• Title/Summary/Keyword: Bleaching

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A Study on the Bleaching and Dyeing Properties of Cotton Fabrics Treated with Ozone($O_{3}$) (Ozone($O_{3}$)을 이용한 선직물의 표백과 양색성에 관한 연구)

  • Cho, Hwan;Woo, Hyun-Seok;Jung, Hee-Chun
    • Textile Coloration and Finishing
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    • v.7 no.1
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    • pp.32-42
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    • 1995
  • In order to reduce the amount of waste water generated from textile dyeing process and processing water, cotton fabric was bleached with ozone in ozone/water contact system, and dyed. The results obtained from the measurement of whiteness, reflectance, tensile strength, color difference, and K/S value of treated samples were as follow : 1) In ozone bleaching, factors affect whiteness most are treatment time and ozone dosage. As treatment time is lengthened, whiteness increases. Futhermore, bleaching effect is high in acidic treatment, but low in alkaline treatment. 2) As bleaching goes on, maximum absorption wave length shifts to shoter wavelengths. 3) As treatment time is lengthened or pH of treatment is low, tensile strenth of treated fabric decrease. 4) In all cases, color difference of dyed cotton fabrics in above 2% o.w.f. dyestuff concentration don't go beyond 1∼2 AN unit, compared with standard.

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Photodarkening and Thermal Bleaching Effect in Ge-doped Multicomponent Oxide Glasses by UV Irradiation (자외선 조사에 따른 게르마늄 함유 다성분계 산화물 유리의 광흑화와 열표백화 현상)

  • 이회관;오영석;강원호
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.3 no.3
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    • pp.161-165
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    • 2002
  • Ge-doped rnulticomponent oxide glasses were prepared by a conventional melting method. The change of micro structure in glasses was investigated by using PL (photoluminescence) and ESR (electron spin resonance). Before UV irradiation, the PL intensity increased according to germanium contents, but decreased the intensity as soon as UV irradiation. A changed property was recovered near it original properties when it was annealed. These photodarkening and thermal bleaching effect were observed by ESR intrument. These effect did not change the glass phase but vary only change of micro structure.

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Influences of Temperature and Light on the Herbicidal Activity of Bleaching Herbicides (Bleaching Herbicides의 제초활성에 영향을 미치는 온도 및 광의 영향)

  • Kim, J.S.;Na, J.Y.;Cho, K.Y.
    • Korean Journal of Weed Science
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    • v.9 no.3
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    • pp.230-237
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    • 1989
  • This research was carried out to investigate the influences of temperature and light on the herbicidal activity of oxyfluorfen, oxadiazon and paraquat. Increased temperature from 10 to $35^{\circ}C$ resulted in increase of herbicidal activity in whole plants or leaf discs treated with herbicides. It seemed that temperature affected herbicide penetration into and reaction to the action site rather than appearance process of herbicidal activity (maybe membrane peroxidation after being absorbed. The activity of compounds tested increased with increased light intensity. Paraquat showed similar activities regardless of light qualities but oxyfluorfen and oxadiazon showed the highest activities in blue light spectrum, indicating that they seemed to be closely related to chlorophyll biosynthesis rather than carotenoid biosynthesis or electron transport systems of photosynthesis and respiration.

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Quality Improvement of Rayon Grade Bamboo Pulp by Modified Bleaching

  • Tripathi, Sandeep;Mishra, Om Prakash;Sharma, Nirmal;Chakrabarti, Swapan Kumar;Varadhan, Raghavan
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.2
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    • pp.1-8
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    • 2011
  • The presence of high silica in bamboo hinders the use of this material for production of rayon grade pulp. Research has been carried out to overcome this deficiency and improve quality of rayon grade pulp with the modification in pulping and bleaching process. Effect of acid boosted water prehydrolysis, sulphuric acid pre-treatment of unbleached pulp, chlorination stage at lower pH and treatment of bleached pulp with $SO_2$ water were evaluated. Acid boosted water prehydrolysis of chips reduces prehydrolysis time by 50 minutes as compared to water prehydrolysis. Treatment of unbleached pulp with sulphuric acid reduces ash, acid insoluble, silica, calcium and iron contents of the pulp by 56, 31, 82, 84 and 60% respectively. The addition of acid, increase in kappa factor in $C_D$ stage and combination of both were effective in removing silica in the pulp. Treatment of final bleached pulp with $SO_2$ water removes silica to a great extent and improves optical properties of the pulp as compared to $H_2SO_4$ or PAA. Pretreatment of the pulp with acid and modification in the bleaching process can reduce silica substantially and improve the quality of rayon grade bamboo pulp.

