• 제목/요약/키워드: Block composition

검색결과 258건 처리시간 0.021초

PREPARATION, PHYSICAL PROPERTIES AND MODEL ANALYSIS OF LINEAR HOMOGENEOUS POLYURETHANE

  • Laporta, M.;Pegoraro, M.;Bianchi, F.;Consolati, G.;Zanderighi, L.
    • 한국막학회:학술대회논문집
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    • 한국막학회 2003년도 The 4th Korea-Italy Workshop
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    • pp.81-85
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    • 2003
  • PU block polymers are constituted by sequences of constitutional units CU which are : a diisocyanate T, a polyol or a polyamine V, an extensor E .Due to the CU different solubility parameters ,hard and soft micro domains are formed;they can aggregate into different phases. A linear PU can be described by two parameters R=T/N and $R_{E}$=(R-1)V/E.A stoichiometric model is proposed which gives the general formula of all the possible PU: X((TV)$_{k}$(TE)$_{n}$)$_{m}$X , where k and m can be calculated from the experimental molecular weights respectively of pre polymer and polymer and n= R-1.Physical properties depend on PU composition and on nature of CU. I.R. analysis is useful for discovering the hydrogen bonds location : DSC gives informations on the presence of the different phases .PALS analysis shows that nano cavities become tighter on increasing n. A series of particular Pus ,obtained from :TDI, a low molecular weight polyol, a cyclic extensor, at different R and RE was prepared and analysed. These PU are amorphous, monophasic and appear to be good candidates for membranes.nes.nes.

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Production of concrete paving blocks using electroplating waste - Evaluation of concrete properties and solidification/stabilization of waste

  • Sgorlon, Juliana Guerra;Tavares, Celia Regina Granhen;Franco, Janaina de Melo
    • Advances in environmental research
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    • 제3권4호
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    • pp.337-353
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    • 2014
  • The determination of the effectiveness of the immobilization of blasting dust (waste generated in galvanic activities) in cement matrix, as well of mechanical, physical and microstructural properties of concrete paving blocks produced with partial replacement of cement was the objective of this work. The results showed that blasting dust has high percentage of silica in the composition and very fine particle size, characteristics that qualify it for replacement of cement in manufacturing concrete blocks. The replacement of Portland cement by up to 5% residues did not cause a significant loss in compressive strength nor increase in water absorption of the blocks. Chemical tests indicated that there is no problem of leaching or solubilization of contaminants to the environment during the useful life of the concrete blocks, since the solidification/stabilization process led to the immobilization of waste in the cement mass. Therefore, the use of blasting dust in the manufacture of concrete paving blocks is promising, thus being not only an alternative for proper disposal of such waste as well as a possibility of saving raw materials used in the construction industry.

"의감중마(醫鑑重磨)"의 판본 및 구성에 대한 연구 (A Study on the Editions and Composition of Uigamjungma)

  • 권오민;박상영;한창현;안상영;김진희;안상우
    • 한국한의학연구원논문집
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    • 제16권1호
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    • pp.1-9
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    • 2010
  • Lee Gyujun put forward Buyang as core medical tenet, which has been one of the prominent medical theories since around the first decade in the 20th century. He wrote two major medical books except for small kinds: Somundaeyo(素問大要) and Uigamjungma(醫鑑重磨). Until recently, studies on that theory have tended to focus on examining Somundaeyo. However, study on Uigamjungma is equally as important and is to be done as that on Somundaeyo. This is because the former is rather clinically oriented as the latter is theoretical so that the two is twins of one medical theory, in other words the other side of a coin. There are four versions of Uigamjungma editions: the first edition in 1922 by wooden block; one with annotation and Korean translation by Park Heesung; one edited and manually transcribed by Lee Wonse(李元世); and Daesung publisher's in 2000. Lee Gyujun revised medical theories, prescription, and herbology extracted not only from Donguibogam(東醫寶鑑) as well known wide, but also from Bangyakhappyeon(方藥合編) and Gyengakjeonse(景岳全書), based on the Buyang Theory(扶陽論).

