• Title/Summary/Keyword: Biomass and waste

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Size Distributions of Trace Elements in Airborn Particulates Collected using Drum impactor at Gosan, Jeju Island : Measurements in Springtime 2002 (DRUM impactor를 이용한 대기 입자상 물질 중 원소성분의 입경분포 특성 : 제주도 고산지역의 2002년 봄철 (3.29-5.30) 측정 연구)

  • 한진석;문광주;류성윤;안준영;공부주;홍유덕;김영준
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.4
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    • pp.555-569
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    • 2004
  • Size -segregated measurements of aerosol composition using 8-stage DRUM impactor are used to determine the transport of natural and anthropogenic aerosols at Gosan site from 29 March to 30 May in 2002. Separation of ambient aerosols by DRUM impactor offers many Advantages over other standard filtration techniques. Some of the most important advantages are the ability to segregate into details by particle tire, to better preserve chemical integrity since the air stream doesn't pars through the deposit, to collect samples as a function of time, and to have a wide variety of impaction surfaces available to match analytical needs. Although the transport of Yellow sand is a well-known phenomenon in springtime, the result of measurement shows that not only soil dust but also anthropogenic aerosols, including sulfur, enriched trace metals such as Pb, Ni, Zn. Cu, Cr, As, Se, Br, are transported to Gosan in springtime. This study combines the size- and time-resolved aerosol composition measurements with isentropic, backward air-mass trajectories in order to identify some potential source regions of anthropogenic aerosols. As a result, during the NYS period, the average concentration of PM$_{10}$ was 46$\mu\textrm{g}$/㎥, Si, Al. S, Fe, Cl, K, Ca were higher than 1,000 ng/㎥ and Ti was about 100 ng/㎥. The concentrations of Zn, Mn, Cu. Pb, Br, Rb, V, Cr, Ni. At, Se ranged between 1 and 70 ng/㎥. More than 50% typical soil elements, tuck as Al, Si, Fe, Cd. Ti, Cr, Cu, Br. were distributed in a coarse particle range(5.0-12${\mu}{\textrm}{m}$). In other hand, anthropogenic pollutants, luck as S, N, Vi, were mainly distributed in a fine particle range (0.09-0.56${\mu}{\textrm}{m}$). During the YS period, PM$_{10}$ increased about 8 times than NYS period, and main soil elements, such as Al, Si, S, K, V, Mn, Fe also doubled in coarse particle range (1.15-12${\mu}{\textrm}{m}$). But Zn, As, Pb, Cu and Se, which distributed in the time aerosols (0.09-0.56${\mu}{\textrm}{m}$), were on the same level with or decreased than NYS period. Finally. except the YS Period, coarse particles (2.5-12${\mu}{\textrm}{m}$) are inferred to be influenced by soil, coal combustion, waste incineration, ferrous and nonferrous sources through similar pathways with Yellow Sand. But fine particles have different sources, such as coal combustion, gasoline vehicle, biomass burning, oil or coal combustion, nonferrous and ferrous metal sources, which are transported from China, Korea peninsula and local sources.ces.

International Trends in Development, Commercialization and Market of Bio-Plastics (국내외 바이오 플라스틱의 연구개발, 제품화 및 시장 동향)

  • You, Young-Sun;Oh, Yu-Sung;Hong, Seung-Hoi;Choi, Sung-Wook
    • Clean Technology
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    • v.21 no.3
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    • pp.141-152
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    • 2015
  • As environmental issues are emerging, bio-plastic suppliers in leading countries have been foreseeing the strong needs for environment-friendly materials such as eco-packing materials due to increased attention and regulation on recycle. To catch up with the demand, various types of bio-plastics based on natural feedstocks were developed and released on a market. These bio-plastic products drew the great attention even in domestic industries. At present, international oil price fluctuation and heavy charge on waste raise the unit cost of production and disposal expense of conventional plastic materials. These conditions make bio-plastic an alternative, because it is not restrained by oil prices and problem in the disposal. It is also expected that bio-plastic will be applied to various types of products including containers, industrial supplies, disposables, and medical supplies. However, the bio-plastic is still in its infancy, thus more research and understanding should be followed to put it to application. Bio-plastic is considered as environment-friendly material with high potential which has the advantages of production and disposal.

