• Title/Summary/Keyword: Blending Surface

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Mechanical Properties and Failure Analysis of $Al_2O_3/ZrO_2$ Composites ($Al_2O_3/ZrO_2$복합체의 기계적 물성 및 파괴거동)

  • Hong, Gigon-Hong;Han, Dong-Bin
    • Korean Journal of Materials Research
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    • v.2 no.3
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    • pp.172-179
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    • 1992
  • $Al_2O_3/ZrO_2$ composites were fabricated by pressureless sintering from commercial powders and/or nano composite powder of $Al_2O_3/ZrO_2$. The Properties of the composites such as density, strength, hardness and fracture toughness were evaluated. Microstructures and fracture surfaces ware also examined. The flexural strength remains unchanged(~640 MPa) as long as the content of commercial powders is not extreamly high, and depends on microstructures of the composites. Fracture toughness(4.3-5.3 $Mpa{\cdot}m^{1/2}$) increases with increasing content of commercial powders. Fractography shows that failure-initiating sources are 1)surface flaws resulting from machining damage, 2)crack-shaped voids formed due to $ZrO_2$ agglomeration, and 3)surface separation caused by inhomogeneous blending and by sinterability difference between nato composite powder and commercial powders of $Al_2O_3/ZrO_2$. Failure mode of the composites was mainly transgranular.

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Structure and Characteristic of Chitosan/Bombyx mori Silk Fibroin Blend Filems (키토산/Bombyx mori 견 피브로인 블렌드 필름의 구조와 특성)

  • Kim, Dong-Keon;Kim, Hong-Sung
    • Polymer(Korea)
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    • v.29 no.4
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    • pp.408-412
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    • 2005
  • Structure and characteristic of the films blended chitosan matrix with silk fibroin, extracted from Bombyx mori, were studied by X-ray diffraction, differential scanning calorimetry, FT-IR spectra analysis, SEM photographs, contact angle measurement and water absorbency in order to use as biomaterials. The blend films of $0\~30 wt\%$ fibroin content were prepared in acetic solution with $Li^+$ ion. It was found that the crystallinity of chitosan/fibroin blend films was decreased by the presence of intermolecular interactions such as hydrogen bonding between animo groups of chitosan and carbonyl groups of fibroin. As the proportion of fibroin in the blend increased, anhydrous crystalline phase of chitosan disappeared, and hydrated crystalline phase decreased, and $\beta$-structure crystalline phase of fibroin was formed. Therefore the blend films were crystallized into two different crystalline region of chitosan and fibroin. Surface hydrophilicity and water absorbency increased with blending fibroin. Above 20 $wt\%$ fibroin content, hydrogel film was formed. The surface and section of the film showed uniform microstructure on SEM photographs.

Studies on the Blistering Resistance(I) - The influence of pigment ratio on blistering resistance - (블리스터링에 관한 연구(제1보) - 안료의 배합비가 블리스터링에 미치는 영향 -)

  • Lim, Won-Seok;Ha, Young-Baeck;Kim, Chang-Keun;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.2 s.120
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    • pp.25-30
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    • 2007
  • Recently the use of web offset printing has been increasing, which can provide high print speed, mass production, and high print quality. However, high speed web offset printing has frequently undergone a blistering problem when the printed paper passes through hot air dryers. Blistering occurs in the middle of the base paper or in the coating layer. This paper focused on the blistering occurring in the base paper. In order to elucidate the effect of pigment ratio on blistering, 6 types of coating color were prepared with varying GCC/clay ratios and printability and blistering were investigated focusing on structure changes in the coating layer. When the clay content in the coating layer was increased, surface roughness and surface strength were decreased and paper gloss was increased. In addition, it was found that the coating layer structure with high clay content, which contains lots of discontinuous pores, hindered water vapors to penetrate out and, as a result, blistering occurred.

Construction of the Regional Prediction System using a Regional Climate Model and Validation of its Wintertime Forecast (지역기후모델을 이용한 상세계절예측시스템 구축 및 겨울철 예측성 검증)

  • Kim, Moon-Hyun;Kang, Hyun-Suk;Byun, Young-Hwa;Park, Suhee;Kwon, Won-Tae
    • Atmosphere
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    • v.21 no.1
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    • pp.17-33
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    • 2011
  • A dynamical downscaling system for seasonal forecast has been constructed based on a regional climate model, and its predictability was investigated for 10 years' wintertime (December-January-February; DJF) climatology in East Asia. Initial and lateral boundary conditions were obtained from the operational seasonal forecasting data, which are realtime output of the Global Data Assimilation and Prediction System (GDAPS) at Korea Meteorological Administration (KMA). Sea surface temperature was also obtained from the operational forecasts, i.e., KMA El-Nino and Global Sea Surface Temperature Forecast System. In order to determine the better configuration of the regional climate model for East Asian regions, two sensitivity experiments were carried out for one winter season (97/98 DJF): One is for the topography blending and the other is for the cumulus parameterization scheme. After determining the proper configuration, the predictability of the regional forecasting system was validated with respect to 850 hPa temperature and precipitation. The results showed that mean fields error and other verification statistics were generally decreased compared to GDAPS, most evident in 500 hPa geopotential heights. These improved simulation affected season prediction, and then HSS was better 36% and 11% about 850 hPa temperature and precipitation, respectively.

