• Applied Chemistry for Engineering
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• v.24 no.1
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• pp.99-103
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• 2013

An emzymatic bioanode for a glucose/oxygen biofuel cell was prepared by the sequential coating of carbon nanotube (CNT), charge transfer complex (CTC) based on tetracyanoquinodimethane (TCNQ) and tetrathiafulvalene (TTF), glucose oxidase (GOx), and polyion complex (mixture of poly-L-lysine hydrobromide and poly (sodium 4-styrenesulfonate)) on a glassy carbon electrode. A biocathode was also prepared by the sequential coating of CNT, bilirubin oxidase (BOD), 2,2'-Azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS), and polyion complex. The effect of CNT and CTC on the electrochemical performance was investigated. The biofuel cell exhibited a promising performance with maximum power densities of 3.6, 10.1, and $46.5{\mu}W/cm^2$ at 5, 20, and 200 mM of glucose concentration, respectively. The result indicates that the biofuel cell architecture prepared in this study can be used in the development of biofuel cells and biosensors.

• Bulletin of the Korean Chemical Society
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• v.35 no.9
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• pp.2803-2808
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• 2014

High potential and fast electron transfer of a cathode mediator are significant factors for improving the performance of biofuel cells. This paper reports the first synthesis of a cathode redox polymer that is a coordination complex of poly (acrylic acid-vinylpyridine-acryl amide) (PAA-PVP-PAA) and [Os(4,4'-dicarboxylic acid-2,2'-bipyridine)$_2Cl_2]^{/+}$ ($E^{\circ}=0.48V$ versus Ag/AgCl). Bilirubin oxidase can be easily incorporated into this polymer matrix, which carried out the four-electron oxygen under typical physiological conditions (pH 7.2, 0.14 M NaCl, and $37^{\circ}C$). This new polymer showed an approximately 0.1 V higher redox potential than existing cathode mediators such as PAA-PVI-$[Os(dCl-bpy)_2Cl]^{+/2+}$. In addition, we suggest increasing the polymer solubility with two hydrophilic groups present in the polymer skeleton to further improve fast electron transfer within the active sites of the enzyme. The maximum power density achieved was 60% higher than that of PAA-PVI-$[Os(dCl-bpy)_2Cl]^{+/2+}$. Furthermore, high current density and electrode stability were confirmed for this osmium polymer, which makes it a promising candidate for high-efficiency biofuel cells.

• New & Renewable Energy
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• v.9 no.1
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• pp.33-43
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• 2013

The objective of this paper is to provide a review on the latest development on the main initiative and approaches for the sustainability criteria for biofuels. A large number of national and international initiative lately experienced rapid development in the review of the biofuels targets announced in the European Union (EU), United States (US) and other countries worldwide. The global biofuel targets are likely to have a strong impact on land use and agricultural markets. Although biofuels production provides new options for using agricultural crops, there are environmental, social and economic concerns associated with biofuel production. The diversity of feedstock, large number of biofuels pathway an their complexity lead to a high uncertainty over the greenhouse gas (GHG) performances of biofuels, in terms of GHG emission reductions compared to the fossil fuels, expecially if land use change is involved. This paper describes an overview of current status of ongoing certification initiative in Europe and worldwide for biofuels sustainability. It also provides mandatory requirements as part of an sustainability scheme in EU, United Kingdom, US and international approaches and should be reviewed to introduce based on global trends in Korea.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.4
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• pp.386-403
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• 2016

Biofuels produced from biomass can be substituted for petroleum fuels due to GHG reduction, sustainability and environmental friendly. The process technologies that convert biomass into biofuels are varied and depend on the feedstocks. Microalgae are considered to be one of the most promising alternative source to the conventional feedstocks for biofuel. Microalgae can be converted to biodiesel, bioethanol, biogas and biojet fuel via thermolchemical and biochemical production technologies. This reviews discusses recent advance in understanding the effects of the characteristics of various processes on the production of biofuels using microalgae. The performances of microalgae based biofuel are compared.

• Journal of Marine Bioscience and Biotechnology
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• v.6 no.1
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• pp.8-16
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• 2014

Macroalgae has been strongly touted as an alternative biomass for biofuel production due to its higher photosynthetic efficiency, carbon fixation rate, and growth rate compared to conventional cellulosic plants. However, its unique carbohydrate composition and structure limits the utilization efficiency by conventional microorganisms, resulting in reduced growth rates and lower productivity. Nevertheless, recent studies have shown that it is possible to enable microorganisms to utilize various sugars from seaweeds and to produce some energy chemicals such as methane, ethanol, etc. This paper introduces the basic information on macroalgae and the overall conversion process from harvest to production of biofuels. Especially, we will review the successful efforts on microbial engineering through metabolic engineering and synthetic biology to utilize carbon sources from red and brown seaweed.

