• Korean Journal of Environmental Biology
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• v.29 no.2
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• pp.98-106
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• 2011

In order to investigate water quality factors controlling chlorophyll-$a$ concentrations, the by-daily monitoring was conducted from February to November 2010 in 4 stations of Masan Bay. Seasonal variability in physico-chemical factors was mainly controlled by freshwater loading as a result of precipitation: chemical oxygen demand, suspended solids and nutrient concentrations rapidly increase during the heavy rainy season, whereas they decrease in the dry season. From late winter to mid spring, phosphorus and silica sources relative to Redfield ratio were probably functioned as limiting factor for phytoplankton flourishing in surface waters, but nitrogen concentration during mid-spring to autumn might be responsible for the increase of phytoplankton biomass. The multiple regression analysis revealed that variations in chlorophyll-$a$ concentration may be strongly correlated with changes of water temperature, chemical oxygen demand, dissolved inorganic phosphorus in spring, and salinity, chemical oxygen demand and precipitation in summer. Consequently, in the Masan Bay, a heavy rainfall event is an important factor to determine changes of biotic and abiotic factors, and in addition the dynamics of chlorophyll-$a$ concentration are strongly affected by changes of hydrological factors, especially water temperature, precipitation and nutrients.

• Journal of Environmental Science International
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• v.10 no.2
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• pp.119-127
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• 2001

The Keum river is one of the important river in Korea and has a drainage area of 9,873$\textrm{km}^2$. The Keum river is deepening pollution state due to development of the lower city and construction of a industrial complex. The water quality of the Keum river come to eutrophication state and belong to III grade of water quality standard. The concentration BOD in river is affected by the organic loading from a tributary and the algae biomass that largely happen to under eutrophication state. In the eutrophic water mass such as the Keum river, the autochthonous BOD was very important part for making a decision of water quality management, because it was accounted for majority of the total BOD. The purpose of this study was to survey the chatacteristics of water quality in summer and to estimate reaction coefficient. Also, we studied to correlationship between chlorophyll a and BOD(COD) for estimation of the autochthonous BOD. The correlationship between chlorophyll a and BOD(COD) were obtained through the culture experiment of phytoplankton in the laboratory. The results of this study may be summarized as follows ; The characteristics of water quality in summer were belong to III~IV grade of water quality standard as BOD and nutritive condition is very high. The BOD, ammonia nitrogen and phosphate loadings in Miho stream which inflowing untreated sewage from Chungju city was occupied with 64.07%, 26.36%, 46.08%, respectively. Maximum nutrient uptake (Vmax) was 0.4400$\mu$M/hr as substrate of ammonia nitrogen, 0.1652$\mu$M/hr as substrate of phosphate. Maximum specific growth rate ($\mu$max) was 1.2525$hr^{-1}$ as substrate of ammonia nitrogen, 1.5177$hr^{-1}$ as substrate of phosphate. The correlation coefficient between chlorophyll a and BOD by the culture experiment were found to be 0.911~0.935 and 0.942~0.947 in the case adding nutrient and no adding nutrient, respectively. The correlation coefficient between chlorophyll a and COD through the culture experiment were found to be 0.918~0.977 and 0.880~0.931 in the case adding nutrient and no adding nutrient, respectively. The autochthonous BOD(COD) was estimated to the relationship between BOD(COD) and chlorophyll a. The regression equation were found to be autochthonous BOD=(0.045~0.073)${\times}chlorophyll$ a and autochthonous $COD=(0.137~0.182){\times}chlorophyll$ a.

• Korean Chemical Engineering Research
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• v.51 no.3
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• pp.335-341
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• 2013

Ammonia circulation reactor (ACR) was devised for the effective pretreatment of corn stover. This method is designed to circulate aqueous ammonia continuously so that it can reduce the chemical and water consumption during pretreatment. In this study, ammonia pretreatment with various reaction conditions such as reaction time (4~12 hour), temperature ($60{\sim}80^{\circ}C$), and solid:liquid ratio (1:3~1:8) was tested. Chemical compositions including solid remaining after reaction, lignin and carbohydrates were analyzed and enzymatic digestibility was also measured. It was observed that as reaction conditions become more severe, lignin removal was significantly affected, which was in the range of 47.6~70.6%. On the other hands, glucan and xylan losses were not substantial as compared to that of lignin. At all tested conditions, the glucan loss was not changed substantially, which was between 4.7% and 15.2%, while the xylan loss varied, which was between 7.4% and 25.8%. With (15 FPU-GC220+30 CBU)/g-glucan of enzyme loading, corn stover treated using ammonia circulation reactor for 8~12 hours resulted in 90.1~94.5% of 72-h glucan digestibility, which was higher than 92.7% of $Avicel^{(R)}$-101. In addition, initial hydrolysis rate (at 24 hour) of this treated corn stover was 73.0~79.4%, which was shown to be much faster than 69.5% of $Avicel^{(R)}$-101. As reaction time increased, more lignin removal and it was assumed that the enhanced enzymatic digestibility of treated biomass was attributed to the lignin removal.

