• Title/Summary/Keyword: Blend ratio

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Effect of Phenyl Vinyl Methyl Silicone (PVMQ) on Low Temperature Sealing Performance of Fluorosilicone Composites

  • Lee, Jin Hyok;Bae, Jong Woo;Choi, Myoung Chan;Yun, Yu-Mi;Jo, Nam-Ju
    • Elastomers and Composites
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    • v.56 no.4
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    • pp.209-216
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    • 2021
  • In this study, we observed the mechanical properties, thermal stability, and low temperature sealing performance of fluorosilicone elastic composites. When the blend ratio of Phenyl vinyl methyl silicone (PVMQ) was increased, the tensile strength, modulus at 100%, and compression set were decreased. The thermal stability of fluorosilicone elastic composites showed a similar tendency. These were caused by poorer green strength of PVMQ than Fluorosilicone rubber (FVMQ). The change in the tensile strength and elongation at -40℃ showed a decreasing tendency with increasing PVMQ blend ratio. By increasing the PVMQ blend ratio, low-temperature performance was improved. The Dynamic mechanical analysis (DMA) results showed that Tg was decreased and low-temperature performance was improved with increasing PVMQ blend ratio. However tanδ was decreased becaused of the poor green strength and elasticity of PVMQ. From a hysteresis loss at -40℃, the hysteresis loss value was increased and fluorosilicone elastic composites showed the decreasing tendency of elasticity with increasing PVMQ blend ratio. From the TR test, TR10 was decreased with increasing PVMQ blend ratio. FS-4 (45% PVMQ blended composites) showed a TR10 of -68.0℃ that was 5℃ lower than that of FS-1 (100% FVMQ). The gas leakage temperature was decreased with increasing PVMQ blend ratio. The gas leakage temperature of FS-4 was -69.2℃ that was 5℃ lower than that of FS-1. Caused by the polymer chain started to transfer from a glassy state to a rubbery state and had a mobility of chain under Tg, the gas leakage temperature showed a lower value than Tg. The sealing performance at low temperature was dominated by Tg that directly affected the mobility of the polymer chain.

The Effect of HPMC Concentration on the Morphology and Post Drawing of Wet Spun Regenerated SF/HPMC Blend Filaments

  • Ko, Jae-Sang;Um, In-Chul
    • International Journal of Industrial Entomology and Biomaterials
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    • v.19 no.1
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    • pp.181-185
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    • 2009
  • In this paper, the regenerated silk fibroin (SF)/hydroxypropyl methylcellulose (HPMC) blend filaments were prepared by wet spinning and the effect of HPMC concentration on the post drawing and morphology of blend filaments was elucidated. The result of maximum draw ratio indicated that the wet spinnability of wet spun SF / HPMC was improved with increasing HPMC concentration until 8% and remained constant after that concentration. The SEM observation revealed that the enhanced wet spinnability of blend filaments was strongly related to the morphological change by increasing HPMC concentration. Regardless of HPMC concentration, as SF content was reduced, the wet spinnability of blend film decreased resulting in reduced maximum draw ratio. It was also found by SEM observation that the cross section of blend filament deviated from circularity with an increase of HPMC content.

Building Calibration Curve for Py-GC/MS Analysis of SBR/BR Blend Rubber Compounds

  • Chae, Eunji;Choi, Sung-Seen
    • Elastomers and Composites
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    • v.55 no.4
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    • pp.281-288
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    • 2020
  • A calibration curve is needed to determine the SBR and BR blend ratio of SBR/BR blend rubber compounds using pyrolysis-gas chromatography/mass chromatography (Py-GC/MS) or Py-GC. In general, a calibration curve is obtained using reference SBR/BR vulcanizates with various blend ratios. In this study, the calibration curves were obtained using reference samples made of rubber solutions and were compared to those plotted using the reference SBR/BR vulcanizates. Calibration curves using variations of 1,3-butadiene/styrene, 4-vinylcyclohexene (VCH)/styrene, 2-phenylpropene (PhP)/butadiene, PhP/VCH, 4-phenylcyclohexene (PhCH)/butadiene, and PhCH/VCH ratios with the BR content were examined for the suitability. We found that the calibration curves obtained using the mixed rubber solution references (1,3-butadiene/styrene and PhP/butadiene) could replace those constructed using the reference SBR/BR vulcanizates. The calibration curves of 1,3-butadiene/styrene and PhP/butadiene obtained using the raw references can be used for the determination of the SBR/BR blend ratios by applying some correction factors.