• Feed Journal
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• v.5 no.6 s.46
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• pp.60-64
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• 2007

석유의 매장량은 한정되어있고 석유에 대한 수요량은 지속적으로 증대됨에 따라 국제원유가격은 끝없이 치솟고 있다. 아울러 석유를 비롯한 화석연료는 지구온난화를 가속시키고 있어 대체에너지의 개발에 세계가 관심과 노력을 경주하고 있다. 세계최대의 석유소비국인 미국에서는 지속적 재생이 가능하고 온실가스발생이 적은 biofuel의 생산에 박차를 가하고 있는데 특히 옥수수를 이용한 에탄올 생산을 지속적으로 증대시켜 화석연료의 사용량을 줄이겠다는 원대한 계획을 Bush대통령이 직접 진두지휘하고 있다. 이러한 정책의 결과로 이미 국제 옥수수가격은 폭등하고 있다. 옥수수가 에탄올 생산에 사용되는 비중이 높아짐에 따라 사료용 옥수수 가격의 지속적인 상승이 예상되는 한편 부산물로 생산되는 옥수수주정박(DDGS; distiller's dried grains with solubles) 공급량의 지속적인 증가도 예상된다. 이러한 대세가 원료수입 의존도가 높은 한국의 사료산업과 축산업계에 미치는 충격을 최소화 하기 위해서는 대체사료자원의 개발과 DDGS의 활용에 관한 관심과 연구가 그 어느때 보다 더욱 절실하게 요망된다. 차제에 DDGS에 대한 이해와 사료적가치평가 및 활용에 보탬이 되고자 앞으로 biofuel과 DDGS산업개황, DDSG의 물리화학적 특성, 영양성분 및 품질변이, 축종별 사용방안, DDGS의 상대적 가치, 구매요령 등에 대하여 약 10회에 걸쳐 연재로 소개하고자 한다.

• 사료
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• s.30
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• pp.67-73
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• 2007

• Proceedings of the Zoological Society Korea Conference
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• 2000.10a
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• pp.64.2-65
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• 2000

No Abstract, See Full Text

• Journal of the Korean Wood Science and Technology
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• v.46 no.5
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• pp.577-596
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• 2018

ASEAN countries consist of vast coastal areas and thousands of islands that are vulnerable to the effects of climate change on sea level rise. It is believed that this will play an important role in reducing greenhouse gas emissions globally in order to minimize the damage suffered by ASEAN countries. To overcome this issue, biofuels have been used to minimize the impact on the environment by replacing fossil fuels and to reduce greenhouse gas emissions. In those cases of United States, Brazil and Europe, where biofuels are highly utilized, research, development and investment in this field have been actively conducted in the past. In ASEAN countries, however, it has not been a long time since the biofuel policies were established. To overcome this problem, we investigated the renewable fuel policy in the United States, Brazil and the European Union. Based on this, we suggested the utilization plan and prospect of biofuel policy in ASEAN countries.

• Journal of Korean Society on Water Environment
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• v.28 no.6
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• pp.796-803
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• 2012

Potential feasibility of nutrients removal and biofuel production with microalgae was evaluated in batch culture. Distribution of microalgae in fresh water including reservoir and river was investigated to search for the species with high content of lipid that could converted into biofuel. Green algae, Chlorella and Scenedesmus sp., these are known as species containing high lipid content for biodiesel production, were observed in both summer and autumn season. However another highly lipid-containing species, botryococcus sp. was not observed in this study. In mixed culture of microalgae using synthesized wastewater medium, green algae were found to be dominant, comparing to other species of diatoms and blue-green algae. And microalgae were also capable of removing nitrogen and phosphorus in batch experiments. During the culture period of 14 days, removal efficiencies of nitrate and phosphorus were 30% and 82%, respectively. Furthermore, content of the intracellular lipid extracted from algae cell was as favorable as 12-30% in the mixed culture where Scenedesmus and Chlorella sp. were dominant. Therefore the mixed culture of microalgae could be applied to biofuel production and tertiary wastewater treatment, even though there are economic barriers to overcome.