Preparation and Water Vapor Barrier Properties of PET/Nanohybrid PI Films (폴리에스테르/폴리이미드 나노복합필름의 제조 및 수분차단 특성)

  • Han, Seung San;Kim, Yong Seok;Won, Jong Chan;Lee, Jae Heung;Choi, Kil-Yeong
    • Journal of Adhesion and Interface
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    • v.5 no.1
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    • pp.29-35
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    • 2004
  • We have prepared polyster/nanQhybridized polyimide films in the range of 1~9 wt% of organophilic synthetic layered silicate (STN). Firstly, poly(amic acid)/STN nanocomposite solutions were prepared via solution blending method in DMAc or THF/MeOH solution, and then cast on the polyester film followed by imidization reaction, thermal and chemical method repestively. XRD and TEM experiment showed that the STN was fully exfoliated through the polyimide matrix. Surface morphologies of nanohybridized polyimide films were characterized by AFM and thermal, mechanical properties were also confirmed by TGA, DMA and UTM each. And also, the water vapor permeabilities highly depended on the content of STN. The sample from chemical imidization route and THF/MeOH solvent system showed better water vapor barrier properties than thermal one and DMAc system.

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Electrochemical Characteristics of Si/PC/CNF/PC Composite for Anode Material of Lithium ion Battery (이차전지 음극활물질 Si/PC/CNF/PC 복합 소재의 전기화학적 특성)

  • Jeon, Do-Man;Na, Byung-Ki;Rhee, Young-Woo
    • Korean Chemical Engineering Research
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    • v.56 no.6
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    • pp.798-803
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    • 2018
  • In order to use Si as an anode material for lithium-ion battery, the particle size was controlled to less than $0.5{\mu}m$ and carbon was coated on the surface with the thickness less than 10 nm. The carbon fiber was grown on the Si surface with 50~150 wt%, and the carbon coating was carried out once again. The Si composite material was mixed with dissimilar metals to increase the conductivity, and graphite was mixed to improve cyclic life characteristics. The physical and electrochemical characteristics of composite materials were measured with XRD, SEM, TEM and coin cell. The discharge capacity of Si/PC/CNF/PC was lower than that of Si/PC (Pyrolytic Carbon)/CNF (Carbon Nano Fiber). However, the cyclic life of Si/PC/CNF/PC was higher. Initial discharge capacity of 1512 mA h g-1 at 0.2 C rate and initial efficiency of 78% were shown. It also showed a capacity retention of 94% in 10 cycles.

Charateristics of Soft Paving Materials used Eco-friendly (친환경 소프트 포장재의 공학적 특성에 관한 연구)

  • Jeon, Du-Jun;Park, Sung-Jin
    • Journal of the Society of Disaster Information
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    • v.15 no.2
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    • pp.206-213
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    • 2019
  • Purpose: This study aims to develop eco - friendly paving materials using Sawdust and EPDM chips. Method: Materials are eco-friendly materials and have no environmental problems. By using EPDM chip, the walking feeling can be increased. Results: In this study, the optimum mixing ratio was calculated through mixing design test. Based on the blending ratio, the surface layer of the sidewalk is made of fine sawdust and EPDM chips. We used only sawdust of grain - 107 -size to make the base layer of the sidewalks and the surface layer of the bicycle road with the permeability and the anti - resilience, and suggested the application method through the test construction. Conclusion: This study the expected that the recent efforts of the government to reduce the elastic paving material, which is the environmentally harmful problem with the complete eco-friendly paving material, are expected to revive.

Processing Optimization of Seasoned Salmon Oncorhynchus keta Jerky Using Response Surface Methodology (반응표면분석법을 활용한 연어(Oncorhynchus keta) 육포의 제조공정 최적화)

  • Kim, Min-Woo;Yoon, In Seong;Kim, Ye Youl;Lee, Jung Suck;Heu, Min Soo;Kim, Jin-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.54 no.3
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    • pp.261-270
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    • 2021
  • This study was conducted to optimize the processing of seasoned salmon Oncorhynchus keta jerky (SSJ) using response surface methodology (RSM). For seasoning sauces-blending conditions of jerky using the RSM program, salt [X1, % (w/v)] and amino-basic material [X2, % (w/v)] were chosen as independent variables, and salinity (Y1) and amino-N (Y2) were chosen as dependent variables. The optimum conditions of X1 and X2 were 1.2% and 12.9%, respectively. To optimize drying conditions of seasoned salmon jerky using RSM program, soaking time (X1, min), drying temperature (X2, ℃) and drying time (X3, min) were chosen as independent variables, and moisture content (Y1), hardness (Y2) and overall acceptance (Y3) were chosen as dependent variables. Optimum conditions of X1, X2 and X3 were 183.0 min, 62.5℃ and 351.0 min, respectively. In the sensory evaluation, the scores for taste, flavor, and texture for of SSJ were higher than those for a commercial product. The results suggest that the developed seasoned salmon jerky can be industrialized.

