• Title/Summary/Keyword: Blends

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A Study on the Commercialization of Polyamide 66/Polypropylene Blend (폴리아마이드 66/폴리프로필렌 블렌드의 상업화 연구)

  • Kim, Seog-Jun;Nam, Byeong-Uk
    • Elastomers and Composites
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    • v.38 no.3
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    • pp.262-272
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    • 2003
  • Maleic anhydride-grafted-polypropylene(PP-g-MA) were used as a blend component and a compatibilizer, respectively, for two reactive blends of polyamide 66(PA 66)PP-g-MA binary blends and PA 66/polypropylene(PP)/PP-g-MA ternary blends. The goal of this work was to investigate the property differences between binary and ternary blends. Tensile strength, flexural modulus, heat deflection temperature, impact strength, melt flow index, and the dependence of melt viscosity on the shear rate were examined. The impact strengths of binary blends were higher than those of ternary blends at all compositions, since the in situ synthesis of PP-g-PA 66 copolymer through the imide formation between the amine end group of PA 66 and the anhydride group of PP-g-MA gave the increase of molecular weight and was more popular in binary blends than in ternary blends. In case of ternary blends, most of the properties were superior to those of binary blends, owing to the better properties of PP compared with PP-g-MA. The toughened binary blends with 70/30(PA 66/PP-g-MA) and 80/20 ratios were not commercially applicable due to their poor processibility. So, the ternary blends which showed lower melt viscosities were recommended for the commercial applications.

Fibrillation in TLCP/Polyester Binary Blends

  • Kim, Jun-Young;Kim, Seong-Hun
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.101-101
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    • 2003
  • TLCP/Polyester binary blends were prepared by melt blending. Rheological, morphological, and thermal properties of of TLCP/polyester blends were investigated with viscosity ratio. Diameter of TLCP fibrils decreased with viscosity ratio. More and smaller TLCP fibrils were obtained at higher shear rate. Lower viscosity ratio was necessary for the fibrillation of TLCP in the binary blends.

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Studies on the Physical Properties and Application of EPDM-Polymer Blends. Part 2. Physical Properties for EPDM-SBR Blends (EPDM과 각종(各種) Polymer의 Blend에 의(依)한 성능변화(性能變化) 및 그 응용(應用)에 관(關)한 연구(硏究) (제2보(第2報)) EPDM과 Butadiene-Styrene Rubber의 Blend에 대(對)하여)

  • Kim, Joon-Soo
    • Elastomers and Composites
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    • v.6 no.2
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    • pp.73-79
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    • 1971
  • As a series of the studies of EPDM-Polymer blends, the experiments are concentrated to the investigation of the physical properties of the EPDM-SBR blends. The results are shown as follows: 1. Tensile strength decreased with increase in EPDM contents and the decreasing value was good results than NR blending. 2. It was found that the aging were much improved after blending and experiments data was good results than NR blending.

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Protected Organic Acid Blends as an Alternative to Antibiotics in Finishing Pigs

  • Upadhaya, S.D.;Lee, K.Y.;Kim, In Ho
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.11
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    • pp.1600-1607
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    • 2014
  • A total of 120 finishing pigs ([Yorkshire${\times}$Landrace]${\times}$Duroc) with an average body weight (BW) of $49.72{\pm}1.72kg$ were used in 12-wk trial to evaluate the effects of protected organic acids on growth performance, nutrient digestibility, fecal micro flora, meat quality and fecal gas emission. Pigs were randomly allotted to one of three dietary treatments (10 replication pens with 4 pigs per pen) in a randomly complete block design based on their initial BW. Each dietary treatment consisted of: Control (CON/basal diet), OA1 (basal diet+0.1% organic acids) and OA2 (basal diet+0.2% organic acids). Dietary treatment with protected organic acid blends linearly improved (p<0.001) average daily gain during 0 to 6 week, 6 to 12 week as well as overall with the increase in their inclusion level in the diet. The dry matter, N, and energy digestibility was higher (linear effect, p<0.001) with the increase in the dose of protected organic acid blends during 12 week. During week 6, a decrease (linear effect, p = 0.01) in fecal ammonia contents was observed with the increase in the level of protected organic acid blends on d 3 and d 5 of fermentation. Moreover, acetic acid emission decreased linearly (p = 0.02) on d7 of fermentation with the increase in the level of protected organic acid blends. During 12 weeks, linear decrease (p<0.001) in fecal ammonia on d 3 and d 5 and acetic acid content on d 5 of fermentation was observed with the increase in the level of protected organic acid blends. Supplementation of protected organic acid blends linearly increased the longissimus muscle area with the increasing concentration of organic acids. Moreover, color of meat increased (linear effect, quadratic effect, p<0.001, p<0.002 respectively) and firmness of meat showed quadratic effect (p = 0.003) with the inclusion of increasing level of protected organic acid in the diet. During the 6 week, increment in the level of protected organic acid blends decreased (linear effect, p = 0.01) Escherichia coli (E. coli) counts and increased (linear effect, p = 0.004) Lactobacillus counts. During 12-wk of experimental trial, feces from pigs fed diet supplemented with organic acid blends showed linear reduction (p<0.001) of E. coli counts and the tendency of linear increase (p = 0.06) in Lactobacillus count with the increase in the level of organic acid blends. In conclusion, 0.2% protected organic acids blends positively affected growth performance, nutrient digestibility, fecal gas emission and meat quality in finishing pigs without any adverse effects on blood parameters.