White Light-Emitting Diodes Using Conjugated Polymer Blends

  • Hwang, Do-Hoon;Park, Moo-Jin;Kim, Suk-Kyung;Lee, Chang-Hee;Kim, Yong-Bae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.585-587
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    • 2004
  • We report the characterization of white light emitting devices fabricated using conjugated polymer blends. Blue emissive poly[9,9-bis(4'-n-octyloxyphenyl) fluorene-2,7-diyl-co-10-(2'-ethylhexyl)phenothiazine-3,7-diyl] [poly(BOPF-co-PTZ)] and red emissive poly(2-(2'-ethylhexyloxy)-5-methoxy-1,4-phenylenevinylene) (MEH-PPV) were employed in the blends. The inefficient energy transfer between these blue and red light emitting polymers (previously deduced from the PL spectra of the blend films) enables the production of white light emission through control of the blend ratio. The PL and EL emission spectra of the blend systems were found to vary with the blend ratio. The EL devices were fabricated in the ITO/PEDOT/blend/LiF/Al configuration and white light emission was obtained for one of the tested blend ratios.

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Characterization of Mixed Apple and Carrot Retentates Using Response Surface Methodology

  • Lee, Jun-Ho
    • Preventive Nutrition and Food Science
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    • v.11 no.2
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    • pp.155-159
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    • 2006
  • Models capable of predicting the product quality of mixed apple and carrot retentates (MACR) have been developed using response surface methodology and used to characterize the effects of processing conditions including average transmembrane pressure (ATP), temperature, and blend ratio. Color, soluble solids, total sugar, vitamin C, acidity, turbidity, and viscosity were used to assess the product quality following the ultrafiltration (UF) process. $L^*-value$ decreased with increased ATP, but the value was not affected by changes in temperature. Blend ratio also greatly influenced the $L^*-value$. Redness ($a^*-value$), on the other hand, was less affected by temperature and ATP. As the ATP and temperature increased, yellowness increased gradually. Soluble solids contents appeared to decrease gradually as the ATP increased for all blend samples, but the effect of temperature seemed to be less. Total sugar content was more affected by temperature than ATP. In general, samples containing 75% carrot had higher amounts of vitamin C regardless of processing conditions. Changes in acidity were also complex and appeared to respond to interactions among ATP, temperature, and blend ratio. Turbidity increased for all samples as both ATP and temperature increased. The higher the amount of carrot in the blend samples, the higher values for turbidity. Although the changes were small, viscosity appeared to increase as the ATP and temperature increased during UF.

A Study on Fabrication of Polyester Copolymers (Ⅵ) -Physical Properties of PET/PETG Copolymer Blend by the Drawing Conditions- (폴리에스테르 공중합체의 Fabrication 연구 (Ⅵ) -PET/PETG 공중합체 블렌드의 연신조건에 따른 물리적 특성-)

