• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.3
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• pp.102-109
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• 2011

In this study, in order to develop ultra rapid hardening mortar(URHM) for tunnel repairs using bottom ash of low recycle ratio and Admixture as Eco concept, watertightness and durability properties of URHM on temperature condition of construction field were performed. Test result, seepage quantity and water absorption coefficient regarding watertightness of URHM were as in the following : series II > series I. Seepage quantity for the standard condition were smaller than low temperatures. all specimens were satisfied below 20g as standards of seepage quantity on KS F 4042. Because of the decrease of unit cement content by to replacement of blast furnace slag, the neutrlization resistance for durability properties was reduced. The result of alkali resistance and acide resistance, compressive strengths for specimens soaked in calcium hydroxide solution of seriesI were lower than compressive strengths for specimens not soaked. On the other hand, the case of series II show that the deterioration of compressive strengths for specimens was not almost showed. Compressive strengths of specimens soaked were similar with specimens not soaked except series II-C in $5^{\circ}C$. Therefore, specimens using both blast furnace slag and bottom ash were good in alkali resistance and acide resistance.

• Journal of the Korea Concrete Institute
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• v.28 no.5
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• pp.593-600
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• 2016

The paper presented investigates the effects of kaolinite on strength properties of alkali-activated multi-component cement. The binders of this study was blended of ground granulated blast furnace slag (GGBFS), fly ash (FA), silica fume (SF) and kaolinite (KA). In this study, the specimens of combination of 20%~70% GGBFS, 10%~60% FA, 10% SF (constant ratio) and 10%~50% KA binder were used for strength properties tests. The water/binder ratio was 0.5. The binders (GGBFS + FA + SF + KA) was activated by sodium hydroxide (NaOH) and sodium silicate ($Na_2SiO_3$) was 10% by total binder weight (10% NaOH + 10% $Na_2SiO_3$). The research carried out is on the compressive strength, water absorption, ultrasonic pulse velocity (UPV) and X-ray diffraction (XRD). The compressive strength decreased as the contents of KA increase. One of the major reason for this is the low reactivity of KA compared with other raw materials used as precursors such as GGBFS or FA. The presence of remaining KA indicates that the initially used quantity has not fully reacted during hydration. Moreover, the results have indicated that increased of KA contents decreased UPV under all experimental conditions. The drying shrinkage and water absorption increased as the content of KA increase. Test result clearly showed that the strength development of multi-component blended cement were significantly dependent on the content of KA and GGBFS.

• Journal of the Korea Concrete Institute
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• v.17 no.3 s.87
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• pp.455-464
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• 2005

Today the application of antiwashout underwater concrete to the construction sites is increasing steadily, while its reliability is in issue. Particularly, antiwashout underwater concrete is known to have very weak durability on frost attack, and hence Japan society of civil engineers(JSCE) regulated that not to use of antiwashout underwater concrete where the freezing and thawing is suspected. This study aims the improvement of the freezing and thawing resistance for antiwashout underwater concrete. From the results of fundamental test, FA20 and SG50 showed good performance in fluidity and long term compressive strength than control concrete. Meanwhile, MK10 marked the highest compressive strength through the whole curing age but a defect on fluidity was discovered. The results from the repeated freezing and thawing test show that the large volumes of air entrapped by cellulose based antiwashout underwater admixture gave bad effects to frost durability and hence not much benefits were confirmed from the use of mineral admixtures. However there were some increasing effects on frost durability of MK10 and SG50 by securing $6{\pm}0.5\%$ of entraining air. In the meantime, there was a increasing tendency of frost durability by increasing blame's fineness of ground granulated blast furnace slag.

• Journal of the Korea Concrete Institute
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• v.27 no.3
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• pp.237-244
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• 2015

Entering the 20th century since the industrial revolution, the cement has been widely used in the field of construction and civil engineering due to the remarkable development of construction industry. However, result from that development, each kind of industrial by-products and waste and the carbon dioxide generated in the process of cement production cause air pollution and environmental damage so earth is getting sick now slowly. Therefore, we have to recognize importance about this. It means that the time taking specific and long-term measures have come. In this research paper, as substitution of the cement generating environmental pollution, we investigate the hydration reaction of non-Sintered Cement mortar mixed with GBFS, active stimulant of alkaline and sulphate series by using SEM and XRD, mechanical and chemical properties according to the curing method. As a result of this experiment, NSC realized outstanding strength for water curing and steam curing. It means that it has a good possibility as substitution of cement. From now on, it can be used for structure satisfying specific standard. We expect to find a substitution of outstanding cement by progressing continuous research making the best use of pros and cons according to the curing method.

• Journal of the Korea Concrete Institute
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• v.28 no.3
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• pp.299-308
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• 2016

This paper presents an investigation of the mechanical and microstructural properties on hardened samples that were synthesized using blended binder(fly ash(FA) and blast furnace slag cement(BFSC)), alkali activator and sea water or distilled water. Binders were prepared by mixing the FA and BFSC in different blend weight ratios of 6:4, 7:3 and 8:2. Sodium hydroxide and sodium silicate were used 5 wt% of binder, respectively, as an alkaline activator. The compressive strength and absorption were measured at the age of 3, 7 and 28 days, and the XRD, TGA and MIP tests were performed at the age of 28 days. An increase in the content of BFSC leads to an increase in the quantities of ettringite and C-S-H formed, regardless of the type of mixing water. And it also shows higher strength due to the reduction of pores larger than ~50 nm. All hardened samples in this study have common hydration products of C-S-H, $Ca(OH)_2$ and calcite. Hydrocalumite of all reaction products formed was only present in hardened sample mixed with sea water. For each FA/BFSC mixing ratio, the compressive strength of hardened sample mixed with sea water was similar to that mixed with distilled water. It is proposed that the slight increase of strength of samples mixed with sea water is mainly due to the presence of hydrocalumite phase containing chlorine ion, contributing to the change of total porosity and pore size distribution in samples.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.1
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• pp.64-71
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• 2015

