• 제목/요약/키워드: Blue-shift

검색결과 255건 처리시간 0.116초

광결정 Nanocavity를 갖는 InGaN/GaN 양자우물구조의 청색 광소자 공정 및 특성평가 (Fabrications and Characterizations of InGaN/GaN Quantum Well Light Emitting Devices Including Photonic Crystal Nanocavity Structures)

  • 최재호;이정택;김근주
    • 한국전기전자재료학회논문지
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    • 제22권12호
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    • pp.1045-1057
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    • 2009
  • The authors investigated the InGaN/GaN multi-quantum well blue light emitting devices with the implementation of the photonic crystals fabricated at the top surface of p-GaN layer and the bottom interface of n-GaN layer. The top photonic crystals result in the lattice-dependent photoluminescence spectra at the wavelength of 450 nm and however, the bottom photonic crystal shows a big shift of the photoluminescence peak from 444 nm to 394 nm. The sample with the bottom photonic crystal structure also shows the lasing effect at the wavelength of 468 nm. Furthermore, the quality enhancement for the crystal growth of GaN thin film on the bottom photonic crystal comes from the modulated compressive stress which was measured by the micro-Raman spectroscopy.

Color Tuning of PLED based on Poly(fluorene)s

  • Lee, Jeong-Ik;Do, Lee-Mi;Chu, Hye-Yong;Kim, Sung-Hyun;Zyung, Tae-Hyoung
    • Journal of Information Display
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    • 제6권1호
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    • pp.33-36
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    • 2005
  • To obtain various colors from the blue emitting poly(fluorene)s, two different approaches are introduced. One is copolymerization with low band gap comonomers and the other is molecular doping with various dyes. As fast and efficient exciton migration and trapping and/or energy transfer between the chromorphoric segments or doped dyes in conjugated polymers can shift the emission to longer wavelengths, these phenomena can be utilized to obtain various colors from the intrinsically blue light emitting poly(fluorene)s.

Green and Blue Light Emitting InN/GaN Quantum Wells with Nanosize Structures Grown by Metalorganic Chemical Vapor Deposition

  • Kim, Je-Won;Lee, Kyu-Han
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제5권2호
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    • pp.127-130
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    • 2005
  • The structural and electrical properties of InN/GaN multiple quantum wells, which were grown by metalorganic chemical vapor deposition, were characterized by transmission electron microscopy and electroluminescence measurements. As the quantum well growth time was changed, the wavelength was varied from 451 to 531 nm. In the varied current conditions, the blue LED with the InN MQW structures did not have the wavelength shift. With this result, we can expect that the white LEDs with the InN MQW structures do not show the color temperature changes with the variations of applied currents.

Enhancement of Magneto-Optic Figure of Merit of Bi:YIG Films in Blue Wavelengths by La Substitution

  • Lee, Euibok;Jaekyong Cho
    • Journal of Magnetics
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    • 제2권2호
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    • pp.46-49
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    • 1997
  • This paper reports the first success in enhancement of the magneto-optic figure of merit of garnet films in blue wavelengths. The maximum of the absolute value of the Faraday rotation angle observed at about 500 nm for the films with no La substitution shifted toward shorter wavelength as La content increased, that leads the increase of the absolute value of the Faraday rotation angle in the wavelengths shorter than about 480 nm. The optical absorption coefficient at the wavelengths shorter than 500 nm decreased as La content increased. As a result the magneto-optic figure of merit increased in the wavelengths shorter than 470 nm as La content increased and was about two times larger for the film with La content of 0.6 in formular unit compared to that of the film without La substitution. This might be attributed to the shift of the centers of the charge transfer and crystal field transitions by La substitution.