DRM/DRM+ 이더넷모드의 다중화분산접속 설계분석 (Multiplex Distribution Interface Analyzer Using Memory Sharing Techniqyes on Ethernet Mode for DRM/DRM+ Systems)

  • 우용제;강민구;서정욱
    • 인터넷정보학회논문지
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    • 제15권2호
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    • pp.143-147
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    • 2014
  • 본 논문에서는 디지털 라디오 표준인 DRM(Digital Radio Mondiale) 및 DRM+(Digital Radio Mondiale Plus) 시스템을 이더넷모드에서 분석할 수 있는 다중화분산접속(MDI, Multiplex Distribution Interface) 분석기를 설계한다. 제안하는 MDI 분석기는 메모리 공유 기술을 가진 공통 블록 모듈을 사용하여 MDI 패킷들의 부하를 감소시키며, 차세대 디지털 라디오 방송시스템을 위해 수신된 MDI 패킷을 통해 IP(Internet Protocol)와 DRM/DRM+ 시스템의 FAC(Fast Access Channel)/SDC(Service Description Channel) 구성정보를 확인할 수 있다.

A Theory on Phase Behaviors of Diblock Copolymer/Homopolymer Blends

  • 윤경섭;박형석
    • Bulletin of the Korean Chemical Society
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    • 제16권9호
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    • pp.873-885
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    • 1995
  • The local structural and thermodynamical properties of blends A-B/H of a diblock copolymer A-B and a homopolymer H are studied using the polymer reference interaction site model (RISM) integral equation theory with the mean-spherical approximation closure. The random phase approximation (RPA)-like static scattering function is derived and the interaction parameter is obtained to investigate the phase transition behaviors in A-B/H blends effectively. The dependences of the microscopic interaction parameter and the macrophase-microphase separation on temperature, molecular weight, block composition and segment size ratio of the diblock copolymer, density, and concentration of the added homopolymer, are investigated numerically within the framework of Gaussian chain statistics. The numerical calculations of site-site interchain pair correlation functions are performed to see the local structures for the model blends. The calculated phase diagrams for A-B/H blends from the polymer RISM theory are compared with results by the RPA model and transmission electron microscopy (TEM). Our extended formal version shows the different feature from RPA in the microscopic phase separation behavior, but shows the consistency with TEM qualitatively. Scaling relationships of scattering peak, interaction parameter, and temperature at the microphase separation are obtained for the molecular weight of diblock copolymer. They are compared with the recent data by small-angle neutron scattering measurements.

NR, SBR, BR로 이루어진 고무배합물의 고무조성비에 따른 가황 특성 (Cure Characteristics of Carbon Block-Filled Rubber Compounds Composed of NR, SBR, and BR)

  • 최성신
    • Elastomers and Composites
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    • 제35권3호
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    • pp.215-226
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    • 2000
  • 고무 조성비가 다른 카본블랙으로 보강된 고무 배합물의 가황 특성을 연구하였다. 한 가지 고무로 이루어진 고무 배합물, 두 가지 고무로 이루어진 고무 배합물, 그리고 세 가지 고무로 이루어진 고무 배합물을 실험 대상으로 삼았다. NR/BR과 SBR/BR 배합물 중에서 BR의 함량이 높은 것의 델타토크는 단일 고무 배합물의 경우보다 높다. 삼중 고무 배합물의 델타 토크의 경우에는 세가지 고무의 함량비가 유사할수록 델타 토크가 낮아졌다. 스코치 시간과 적정 가황 시간은 NR이 증가할수록 빨라졌고 SBR이 증가할수록 느려졌다. 가황 속도는 SBR 함량이 증가할수록 느려졌다. 가교 역전(reversion) 현상은 SBR 함량이 증가할수록 감소하였다.

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Growth, Hay Yield and Chemical Composition of Cassava and Stylo 184 Grown under Intercropping

