• Title/Summary/Keyword: Blue light-emitting

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Development of Blue Organic Light-emitting Diodes(OLEDs) Due to Change in Mixed Ratio of HTL:EML(DPVBi:NPB) Layers (HTL:EML(DPVBi:NPB)층의 조성비 변화에 따른 청색 유기 발광 소자 개발)

  • Lee, Tae-Sung;Lee, Byoung-Wook;Hong, Chin-Soo;Kim, Chang-Kyo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.9
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    • pp.853-858
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    • 2008
  • The structure of organic light-emitting diodes(OLEDs) with typical heterostructure consists of anode, hole injection layer, hole transport layer, light-emitting layer, electron transport layer, electron injection layer, and cathode. 4,4bis[N-(1-napthyl)-N-phenyl-amino]-biphenyl(NPB) used as a hole transport layer and 4'4-bis(2,2'-diphenyl vinyl)-1,1'-biphenyl(DPVBi) used as a blue light emitting layer were graded-mixed at selected ratio. Interface at heterojunction between the hole transport layer and the elecrtron transport layer restricts carrier's transfer. Mixing of the hole transport layer and the emitting layer reduces abrupt interface between the hole transport layer and the electron transport layer. The operating voltage of OLED devices with graded mixed-layer structure is 2.8 V at 1 $cd/m^2$ which is significantly lower than that of OLED device with typical heterostructure. The luminance of OLED devices with graded mixed-layer structure is 21,000 $cd/m^2$ , which is much higher than that of OLED device with typical heterostructure. This indicates that the graded mixed-layer enhances the movement of carriers by reducing the discontinuity of highest occupied molecular orbital(HOMO) of the interface between hole transport layer and emitting layer.

Light-Emitting Properties of Organic Electroluminescent Devices using Zinc Complexes (아연 착체를 이용한 유기 EL 소자의 전계발광 특성)

  • Kim, Hong-Soo;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.4
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    • pp.316-323
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    • 2003
  • Zinc complexes with bis[2-(o-hydroxyphenyl) naphtol [1,2] oxazolato ligands (ZnPBO-4) and its derivatives (ZnPBO-S) were synthesized, and luminescent properties of these materials were investigated. Both the fluorescent emission band and electroluminescent emission band were discussed based on their ligand structure differences. The emission band found that it strongly depends on the molecular structure of introduced ligand. It was tuned from 446 nm to 491 nm by changing the ligand structures. Spreading of the ${\pi}$-conjugation in 2-(o-hydroxyphenyl) group gives rise to a blue shift. The EL properties also showed good consistency with their differences of ligand structure. Bright-blue EL emission with a maximum luminance of 3,100 $cd/m^2$ at 12V, current density, 575 $mA/m^2$ was obtained from the organic light-emitting diodes (OLEDs) using ZnPBO-4 as emitting layer. It was also found that the newly synthesized materials were suitable to be used as emitting materials in organic EL device.

Synthesis and Light-Emitting Properties of Zinc Chelate Compounds (아연 킬레이트 화합물의 합성 및 전계발광 특성)

  • Kim, Hong-Soo;Nam, Ki-Dae;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.4
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    • pp.292-297
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    • 2001
  • Zinc complexes with Bis[2-(o-hydroxyphenyl) benzothiazolato ligands (ZnPBS-0) and Bis[2- (o-hydroxynaphthyl) benzothiazolato ligands (ZnPBS-05) were synthesized, and luminescent properties of these materials were investigated. The emission band found that it strongly depends on the molecular structure of introduced ligand and was tuned from 525 nm to 535 nm by changing the ligand structures. Spreading of the ${\pi}-conjugation$ in 2-(o-hydroxyphenyl) group gives rise to a blue shift. On the other hand, spreading of the ${\pi}-conjugation$ in benzothiazole groups leads to a red shift. The EL properties also showed good consistency with their differences of ligand structure. Bright-blue EL emission with a maximum luminance of 8300 $cd/m^{2}$ at 11V was obtained from the organic light - emitting diodes (OLEDs) using ZnPBS-0 as emitting layer. It was also found that the newly synthesized materials were suitable to be used as emitting materials in organic EL device.

