• 폴리머
• /
• 제27권1호
• /
• pp.17-25
• /
• 2003

원자 이동 라디칼 중합 (ATRP)을 이용하여 CuBr/N,N,N',N",N"-pentamethyldiethylene triamine 촉매 시스템하에서 용액중합으로 polystyrene 거대 개시제와 polystyrene-b-t-poly(butyl acrylate) (PS-b-P(tBA)) 블록 공중합체를 합성한 후, 가수분해를 통해 polystrene-b-poly(acrylic acid) 양친매성 블록 공중합체를 얻었다. 또한, 이를 중화하여 블록 이오노머를 제조하였다. 합청된 PS-b-P(tBA) 블록 공중합체는 분자량이 5000-10000 정도로 조절되었고, 분자량 분포도 1.2 이하로 비교적 좁게 나타났다. 공중합체는 $^1$H-NMR, FT-IR로 분석하였으며, DSC로 열적 성질을 측정한 결과, styrene의 비율이 더 많기 때문에 100 $^{\circ}C$ 근처에서 T$_{g}$가 나타났으며, TEM을 통해 이온 그룹의 상분리를 확인하였다.분리를 확인하였다.

• The Korean Journal of Pain
• /
• 제24권1호
• /
• pp.31-35
• /
• 2011

Background: Circumcision is a painful intervention frequently performed in pediatric surgery. We aim to compare the efficacy of caudal block versus dorsal penile block (DPNB) under general anesthesia for children undergoing circumcision. Methods: This study was performed between July 1, 2009 and October 16, 2009. Fifty male children American Society of Anesthesiolgists physical status classification I, aged between 3 and 12 were included in this randomized, prospective, comparative study. Anesthetic techniques were standardized for all children. Patients were randomized into 2 groups. Using 0.25% 0.5 ml/kg levobupivacain, we performed DPNB for Group 1 and caudal block for Group 2. Postoperative analgesia was evaluated for six hours with the Flacc Pain Scale for five categories; (F) Face, (L) Legs, (A) Activity, (C) Cry, and (C) Consolability. For every child, supplemental analgesic amounts, times, and probable local or systemic complications were recorded. Results: No significant difference between the groups (P > 0.05) was found in mean age, body weight, anesthesia duration, FLACC pain, and sedation scores (P > 0.05). However, on subsequent measurements, a significant decrease of pain and sedation scores was noted in both the DPNB group and the caudal block group (P < 0.001). No major complication was found when using either technique. Conclusions: DPNB and caudal block provided similar postoperative analgesic effects without major complications for children under general anesthesia.

• 대한조선학회논문집
• /
• 제43권1호
• /
• pp.87-95
• /
• 2006

There are hundreds of ship blocks which are under the block assembly, painting, and outfitting assembly works in the pre-erection shops of shipyard. Generally, each block is planned to be processed in a pre-erection shop according to the block type by the long-term production-scheduling before six months. However, many blocks can't be processed in the planned time and the planned shop since the before and after block-processing changes or delays the planned sequential works in pre-erection shops. Therefore, it is essential to monitor the current location of each block and work in process to cope with the changed situation of pre-erection shops. Present study integrates PDA, GPS, and CDMA not only to chase the location of each block but also to exchange the pre-erection work order and the work report between the production-scheduling server and the production managers in the pre-erection shops. This study shows a prototype for the block tracing and process monitoring in the pre-erection shops.

• The Korean Journal of Pain
• /
• 제34권4호
• /
• pp.487-500
• /
• 2021

Background: Although the erector spinae plane block has been used in various truncal surgical procedures, its clinical benefits in patients undergoing spinal surgery remain controversial. The aim of this meta-analysis was to evaluate the clinical benefits of erector spinae plane block in patients undergoing spinal surgery. Methods: We searched the Cochrane Library, PubMed, EMBASE, and China National Knowledge Infrastructure for randomized controlled trials comparing the erector spinae plane block with a nonblocked control for spinal surgery. Results: Twelve studies encompassing 696 subjects were included in our systematic review and meta-analysis. We found that the erector spinae plane block decreased postoperative pain scores and opioid consumption in the postoperative and intraoperative periods. Moreover, it prolonged the time to the first rescue analgesic, reduced the number of patients who required rescue analgesia, and lowered the incidence of postoperative nausea and vomiting. However, it did not exhibit efficacy in decreasing the incidence of urinary retention and itching or shortening the length of hospital stays, or the time to first ambulation. Conclusions: Erector spinae plane block improves analgesic efficacy among patients undergoing spinal surgery compared with nonblocked controls; however, there is insufficient evidence regarding the benefits of erector spinae plane block for rapid recovery.

• The Journal of Asian Finance, Economics and Business
• /
• 제8권12호
• /
• pp.261-269
• /
• 2021

This study examines the effect of block diversity on the risk of firms listed on the Korean Stock Exchange between 2010 and 2017. To examine the effect of block diversity on corporate risk, we measure block diversity in terms of a single component, portfolio size, by referring to prior literature. This diversity component accounts for the differences in portfolio size across corporate blocks. In line with existing research on corporate risk, we consider several variables to measure corporate risk: volatility, beta, and idiosyncratic risk. The results show a negative relationship between the size of a block shareholder's portfolio and corporate risk. We also show no difference in the effect of block diversity on the corporate risk between KOSPI and KOSDAQ. This implies that the difference in portfolio size among corporate blocks reduces corporate risk. This may be due to the effect of inter-block monitoring activities in the Korean securities market, which benefits from block diversity. This empirical result supports previous studies that predicted that block diversity would have beneficial influences on firm monitoring in general. This study is significant in that it analyzes the relationship between block diversity and firm risk and provides relevant information to business practitioners and investors.