  • Kiyothong, K.;Wanapat, M.
    • Asian-Australasian Journal of Animal Sciences
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    • 제17권6호
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    • pp.799-807
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    • 2004
  • The objective of this field experiment was to investigate the growth, hay yield and chemical composition of cassava and stylo 184 grown under intercropping. The experiment was arranged in a Randomized Complete Block (RCB) design with 5 treatments and 4 replications. The treatments were: sole crop cassava (C); sole crop stylo 184 (S) and three intercropping treatments comprising an additive series of one (SC), two (SSC) and three (SSSC) rows of stylo 184 to one row of cassava. The results showed that leaf area per plant (LA) of cassava was significantly higher (p<0.05) in the sole crop relative to the intercropping treatments. Both total hay yield and CPDM yield were significantly higher (p<0.05) for C treatment and lower (p<0.05) for SSSC treatment. The total hay yield and CPDM yield were significantly greater (p<0.05) in the sole crop relative to the intercropping treatments. At the first and second harvests, CP content was similar among treatments; while at third and fourth harvests, CP contents were significantly greater (p<0.05) for the intercropping treatment relative to the sole crop. At the first and second harvest, NDF contents were significantly greater (p<0.05) in the sole crop relative to the intercropping treatments, whereas NDF contents were similar among intercropping treatments. Leaf area of stylo 184 at first and second harvest were significantly greater (p<0.05) for C, SC and SSC as compared with the SSSC treatments. At each harvesting, there were no significant differences in ash, CP, NDF, ADF and ADL contents of stylo 184 hay between the sole crop and intercropping treatments, except for the first harvest. ADF contents were significantly greater (p<0.05) in S, SC treatments relative to SSC and SSSC treatments. Both collective hay yield and CPDM yield of cassava and stylo 184 were significantly greater (p<0.05) for the SSC treatment and significantly lower (p<0.05) for the S treatment. Collective hay yield and CPDM yield were significantly greater (p<0.05) for the intercropping treatments relative to the sole crop. Based on this research, it was concluded that stylo 184 showed potential for intercropping with cassava. Intercropping cassava with stylo 184 has beneficial effects and can improve foliage biomass yield and soil fertility, which would be a more sustainable system than growing the cassava as a pure stand. In terms of hay yield and CP production, two rows of stylo 184 to one row of cassava could be the optimal pattern for this intercropping system.

Use of Leucaena leucocephala and Gliricidia sepium as Nitrogen Sources in Supplementary Concentrates for Dairy Goats Offered Rhodes Grass Hay

  • Ondiek, J.O.;Tuitoek, J.K.;Abdulrazak, S.A.;Bareeba, F.B.;Fujihara, T.
    • Asian-Australasian Journal of Animal Sciences
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    • 제13권9호
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    • pp.1249-1254
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    • 2000
  • A study was conducted to evaluate the replacement value of Leucaena leucocephala and Gliricidia sepium as nitrogen sources in commercial type supplements for dairy goats. Six crossbred $(Toggenburg{\times}Saanen)$ goats at late stage of lactation were allocated to three dietary treatments in a double $3{\times}3$ Latin square design. The animals were offered rhodes grass (Chloris gayana) hay ad libitum and supplemented with either Leucaena-based concentrate (LBC), Gliricidia-based concentrate (GBC) or commercial based concentrate (CC). Voluntary food intake, milk yield and composition and changes in live weight were measured. The total dry matter (DM) intake was higher (p<0.05) in goats fed GBC than CC (1385 vs 1331 g/d). The DM intake for LBC (1343 g/d) was similar to CC (1331 g/d). The DM intake of hay was also higher (p<0.05) in goats fed GBC (834 g/d) than those receiving LBC or CC (789, 782 g/d, respectively). Animals supplemented with GBC recorded positive (11 g/d) weight gain while the other groups lost weight (13, 19 g/d) for LBC and CC respectively, although these differences were not statistically significant (p>0.05). The composition of milk were: butterfat 58, 49 and 55 g/kg; crude protein 37.0, 35.4 and 36.1 g/kg; lactose 33, 29 and 30 g/kg; Ash 8.5, 8.5 and 7.9 g/kg and total solids 136.5, 121.9 and 129.0 g/kg, for goats fed LBC, GBC and CC respectively. There were no differences in the composition of milk due to these dietary treatments. At the end of performance trial, a digestibility trial was conducted using 6 female goats allocated to the three treatments (LBC, GBC and CC) in an incomplete randomized block design and each goat received a different supplement in each of two successive periods. There were no differences in nutrient digestibility except for DM, which was higher (p<0.05) in CC compared to the other treatments (615, 622, 720 g/kg for LBC, GBC and CC, respectively). Economic analysis showed that CC diet was more expensive (0.20 US$/kg) and had a lower margin over supplementation (0.11 US$) compared to LBC and GBC (0.13 vs 0.12 US$/kg and 01.5 vs 0.12 US$, respectively). It is concluded that the Leucaena and Gliricidia could contribute as nitrogen sources in compounded diet supplements without any detrimental effects on production in dairy goats.