Nickel Catalysts Supported on Ash-Free Coal for Steam Reforming of Toluene (무회분탄에 분산된 니켈 촉매의 톨루엔 수증기 개질)

  • PRISCILLA, LIA;KIM, SOOHYUN;YOO, JIHO;CHOI, HOKYUNG;RHIM, YOUNGJOON;LIM, JEONGHWAN;KIM, SANGDO;CHUN, DONGHYUK;LEE, SIHYUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.6
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    • pp.559-569
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    • 2018
  • Catalytic supports made of carbon have many advantages, such as high coking resistance, tailorable pore and surface structures, and ease of recycling of waste catalysts. Moreover, they do not require pre-reduction. In this study, ash-free coal (AFC) was obtained by the thermal extraction of carbonaceous components from raw coal and its performance as a carbon catalytic support was compared with that of well-known activated carbon (AC). Nickel was dispersed on the carbon supports and the resulting catalysts were applied to the steam reforming of toluene (SRT), a model compound of biomass tar. Interestingly, nickel catalysts dispersed on AFC, which has a very small surface area (${\sim}0.13m^2/g$), showed higher activity than those dispersed on AC, which has a large surface area ($1,173A/cm^2$). X-ray diffraction (XRD) analysis showed that the particle size of nickel deposited on AFC was smaller than that deposited on AC, with the average values on AFC ${\approx}11nm$ and on AC ${\approx}23nm$. This proved that heteroatomic functional groups in AFC, such as carboxyls, can provide ion-exchange or adsorption sites for the nano-scale dispersion of nickel. In addition, the pore structure, surface morphology, chemical composition, and chemical state of the prepared catalysts were analyzed using Brunauer-Emmett-Taylor (BET) analysis, transmission electron microscopy (TEM), scanning electron microscopy (SEM), x-ray diffraction (XRD), Fourier-transform infrared (FT-IR) spectroscopy, and temperature-programmed reduction (TPR).

Lead Biosorption by Alginate Beads Immobilizing Aspergillus niger (Aspergillus niger를 고정화한 Alginate Bead에 의한 납 흡착)

  • Bang, Byung-Ho
    • Applied Biological Chemistry
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    • v.44 no.3
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    • pp.185-190
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    • 2001
  • Alginate, a well-known biopolymer, is universally applied for immobilization of microbial cells. Biosorption characteristics of lead by waste biomass of immobilized A. niger beads, used in fermentation industries to produce citric acid, were studied. The immobilized A. niger beads, prepared via capillary extrusion method using calcium chloride, were applied in the removal of lead. Pb uptake was the highest in A. niger beads cells grown for 3 days with medium producing citric acid (12% sucrose, 0.5% $NH_4NO_3$, 0.1% $KH_2PO_4$, and 0.025% $MgSO_4$). Lead uptake by the immobilized A. niger beads and free A. niger mycellia beads increased sharply with time. However, while uptake by the immobilized A. niger beads continued to increase slowly, that by free A. niger mycellia beads stopped after 30 min. The optimum pH and temperature of lead uptake were found to be 6 and $35^{\circ}C$, respectively. The maximum uptake of lead was achieved with $50{\sim}100$ beads and 50 ml lead solution in a 250-ml Erlenmeyer flask, while, at over 100 beads, uptake of the lead decreased. The order of biosorption capacity for heavy metals was Pb>Cu>Cd. Pb uptake capacity of the immobilized A. niger beads treated with 0.1 M $CaCI_2$, 0.1 M NaOH, and 0.1 M KOH decreased compared to the untreated beads. On testing the desorption of Pb from the immobilized A. niger beads, re-uptake of Pb was found possible after desorption of the binding metal with 0.1 M HCI.

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Analysis of Environmental Impacts for the Biochar Production and Soil Application (폐목재를 이용한 바이오차 생산 및 토양적용의 환경평가)

  • Kim, Mihyung;Kim, Geonha
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.7
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    • pp.461-468
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    • 2014
  • Biochar is a carbon rich solid produced by the pyrolysis of biomass such as energy crops, forestry residues, and wood wastes. Biochar returned to soil is to mitigate climate change and the feedstock of wood wastes reduces fossil fuel consumption as well as disposal costs. This study was practiced to evaluate a biochar system by gasification in terms of global warming regarding the soil application of the produced biochar. Life cycle assessment methodology was used to analyze the environmental impacts of the system, and the functional unit was 1 tonne of wood wastes. The result shows that the biochar system by using wood wastes as feedstock produces 4.048E-01 $kgCO_2-eq$ from the pre-treatment process as chipping and drying, 4.579E-01 $kgCO_2-eq$ from the pyrolysis process, and 9.070E-02 $kgCO_2-eq$ from the spreading to agricultural land, therefore total 9.534E-01 $kgCO_2-eq$ are generated. About 252 kg of $CO_2$ is still stored in the produced biochar in soil after carbon offsetting of the system. Therefore, the net carbon of the system is -251 kg of $CO_2-eq$.

