• 제목/요약/키워드: Biopolymers

검색결과 130건 처리시간 0.023초

Geotechnical behavior of a beta-1,3/1,6-glucan biopolymer-treated residual soil

  • Chang, Ilhan;Cho, Gye-Chun
    • Geomechanics and Engineering
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    • 제7권6호
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    • pp.633-647
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    • 2014
  • Biopolymers, polymers produced by living organisms, are used in various fields (e.g., medical, food, cosmetic, medicine) due to their beneficial properties. Recently, biopolymers have been used for control of soil erosion, stabilization of aggregate, and to enhance drilling. However, the inter-particle behavior of such polymers on soil behavior are poorly understood. In this study, an artificial biopolymer (${\beta}$-1,3/1,6-glucan) was used as an engineered soil additive for Korean residual soil (i.e., hwangtoh). The geotechnical behavior of the Korean residual soil, after treatment with ${\beta}$-1,3/1,6-glucan, were measured through a series of laboratory approaches and then analyzed. As the biopolymer content in soil increased, so did its compactibility, Atterberg limits, plasticity index, swelling index, and shear modulus. However, the treatment had no effect on the compressional stiffness of the residual soil, and the polymer induced bio-clogging of the soil's pore spaces while resulting in a decrease in hydraulic conductivity.

생체고분자의 팽윤현상연구를 위한 핵자기공명 현미영상법의 응용 (Application of NMR Microscopy for the Study of the Swelling Effect in Biopolymers)

  • 이동훈;김승수
    • 대한의용생체공학회:의공학회지
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    • 제18권2호
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    • pp.167-172
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    • 1997
  • Novel measurement method has been performed for the noninvasive study of the swelling effect detected in hydrophilic polymers using Magnetic Resonance Microscopy. iN NMR images were acquired to measure geometric changes due to the swelling effect occurred in the polymer specimens. In addition to the geometric changes, the water ingress process was visualized noninvgsively. The measurement method performed .in the present study utilized some of NMR's valuable properties, both noninvasiveness and parameter selectivity. It is believed that the method used in the present study may be applicable to the study of biopolymers in which noninvasiveness is particularly important.

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TGase 첨가 바이오폴리머의 침식특성 연구 (Erosion Characteristics of TGase-added Biopolymers)

  • 김강현;김승현;김도희;신종호
    • 한국지반환경공학회 논문집
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    • 제24권9호
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    • pp.5-13
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    • 2023
  • 대표적 사면 보강재료인 시멘트 계열의 보강재는 지반주입 또는 지표 도포 시 지반 및 지하수의 오염이 발생할 수 있다. 이에 따라 친환경 바이오폴리머를 사용한 사면 보강재료가 기존의 재료를 대체할 수단으로 관심받고 있으나, 현재 사용되고 있는 바이오폴리머는 지하수 또는 강우 환경에 노출되면 쉽게 용해되어 강도가 감소되는 문제가 있다. 이러한 문제를 해결하기 위하여 본 연구에서는 카제인나트륨과 Transglutaminase(TGase, C20H16N4O2S2)의 단백질 교차결합을 이용하여 바이오폴리머의 내수성을 증가시켰으며, 사면 보강재료로서 사용성과 적용성을 평가하기 위해 강우사면시험을 수행하였다. 카제인나트륨만으로 보강한 경우 강우로 인해 카제인나트륨이 용해되어 1시간 만에 사면이 완전히 파괴되었다. 반면 TGase를 소량(0.5%) 첨가하여 보강한 사면은 내수성이 증가하여 강우 지속시간 80시간이 지나도 붕괴되지 않음을 관찰하였다. TGase 소량 첨가로 인한 강도 및 내수성 증가가 나타났으며, 친환경 보강재로서의 적용성을 확인하였다.

Preparation of a Porous Chitosan/Fibroin-Hydroxyapatite Composite Matrix for Tissue Engineering

  • Kim, Hong-Sung;Kim, Jong-Tae;Jung, Young-Jin;Ryu, Su-Chak;Son, Hong-Joo;Kim, Yong-Gyun
    • Macromolecular Research
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    • 제15권1호
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    • pp.65-73
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    • 2007
  • Chitosan, fibroin, and hydroxyapatite are natural biopolymers and bioceramics that are biocompatible, biodegradable, and resorb able for biomedical applications. The highly porous, chitosan-based, bioceramic hybrid composite, chitosanlfibroin-hydroxyapatite composite, was prepared by a novel method using thermally induced phase separation. The composite had a porosity of more than 94% and exhibited two continuous and different morphologies: an irregularly isotropic pore structure on the surface and a regularly anisotropic multilayered structure in the interior. In addition, the composite was composed of an interconnected open pore structure with a pore size below a few hundred microns. The chemical composition, pore morphology, microstructure, fluid absorptivity, protein permeability, and mechanical strength were investigated according to the composition rate of bioceramics to biopolymers for use in tissue engineering. The incorporation of hydroxyapatite improved the fluid absorptivity, protein permeability, and tenacity of the composite while maintaining high porosity and a suitable microstructure.