Silica fume is generally adopted as admixture for Ultra High Strength Concrete (UHSC) owing to its remarkable contribution to the strength and durability but increases significantly the fabrication cost of UHSC. Accordingly, this study investigates the replacement of silica fume by blast furnace slag (BS) and fly ash (FA) in order to lower the fabrication cost of 80MPa-UHSC. To that goal, experiment is conducted on the mix proportions of mortar in terms of its binder combination, water-to-binder ratio (W/B) and unit binder content. Based on the experimental data, a mix design of concrete is derived and its properties are verified. The results reveal that a W/B of 21% and unit binder content of $720kg/m^3$ are appropriate to achieve 80MPa-UHSC using a binder composed of 60% of OPC, 30% of BS and 10% of FA. The properties of the corresponding UHSC are seen to be satisfactory with a slump flow of 715mm and compressive strength of 97MPa at 28days. The application of the binder combination derived in this study is analyzed to reduce the cost by 50% of binder compared to the mix using silica fume while realizing equivalent performance.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.1
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• pp.50-57
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• 2015

Portland cement production is under critical review due to high amount of $CO_2$ gas released to the atmosphere. Attempts to increase the utilization of a by-products such as fly ash and ground granulated blast-furnace slag to partially replace the cement in concrete are gathering momentum. Many researchs on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. Instead, the sources of material such as fly ash, that are rich in Silicon(Si) and Aluminium(Al), are activated by alkaline liquids to produce the binder. Hence concrete with no cement is effect reduction of $CO_2$ gas. In this study, we investigated the influence of the fluidity, air content and compressive strength of mortar on alkaline activator in order to develop cementless fly ash and ground granulated blast-furnace slag based alkali-activated mortar with superplasticizer. In view of the results, we found out that Pn of fluidity and compressive strength is the best in four type of superplasticizer, and PNS of powder type of fluidity is better than that of liquid type in the case of AA.

• Journal of the Korean Recycled Construction Resources Institute
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• v.3 no.1
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• pp.1-6
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• 2015

Recently, lots of researches on concrete with high volume mineral admixture such as ground granulated blast furnace slag (GGBFS) have been carried out to reduce $CO_2$. It is known that the precast concrete has an advantage of high strength at early age due to steam curing, even if concrete has high replacement level of mineral admixture. However it demands the investigation of compressive strength properties according to steam curing regimens. In this study, concretes with water-binder ratio of 32, 35% and water content of 135, 150, $165kg/m^3$ were produced to investigate compressive strength properties of high volume (60% by mass) GGBFS cement concrete according to steam curing regimens. Then steam curing was implemented with the maximum temperature of 50, $60^{\circ}C$ and steaming time of 5, 6, 7 hours. From the test results, it was found that steam curing was effective to raise early strength of high volume GGBFS cement concrete, but 28 day compressive strengths of steam cured specimens were lower than those of water cured specimens. Thus, a further study would be needed for the optimum steam curing regimens to satisfy target demolded strength and specified strength for the application of high volume GGBFS cement concrete to precast concrete members.

• Journal of the Korea institute for structural maintenance and inspection
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• v.19 no.1
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• pp.90-99
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• 2015

This study examined dynamic and characteristics and chloride penetration of concrete mixed with large amount of FA and BFS, which are considered for positive application to construction fields with purpose of long-tern durability of concrete structures. As a result of strength test on FA and BFS, FA concrete showed higher increase of strength compared to OPC, when FA4000 and FA5000 were mixed 30%, respectively. For BFS concrete, those mixed with 30% and 50% of BFS8000, respectively, showed higher or equivalent strength compare to OPC. As a result of test of chloride penetration on FA and BFS, diffusion coefficients of concrete mixed with 30% FA4000 and FA5000, respectively, showed to restrain average 6.5% of diffusion coefficient compared to OPC. And in case of BFS concrete, those mixed with BFS6000 and BFS8000, restrained diffusion of chloride ions 253% and 336%, respectively, compared to OPC. Therefore, Mixing 50% of BFS was most efficient in order to maximize restraint of chloride penetration according to metathesis of large amount. For relation between compression strength and diffusion coefficient of FA and BFS concrete, as strength increased, diffusion coefficient decreased. In this study, when mixing FA and BFS to concrete for long-run durability and restraint against chloride penetration, for FA, mixing it to concrete with less or equivalent 30% of replacement rate was most efficient. And for BFS, as fineness was higher and mixing it to concrete with less or equivalent 50% of replacement rate, there were results of higher strength compared to OPC and more efficient restraint of chloride ions.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.1
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• pp.74-80
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• 2009

This study analysis the fundamental properties of temperature-dependence corresponding the change of curing temperature classified by the replacement ratio of BS, and the results are summarized as following. As the properties of flow, plain satisfied with the target slump, and as the replacement ratio of BS increased, the flow increased, but the air content slightly decreased. The time of set delayed as the replacement ratio of BS increased, but the curing temperature $35^{\circ}C$, even with 80% BS replaced concrete, the time of set was faster than $5^{\circ}C$, $20^{\circ}C$ plain, so the temperature-dependence was much greater. The compressive strength was decreased as the replacement ratio of BS increased, especially as the curing temperature lower, the compressive strength was lower comparatively. Also as the age increased, the plain developed more strength, therefore it show the temperature-dependence is much larger.