  • 현은재;이소화;김기영;제갈영순;장상희
    • Polymer(Korea)
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    • v.26 no.3
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    • pp.335-343
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    • 2002
  • Blend resin (PET/PETG 70/30 blend) of poly (ethylene terephthalate) (PET) and poly (ethylene terephthalate glycol) (PETG) of weight percent 70/30 was prepared by a twin-screw extruder. Undrawn films of the blend and pure PETG were made by melt-press in hot press. Drawn films were made by capillary rheometer. Crystallinity, shrinkage, thermal, dynamic mechanical, and mechanical properties of these blends and PETG drawn films were investigated by wide angle X-ray diffractometer, dry oven, DSC thermal analyzer, and tensile tester. The crystallinity and density of these films increased with increasing draw ratio and draw rate but decreased with increasing draw temperature. The crystallinity and density of the blend films were higher than those of PETG films. The tensile strength and tensile modulus of these drawn alms increased with increasing draw ratio and draw rate but decreased with increasing draw temperature. The tensile strength and tensile modulus of blend films were higher than those of PETG films. Shrinkage of PETG md blend films decreased with draw ratio and draw rate. Shrinkage of undrawn blend film was 600% higher than that of pure PET film.

Effect of Relative Levels of Mineral Admixtures on Strength of Concrete with Ternary Cement Blend

  • Mala, Kanchan;Mullick, A.K.;Jain, K.K.;Singh, P.K.
    • International Journal of Concrete Structures and Materials
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    • v.7 no.3
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    • pp.239-249
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    • 2013
  • In the present scenario to fulfill the demands of sustainable construction, concrete made with multi-blended cement system of OPC and different mineral admixtures, is the judicious choice for the construction industry. Silica fume (SF) and fly ash (FA) are the most commonly used mineral admixtures in ternary blend cement systems. Synergy between the contributions of both on the mechanical properties of the concrete is an important factor. This study reports the effect of replacement of OPC by fly ash (20, 30, 40 and 50 % replacement of OPC) and/or silica fume (7 and 10 %) on the mechanical properties of concrete like compressive strength and split tensile strength, with three different w/b ratio of 0.3, 0.4 and 0.45. The results indicate that, as the total replacement level of OPC in concrete using ternary blend of OPC + FA + SF increases, the strength with respect to control mix increases up to certain replacement level and thereafter decreases. If the cement content of control mixes at each w/b ratio is kept constant, then as w/b ratio decreases, higher percentage of OPC can be replaced with FA + SF to get 28 days strength comparable to the control mix. A new method was proposed to find the efficiency factor of SF and FA individually in ternary blend cement system, based on principle of modified Bolomey's equation for predicting compressive strength of concrete using binary blend cement system. Efficiency factor for SF and FA were always higher in ternary blend cement system than their respective binary blend cement system. Split tensile strength of concrete using binary and ternary cement system were higher than OPC for a given compressive strength level.

Technical Feasibility of Ethanol-Kerosene Blends for Farm Kerosene Engines (에타놀-석유(石油) 혼합연료(混合燃料)의 농용석유(農用石油)엔진에의 이용(利用)에 관(關)한 연구(硏究))

