DOI QR코드

DOI QR Code

Development of Blue Organic Light-emitting Diodes(OLEDs) Due to Change in Mixed Ratio of HTL:EML(DPVBi:NPB) Layers

HTL:EML(DPVBi:NPB)층의 조성비 변화에 따른 청색 유기 발광 소자 개발

  • 이태성 (순천향대학교 전자정보공학과) ;
  • 이병욱 (순천향대학교 전자정보공학과) ;
  • 홍진수 (순천향대학교 물리학과) ;
  • 김창교 (순천향대학교 전자정보공학과)
  • Published : 2008.09.01

Abstract

The structure of organic light-emitting diodes(OLEDs) with typical heterostructure consists of anode, hole injection layer, hole transport layer, light-emitting layer, electron transport layer, electron injection layer, and cathode. 4,4bis[N-(1-napthyl)-N-phenyl-amino]-biphenyl(NPB) used as a hole transport layer and 4'4-bis(2,2'-diphenyl vinyl)-1,1'-biphenyl(DPVBi) used as a blue light emitting layer were graded-mixed at selected ratio. Interface at heterojunction between the hole transport layer and the elecrtron transport layer restricts carrier's transfer. Mixing of the hole transport layer and the emitting layer reduces abrupt interface between the hole transport layer and the electron transport layer. The operating voltage of OLED devices with graded mixed-layer structure is 2.8 V at 1 $cd/m^2$ which is significantly lower than that of OLED device with typical heterostructure. The luminance of OLED devices with graded mixed-layer structure is 21,000 $cd/m^2$ , which is much higher than that of OLED device with typical heterostructure. This indicates that the graded mixed-layer enhances the movement of carriers by reducing the discontinuity of highest occupied molecular orbital(HOMO) of the interface between hole transport layer and emitting layer.

Keywords

References

  1. C. W. Tang and S. A. VanSlyke, "Organic electroluminescent diodes", Appl. Phys. Lett., Vol. 51, No. 12, p. 913, 1987 https://doi.org/10.1063/1.98799
  2. S. Chen, R. Song, J. Wang, Z. Zhao, Z. Jie, Y. Zhao, B. Quan, W. Huang, and S. Liu, "Improved performances in top-emitting organic light-emitting diodes based on a semiconductor zinc oxide buffer layer", Journal of Luminescence, Vol. 128, No. 7, p. 1143, 2008 https://doi.org/10.1016/j.jlumin.2007.11.087
  3. H.-H. Huang, S.-Y. Chu, P.-C. Kao, and Y.-C. Chen, "High efficiency white organic light emitting diodes using Rubrene doped N,N'-bis-(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine as an emitting layer", Thin Solid Films, Vol. 516, No. 16, p. 5669, 2008 https://doi.org/10.1016/j.tsf.2007.07.082
  4. 오환술, 조재영, 최성신, 강명구, 윤석범, "DPVBi/ Rubrene 구조를 사용한 2-파장 방식의 백색유기발광소자의 광학적.전기적 특성에 관한 연구", 전기전자재료학회논문지, 17권, 2호, p. 217, 2004
  5. C.-W. Han, O.-H. Kim, S.-J. Bae, and M.-K. Lee, "15-inch XGA Dual-plate OLED Display (DOD) Based on Amorphous Silicon (a-Si) TFT Backplane", Proc. of SID 2008, p. 5, Los Angeles, CA, USA, 2008
  6. J.-H. Lee and C.-I. Wu, "Mixed host organic light-emitting devices with low driving voltage and long lifetime", Appl. Phys. Lett., Vol. 86, p. 103506-103511 , 2005 https://doi.org/10.1063/1.1879093
  7. J. Hao, Z. Deng, and S. Yang, "Relationship between exciton recombination zone and applied voltage in organic light-emitting diodes", Displays, Vol. 27, p. 108, 2006 https://doi.org/10.1016/j.displa.2006.01.001
  8. A. B. Chwang, R. C. Kwong, and J. J. Brown, "Graded mixed-layer organic light-emitting devices", Appl. Phys. Lett., Vol. 80, No. 5, p. 725, 2002 https://doi.org/10.1063/1.1446992
  9. C.-W. Chen, T.-Y. Cho, and C.-C. Wu, "Fuzzy- junction organic light-emitting devices", Appl. Phys. Lett., Vol. 81, No. 9, p. 1570, 2002 https://doi.org/10.1063/1.1502912