The Spacer Thickness Effects on the Electroluminescent Characteristics of Hybrid White Organic Light-emitting Diodes

  • Seo, Ji-Hoon;Park, Jung-Sun;Seo, Bo-Min;Kim, Young-Kwan;Lee, Kum-Hee;Yoon, Seung-Soo
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.6
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    • pp.208-211
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    • 2009
  • The authors have demonstrated the various characteristics of hybrid white organic light-emitting diodes (HWOLED) using fluorescent blue and phosphorescent red emitters. We also demonstrated that two devices showed different characteristics in accordance with thickness of the 4,4′-N,N′-dicarbazole-biphenyl (CBP) spacer (CS) inserted between the blue and the red emitting layer. It was found that the device with a CS thickness of 70 $\AA$ showed a current efficiency 2.5 times higher than that of the control device with a CS thickness of 30 $\AA$ by preventing the triplet Dexter energy transfer from the red to the blue emitting layer. The HWOLED with the CS thickness of 70 $\AA$ exhibited a maximum luminance of 24500 cd/$m^2$, a maximum current efficiency of 42.9 cd/A, a power efficiency of 37.5 lm/W, and Commission Internationale de I'Eclairage coordinates of (0.37, 0.42).

Synthesis and Characterization of Carbazole Derivate for Blue light Emitting Material (카바졸을 포함하는 청색 OLED 재료의 합성)

  • Shin, Min-Gi;Park, Hyun-Tea;Jang, Sang-Hun;Koh, Hye-Jin;Jang, Jae-Wan;Kim, Yun-Hi;Kwon, Soon-Ki
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.58-58
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    • 2010
  • We designed and synthesized DFPCE blue emitting materials by Mc Murry coupling reaction in order to improve the device efficiency and stability. The structure was confirmed by $^1H$-NMR. The physical properties were characterized by differential scanning calorimetry, thermogravimetric analysis, UV-vis, photoluminescence spectrum and cyclic voltammetry. The decomposition temperature of the material, which correspond to a 5% weight loss upon heating, is $513.58^{\circ}C$. The photoluminescence (PL) spectrum of DFPCE exhibited blue emission at 425 nm in chloroform solution and 462 nm in film.

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Evaluation of light-emitting diode colors and intensities on slaughter performance, meat quality and serum antioxidant capacity in caged broilers

  • Zichao Tan;Chuanfeng Zhou;Xueping Shi;Lihua Wang;Shubai Wang
    • Animal Bioscience
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    • v.36 no.5
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    • pp.731-739
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    • 2023
  • Objective: This study was to evaluate the interaction of three different light-emitting diode (LED) light colors (white, green, and blue) and three intensities (5, 10, and 15 lx) on slaughter performance, meat quality and serum antioxidant capacity of broilers raised in three-layer cages. Methods: A total of 648 (8-days-old) male broiler chicks (Cobb-500) were randomly assigned in 3×3 factorially arranged treatments: three light colors (specifically, white, blue, and green) and three light intensities (namely, 5, 10, and 15 lx) for 35 days. Each treatment consisted of 6 replicates of 12 chicks. The test lasted for 35 days. Results: The semi-eviscerated weight percentage (SEWP) in 5 lx white was higher than that in 15 lx (p<0.01). The eviscerated weight percentage (EWP) (p<0.05) and water-loss percentage (WLP) (p<0.01) decreased in 10 lx white light than those in green light. Under blue light, the content of hypoxanthine (Hx) in muscle was lower than that under white and green light (p<0.01). The content of malondialdehyde (MDA) in 15 lx blue light was higher than that in 10 lx green light (p<0.05). Light color had an extremely significant effect on thigh muscle percentage, WLP, Hx, and crude protein content (p<0.01). Light intensity had a significant effect on SEWP (p<0.05), EWP (p<0.05), lightness (L*) value (p<0.05), WLP (p<0.01), and the contents of superoxide dismutase (p<0.05), MDA (p<0.01), glutathione peroxidase (p<0.01). Conclusion: Using white LED light with 10 lx light intensity can significantly improve the chicken quality of caged Cobb broilers, improve the content of inosine acid in chicken breast and enhance the antioxidant capacity of the body. We suggest that the broiler farm can use 10 lx white LED light source for lighting in 8 to 42 days.

