• Journal of Energy Engineering
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• v.24 no.1
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• pp.132-136
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• 2015

The objective of this study is to investigate the effect of biodiesel blending on spray and combustion characteristics. In order to this, blended fuels containing 0, 5, 20, 50, 100% biodiesel in weight fraction was injected via common rail to constant volume combustion chamber. As a result, spray cone angle decreased and the Sauter mean diameter increased because of the higher dynamic viscosity and density of biodiesel, however, it does not seemed that spray penetration was affected by these factors considerably. In the combustion experiment, ignition delay of biodiesel was shorter than that of diesel due to higher cetane number. And the peak value of heat release rate increased and the end of combustion was advanced owing to higher combustion efficiency cause by the characteristic of oxygenated fuel.

• Journal of the Korean Applied Science and Technology
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• v.35 no.4
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• pp.1013-1030
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• 2018

Biodiesel is a fuel produced in the form of a fatty acid methyl ester by using raw materials such as animal fat, vegetable oil and its by-products, and is being seen as a biofuel that can replace petroleum energy. However unsaturated fatty acid methyl esters in biodiesel causes to oxidize during storage and distribution, resulting in poor fuel quality and corrosion of vehicle engine components. In this study, the influence of quality and oxidation characteristics of biodiesel on the oxidation stability is investigated and the evaluation method related it is described. We also propose a method to improve the drawback of oxidation stability in biodiesel.

• Tribology and Lubricants
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• v.34 no.4
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• pp.160-167
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• 2018

Vegetable oils can contribute to the goal of energy independence and security owing to their naturally renewable resources. One of the representative vegetable oils is biodiesel, which is being used in domestic and European markets as a blended fuel with automotive diesel. Vegetable oils are promising candidates as base fluids to replace petroleum lubricants because of their excellent lubricity and biodegradability. We prepared biodiesel with a purity of 99.9% via the esterification of waste cooking oil. Blended biodiesel and Petro-lube base oil were mixed to produce five types of mixed lubricating oil. We analyzed the various characteristics of the blended biodiesel with Petro-lube base oil for different blending ratios. The lubricity of the vegetable lubricant improves as the content of biodiesel increases. In addition, since zinc dialkyldithiophosphates (ZnDTPs) are widely used as multifunctional additives in petroleum-based lubricants, we optimized the blending ratio for lubricity, oxidation stability, and shear stability by adding ZnDTP as a performance additive to improve the biodiesel properties, such as oxidation stability and hydrolysis. The optimized lubricants improve by approximately 25% in lubricity and by 20 times in oxidation stability and shear stability after the addition of ZnDTP.

• Tribology and Lubricants
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• v.32 no.3
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• pp.95-100
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• 2016

As an alternative fuel, biodiesel has excellent lubricating property. Previously, our research group reported that the properties of biodiesels depended on their composed molecular structure. In this study, we investigate lubricity and the mechanism of lubricity improvement of synthesized biodiesel molecules. We synthesize four types of biodiesel components from fatty acid via fisher esterification and soybean biodiesel from soybean oil via transesterification in high yield (92-96%). We analyze the lubricity of the five 5 types of biodiesel using HFRR (high frequency reciprocating rig). We estimate that the mechanism of lubricity is relevant to the molecular structure and structure conversion of biodiesel. The test results indicate that the longer the length of molecules and the higher the content of olefin, the better the lubricity of the biodiesel molecules. However, the wear scar size of the first test samples’ do not show a regular pattern with the wear scar size of the second test samples’. Moreover, we investigated the structure conversion of the biodiesels by using GC-MS for the recovered biodiesel samples from the HFRR test. However, we do not detect structure conversion. Thus, we conclude that the lubricity of biodiesel depends on how effectively solid adsorption and boundary lubrication occurs based on the size of the molecule and the content of olefin in the molecule. In addition, HFRR test condition in not sufficient for Diels-Alder cyclization of biodiesel components.

• KSBB Journal
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• v.25 no.2
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• pp.109-115
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• 2010

The demand of biodiesel that is a renewable, alternative fuel for fossil-based petrodiesel seems to keep increasing. Exploiting lipids of microalgae as a raw material for biodiesel is already technically feasible. To realize economical production of microalgal biodiesel, several factors or strategies should be addressed and improved. Especially, researches on improvement of lipid synthesis by genetic or metabolic engineering are now in early stage, and prospects of this field are bright, requiring concerns and interests of many researchers to put practical use of microalgal biodiesel forward.