A Study for Antistress Effects of Two Aromatic Synergic Blending Oils (아로마 에센셜 오일의 항스트레스효과에대한 연구 - 뇌파 검사를 중심으로-)

  • Choi, Jin-Yong;Oh, Hong-Keun;Chun, Kyum-Ku;Lee, Jun-Suk;Park, Dong-Ki;Choi, Sung-Don;Chun, Tae-Il;Kim, Mi-Kyung;Kim, Suk-Bum
    • Annals of Clinical Neurophysiology
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    • v.2 no.2
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    • pp.70-80
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    • 2000
  • Purpose : This study was performed to evaluate the antistress effects of two aromatic blends being composed of synergic essential oils and also to differentiate its effectiveness between two. Methods : The subject were 20(10 for men, 10 for women) for vital factors and another 20(10 for mem, 10 for women) for serum catecholamine. Vital factors(blood pressure, pulse), electroencephalograpy, psychological tests(SACL, STAI) and serum catecholamine were applied to the subjects. Results : 1. All two aromatic synergic blends revealed no significant differnce of vital factors after inhalation but stable conditions generally by lowering pulse and blood pressure after inhalation. 2. Both blends were significantly valuable in antianxiety and antistress effects statistically. There were no statistically difference between two blends. 3. There were no significant difference in all brain waves after inhalation of two blends but generally stable brain waves were seen in all areas. 4. There were antistress effects of both blends in accordance of decreased serum catecholamines after inhalation of both blends. There were no significantly difference between two blends statistically. Conclusion : Both two aromatic synergic blends reached effective antistress and antianxiety states after inhalation of each blends. There were no significant difference between two blends. Further studies about the effectiveness between the amount of aromatic essential oils and the duration of inhalation should be considered. Also clinical applications of these two aromatic synergic blending oils to develop the aromatic products would be affordable in the future.

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Crystallization Behavior of Poly(lactic acid) / Poly($\varepsilon$-caprolactone) Blends (폴리락트산/폴리카프로락톤 블렌드의 결정화 거동)

  • 이종록;천상욱;강호종
    • Polymer(Korea)
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    • v.27 no.4
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    • pp.285-292
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    • 2003
  • The compatibility of poly(lactic acid)/poly($\varepsilon$-caprolactone) (PLA/PCL) blends as a function of blend composition was studied and triphenyl phosphite (TPP) was applied to PLA/PCL blends as a reactive compatibilizer. Especially the effect of compatibility on the crystallization behavior in both PLA/PCL blends and PLA/PCL blends with TPP was considered. PLA/PCL blends were immiscible based on thermal characteristics of PLA/PCL blends and the miscibility was depend upon the blend composition. The enhancement of compatibility was found in PLA/PCL blends with TPP depend upon its content. The rate of crystallization in PLA/PCL blend varied with blend composition. This was understood as the development of nucleation at the interface of PLA-PCL due to the immiscibility. TPP was acting as a compatibilizer as well as an agent for the acceleration of spherulite growth In PLA. As a result, the crystallization rate increased and the size of spherulite became larger than that of PLA/PCL blend without TPP.