Carcass characteristics of lambs fed spineless cactus as a replacement for sugarcane

  • de Oliveira, Juliana Paula Felipe;Ferreira, Marcelo de Andrade;Alves, Adryanne Marjorie Souza Vitor;de Melo, Ana Caroline Cerqueira;de Andrade, Ida Barbosa;Urbano, Stela Antas;Suassuna, Juraci Marcos Alves;de Barros, Leonardo Jose Assis;Melo, Tobias Tobit de Barros
    • Asian-Australasian Journal of Animal Sciences
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    • 제31권4호
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    • pp.529-536
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    • 2018
  • Objective: Fresh sugarcane has been a new roughage source for ruminant's in semiarid regions, a function of the decline of sugar and alcohol industry in recent years. However, there is little data published regarding lambs fed sugarcane associated with spineless cactus. This study evaluated the effect of sugarcane replacement with spineless cactus (0%, 33%, 66%, and 100%) in the diet of Santa $In\hat{e}s$ lambs on carcass characteristics. Methods: Thirty-six non-castrated Santa Ines lambs at four months of age and an initial body weight of $22{\pm}2.3kg$ were assigned in a randomized block design and slaughtered after 70 days of confinement. The effects of spineless cactus as a replacement for sugarcane in the diet of the lambs on the carcass characteristics, commercial cut weight and yield, leg tissue composition, and carcass measurements were studied. Results: The study revealed quadratic behavior in slaughter body weight, and hot and cold carcass weight, with maximum values of 38.60, 18.60, and 18.11 kg and replacement levels of 40.18%, 44.42%, and 43.14%, respectively. The cold carcass yield presented an increasing linear behavior. The compactness index of carcass and leg presented a quadratic effect, with estimated maximal values of 0.28 and 0.57 kg/cm and replacement levels of 43.37% and 45.5%, respectively. The weights of commercial cuts of leg, loin, shoulder, and breast showed quadratic behavior, with maximum values of 2.79, 0.852, 1.46, and 1.30 kg and replacement levels of 49.5, 45.32, 39.0, and 40.7, respectively. For tissue composition, quadratic behavior was verified for leg weight, subcutaneous fat, and total fat. Conclusion: The replacement of sugarcane by spineless cactus at level 44% is recommended for finishing lambs considering that this level improved most of the carcass characteristics, weights, and yields of commercial cuts and leg tissue composition.

Effect of Level of Crude Protein and Use of Cottonseed Meal in Diets Containing Cassava Chips and Rice Straw for Lactating Dairy Cows

  • Promkot, C.;Wanapat, M.
    • Asian-Australasian Journal of Animal Sciences
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    • 제18권4호
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    • pp.502-511
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    • 2005
  • The effects of different levels of crude protein (CP) and cottonseed meal replacing for soybean meal in cassava chips and rice straw-based diets for mid-lactating cows (100-150 day in milk [DIM]), were studied using 32 multiparous Holstein Fresian crossbred dairy cows. Diets containing 10.5, 12.5, 13.7, 14.4% CP of the rations and 0, 12.1, 14.9, 17.8% cottonseed meal were fed to cows for 60 days. Thirty two cows were randomly divided into four dietary treatments using a Randomized complete block design. Four dietary treatments were offered in the form of total mixed ration (TMR) with concentrate to roughage (chopped rice straw) at 60:40 and offered ad libitum. Dry matter (DM) and neutral detergent fiber (NDF) intakes tended to linearly increase with increasing dietary CP levels. Intakes and digestibility of crude protein increased linearly with increasing dietary CP level (p<0.01). Crude protein digestibility of the 10.5% CP diet was lower (p<0.05) than that in diets with higher levels of CP, while there were no significant differences among the other three levels of CP (12.5, 13.7 and 14.4%). Daily milk yield tended to increase with increased CP from 10.5 to 14.4%. Income over feed in terms of US$/kg of milk increased with increased CP from 10.5 to 13.7% and decreased when the CP level was higher than 13.7% (quadratic effect p<0.09). Milk composition was not significantly affected by increasing level of CP, however there were relatively high contents of protein and fat among treatments. The proportion of milk-urea N (MUN), ammonia-N ($NH_3$-N) and bloodurea N (BUN) were closely correlated and increased linearly with increasing CP levels (p<0.01). Balanced diet was found in diet containing 12.5 and 13.7% CP of the rations when BUN and MUN were used as indicators of the protein to energy ratio in the diet. Conclusions can be made that increasing dietary CP levels from 10.5 to 13.7% using cottonseed meal as the main source to completely replace soybean meal was beneficial to cows consuming rice straw and cassava chips based-diets. Increasing the CP level above 13.7% of total ration did not additionally improve milk yield and composition or net income.