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유비퀴틴 단백질의 부분적으로 폴딩된 구조에 대한 분광학적 분석 (Spectroscopic Analysis of Partially Folded State of Ubiquitin)

  • 박순호
    • Applied Biological Chemistry
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    • 제46권4호
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    • pp.305-310
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    • 2003
  • Hydrophobic core가 변이된 유비퀴틴 단백질이 pH 2 용액에서 보이는 구조적인 특성을 여러 분광학적 방법으로 측정하였다. 낮은 pH값을 갖는 용액에서 이 변이 유비퀴틴의 intrinsic tryptophan fluorescence emission spectrum은 unfolded 상태보다 약간 blue shift되어 있고 또한 그 intensity도 상당히 낮게 나타났다. 이는 이 용액 조건에서 이 변이 유비퀴틴의 삼차구조가 약간 남아 있는 것을 의미한다. 같은 용액에서 이 변이 유비쥐틴의 far-UV circular dichroic spectrum은 native 상태나 unfolded 상태의 spectrum과 현저히 달랐으며 220 nm 에서의 molar ellipticity 값을 통하여 볼 때 pH 2인 용액에서 상당량의 이차구조를 지니고 있었다. 또한 같은 용액에서 이 변이 유비퀴틴은 hydrophobic dye인 8-anilinonaphthalene-1-sulfonic acid(ANS)외 fluorescence emission intensity를 증가시키고 fluorescence emission maximum이 짧은 파장에서 나타나게 하였다(blue shift). 이러한 현상은 pH 2 용액에서 이 변이 유비퀴틴의 hydrophobic core가 느슨하여져서 hydrophobic dye인 ANS가 결합할 수 있는 구조를 띠고 있음을 나타낸다. 이러한 분광학적인 관찰은 이 변이 유비귀틴이 pH 2인 용액에서 상당량의 이차구조를 지니고 있지만 hydrophobic core는 느슨하게 형성된 molten globule과 같은 형태를 지니고 있음을 나타낸다. 이 변이 유비퀴틴의 molten 히obule 형태는 단백질 폴딩 반응의 경로를 연구할 수 있는 좋은 모델이 될 수 있을 것으로 생각된다.

MOCVD로 성장한 Zn-doped InGaN의 광특성 연구 (Optical properties of Zn-doped InGaN grown by MOCVD)

  • 이창명;이주인;임재영;신은주;김선운;서준호;박근섭;이동한
    • 한국진공학회지
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    • 제10권1호
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    • pp.67-71
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    • 2001
  • MOCVD법으로 성장한 Zn-doped InGaN의 광학적 특성을 photoluminescence를 사용하여 연구하였다. 상온에서 Zn와 관련한 acceptor-like conte들에 대한 넓은 스펙트럼들은 2.81 eV와 2.60 eV에서 관측되었다. 특히, 2.81 eV영역에서는 포논과의 상호작용에 의한 스펙트럼이 나타났으며, 포논 에너지가 $\omega$=92.5 meV의 값을 가짐을 확인하였다. InGaN 시료의 온도 변화에 대한 스펙트럼에서, 온도가 증가함에 따라 청색 발광을 기준으로 낮은 쪽의 에너지에 비해 높은 에너지 쪽의 발광이 빠른 감소를 가져왔으며 아울러 2.81eV 영역에 해당하는 스펙트럼은 18meV만큼 높은 에너지 쪽으로 이동함을 관측하였다. 그러므로 청색 영역에서의 발광은 Zn와 관련된 complex conte체서의 국소화된 천이에 따른 결과이다.

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아연 착체를 이용한 유기 EL 소자의 전계발광 특성 (Light-Emitting Properties of Organic Electroluminescent Devices using Zinc Complexes)

  • 김홍수;정노희
    • 한국응용과학기술학회지
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    • 제20권4호
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    • pp.316-323
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    • 2003
  • Zinc complexes with bis[2-(o-hydroxyphenyl) naphtol [1,2] oxazolato ligands (ZnPBO-4) and its derivatives (ZnPBO-S) were synthesized, and luminescent properties of these materials were investigated. Both the fluorescent emission band and electroluminescent emission band were discussed based on their ligand structure differences. The emission band found that it strongly depends on the molecular structure of introduced ligand. It was tuned from 446 nm to 491 nm by changing the ligand structures. Spreading of the ${\pi}$-conjugation in 2-(o-hydroxyphenyl) group gives rise to a blue shift. The EL properties also showed good consistency with their differences of ligand structure. Bright-blue EL emission with a maximum luminance of 3,100 $cd/m^2$ at 12V, current density, 575 $mA/m^2$ was obtained from the organic light-emitting diodes (OLEDs) using ZnPBO-4 as emitting layer. It was also found that the newly synthesized materials were suitable to be used as emitting materials in organic EL device.

