• 보존과학연구
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• s.27
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• pp.103-128
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• 2006

Rock properties of the five storied stone pagoda in the Mooryangsa temple are consist mainly in medium grained biotite granite with partly pegmatite veinlet. A part of the foundation stone is substituted in identical rock properties of the pagoda. The upper part of the pagoda is used purples and stone, gray shale and granodiorite. The most serious problem of the pagoda is structual instability from centered subsidence of the ground in northwestern direction remarkably. In southern view, the upper part of the pagoda also is slanted a little in right, it will need reinforcement by engineering method for structual stability of the stone pagoda. Weathering states of the stone pagoda are affected results of natural and artifical factors due to the surface-exfoliation, fine-fissure, crack, falling offs. On the rock surface of the pagoda, ferro-manganese hydroxide compounds are coated along the rainpathway. Also, bryophyte range concentration spreads raindrops face of roof rock properties, which areadd biological weathering effects. For the synthetic evaluation of the deterioration state, we make detailed surface weathering maps, it will be contribute to investigation for future conservation schemes.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.7
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• pp.1116-1123
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• 2021

Oil spilled in seawater undergoes physical and chemical changes as well as biological degradation through various weathering processes, such as evaporation, diffusion, dispersion, emulsification, dissolution, oxidation, and sedimentation. Evaporation is one of the most immediate and prompt weathering processes, and it has the greatest influence on majority of pollutants. In this study, the evaporation characteristics of different oil samples were studied; the volatilization characteristics of gasoline, kerosene, and diesel were compared at average seawater (25 ℃) and near-equator (35 ℃) temperatures. The oil samples were pre-treated and then collected at regular intervals. Gas chromatography-mass spectrometry analysis was performed, and the changes in the amount of the hydrocarbons were calculated.

• Economic and Environmental Geology
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• v.55 no.6
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• pp.583-596
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• 2022

The rock surface of Bangudae petroglyphs is mainly dark brown hornfelsified shales by contact metamorphism. The surface form a weathered layer of a invariable depth, and there is a difference with mineral and chemical composition between weathered and non-weathered layers. Surface of the petroglyphs has been discolored to light brown over the face due to biological and chemical weathering. As the measuring chromaticity based on the non-weathered layer, the whiteness and yellowness increased in the weathered layer, and the color difference (ΔE) was 5.54 to 36.89 (mean 17.26). In the weathered layer of the petroglyph surface, the CaO content was reduced by about 90% compared to the non-weathered layer, and Sr also showed the same trend. In particular, the mean porosity of the non-weathered layer was 0.4%, but it was estimated as 25.0% in the weathered layer. This is interpreted as the fact that calcite reacts with water, and forms a weathered layer from the surface as it is eluted. Based on the weathering depth modeling of the petroglyphs using the penetration characteristics of X-rays, the weathering depth of rock faces was found to be 1 to 2mm. However, the area classified as 2mm or more estimated to be a maximum of 3 to 4mm, considering the weathering depth around the petroglyphs surface.

• 보존과학연구
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• s.24
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• pp.5-28
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• 2003

Stone has been one of the most intensely studied materials in conservation. Understanding the deterioration of stone needs various knowledge in different mineralogical and physical characteristics and its weathering response under different climate and environment. The alteration and weathering of stone is affected by natural or artificial elements whether they are physical, chemical or biological damaging factors. It can be said that the bio deterioration of stone is coupled with every environmental factors, which induce decomposition of stone structure, either directly or indirectly as a form of catalysis. Many elements contribute to the deterioration of stone monuments and other objects of cultural value such as pagoda, stature of Buddha, etc. This report concentrates on the action of biodeteriorative factorsincluding bacteria, algae and higher plants. Preventive and remedial methods and a selection of chemical treatments are also described.

• Journal of Conservation Science
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• v.26 no.4
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• pp.385-395
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• 2010

This study aimed to identify weathering factors and to assess the conservation environment through microclimatic analysis of Hyeonpung Seokbinggo (ice-storing stone warehouse). The stone blocks inside Seokbinggo suffered crack, displacement, break-out, exfoliation, efflorescence, brown and black discoloration, and biological colonization. Biological colonization represented the maximum deterioration rate(24%) among those weathering forms. The indoor microclimate showed parallel patterns with outdoor one, but the indoor temperature and relative humidity ranged far narrower than outdoor and remained steady. The environmental characteristics resulted from blocking-out of outdoor heat by the closed entrance and surrounding microtopography. This prevented water condensation and freezing effects, so that it reduced physical deterioration of rock, and maximized ice-storing effect for long time. However, contrary to positive effect, extremely high relative humidity over 99% accelerated biological colonization inside the Seokbinggo.