Thermal behavior and rheology of polypropylene and its blends with poly($\varepsilon$-caprolactone)

  • Chun, Yong-Sung;Minsoo Han;Park, Junghoon;Kim, Woo-Nyon
    • Korea-Australia Rheology Journal
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    • v.12 no.2
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    • pp.101-105
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    • 2000
  • The crystallization behavior of homo polypropylene (PP) and PP in the PP-poly($\varepsilon$-caprolactone) (PCL) blends during isothermal crystallization has been investigated using differential scanning calorimeter (DSC) and advanced rheometric expansion system (ARES). From the storage modulus data of the homo PP and PP-PCL blends during isothermal crystallization, the volume fraction of crystallized material ($X_t$) of the homo PP and PP in the PP-PCL blends was calculated using the various rheological models. The results of $X_t$ of the homo PP and PP in the PP-PCL blends from ARES measurement were compared with the results from DSC. The $X_t$ of the homo PP was found to be higher in the ARES measurement than in the DSC. The crystallization rate of the homo PP was found to be faster in the rheological measurements than in the thermal analysis. The $X_t$ of PP in the PP-PCL blends with various compositions was obtained from the thermal analysis and rheological measurements. The $X_t$ of PP in the PP-PCL blends obtained from the thermal analysis and rheological measurements are not consistent. This discrepancy of $X_t$ may be due to the morphological changes resulted from the different crystallization kinetics of PP in the PP-PCL blends.

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Influence of Thermal Aging on the Properties of EPDM/Silicone Rubber Blends (열노화가 EPDM/실리콘 고무 블렌드의 물성에 미치는 영향)

  • Chung Yu-Kyoung;Lee Sung-Goo;Cho Bong Rae;Choi Kil-Yeong
    • Polymer(Korea)
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    • v.29 no.2
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    • pp.166-171
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    • 2005
  • EPDM (ethylene propylene diene monomer)/silicone rubber blends were prepared and the influence of a compatibilizer and thermal aging on the properties of the blends was investigated. The blends of which the compositions were varied in the range of 90/10 through $10/90\;wt\%$ were melt mixed by using a Brabender Plasticoder (internal mixer) and were vulcanized by a hot press. The morphology of the vulcanized EPDM/SR blends was examined by scanning electron microscopy (SEM). After the thermal Aging for 24, 48, 96 hrs at $100^{\circ}C$ in an air oven, hardness, tensile strength, elongation and contact angle of the blends were investigated. From the result of the morphology, it was confirmed that the domain size of the blends containing the compatibilizer was reduced. As the increase of the thermal aging time, hardness and tensile strength of the blends decreased but elongation and contact angle increased.

Thermal Behavior and Physical Properties of Low Density Polyethylene/Metallocene Linear Low Density Polyethylene Blends (저밀도 폴리에틸렌/메탈로센 선형 저밀도 폴리에틸렌 블렌드의 열적 거동 및 물성)

  • Kim, Jang-Yup;Hyun, Uk;Lee, Dong-Ho;Noh, Seok-Kyun;Lee, Sang-Won;Huh, Wan-Soo
    • Polymer(Korea)
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    • v.27 no.5
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    • pp.502-507
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    • 2003
  • The thermal and physical properties of low density polyethylene melt-blended with Metallocene linear low density polyethylenes were investigated. Since the Metallocene polyethylenes have similar MW and MWD except m-LLDPE4, it can be said that the thermal behavior and mechanical properties of the blends depend upon the l-octene comonomer content. The melting behavior of LDPE/m-LLDPE1 blends shows two melting peaks with LDPE contents higher than 50%, while the other blends show only one melting peak. It was observed that the blends show higher crystallization temperature and higher crystallinity with lower comonomer content. Initial modulus of a blend exhibited the behavior proportional to the crystallinity and the elongation at break of the blends was increased with increasing the m-LLDPE composition. Melt indices of the blends decreased with increasing the comonomer content of Metallocene LLDPE. Melt Index values of the blends show negative deviation.

Morphology and Mechanical Properties of Waste PVC Blends (II)- The Relationship between Rheology and Morphology of Waste PVC/PE Blends (폐폴리(염화 비닐)계 고분자 블렌드의 구조 및 물성 연구(II)-폐폴리(염화 비닐)/폴리에틸렌 고분자 블렌드의 형태학 및 유변학적 거동)

  • 유영재;박재찬;원종찬;최길영;이재흥
    • Polymer(Korea)
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    • v.28 no.6
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    • pp.460-467
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    • 2004
  • The polymer blends of waste poly(vinyl chloride) (RPVC) and waste polyethylene (RPE) were prepared by melt mixing. Their morphologies and rheological properties were investigated and torque changes were also measured. Comparing the torques calculated by the log additivity rule with measured torque changes, the polymer blends showed the large negative deviation behavior (NDB) due to their incompatibility. The shear viscosities of the blends decreased with increasing shear rates, showing shear thinning behavior. The shear viscosity of the blends with compatibilizer was larger than that of the blends without compatibilizer. SEM micrographs of the strands after measurement showed that the domain size of the blends was slightly enlarged with increasing the shear rate. Also, RPVC domain size was larger in the core-sections of the strands from capillary viscometer than in the surface region.