Removal of Heavy Metals from Aqueous Solution by a Column Packed with Peat-Humin (Peat-Humin 충전 칼럼을 이용한 수용액 중의 중금속 제거)

  • Shin, Hyun-Snag;Lee, Chang-Hoon;Lee, Yo-Snag;Kang, Ki-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.5
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    • pp.535-541
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    • 2005
  • Peat humin(p-Humin) extracted from Canadian Sphagnum peat moss was packed in a column and removal of heavy metal ions such as Cd, Cu and Pb from aqueous solution under flow conditions was studied. The metal ions were removed not only from single-element solutions but also from a multi-metal solution. Column kinetics for metal removal were described by the Thomas model. For single-component metal solutions, the maximum adsorption capacities of the p-Humin for Pb, Cu and Cd were 138.8, 44.66 and 41.61 mg/g, respectively. The results of multi-component competitive adsorption showed that adsorption affinity was in the order of Pb $\gg$ Cu > Cd. The adsorbed metal ions were easily deserted from the p-Humin with 0.05 N $HNO_3$ solution. It is apparent that 95% of the heavy metal ions were recovered from the saturated column. This investigation provides possibility to clean up heavy-metal contaminated waste waters by using the natural biomass, p-Humin as an environmentally friendly and cost-effective new biosorbents.

Application of QUAL-2E Model for Water Quality Management in the Keum River -Waste loads Allocation Analysis by Considering Autochthonous BOD- (금강수계의 수질관리를 위한 QUAL-2E 모델의 적용(II) -자생BOD를 고려한 허용오염부하량 산정-)

  • 김종구;이지연
    • Journal of Environmental Science International
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    • v.10 no.1
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    • pp.21-25
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    • 2001
  • The Keum river has been utilized for drinking water supply of several city including Kunsan city and is deepening pollution state due to numerous municipal and industrial discharges. The concentration BOD in river is affected by the organic loading from a tributary and the algae biomass that largely happen to under eutrophication state. In the eutrophic water mass such as the Keum river, the autochthonous BOD was very important part for making a decision of water quality management, because it was accounted for majority of the total BOD. The predict of water quality has important meaning for management of water quality pollution of the Keum river. The purpose of this study will manage and predict water quality of the Keum river using QUAL-2E model considering the autochthonous BOD. The estimation of autochthonous BOD represented that the relationship between BOD and chlorophyll a. The regression equation was shown to be autochthonous BOD=$\beta$(sub)5$\times$chlorophyll a. The results of this study may be summarized as followed; The QUAL-2E model was calibrated with the data surveyed in the field of the study area in June, 1998. The calculated value by QUAL-2E model are in good agree to measured value within relative error of 7.80~20.33%. Especially, in the case of the considering autochthonous BOD, the calculated value of BOD were fairly good coincided with the observed values within relative error of 15%. But the case of not considering autochthonous BOD, relative error of BOD was shown to be 43.2%. In order to attain II grade of water quality standard in Puyo station which has a intake facility of water supply, we reduced to the pollutants loading of tributaries. In the case of removed 100% BOD of tributaries, the BOD of Puyo station was 4.07mg/$\ell$, belong to III grade of water quality standard. But in the case of removed 88% nutrient of tributaries, it was satisfied to II grade of water quality standard as below 3mg/$\ell$ of BOD. For estimation of autochthonous BOD in Keum river, we are performed simulating in accordance with reduction of nutrient load(50~100%) under conditions removal 90% organic load. Occupancy of autochthonous BOD according to nutrient loading reductions were varied from 25.97~79.51%. Occupancy of autochthonous BOD was shown to be a tendency to increasing in accordance with reduction of nutrient loading. Showing the above results, the nutrient that one of the growing factor of algae was important role in decision of BOD in the Keum river. For the water quality management of the Keum river, therefore, it is necessary to considering autochthonous BOD and to construction of advanced sewage treatment plant for nutrient removal.