• Geophysics and Geophysical Exploration
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• v.8 no.1
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• pp.18-25
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• 2005

We derive refraction statics for seismic data recorded in a hard rock terrain, in which there are large and rapid variations in the depth of weathering. The statics corrections range from less than 10 ms to more than 70 ms, often over distances as short as 12 receiver intervals. This study is another demonstration of the importance in obtaining accurate initial refraction models of the weathering in hard rock terrains in which automatic residual statics may fail. We show that the statics values computed with a simple model of the weathering using the Generalized Reciprocal Method (GRM) and the Refraction Convolution Section (RCS) are comparable in accuracy to those computed with a more complex model of the weathering, using least-mean-squares inversion with the conjugate gradient algorithm (Taner et al., 1998). The differences in statics values between the GRM model and that of Taner et al. (1998) systematically vary from an average of 2ms to 4ms over a distance of 8.8 km. The differences between these two refraction models and the final statics model, which includes the automatic residual values, are generally less than 5 ms. The residuals for the GRM model are frequently less than those for the model of Taner et al. (1998). The RCS statics are picked approximately 10 ms later, but their relative accuracy is comparable to that of the GRM statics. The residual statics values show a general correlation with the refraction statics values, and they can be reduced in magnitude by using a lower average seismic velocity in the weathering. These results suggest that inaccurate average seismic velocities in the weathered layer may often be a source of short-wavelength statics, rather than any shortcomings with the inversion algorithms in determining averaged delay times from the traveltimes.

• Korean Journal of Heritage: History & Science
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• v.56 no.4
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• pp.160-189
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• 2023

The Cheonjeon-ri petroglyph is inscribed with shale formation belonging to the Daegu Formation of the Gyeongsang Supergroup in the Cretaceous of the Mesozoic Era. This rock undergoes thermal alteration to become hornfels, and has a high hardness and dense texture. Rock-forming minerals have almost the same composition as quartz, alkali felspar, plagioclase, calcite, mica, chlorite and opaque minerals, but calcite is rarely detected in the weathered zone. The petroglyph forms a weathered zone with a certain depth, and there is a difference in mineral and chemical composition between weathered and unweathered zones, respectively. The CaO contents of the weathered zone were reduced by more than 90% compared to that of the unweathered zone, because calcite reacted with water and dissolved. As a result of calculating the surface weathering depth for the petroglyph with the transmission characteristics of X-rays, depth of the parts in falling off and exfoliation showed a depth of about 0.5 to 1 mm, but the weathering depth in most areas was calculated to be about 3 to 4 mm. This can be proved by the contents and changes of Ca and Sr. The surface discolorations of the petroglyph are distributed with different color density, and the yellowish brown discoloration is alternated with a thin biofilm layer, showing a coverage of 79.6%. Therefore, periodic preservation managements and preventive conservation monitoring that can effectively control the physicochemical and biological damages of the Cheonjeonri petroglyph will be necessary.

• 보존과학연구
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• s.29
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• pp.255-278
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• 2008

Considering the physical quality of the wall body in this study we tried to select a replenishing that is proper for filling the cracked part of the painting wall layer and apply the natural adhesives that have traditionally been used, investigating whether it is possible to substitute those for the chemical adhesive which is used at present time. The result of this study showed the red algae adhesive was, in a weathering environment, as safe as the synthetic resin originated from the polyvinyl acetate which is used generally on the present spot, and it was concluded that although the starch adhesive displayed its superiority in enhancing the strength of the earth mortar and its work disposition, it seemed proper for it to be used as a filling adhesive for the first or midterm layer because it showed a surface hardening phenomenon. And also the glue and fish glue were judged they were not qualified as a filling adhesive due to mold occurring in a environment of high moisture that is a biological problem, showing at same time a weak physical feature in a weathering environment. Therefore it would be possible to use the red algae adhesive or starch one substituting them for the original one sold on the present market, if among natural adhesives the weak points of the them were to be corrected.

• Journal of Conservation Science
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• v.27 no.1
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• pp.101-114
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• 2011