Effect of various bleaching treatments on shear bond strength of different universal adhesives and application modes

  • Oz, Fatma Dilsad;Kutuk, Zeynep Bilge
    • Restorative Dentistry and Endodontics
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    • v.43 no.2
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    • pp.20.1-20.9
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    • 2018
  • Objectives: The aim of this in vitro study was to evaluate the bond strength of 2 universal adhesives used in different application modes to bleached enamel. Materials and Methods: Extracted 160 sound human incisors were used for the study. Teeth were divided into 4 treatment groups: No treatment, 35% hydrogen peroxide, 16% carbamid peroxide, 7.5% carbamid peroxide. After bleaching treatments, groups were divided into subgroups according to the adhesive systems used and application modes (n = 10): 1) Single Bond Universal, etch and rinse mode; 2) Single Bond Universal, self-etch mode; 3) Gluma Universal, etch and rinse mode; 4) Gluma Universal, self-etch mode. After adhesive procedures nanohybrid composite resin cylinders were bonded to the enamel surfaces. All specimens were subjected to shear bond strength (SBS) test after thermocycling. Data were analyzed using a 3-way analysis of variance (ANOVA) and Tukey post hoc test. Results: No significant difference were found among bleaching groups (35% hydrogen peroxide, 16% carbamid peroxide, 7.5% carbamid peroxide, and no treatment groups) in the mean SBS values. There was also no difference in SBS values between Single Bond Universal and Gluma Universal at same application modes, whereas self-etch mode showed significantly lower SBS values than etch and rinse mode (p < 0.05). Conclusions: The bonding performance of the universal adhesives was enhanced with the etch and rinse mode application to bleached enamel and non-bleached enamel.

Elemental Chlorine Free Bleaching of Kraft Pulps with Enzymes(II) -Pinewood Kraft Pulp- (효소를 이용한 크라프트펄프의 무감소표백(제2보) -소나무 크라프트펄프-)

  • 강진하;박성종;정인수
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.3
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    • pp.84-96
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    • 1998
  • This study was carried out to bleach the Pinewood kraft pulp without the elemental chlorine using the xylanase or wastewater(We:wastewater enzymes) effluented from the submerged biofilter reactor containing the fungi, Phanerochaete sordida YK-624. So in this research, the proper treatment conditions(pH, temperature, dosage and time) were investigated respectively. And after the various kinds of multistage bleaching of pulps, the properties of pulps were tested. From the experimental results, we can conclude as follows. In the treatments of Pinewood kraft pulps with xylanase, the proper pH, temperature, enzyme dosage and time were 8.0, $35^{\circ}C, 400EXU/kg and 3 hr. respectively. And in the case of treatment with a wastewater(We) effluented from the submerged biofilter reactor, the proper pH, temperature and time were 5.0, $37^{\circ}C and 3 hr. respectively. On the other hand, Pinewood kraft pulps were bleached by the method of a multistage bleaching using xylanase or We instead of elemental chlorine. Consequently, the strengthes and brightnesses of pulps bleached by the method mentioned above were lower than those of pulp bleached by the conventional method using the elemental chlorine. But it is possible to improve the brightnesses through the increase of chlorine dioxide dosage or use of hydrogen peroxide in the final bleaching stage.

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Use of Additive in Peroxide Bleaching with Unbleached Kraft Pulp (크라프크 펄프 표백의 과산화수소 표백시 첨가제의 이용)

  • 김용식;김세종;윤병호
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.1
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    • pp.78-85
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    • 2000
  • Due to environmental proessures there is increasing use of hydrogen peroxide as a total or partial substitute for chlorine based bleaching agents within ECF or TCF sequences. However, to aceive satifactory brightness using peroxide alone, stages having a combination of high temperature, pressure, pH or residence time are required. It may also have negative impact on fiber quality . Therefore, it would be of advantage if vertain means could be found to make hydrogen peroxide more effective in bleacing , via shortening treaction time and allevaiating the need for such forcing reaction conditions. This can be achieve by converting the peroxide in-situ to stronger oxidant through the use of 손 bleach activator. In this study to investigate the influence of additives, such as tetraacetylethylenediamine (TAED) and Molybdate (MO) . addition on peroxide bleaching were carried out. Under alkaline conditions the bleching additives. TAED and Mo. can react H2O2 to form peracetic acid and peroxomolybdate respectively and these generated activators can improve deliginification,. The activators make it possible to bleach the pulp efficiently at low temperature in the range 50 to 7$0^{\circ}C$. Also, addition of TAED and Mo is an environmentally friendly way of enhancing the performance of peroxide bleaching can be incorporated into TCF and ECF sequences.