• 한국컴퓨터정보학회논문지
• /
• 제24권8호
• /
• pp.9-17
• /
• 2019

In this paper, we propose a block mapping technique applicable to NAND flash memory. In order to use the NAND flash memory with the operating system and the file system developed on the basis of the hard disk which is mainly used in the general PC field, it is necessary to use the system software known as the FTL (Flash Translation Layer). FTL overcomes the disadvantage of not being able to overwrite data by using the address mapping table and solves the additional features caused by the physical structure of NAND flash memory. In this paper, we propose a new mapping method based on the block mapping method for efficient use of the NAND flash memory. In the case of the proposed technique, the data modification operation is processed by using a blank page in the existing block without using an additional block for the data modification operation, thereby minimizing the block unit deletion operation in the merging operation. Also, the frequency of occurrence of the sequential write request and random write request Accordingly, by optimally adjusting the ratio of pages for recording data in a block and pages for recording data requested for modification, it is possible to optimize sequential writing and random writing by maximizing the utilization of pages in a block.

• Mycobiology
• /
• 제47권1호
• /
• pp.97-104
• /
• 2019

Mushroom cultivation has gained increased attention in recent years. Currently, only four types of spawn, including sawdust spawn, grain spawn, liquid spawn, and stick spawn, are commonly available for mushroom cultivation. This limited spawn diversity has led to difficulty in selecting suitable inoculum materials in some cultivation. In this study, three small blocks of lignocellulosic agro-wastes and one block of a synthetic matrix were prepared as support for growing Pleurotus ostreatus in liquid medium. Mycelium-adsorbed blocks were then evaluated for their potential as block spawn for fructification. Our results indicated that the edible fungus was adsorbed and abundantly grew internally and externally on loofah sponge and synthetic polyurethane foam (PUF) supports and also has the ability to attach and grow on the surface of sugarcane bagasse and corncob supports. The mycelia of P. ostreatus adhered on corncob exhibited the highest metabolic activity, while those on the PUF showed the least activity. Mycelial extension rates of block spawns made of agro-waste materials were comparable to that of sawdust spawn, but the block spawn of PUF showed a significantly lower rate. No significant differences in cropping time and yield were observed among cultivations between experimental block spawns and sawdust spawns. Moreover, the corncob block spawn maintained its fruiting potential during an examined period of 6-month storage. The developed block spawn could be practically applied in mushroom cultivation.

• Journal of the Korean Wood Science and Technology
• /
• 제47권1호
• /
• pp.51-65
• /
• 2019

A wood-plastic composite (WPC) paver block was manufactured using wood chips waste through an extrusion process, and it was intended to be used for paving in basic rest areas. The first stage in this study covered preliminary tests in terms of flexural strength and dimensional swelling to determine the optimal WPC compounding mix condition, by variation of the WPC ingredients. Next, three different paver blocks including the WPC block, a non-porous cement block, and a porous cement block were tested in terms of various material properties in the laboratory. Finally, two outdoor test sections of the proposed paver blocks were prepared to simulate a basic rest area. Test results indicated that the flexural strength of the WPC paver blocks was about 1.6 times greater than that of the tested cement paver blocks. The WPC block pavement was unaffected by water buoyance as well as volume expansion due to swelling. Results from the impact absorbance test and light falling weight deflectometer (LFWD) test clearly showed that the WPC block paving system marginally satisfied the comfortable and safe hardness range from the pedestrians' perspective, while the results demonstrated that it is structurally sound for application as a road paving block.

• KSII Transactions on Internet and Information Systems (TIIS)
• /
• 제15권11호
• /
• pp.3970-3990
• /
• 2021

In view of the problems of insufficient data collection and processing capability of multi-source heterogeneous equipment, and low visibility of equipment status at the ship block construction site. A data collection method for ship block construction equipment based on wireless sensor network (WSN) technology and a data processing method based on edge computing were proposed. Based on the Browser/Server (B/S) architecture and the OneNET platform, an online monitoring system for ship block construction equipment was designed and developed, which realized the visual online monitoring and management of the ship block construction equipment status. Not only that, the feasibility and reliability of the monitoring system were verified by using the intelligent tire frame system as the application object. The research of this project can lay the foundation for the ship block construction equipment management and the ship block intelligent construction, and ultimately improve the quality and efficiency of ship block construction.

• 한국소프트웨어감정평가학회 논문지
• /
• 제15권1호
• /
• pp.115-121
• /
• 2019

지속적으로 확산되어져 가고 있는 블록체인 시스템과 블록체인 기반의 서비스 시스템의 구조를 분석하였다. 거래 쌍방 간의 신뢰 확보를 위한 제 3 자를 필요로 하지 않는, 분산화된 장부 암호화 시스템 소프트웨어 기술이다. 블록체인은 자료 구조적으로는 링크드 리스트 구조로 되어 있다. 블록체인은 거래 정보를 블록화 하여 다른 블록들과 연결해서 거래 정보를 관리한다. 해시 함수를 사용하여 블록화와 연결을 하게 된다. 결과적으로, 현재의 블록체인 시스템과 블록체인 기반의 서비스 시스템의 구조적 취약성을 발견하였다. 본 논문에서 제시한 블록체인 시스템과 블록체인 기반의 서비스 시스템의 구조적인 문제점 등이 해결되어지게 되면, 다양한 산업적 기여가 예상된다.