Effect of Light-emitting Diodes (LEDs) and Ventilation on the in vitro Shoot Growth of Eucalyptus pellita (Eucalyptus pellita의 기내(器內) 줄기생장에 미치는 LEDs (Light-emitting diodes) 및 환기처리(換氣處理) 효과)

  • Kim, Ji-Ah;Moon, Heung Kyu
    • Journal of Korean Society of Forest Science
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    • v.95 no.6
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    • pp.716-722
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    • 2006
  • Various light sources including LEDs (Light emitting diodes) affecting on shoot growth was examined using in vitro shoots of E. pellita. Generally, it appeared that ventilation treatment was the most important factor affecting on normal shoot growth, irrespective of irradiation sources. Ventilation resulted in better performance of the cultures under 100% blue LED radiation. These include better shoot growth, more number of leaves, more number of internodes, more number of axillary buds, and heavier dry matters. The highest total chlorophyll content was obtained under both cool-white fluorescent lamps and R5B5 (50% red LED + 50% blue LED). The value was $24.5{\mu}g/g$ and $20.1{\mu}g/g$, respectively. In addition, ventilation resulted in higher carotenoid content in all irradiation sources except 100% red LED radiation. In conclusion, shoot growth of E. pellita could be reached maximum by ventilation under R5B5 (50% red LED + 50% blue LED).

White Light-Emitting Diodes Using Conjugated Polymer Blends

  • Hwang, Do-Hoon;Park, Moo-Jin;Kim, Suk-Kyung;Lee, Chang-Hee;Kim, Yong-Bae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.585-587
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    • 2004
  • We report the characterization of white light emitting devices fabricated using conjugated polymer blends. Blue emissive poly[9,9-bis(4'-n-octyloxyphenyl) fluorene-2,7-diyl-co-10-(2'-ethylhexyl)phenothiazine-3,7-diyl] [poly(BOPF-co-PTZ)] and red emissive poly(2-(2'-ethylhexyloxy)-5-methoxy-1,4-phenylenevinylene) (MEH-PPV) were employed in the blends. The inefficient energy transfer between these blue and red light emitting polymers (previously deduced from the PL spectra of the blend films) enables the production of white light emission through control of the blend ratio. The PL and EL emission spectra of the blend systems were found to vary with the blend ratio. The EL devices were fabricated in the ITO/PEDOT/blend/LiF/Al configuration and white light emission was obtained for one of the tested blend ratios.

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Optical Properties of White Light Sources Using Red, Green, Blue Emitting Phosphors and Violet Light Emitting Diodes (적색, 녹색, 청색 발광 형광체와 보라색 발광 다이오드를 이용한 백색 광원의 광 특성)

  • Kweon, Seok-Soon;Park, Jong-Yun;Huh, Young-Duk
    • Korean Journal of Materials Research
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    • v.16 no.3
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    • pp.145-150
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    • 2006
  • Various colors of light emitting diodes(LED) and four-band white light sources are obtained using a violet LED and various phosphor films. $BaMg_2Al_{16}O_{27}:Eu\;(blue),\;SrGa_2S_4:Eu\;(green),\;and\;Eu(TTA)_3(PTA)$ (red) phosphors are dispersed in poly-vinyl-alcohol aqueous solutions, and phosphor films are prepared by coating the suspensions to PET film. The narrow band emission of $Eu(TTA)_3(PTA)$ phosphor has excellent red luminescent property for four-band white light excited by the violet LED.

Development of Blue Organic Light-Emitting Diodes(OLEDs) Due to Change in Mixed Ratio of HTL:EML(DPVBi:NPB) Layers (HTL:EML(DPVBi:NPB) 층의 조성비 변화에 따른 청색 유기 발광 소자 개발)

  • Lee, Tae-Sung;Lee, Byoung-Wook;Hong, Chin-Soo;Kim, Chang-Kyo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04a
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    • pp.31-32
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    • 2008
  • The structure of OLEDs with conventional heterostructure consists of anode, hole injection layer, hole transport layer, light-emitting layer, electron transport layer, electron injection layer, and cathode. NPB used as a hole transport layer and DPVBi used as a blue light emitting layer were graded-mixed at selected ratio. Interface at heterojunction between the hole transport layer and the elecrtron transport layer restricts device's stability. Mixing of the hole transport layerand the emitting layer removes abrupt interface between the hole transport. layer and the electron transport layer. The stability of OLED with graded mixed-layer developed in this study was improved.

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