• KSBB Journal
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• v.17 no.4
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• pp.396-402
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• 2002

Biodiesel has attracted considerable attention during the past decade as a biodegradable, nontoxic, and renewable fuel, Several processes for the production of biodiesel have been developed, among which transesterification under alkali-catalysis gives high level yield of methyl esters in short reaction times. In this research, response surface method was applied to optimize the transesterification reaction under alkali-catalysis. It was found that reaction temperature, reaction time, and agitation rate of reactor had profound effects among the seven variables affecting on biodiesel conversion. The optimal temperature, reaction time, and agitation speed were 67$^{\circ}C$, 68 minutes, and 94 rpm, respectively. Under the optimal conditions, the experimental value of biodiesel conversion was 99.7%.

• New & Renewable Energy
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• v.8 no.4
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• pp.30-37
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• 2012

Biodiesel was produced by "transesterification" of vegetable oils and animal fats as an alternative to petroleum diesel. The research analysed the fuel characteristics of biodiesel, the yield of by-products and biodiesel, using several vegetable oils - rapeseed oil, camellia oil, peanut oil, sesame oil, perilla oil, palm oil, olive oil, soybean oil, sunflower oil and animal fats such as lard, tallow, and chicken fat. The results showed the yields of biodiesel made from the vegetable oils and animal fats were $90.8{\pm}1.4{\sim}96.4{\pm}0.9%$ and $84.9{\pm}1.1{\sim}89.6{\pm}1.5%$ respectively. Production rates and oxidation characteristics were different depending on the fats applied.

• Applied Chemistry for Engineering
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• v.33 no.2
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• pp.222-228
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• 2022

As a possible feedstock for biodiesel, the marine green alga Tetraselmis sp. was cultivated under different conditions of phototrophic, mixotrophic and heterotrophic cultures. Glycerol, a byproduct from biodiesel production process, was used as the carbon source of mixotrophic and heterotrophic culture. The effects of glycerol supply and nitrate-repletion were compared for different trophic conditions. Mixotrophic cultivation exhibited higher biomass productivity than that of phototrophic and heterotrophic cultivation. Maximum lipid productivity of 55.5 mg L^-1 d^-1 was obtained in the mixotrophic culture with 5 g L^-1 of glycerol and 8.8 mM of nitrate due to the enhancement of both biomass and lipid accumulation. The major fatty acid methyl esters (FAME) in the produced biodiesel were palmitic acid (C16:0), oleic acid (C18:1), linoleic acid (C18:2), and linolenic acid (C18:3). The degree of unsaturation was affected by different culture conditions. The biodiesel properties predicted by correlation equations based on the FAME profiles mostly complied with the specifications from the US, Europe and Korea, with the exception of the cold-filter plugging point (CFPP) criterion of Korea.

• Journal of Advanced Marine Engineering and Technology
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• v.37 no.7
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• pp.685-693
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• 2013

The biodiesel used as an alternative fuel for diesel engines is well- known, however the price of the bio-diesel is still higher than conventional diesel oil (DO) by 10% to 15% depending on a kind of bio-oil and a country producing the bio-diesel. One of idea to reduce the price of bio-diesel is to use the pure bio-oil as fuel for marine diesel engines, because to use the pure bio-oil as fuel without the esteritification process can reduce the price of bio-fuel. At present time, some experts in some countries who have been carrying out experiments on the use of pure bio-oil produced from rape seeds, sunflower seeds... as fuel for marine diesel engines have achieved important results. In recent years, at Vietnam Maritime University we also have been using the pure palm oil and its blended fuel (Palm oil and DO) as fuel for marine diesel engines in laboratory and on board of ships. The blended fuel is a mixing fuel of the pure palm oil and diesel oil with content of pure palm oil by 5%, 10%, 15%, 20% and 35%. In this paper, we would like to present some results from our experiments to investigate the impacts of using the palm oil and its blended fuel on the important technical features of the fuel supply system of marine diesel engines such as the fuel supply amount for one cycle, fuel supplying pressure, ignition delay time and so on. The results from the research will be good fundamental parameters to support proper operation of marine diesel engines using bio-oil and blended fuels as alternative fuel in near future.

• Applied Chemistry for Engineering
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• v.19 no.2
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• pp.137-144
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• 2008

In these days, there has been increased focus on global warming and the exhaustion of resources caused by the heavy consumption of fossil resources. In order to resolve these problems, biomass is increasingly gaining international attention as a source of renewable energy. Biodiesel fuel produced by the transesterification of vegetable oils and animal fats is expected to be one of the eco-friendly biomass based alternatives to petrodiesel. This article reviews some of the research for effective of biodiesel production.