• 한국해양학회지
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• v.29 no.2
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• pp.107-118
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• 1994

An investigation of the annual change and C:N:P ratio in particulate organic matter (POM) in Chinhae Bay, a semi-enclosed bay of the southern coast of Korean Peninsula, was carried out for a period of 12 months between January and December, 1993. The concentrations of POM have a broad range: 198∼4,416 ugC/l, 24∼792 ugN/l and 4.5∼69.0 ugP/l, Marked seasonal changes of POM, particularly particulate organic carbon (POC) and nitrogen (PON), were observed in the surface water. Generally, the concentration of POM peaks in summer. The C:N:P composition ratio of particulate organic matter, which is high in summer, also shows a seasonal change. The C:N assimilation ratio is constant at 6.53, which is consistent with the Redfield ratio. The significant linear relationship between POM and chlorophyll-a in the surface water during the survey period (except for January and February) and the C:N ratio suggest that the concentration of POM is controlled by phytoplankton biomass. POM peaks in summer, a period characterized by high freshwater input and the strong stratification, as a result of the intense proliferation of phytoplankton by a large amount of nutrient loading from the tributaries. On the other hand, the high C:P and N:P ratios in summer indicate that P is limited for phytoplankton growth owing to N-enrichment from a high input of freshwater with a high dissolved inorganic N:P ratio.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.2
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• pp.77-84
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• 2011

This study was conducted to develop a novel combined system of a hybrid rotating biological contactor (RBC) process that was composed of an attached- and suspended- biomass reactor, followed by a settler and a biological aerated filter (BAF) column to treat a high strength slaughter wastewater. Long term influences of organic and nitrogen loading rates were investigated to see how the combined system worked in terms of the removal efficiency. A synthetic wastewater containing a pork cutlet steak source (commercially available) and swine blood was used to feed the combined system. The hybrid RBC process showed excellent removals: about 95% for soluble COD and 85% for ammonium nitrogen. However, the unsettled solids seriously deteriorated the removal efficiency of total COD (TCOD) and total nitrogen (TN) in the RBC process. A significant fraction of the TCOD and suspended solids (SS) was further removed in the BAF column although the effluent quality was still unsatisfactory, giving TCOD 300 mg/L, SS 180 mg/L and TN 59 mg/L. An addition of polyaluminium chloride into the RBC effluent improved the performance of the settler and BAF, producing an excellent quality of final effluent; TCOD 16.5 mg/L, SS 0 mg/L, TN 55.5 mg/L, TP 1.3 mg/L. Therefore, it was confirmed that the combined system of hybrid RBC and BAF could treat a high strength slaughter wastewater excellently.

• Korean Journal of Ecology and Environment
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• v.43 no.1
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• pp.136-141
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• 2010