전문도서관의 블루오션 창출을 위한 사서업무 영역 다변화 (Diversification of Librarian's Works for Creating Blue Ocean of Special Libraries)

  • 이지호;박옥화
    • 정보관리연구
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    • 제38권1호
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    • pp.99-119
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    • 2007
  • 사서직의 업무는 도서관의 패러다임이 전환됨에 따라 그 성격이 함께 변한다고 할 수 있다. 즉 전통적인 정보자료 관리중심의 패러다임에서 소장과 접근의 조화를 강조하는 하이브리드형의 절충형 패러다임으로 변하고 있다. 전문도서관의 블루오션을 창출하기 위하여 내 외부적인 환경변화를 SWOT기법으로 분석하고, 합리적인 도서관 운영을 위하여 ERCR 분석을 하였다. 사서업무 영역의 다변화를 조사하기 위하여 대덕연구단지 전문도서관에 근무하는 사서를 대상으로 하였으며, 문헌조사도 병행하였다.

Variation in IR and Raman Spectra of CD3CN upon Solvation of InCl3 in CD3CN: Distinctive Blue Shifts, Coordination Number, Donor-Acceptor Interaction, and Solvated Species

  • Cho, Jun-Sung;Cho, Han-Gook
    • Bulletin of the Korean Chemical Society
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    • 제30권4호
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    • pp.803-809
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    • 2009
  • Notable blue shifts of the ν2 $C{\equiv}N$ stretching, $_{v4}$ C-C stretching and $_{v8}$ CCN deformation bands of $CD_3CN$ are observed upon solvation of $InCl_3$, resulting from the donor-acceptor interaction. The Raman spectrum in the $_{v2}$ region shows further details; at least two new bands emerge on the blue side of the $_{v2}$ band of free $CD_3CN$, whose relative intensities vary with concentration, suggesting that there exist at least two different cationic species in the solution. The strong hydrogen bonds formed between the methyl group and ${InCl_4}^-$ result in a large band appearing on the red side of the ν1 $CD_3$ symmetric stretching band. The solvation number of $InCl_3$, determined from the Raman intensities of the $C{\equiv}N$ stretching bands for free and coordinated $CD_3CN$, increases from $\sim$1.5 to $\sim$1.8 with decreasing concentration.

건강신념모델을 기반한 소규모 산업장 생산직 남성근로자의 대사증후군 감소 프로그램 개발을 위한 요구사정 (Health Belief Model-based Needs Assessment for Development of a Metabolic Syndrome Risk Reduction Program for Korean Male Blue-collar Workers in Small-sized Companies)

  • 박윤희;김두리
    • 한국직업건강간호학회지
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    • 제27권4호
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    • pp.235-246
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    • 2018
  • Purpose: This study aimed to comprehend the real context of metabolic syndrome-related factors of Korean male blue-collar workers from small-sized companies based on the health belief model. Methods: A total of 37 workers from three companies were interviewed, and three series of focus group interviews were conducted. Data were analyzed using deductive content analysis. Results: Data were classified into four categories: knowledge, perceived susceptibility and severity, perceived barriers, and beliefs. Knowledge referred to low knowledge level; perceived susceptibility and severity referred to unawareness of susceptibility and severity; perceived barriers referred to shift work, overtime work, and a social context including having no choice but to drink; and beliefs referred to believing that health promotion behaviors do not relate to preventing metabolic syndrome, believing that one cannot prevent metabolic syndrome oneself, and believing that professional help is required. Conclusion: To prevent and reduce the risk of metabolic syndrome among Korean male blue-collar workers, interventions should focus on strategies to increase metabolic syndrome-related knowledge and perceptions, social support, and self-efficacy for practicing health behaviors. In addition, it is necessary to develop policies for establishing a healthy drinking culture in companies.