The Influence of Feed Energy Density and a Formulated Additive on Rumen and Rectal Temperature in Hanwoo Steers

  • Cho, Sangbuem;Mbiriri, David Tinotenda;Shim, Kwanseob;Lee, A-Leum;Oh, Seong-Jin;Yang, Jinho;Ryu, Chaehwa;Kim, Young-Hoon;Seo, Kang-Seok;Chae, Jung-Il;Oh, Young Kyoon;Choi, Nag-Jin
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.11
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    • pp.1652-1662
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    • 2014
  • The present study investigated the optimum blending condition of protected fat, choline and yeast culture for lowering of rumen temperature. The Box Benken experimental design, a fractional factorial arrangement, and response surface methodology were employed. The optimum blending condition was determined using the rumen simulated in vitro fermentation. An additive formulated on the optimum condition contained 50% of protected fat, 25% of yeast culture, 5% of choline, 7% of organic zinc, 6.5% of cinnamon, and 6.5% of stevioside. The feed additive was supplemented at a rate of 0.1% of diet (orchard grass:concentrate, 3:7) and compared with a control which had no additive. The treatment resulted in lower volatile fatty acid (VFA) concentration and biogas than the control. To investigate the effect of the optimized additive and feed energy levels on rumen and rectal temperatures, four rumen cannulated Hanwoo (Korean native beef breed) steers were in a $4{\times}4$ Latin square design. Energy levels were varied to low and high by altering the ratio of forage to concentrate in diet: low energy (6:4) and high energy (4:6). The additive was added at a rate of 0.1% of the diet. The following parameters were measured; feed intake, rumen and rectal temperatures, ruminal pH and VFA concentration. This study was conducted in an environmentally controlled house with temperature set at $30^{\circ}C$ and relative humidity levels of 70%. Steers were housed individually in raised crates to facilitate collection of urine and feces. The adaptation period was for 14 days, 2 days for sampling and 7 days for resting the animals. The additive significantly reduced both rumen (p<0.01) and rectal temperatures (p<0.001) without depressed feed intake. There were interactions (p<0.01) between energy level and additive on ruminal temperature. Neither additive nor energy level had an effect on total VFA concentration. The additive however, significantly increased (p<0.01) propionate and subsequently had lower acetate:propionate (A/P) ratios than non-additive supplementation. High concentrate diets had significantly lower pH. Interactions between energy and additive were observed (p<0.01) in ammonia nitrogen production. Supplementation of diets with the additive resulted in lower rumen and rectal temperatures, hence the additive showed promise in alleviating undesirable effects of heat stress in cattle.

Performance Characteristics of p-i-n Type Organic Thin-film Photovoltaic Cell with CuPc: $F_4$-TCNQ Hole Transport Layer (CuPc: $F_4$-TCNQ 정공 수송층이 도입된 P-i-n형 유기 박막 태양전지의 성능 특성 연구)

  • Park, So-Hyun;Kang, Hak-Su;Senthilkumar, Natarajan;Park, Dae-Won;Choe, Young-Son
    • Polymer(Korea)
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    • v.33 no.3
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    • pp.191-197
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    • 2009
  • We have investigated the effect of strong p-type organic semiconductor $F_4$-TCNQ-doped CuPc hole transport layer on the performance of p-i-n type bulk heterojunction photovoltaic device with ITO/PEDOT:PSS/CuPc: $F_4$-TCNQ(5 wt%)/CuPc:C60(blending ratio l:l)/C60/BCP/LiF/Al, architecture fabricated via vacuum deposition process, and have evaluated the J-V characteristics, short-circuit current ($J_{sc}$), open-circuit voltage($V_{oc}$), fill factor(FF), and power conversion efficiency(${\eta}_e$) of the device. By doping $F_4$-TCNQ into CuPc hole transport layer, increased absorption intensity in absorption spectra, uniform dispersion of organic molecules in the layer, surface uniformity of the layer, and enhanced injection currents improved the current photovoltaic device with power conversion efficiency(${\eta}_e$) of 0.16%, which is still low value compared to silicone solar cell indicating that many efforts should be made to improve organic photovoltaic devices.