  • Bae, Yeong Hwan;Ryu, Kwan Hee
    • Journal of Biosystems Engineering
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    • v.7 no.1
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    • pp.53-61
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    • 1982
  • As an attempt to reduce the consumption of petroleum resources and to improve the performance of a kerosene engine, a series of experiments was conducted using several kinds of ethanol-kerosene blends under the various compression ratios. The engine used in this study was a single-cylinder, four-cycle kerosene engine having a compression ratio of 4.5. To investigate the feasibility of ethanol-kerosene blends in the original engine, kerosene and blends of 5-percent, 10-percent, and 20-percent-ethanol, by volume, with kerosene were used. And to investigate the feasibility of improving the performance of the kerosene engine, a portion of the cylinder head was cut off to increase the compression ratio up to 5.0 by reducing the combustion chamber volume. Kerosene and blends of 30-percent and 40-percent-ethanol, by volume, with kerosene were used for the modified engine with an increased compression ratio. Variable speed tests at wide-open throttle were also conducted at five speed levels in the range of 1000 to 2200 rpm for each compression ratio and fuel type. Volumetric efficiency, engine torque, and brake specific fuel consumption were determined, and brake thermal efficiency based on the lower heating values of kerosene and ethanol was calculated. The results obtained in the study are summarized as follows: A. Test with the original engine: (1) No abnormal conditions were found when burning ethanol-kerosene blends in the original engine. (2) Volumetric efficiency increased with ethanol concentration in blends. When burning blends of 5-percent, 10-percent, and 20-percent ethanol, by volume, with kerosene, average volumetric efficiency increased 1.6 percent, 2.6 percent, and 4.1 percent respectively, than when burning kerosene. (3) Mean engine torque increased 5.2 percent for 5-percent-ethanol blend, 9.3 percent for 10-percent-ethanol blend, and 11.5 percent for 20-percent-ethanol blend than for kerosene. Increase in engine torque when using ethanol-kerosene blends was due to the improved combustion characteristics of ethanol as well as an increase in volumetric efficiency. (4) Up to ethanol concentration of 20 percent, mean brake specific fuel consumption was nearly constant inspite of the difference in heating value between ethanol and kerosene. (5) Brake thermal efficiency increased 0.3 percent for 5-percent-ethanol blend, 3.8 percent for 10-percent-ethanol blend, and 6.8 percent for 20-percent-ethanol blend than for kerosene. B. Test with the modified engine with an increased compression ratio: (1) When burning kerosene, mean volumetric efficiency, engine torque, and brake thermal efficiency were somewhat lower than for the original engine. (2) Engine torque increased 15.1 percent for 30-percent-ethanol blend and 18.4 percent for 40-percent-ethanol blend than for kerosene. (3) There was no significant difference in brake specific fuel consumption regardless of ethanol concentration in blends. (4) Brake thermal efficiency increased 15.0 percent for 30-percent-ethanol blend and 19. 5 percent for 40-percent-ethanol blend than for kerosene.

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Fuel properties of biodiesel produced from beef-tallow and corn oil blends based on the variation in the fatty acid methyl ester composition

  • Woo, Duk Gam;Kim, Tae Han
    • Korean Journal of Agricultural Science
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    • v.46 no.4
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    • pp.941-953
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    • 2019
  • Biodiesels are being explored as a clean energy alternative to regular diesel, which causes pollution. In this study, the optimum conditions for producing biodiesel (BD) by combining beef tallow, an animal waste resource with a high saturated fatty acid content, and corn oil, a vegetable oil with a high unsaturated fatty acid content, were investigated, and the fuel properties were analyzed. Furthermore, Multivariate Analysis of Variance (MANOVA) was used to verify the optimum conditions for producing biodiesel. The influences of control factors, such as the oil blend ratio and methanol to oil molar ratio, on the fatty acid methyl ester and biodiesel production yield were investigated. As a result, the optimum condition for producing blended biodiesel was verified to be tallow to corn oil blend ratio of 7 : 3 (TACO7) and a methanol to oil molar ratio of 14 : 1. Moreover, the interaction between the oil blend ratio and the methanol to oil molar ratio has the most crucial effects on the production of oil blended biodiesel. In conclusion, the analysis results of the fuel properties of TACO7 BD satisfied the BD quality standard, and thus, the viability of BD blended with waste tallow as fuel was verified.

Gas Permeation Characteristics of PVC/PS Blend Laminated Membranes Prepared by Water Casting (PVC/PS 혼합 수면 전개 적층막의 기체투과 특성)

  • 남석태;최호상;김병식
    • Membrane Journal
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    • v.3 no.3
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    • pp.108-116
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    • 1993
  • In PVC/PS pelyblend laminated membranes, perrneabilities were increased as increasing the blend ratio of PS and selectivities were increased with increasing the blend ratio of PVC. The gas permeation mechanism was shifted from the combination of Poiseuille and Knudsen flow model to the solution-diffusion model as decreasing the PS blend ratio. The structure of polyblend laminated membranes showed series model, where PS rich phase was formed at air side and PVC rich phase was at water side. The model of permeation in the polyblend laminated membranes also showed series model structure.

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