• 제목/요약/키워드: Bisphenol A

검색결과 609건 처리시간 0.065초

환경조건에 따른 팽창성 혼화재 및 비스페놀 F형 에폭시수지 병용 모르타르의 자기치유 검토 (Self-Healing Investigation of Bisphenol F-Type Epoxy-Modified Mortars with Expansive Admixtures Under Outdoor Exposure Conditions)

  • 박승민;김완기
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 춘계 학술논문 발표대회
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    • pp.22-23
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    • 2017
  • The purpose of this study is to ascertain self-healing function on microcracks in bisphenol F-type epoxy-modified mortars using expansive admixtures. The specimens are prepared with various polymer-binder ratios of 0, 5, 10, 20%, expansive admixture contents of 0% and 10%, a sodium carbonate content of 0.25%, and subjected to exposure conditions of CR1, CR2, CR3 and CR4. The specimens are tested for self-healing effect, porosity and FE-SEM analysis. As a result, self-healing effects of bisphenol F-type EPMMs with expansive admixtures are visible in all of the outdoor exposure conditions. In particular, exposure conditions of CR3 and CR4 are most noticeable. And the porosity of EPMMs is reduced with an increase in the polymer-binder ratio, and is considerably smaller than that of unmodified mortar.

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액상봉지재용 Diglycidyl Ether of Bisphenol F/Nadic Methyl Anhydride 수치 시스템의 경화 및 유변학적 거동 (The Cure and Rheological Behavior of Diglycidyl Ether of Bisphenol F /Nadic Methyl Anhydride Resin System for Liquid Encapsulant)

  • 김윤진;김창제;윤호규
    • 한국마이크로전자및패키징학회:학술대회논문집
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    • 한국마이크로전자및패키징학회 2002년도 춘계 기술심포지움 논문집
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    • pp.152-157
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    • 2002
  • The cure and rheological behavior of Diglycidyl ether of bisphenol F, catalyzed by four kinds of imidazoles and a Nadic methyl anhydride curing agent were studied using a differential scanning calorimeter (DSC) and rheometer. The isothermal traces were employed to analyze cure reaction. The DGEBF/anhydride conversion profiles showed autocatalyzed reaction characterized by maximum conversion rate at 20~40 % of the reaction. The rate constants obtained from isothermal test showed temperature dependance, but reaction order did not. The order of reaction (m+n) was calculated to be close to 3. The measurements of viscosity and relation time in the presence of inorganic fillers were carried out at different isothermal curing temperatures. The viscosity and gelation time increased with filler content at the same isothermal temperature.

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캔 제품의 bisphenol A diglycidyl ether (BADGE), bisphenol F diglycidyl ether (BFDGE) 유도체 및 분해산물 분석법 (Determination of the Levels of Bisphenol A Diglycidyl Ether (BADGE), Bisphenol F Diglycidyl Ether (BFDGE) and Their Reaction Products in Canned Foods Circulated at Korean Markets)

  • 김희연;이진숙;조민자;양지연;백지윤;정소영;최선희;김영선;최재천
    • 한국식품과학회지
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    • 제42권1호
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    • pp.8-13
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    • 2010
  • 캔제품 중 Biphenol A diglycidyl ether(BADGE), bisphenol F diglycidyl ether(BFDGE) 및 그 분해산물인 BADGE $H_2O$, BADGE $2H_2O$, BADGE HCl, BADGE 2HCl, BADGE HCl $H_2O$, BFDGE $H_2O$, BFDGE $2H_2O$, BFDGE HCl, BFDGE 2HCl, BFDGE HCl $H_2O$ 등의 HPLC/FLD와 HPLC/APCI-MS에 의한 정성 및 정량방법을 확립하고 133개 캔 제품을 사용하여 분석방법의 재현성을 검토하였다. 수용성 식품의 경우 BADGE $2H_2O$가 13개 제품에서 0.400-0.888 mg/kg, BADGE HCl $H_2O$가 1개 제품에서 0.566 mg/kg, BFDGE $H_2O$가 3개 제품에서 0.489-0.664 mg/kg, BFDGE $2H_2O$가 3개 제품에서 0.455-0.846 mg/kg, BFDGE HCl $H_2O$가 2개 제품에서 0.455-0.752 mg/kg의 농도로 검출되었다. 지용성 식품의 경우에는 BADGE가 3개 제품에서 0.093-0.486 mg/kg, BADGE $H_2O$가 1개 제품에서 0.183 mg/kg, BADGE HCl이 1개 제품에서 0.097 mg/kg, BADGE 2HCl이 7개 제품에서 0.200-0.452 mg/kg, BFDGE가 3개 제품에서 0.438-0.506 mg/kg, BFDGE $2H_2O$가 1개 제품에서 0.295 mg/kg, BFDGE HCl 및 BFDGE 2HCl이 1개 제품에서 0.324 mg/kg의 농도로 검출되었다. 분석방법의 재현성은 우수하였고, 모니터링 결과는 EU 수준과 유사하거나 안전한 수준으로 나타났다.