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Effect of different types of biochar on the growth of Chinese cabbage (Brassica chinensis)

  • Lee, Jae-Han;Seong, Chang-Jun;Kang, Seong-Soo;Lee, Ho-Cheol;Kim, Soo-Hun;Lim, Ji-Sun;Kim, Jae-Hong;Yoo, Joun-Hyuk;Park, Jung-Hyun;Oh, Taek-Keun
    • Korean Journal of Agricultural Science
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    • v.45 no.2
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    • pp.197-203
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    • 2018
  • Biochar is the carbon solid produced through the pyrolysis of a biomass from organic sources such as agricultural waste, animal manure, and sludge under limited or anaerobic conditions. Biochar has the effect of reducing greenhouse gases through the carbon sequestration method; additionally, biochar is known to function as a soil amendment. This experiment was conducted to evaluate the application of biochar on the growth characteristics of Chinese cabbage at Chungnam National University in Daejeon, Korea. The Chinese cabbage was grown for 50 days in a glasshouse in pots. A pruning branch was used to produce the bead and pellet forms of biochar through pyrolysis. The biochar was added to the soil at 0, 2, and 5% by weight. The Chinese cabbage with the 2% treatment of the bead form of biochar had the highest fresh weight ($149.43{\pm}15.92g\;plant^{-1}$) which was increased by 10% compared to the control ($136.91{\pm}31.46g\;plant^{-1}$). Moreover, for the 5% treatment of the bead form of biochar ($60.91{\pm}9.82g\;plant^{-1}$), the growth decreased by 57% compared to the control. As the content of the bead form of biochar increased, the shoot dry weight, leaf number, leaf length and lead width that appeared decreased. An increase in the total organic matter, Avail. $P_2O_5$, Ex. cation and EC was observed when the biochar content was increased. Our results support the application of 2% biochar in the bead form for increased growth of Chinese cabbage.

Nitrogen Budget Analysis Using a Box Model for Hajeon Tidal Flat in the West Coast of Korea (Box model을 이용한 서해 곰소만 하전 갯벌의 질소 수지)

  • Yoo, Jae-Won;Hong, Jae-Sang;Yang, Sung-Ryull;Park, Kyeong
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.7 no.4
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    • pp.257-266
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    • 2002
  • To estimate the nitrogen budget and assess the purification function of a tidal flat ecosystem, a field survey was carried out at Hajeon tidal flat in Gomso Bay, the southern part of Byeonsan Peninsula, Chollabuk-do, Korea. A study area of 3.0$\times$4.5 ㎢ was established on the tidal flat and the concentrations of chlorophyll-a, DIN, DON, and TN were measured in the water column during the period of April 17-18, 1999: From the budget analysis, the loss rate of Chl-a was estimated to be -0.05 mg Chl/㎡/hr, which is approximately 7% of that at Issiki tidal flat in Aichi Prefecture, Japan. The lower loss rate of Chl-a in the study area was attributable to the lower standing crop of phytoplankton, the lower temperature that may reduce metabolic rates of biotic components and the lower biomass of macrobenthos in the study area. Over the 13.5 ㎢ of study area, Hajeon tidal flat removed 8.36$\times$10$\^$2/ kg N/day of TN, 5.36$\times$10$\^$3/ kg N/day of PON and 1.62$\times$10$\^$2/ kg N/day of phytoplankton-related PON, showing that the tidal flats may play an important role in removing nitrogen in coastal waters. The removal rate of PON, compared to the removal cost of the existing waste water treatment facilities, indicates that the economic value of the purification function of Hajeon tidal flat (13.5㎢) may be more than that of two large facilities.

Development of CO2 Emission Factor for Wood Chip Fuel and Reduction Effects (목질계 바이오매스 중 대체연료 우드칩의 온실가스(CO2) 배출계수 개발 및 저감 효과)

  • Lee, Seul-Ki;Kim, Seung-Jin;Cho, Chang-Sang;Jeon, Eui-Chan
    • Journal of Climate Change Research
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    • v.3 no.3
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    • pp.211-224
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    • 2012
  • Technology for energy recovery from waste can reduce the greenhouse gas emissions. So recently, there are several companies using RDF, RPF, WCF instead of using only coal fuel and it's part of the fuel on the increase. In this study, we developed Wood chip fuel $CO_2$ emission factor through fuel analysis. It's moisture content is 23%, received net calorific value is 2,845 kcal/kg, and received basis carbon is 34%. The result of emission factor is $105ton\;CO_2/TJ$, it's 5.9% lower than 2006 IPCC guideline default factor $112ton\;CO_2/TJ$. The gross GHG(Greenhouse gases) emissions of plant A is $178,767ton\;CO_2 eq./yr$, and Net GHG emissions is $40,359ton\;CO_2 eq./yr$. Therefore, the reduction of GHG emissions is $138,408ton\;CO_2/yr$ through using WCF, and I accounts for 77% of all GHG emissions.