The rock-carved Buddha statue at Dosolam (Korea Treasure No. 1200) of the Seonunsa temple in Gochang is unique style sculptured on natural rock cliff of 13.0m height. The Buddha statue is composed of volcanic complex with tuff, dacitic tuff breccia, tuff bereccia and lithic tuff. Especially, the Buddha statue is characterized by hydrothermal alteration and fragmentation on the upper and lower part. As a result of damage diagnosis, exfoliation and detachment of physical weathering are high of 11.3% and 9.3%, respectively. Infrared thermography analysis, exfoliation and micro-cracks occurred in the measuring parts that have not been confirmed by naked eyes. Chemical index of alteration and weathering potential index of host rock for the Buddha statue are 55.16 to 64.01 and 6.14 to 9.92 which are represented within highly weathering degree. In surface, dark black, reddish brown and white discoloration are observed prominently in the lower. Brown discoloration 6.9% is highest. According to the P-XRF measurements, high concentration of Fe in common, in part of dark black discoloration was Mn, white and brown discoloration in part of S and Ca content were higher. Biological weathering that yellowish brown and dark gray crustoes lichenes appeared by 20.8% and 13.3%, respectively. Therefore, comprehensive deterioration rate of Buddha statue show physical damage by 21.2%, discoloration for inorganic contaminants by 10.8% and biological damage by 39.4%. Ultrasonic velocity measurement carried out of Buddha statue on the surface by 555 points. Measured value of ultrasonic velocity was about 2,273m/s(1,067 to 3,215m/s, and weathering coefficient is 0.5(0.4 to 0.8) that progress on MW(moderately weathered) to HW(highly weathered) grade of rocks.

• Korean Journal of Heritage: History & Science
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• v.37
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• pp.285-307
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• 2004

Synthesize and examine petrological characteristic and geochemical characteristic by weathering formation of rock and progress of weathering laying stress on stone cultural properties of Unjusa temple of Chonnam Hwasun county site in this research. Examine closely weathering element that influence mechanical, chemical, mineralogical and physical weathering of rocks that accomplish stone cultural properties and these do quantification, wish to utilize by a basic knowledge for conservation scientific research of stone cultural properties by these result. Enforced component analysis of rock and mineralogical survey about 18 samples (pyroclastic tuff; 7, ash tuff; 4, granite ; 4, granitic gneiss; 3) all to search petrological characteristic and geochemical characteristic by weathering of Unjusa temple precinct stone cultural properties and recorded deterioration degree about each stone cultural properties observing naked eye. Major rock that constitution Unjusa temple one great geological features has strike of N30-40W and dip of 10-20NE being pyroclastic tuff. This pyroclastic tuff is ranging very extensively laying center on Unjusa temple and stone cultural properties of precinct is modeled by this pyroclastic tuff. Stone cultural propertieses of present Unjusa temple precinct are accomplishing structural imbalance with serious crack, and because weathering of rock with serious biological pollution is gone fairly, rubble break away and weathering and deterioration phenomenon such as fall off of a particle of mineral are appearing extremely. Also, a piece of iron and cement mortar of stone cultural properties everywhere are forming precipitate of reddish brown and light gray being oxidized. About these stone cultural properties, most stone cultural propertieses show SD(severe damage) to MD(moderate damage) as result that record Deterioration degree. X-ray diffraction analysis result samples of each rock are consisted of mineral of quartz, orthoclase,plagioclase, calcite, magnetite etc. Quartz and feldspar alterated extremely in a microscopic analysis, and biotite that show crystalline form of anhedral shows state that become chloritization that is secondary weathering mineral being weathered. Also, see that show iron precipitate of reddish brown to crack zone of tuff everywhere preview rock that weathering is gone deep. Tuffs that accomplish stone cultural properties of study area is illustrated to field of Subalkaline and Peraluminous, $SiO_2$(wt.%) extent of samples pyroclastic tuff 70.08-73.69, ash tuff extent of 70.26-78.42 show. In calculate Chemical Index of Alteration(CIA) and Weathering Potential Index(WPI) about major elements extent of CIA pyroclastic tuff 55.05-60.75, ash tuff 52.10-58.70, granite 49.49-51.06 granitic gneiss shows value of 53.25-67.14 and these have high value gneiss and tuffs. WPI previews that is see as thing which is illustrated being approximated in 0 lines and 0 lines low samples of tuffs and gneiss is receiving esaily weathering process as appear in CIA. As clay mineral of smectite, zeolite that is secondary weathering produce of rock as result that pick powdering of rock and clothing material of stone cultural properties observed by scanning electron micrographs (SEM). And roots of lichen and spore of hyphae that is weathering element are observed together. This rock deep organism being coating to add mechanical weathering process of stone cultural properties do, and is assumed that change the clay mineral is gone fairly in stone cultural properties with these. As the weathering of rocks is under a serious condition, the damage by the natural environment such as rain, wind, trees and the ground is accelerated. As a counter-measure, the first necessary thing is to build the ground environment about protecting water invasion by making the drainage and checking the surrounding environment. The second thing are building hardening and extirpation process that strengthens the rock, dealing biologically by reducing lichens, and sticking crevice part restoration using synthetic resin. Moreover, it is assumed to be desirable to build the protection facility that can block wind, sunlight, and rain which are the cause of the weathering, and that goes well with the surrounding environment.