The effect of fluoride and casein phosphopeptide-amorphous calcium phosphate (CPP-ACP) pplication on the color and microhardness of bleached enamel (치아미백 후 불소와 CPP-ACP 처리가 치아의 색과 미세경도에 미치는 영향)

  • Shim, Youn-Soo;Choi, Woo-Yang
    • Journal of Korean society of Dental Hygiene
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    • v.10 no.3
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    • pp.473-481
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    • 2010
  • Objectives : To evaluate the effect of fluoride application on the color and microhardness of bleached enamel and compare it to that of casein phosphopeptide-amorphous calcium phosphate (CPP-ACP) application. Methods : Twenty freshly extracted human adult molar were each sectioned into halves, the specimens divided and treated according to five experimental groups: Group 1, treatment with 10% carbamide peroxide (CP) bleaching agent; Group 2, treatment with 10% CP followed by a 1.23% fluoride gel application; Group 3, treatment with 10% CP followed by a 2.23% sodium fluoride varnish application; Group 4, treatment with 10% CP followed by a 0.11% sodium fluoride gel application; Group 5, treatment with 10% CP followed by a CPP-ACP gel application. All groups were treated 6 h per day for 14 days then immersed in distilled water for 2 weeks. Changes in enamel color were evaluated on Baseline and Day 14. Microhardness were evaluated on Baseline, Days 7 and 14. Statistical analysis was performed using one-way ANOVA and post-hoc Tukey tests. Results : All the bleached enamel specimens revealed increased whiteness and overall color value. Group 1 showed the lowest microhardness values than that of Groups 2, 3, 4 and 5. In all groups, the hardness of tooth after bleaching showed a significant decrease in the microhardness as compared with the one prior to tooth bleaching. The specimens treated with remineralizing agents showed relatively less reduction in enamel microhardness than control group. Conclusions : The addition of fluoride and CPP-ACP did not impede the whitening effect. The use of remineralizing agents during bleaching treatment can significantly enhance the microhardness of bleached enamel.

The Effect of Hydrogen Peroxide Bleaching on the Properties of Unbleached Hardwood Kraft Pulp Adsorbed with Birchwood Xylan

  • Li, Lizi;Lee, Sang-Hoon;Lee, Hak-Lae;Youn, Hye-Jung
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2011.04a
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    • pp.169-169
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    • 2011
  • Xylans are polysaccharides present in large amounts in cell walls of land plants. However, during kraft cooking, a high portion of hemicelluloses including xylans are dissolved in the cooking liquor. In the current trend for a more effective utilization of biomass, attention has been paid to the exploitation of xylans as strength-enhancing additives for paper. It is believed that surface xylan adds flexibility to the cell wall/fiber surface, resulting in stronger fiber-fiber joints or greater contact area between the fibers. Accordingly, there is proposal for a new pulping process involving the extraction of xylan prior to pulping, followed by their re-adsorption on the unbleached pulp. A suitable bleaching process should be employed then, which ought to does not only improve the brightness of the pulp, but also remain the effect of the adsorption of xylan on pulp fibers. The objective of this research was to investigate the impact of hydrogen peroxide bleaching on the properties of unbleached hardwood kraft pulp pretreated with birchwood xylan by measuring optical properties (brightness, post color number, opacity) as well as physical properties (tensile index, tearing index, bulk) of handsheets made from the bleached pulp. In the meantime, the influence of process variables of peroxide bleaching including bleaching temperature, time, initial pH and $MgSO_4$ dosage were studied.

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A CLINICAL EVALUATION OF SAFETY OF AN OFFICE BLEACHING GEL CONTAINING 30% HYDROGEN PEROXIDE (30% 과산화수소를 함유한 전문가 미백제의 안전성 평가)

  • Kim, Sin-Young;Park, Je-Uk;Kim, Chang-Hyen;Yang, Sung-Eun
    • Restorative Dentistry and Endodontics
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    • v.35 no.3
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    • pp.198-210
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    • 2010
  • This study evaluated the safety of an office bleaching gel (RemeWhite, Remedent Inc., Deurle, Belgium) containing 30% hydrogen peroxide. 37 volunteers were received office bleaching with the RemeWhite for 3 times at one visit, total 2 visits. As control group, the same gel in which hydrogen peroxide was not included was applied to 34 volunteers with the same protocol. There was no difference between experimental group and control group using electric pulp test. In the result of gingival inflammation index and tooth sensitivity test, there was mild pain response in experimental group but it disappeared as time went by. Therefore, safety of the office bleaching gel containing 30% hydrogen peroxide was confirmed.