of Coal Fired Power Plant (화력발전용 복수기 폐열 회수를 위한 유기랭킨사이클 시스템 열교환 특성 해석)

  • Jeong, Jinhee;Im, Seokyeon;Kim, Beomjoo;Yu, Sangseok
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.1
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    • pp.64-70
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    • 2015
  • Organic Rankine cycle (ORC) is an useful cycle for power generation system with low temperature heat sources ($80{\sim}400^{\circ}C$). Since the boiling point of operating fluid is low, the system is used to recover the low temperature heat source of waste heat energy. In this study, a ORC with R134a is applied to recover the waste energy of condenser of coal fired power plant. A system model is developed via Thermolib$^{(R)}$ under Simulink/MATLAB environment. The model is composed of a refrigerant heat exchanger for heat recovery from coal fired condenser, a drum, turbine, heat exchanger for ORC heat rejection, storage tank, water recirculation pump and water drip pump. System analysis parameters were heat recovery capacity, type of refrigerants, and types of turbines. The simulation model is used to analyze the heat recovery capacity of ORC power system. As a result, increasing the overall heat transfer coefficient to become the largest of turbine power is the most economical.

A Study on Performance Characteristics of Propane/Isobutane Refrigerant Mixtures in a Domestic Small Multi-Refrigeration System (프로판/이소부탄(R-290/R-600a) 혼합 냉매를 적용한 가정용 소형 멀티 냉동시스템의 성능특성에 관한 연구)

  • Kim Sanguk;Lee MooYeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.2 s.233
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    • pp.271-278
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    • 2005
  • In this paper, the performance of Kim-chi refrigerator with three evaporator and one compressor was investigated in employing $55\%$ propane and $45\%$ isobutane (R290/R600a) refrigerant mixture as an alternative refrigerant of R134a. The drop-in test was performed by varying both refrigerant charge and capillary tube length in order to find both the performance and reliability of a small multi-refrigeration system. Results show that the power consumption is decreased by about $15\%$ and COP is increased by about $10\%$, respectively as compared to the baseline system using R-134a. In addition, the propane/isobutane refrigerant mixture system took advantage of the minimization of modification and redesigning of system components because thermodynamic properties such as saturation pressure, temperature, normal boiling point(NBP) characteristics are similar to those of R134a. The reduction of sales cost is caused by the decrease of refrigerant cost per unit mass and refrigerant charge amount necessary for the refrigeration system.

The Experimental Study on Exhaust Emission Characteristics with Oxygen Component Addition in Diesel Engine (디젤기관에서 산소성분 첨가에 의한 배기가스 배출특성의 실험적 연구)

  • Oh, Y.T.;Choi, S.H.;Jang, S.J.
    • Proceedings of the KSME Conference
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    • 2001.11b
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    • pp.800-805
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    • 2001
  • Recently, our world is faced with very serious and hard problems related to the air pollution due to the exhaust emissions of the diesel engine. So, lots of researchers have studied to reduce the exhaust emissions which influenced the environment strong. In this paper, the effect of oxygen component in fuel on the exhaust emissions has been investigated for diesel engine. And, we tried to analysis the quantities of the low and high hydrocarbon among the exhaust emissions in diesel engine. It have been investigated by the quantitative analysis of the hydrocarbon $C_1\simC_6$ using the gas chromatography. This study carried out by comparing the chromatogram with diesel fuel and diesel fuel blended DGM(diethylene glycol dimethyl ether) 5%. The results of this study show that the hydrocarbon $C_1\simC_6$ among the exhaust emissions of the mixed fuels are exhausted lower than those of the diesel fuel at the all load and speed. In particular, high boiling point hydrocarbons such as $C_5$ and $C_6$ were reduced remarkably in high speed and load region.

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Low Temperature Effects on the Strength and Fracture Toughness of Membrane for LNG Storage Tank (LNG 저장탱크용 멤브레인재(STS 304강)의 강도 및 파괴인성에 미치는 저온효과)

  • Kim, Jeong-Gyu;Kim, Cheol-Su;Jo, Dong-Hyeok;Kim, Do-Sik;Yun, In-Su
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.3 s.174
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    • pp.710-717
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    • 2000
  • Tensile and fracture toughness tests of the cold-rolled STS 304 steel plate for membrane material of LNG storage tank were performed at wide range of temperatures, 11 IK(boiling point of LNG), 153K , 193K and 293K(room temperature). Tensile strength significantly increases with a decrease in temperature, but the yield strength is relatively insensitive to temperature. Elongation at 193K abruptly decreases by 50% of that at 293K, and then decreases slightly in the temperature range of 193K to 111K. Strain hardening exponents at low temperatures are about four times as high as that at 293K. Elastic-plastic fracture toughness($J_c$) and tearing modulus($T_{mat}$) tend to decrease with a decrease in temperature. The $J_c$ values are inversely related to effective yield strength in the temperature range of 111K to 293K. These phenomena result from a significant increase in the amount of transformed martensite in low temperature regions.