In situ experiments of Nutrient Enrichment Bioassays (NEBs) were conducted in the field along with in the laboratory to determine which nutrient limited phytoplankton growth as a indicator of primary productivity. For the NEBs, the water was sampled using a polyethylene-lined container and dispensed into 6 L water tank in the laboratory. The control (C, no nutrient spike) and six treatments of phosphorus (P), 2-fold phosphorus (2P), 4-fold phosphorus (4P), nitrate nitrogen ($NO_3$-N), 2-fold nitrate nitrogen ($2NO_3$-N), and phosphorus and nitrate nitrogen (P+$NO_3$-N) were set up in the lacustrine zone near the dam site, Daechung Reservoir in September, 2009 and analyzed the diel changes of total nitrogen (TN), total phosphorus (TP), and chlorophyll-$\alpha$ (Chl-$\alpha$) in the cubitainers. The short-term NEBs showed that algal response in the treatments spiked phosphorus (P, 2P, and 4P) were significantly (p < 0.05) greater than the response in the control (C), and nitrogen-spike. Also, the response in 4P-treatment was greater than those in the P- and 2P-treatments. In contrast, there was no significant differences (p > 0.20) between the $NO_3$-N and $2NO_3$-N treatment. The outcomes of the NEBs suggest that phosphorus limited the phytoplankton growth and nitrogen was not limited in this system. Furthermore, in the N + P treatments, the response was minimum, compared to all other treatments and the control, indicating that even if the system is evidently P-limited system, when added the nitrogen, the response showed the inhibition. Also, > 95% of observed long-term TN:TP ratios in the ambient water showed > 17, which is the criteria of P-limitation, supporting the P-limitation in the system. Overall, these results suggest that phytoplankton biomass near the dam is a direct linear function of P-loading near the watershed, if the phosphorus pool is mainly dissolved fraction.

• Korean Journal of Remote Sensing
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• v.22 no.6
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• pp.495-505
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• 2006

In order to classify aerosol type, Aerosol Optical Thickness (AOT) and Fine mode Fraction (FF), which is the optical thickness ratio of small particles$(<1{\mu}m)$ to total particles, data from MODIS (MODerate Imaging Spectraradiometer) aerosol products were analyzed over North-East Asia during one year period of 2005. A study area was in the ocean region of $20^{\circ}N\sim50^{\circ}N$ and $110^{\circ}E\simt50^{\circ}E$. Three main atmospheric aerosols such as dust, sea-salt, and pollution can be classified by using the relationship between AOT and FF. Dust aerosol has frequently observed over the study area with relatively high aerosol loading (AOT>0.3) of large particles (FF<0.65) and its contribution to total AOT in spring was up to 24.0%. Pollution aerosol, which is originated from anthropogenic sources as well as a natural process like biomass burning, has observed in the regime of high FF (>0.65) with wide AOT variation. Average pollution AOT was $0.31{\pm}0.05$ and its contribution to total AOT was 79.8% in summer. Characteristic of sea-salt aerosol was identified with low AOT (<0.3), almost below 0.1, and slightly higher FF than dust and lower FF than pollution. Seasonal analysis results show that maximum AOT $(0.33{\pm}0.11)$ with FF $(0.66{\pm}0.21)$ in spring and minimum AOT $(0.19{\pm}0.05)$, FF $(0.60{\pm}0.14)$ in fall were observed in the study area. Spatial characteristic was that AOT increasing trend is observed as closing to the eastern part of China due to transport of aerosols from China by the prevailing westerlies.

• Clean Technology
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• v.28 no.4
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• pp.269-277
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• 2022

With the recent development of the biological enzymatic reaction industry, lactic acid (LA) can be mass-produced from biomass sources. In particular, a catalytic process that converts LA into acrylic acid (AA) is receiving much attention because AA is used widely in the petrochemical industry as a monomer for superabsorbent polymers (SAP) and as an adhesive for displays. In the LA conversion process, NaY zeolites have been previously shown to be a high-activity catalyst, which improves AA selectivity and long-term stability. However, NaY zeolites suffer from fast deactivation due to severe coking. Therefore, the aim of this study is to modify the acid-base properties of the NaY zeolite to address this shortcoming. First, base promoters, Ca ions, were introduced to the NaY zeolites to tune their acidity and basicity via ion exchange (IE) and incipient wetness impregnation (IWI). The IWI method showed superior catalyst selectivity and stability compared to the IE method, maintaining a high AA yield of approximately 40% during the 16 h reaction. Based on the NH₃- and CO₂-TPD results, the calcium salts that impregnated into the NaY zeolites were proposed to exit as an oxide form mainly at the exterior surface of NaY and act as additional base sites to promote the dehydration of LA to AA. The NaY zeolites were further treated with KOH before calcium impregnation to reduce the total acidity and improve the dispersion of calcium through the mesopores formed by KOH-induced desilication. However, this KOH treatment did not lead to enhanced AA selectivity. Finally, calcium loading was increased from 1wt% to 5wt% to maximize the amount of base sites. The increased basicity improved the AA selectivity substantially to 65% at 100% conversion while maintaining high activity during a 24 h reaction. Our results suggest that controlling the basicity of the catalyst is key to obtaining high AA selectivity and high catalyst stability.