Hypoglycemic Effects of Exo-biopolymers Produced by Five Different Medicinal Mushrooms in STZ-induced Diabetic Rats

  • Yang, Byung-Keun;Kim, Guk-Nam;Jeong, Yong-Tae;Jeong, Hun;Mehta, Pradeep;Song, Chi-Hyun
    • Mycobiology
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    • 제36권1호
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    • pp.45-49
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    • 2008
  • Hypoglycemic effects of exo-biopolymers (EBP) produced by submerged mycelial cultures of Coriolus versicolor, Cordyceps sinensis, Paecilomyces japonica, Armillariella mellea, and Fomes fomentarius were investigated in streptozotocin (STZ)-induced diabetic rats. The rats from each experimental group were orally administered with EBPs (100 mg/kg BW) daily for 2 weeks. Though the hypoglycemic effect was achieved in all the cases, however, C. versicolor EBP proved as the most potent one. The administration of the C. versicolor EBP substantially reduced (29.9%) the plasma glucose level as compared to the saline administered group (control). It also reduced the plasma total cholesterol (TC), triglyceride (TG), aspartate aminotransferase (AST) and, alanine aminotransferase (ALT) levels by 9.22, 23.83, 16.93, and 27.31%, respectively. The sugar and amino acid compositions of this EBP were also analyzed in detail.

Polymer Nanofibers for Biomedical Engineering

  • Shin, Min-Kyoon;Kim, Seon-Jeong;Kim, In-Young;Kim, Sun-I.
    • 대한의용생체공학회:의공학회지
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    • 제29권3호
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    • pp.173-178
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    • 2008
  • Recent advancements in the electrospinning method enable the production of ultrafine solid and continuous fibers with diameters ranging from a few nanometers to a few hundred nanometers with controlled surface and morphological features. A wide range of biopolymers can be electrospun into mats with a specific fiber arrangement and structural integrity. These features of nanofiber mats are morphologically similar to the extracellular matrix of natural tissues, which are characterized by a wide pore diameter distribution, a high porosity, effective mechanical properties, and specific biochemical properties. This has resulted in various kinds of applications for polymer nanofibers in the field of biomedicine and biotechnology. The current emphasis of research is on exploiting these properties and focusing on determining the appropriate conditions for electrospinning various biopolymers for biomedical applications, including scaffolds used in tissue engineering, wound dressing, drug delivery, artificial organs, and vascular grafts, and for protective shields in specialty fabrics. This paper reviews the research on biomedical applications of electrospun nanofibers.

Transformation of dissolved organic matter in a constructed wetland: A molecular-level composition analysis using pyrolysis-gas chromatography mass spectrometry

  • Park, Jongkwan;Choi, Mijin;Cho, Jaeweon;Chon, Kyongmi
    • Environmental Engineering Research
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    • 제23권4호
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    • pp.390-396
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    • 2018
  • This study investigated the transformation of dissolved organic matter (DOM) in a free-water surface flow constructed wetland. Pyrolysis gas chromatography-mass spectrometry (Py-GC/MS) coupled with preparative high-performance liquid chromatography (prep-HPLC) was used to analyze the compositions of biopolymers (polysaccharides, amino sugars, proteins, polyhydroxy aromatics, lipids and lignin) in DOM according to the molecular size at three sampling points of the water flow: inflow, midflow, and outflow. The prep-HPLC results verified the decomposition of DOM through the decrease in the number of peaks from three to one in the chromatograms of the sampling points. The Py-GC/MS results for the degradable peaks indicated that biopolymers relating to polysaccharides and proteins gradually biodegraded with the water flow. On the other hand, the recalcitrant organic fraction (the remaining peak) in the outflow showed a relatively high concentration of aromatic compounds. Therefore, the ecological processes in the constructed wetland caused DOM to become more aromatic and homogeneous. This indicated that the constructed wetland can be an effective buffer area for releasing biochemically stable DOM, which has less influence on biological water quality indicators, e.g., biochemical oxygen demand, into an aquatic ecosystem.