Down-regulation of inducible nitric oxide synthase and tumor necrosis factor-a expression by Bisphenol A via nuclear factor-kB inactivation in macrophages

  • Kim, Ji-Young;Jeong, Hye-Gwang
    • 대한약학회:학술대회논문집
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    • 대한약학회 2002년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2
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    • pp.293.2-293.2
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    • 2002
  • Bisphenol A [BPA. 2.2-bis(4-hydroxyphenyl)propane] is reported to have estrogenic activity: however. its influence on cytokine production or immune system function remains unclear. In this study. we investigated the effects of BPA on the production of nitric oxide (NO) and tumor necrosis factor-a (TNF-a), and on the level of inducible nitric oxide synthase (iNOS) and TNF-a gene expression in mouse macrophages. BPA alone did not affect NO or TNF-a production. (omitted)

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Bisphenol A-induced overall immune downregulation in mice

  • Byun, Jung-A;Pyo, Myoung-Yun
    • 대한약학회:학술대회논문집
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    • 대한약학회 2003년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.1
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    • pp.118.2-119
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    • 2003
  • This study was undertaken to assess overall effects of bisphenol A, a monomer widely used in manufacturing polycarbonate plastics or epoxy resin, exposure on immune system of mice. For in vitro evaluation, serial concentration of SPA was added into culture of various immune cells from normal female ICR mice, and for in vivo or ex vivo assessment, mice were orally exposed to BPA dissolved in olive oil as doses of 500, 1000, 2000 mg/g b.w. for acute expose or 100, 500, 1000 mg/kg/day b.w. 5days a week for subacute exposure. (omitted)

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Dertermination of Alkylphenols, Chlorophenols and Bisphenol A in Various Samples by Freezing Filtration and GC/MS-SIM

  • Kim, Hyub
    • 대한약학회:학술대회논문집
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    • 대한약학회 2003년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2-2
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    • pp.68.1-68.1
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    • 2003
  • A method for determination 11 endocrine disrupting chemicals of phenols in various samples was deloped. The alkylphenols, chlorophenols and bisphenol A were determined by gas chromatography/mass spectrometry-selected ion monitoring (GC/MS-SIM) followed by two work-up methods for comparison; isobutoxycarbonyl (isoBOC) derivatization method and tert-butyldimethylsilyl (TBDMS) derivatization method. Eleven endocrine disrupting chemicals (EDCs) of phenols in biological samples were extracted with acetonitrile and then acetonitrile layer was refrigerated at -60$^{\circ}C$ for 2 hours (freezing filtration). (omitted)

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에스트로겐성 환경화학물질이 zebrafish 발생 단계에 미치는 영향

  • 여민경
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2004년도 봄 학술발표회 발표논문집
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    • pp.261-262
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    • 2004
  • Bisphenol A와 nonylphenol 의 영향이 나타나지 않는다고 알려진 우리나라 자연상 검출 되는 농도보다 낮은 농도에서 에스트로겐 수용체와 결합하는 반응이 나타나는지에 대한 최저농도를 인간세포주 U2OSER$\beta$를 이용하여 조사하였다 조사된 농도 중 bisphenol A와 nonylphenol 의 자연상 검출농도(10000 ng/l)와 자연상 검출되는 농도이하(1000 ng/l) 에서의 zebrafish발생단계에 관한 영향을 관찰한 결과 농도의 차이에 따른 관련성보다는 발생의 특정시기에 노출된 시점에 따라 차이가 나타났다.

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