• 제목/요약/키워드: Bio-solar energy

검색결과 97건 처리시간 0.026초

Novel Water-Soluble Polyfluorenes as an Interfacial layer leading to Cathodes-Independent High Performance of Organic Solar Cells

  • 오승환;심희상;박동원;정연길;이재광;문승현;김동유
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
    • /
    • pp.394-394
    • /
    • 2009
  • Water solubility of conjugated polymers may offer many applications. Potential applications of water-soluble conjugated polymers include the polymer light-emitting diode and new materials for nano and micro hollow-capsules, and bio- or chemo-sensors. We synthesized neutral polyfluorenes containing bromo-alkyl groups by the palladium catalyzed Suzuki coupling reaction. Bromo-alkyl side groups in neutral polyfluorenes were quaternized by tri-methyl amine solution. The electrochemical and optical properties of water-soluble conjugated polymers are discussed. This novel synthesized water-soluble conjugated polymers were used as a interfacial dipole layer between active layer and metal cathode in polymer solar cell for enhancement of open-circuit voltage (Voc), which is one of the most critical factors in determining device characteristics. We also investigated the device performance of polymer solar cell with different metal cathode such as Al, Ag, Au and Cu. In polymer solar cell, novel cationic water-soluble conjugated polymers were inserted between active layer and high-work function cathode (Al, Ag, Au and Cu).

  • PDF

온실의 잉여 태양에너지 회수용 FCU 소요대수 검토 (Estimation of the Required Number of Fan Coil Unit for Surplus Solar Energy Recovery of Greenhouse)

  • 윤성욱;최만권;김하늘;강동현;이시영;손진관;윤용철
    • 생물환경조절학회지
    • /
    • 제25권2호
    • /
    • pp.83-88
    • /
    • 2016
  • 본 연구에서는 이미 보고된 잉여 태양에너지 관련 연구결과와 현재 현장에 설치되어 있는 냉난방용 FCU 현황을 개략적으로 검토한 후, 잉여 태양에너지 회수에 필요한 FCU의 소요대수 결정 방법을 개략적으로 제시하여 앞으로 이 분야의 연구자 및 기술자들에게 기조자료를 제시할 목적으로 연구를 수행하였다. 실험기간 동안 최대, 평균 및 최저 외기온은 각각 $28.2^{\circ}C$, $4.4^{\circ}C$$-11.5^{\circ}C$정도였다. 온실 밖의 수평면 일사량은 $0.8{\sim}20.5MJ{\cdot}m^{-2}$로 정도의 범위였으며, 평균 및 총 일사량은 $10.8MJ{\cdot}m^{-2}$$1,187.5MJ{\cdot}m^{-2}$으로 나타났다. 그리고 주간동안 온실 내의 평균기온과 상대습도는 각각 18.8~45.5 및 53.5~77.5%정도였다. 실험기간 동안 온실로부터 회수한 총 잉여 태양에너지는 6,613.4MJ정도로서 총 난방에너지인 98,600.2MJ 약 6.7%정도를 보충할 수 있을 것으로 나타났다. 또한 사양이 유사한 FCU를 사용하지만, 난방을 위하여 설치되는 FCU의 대수는 제각각 다른 것을 알 수 있었고, 좀 더 효율적이고 경제적인 관점에서 설치높이, 방향 및 설치간격, 적정 대수에 대한 연구가 이루어져야 할 것으로 판단된다. 잉여 태양에너지 회수용 FCU의 적정 소요 대수는 FCU를 통과하는 공기의 질량 및 순환유량을 기준으로 각각 8.4~10.9대 및 6.1~8.0대 정도이었다. 여기에 계산방법이나 FCU의 효율 및 사용 환경 등 위험률을 고려하면, 결국 9대 전후(약 $24m^3$당 1대 정도)를 설치하면 될 것으로 판단되었다.

시설유형별 재배방식이 풋고추 생육과 수량에 미치는 영향 (Effect of Cultivation Type in Different Greenhouses on Growth and Yield of Green Pepper (Capsicum annuum))

  • Hee Chun;Kyung Je Kim;Young Hoe Woo
    • 생물환경조절학회지
    • /
    • 제10권4호
    • /
    • pp.225-231
    • /
    • 2001
  • This study was conducted to examine effect of different environment conditions in glass, PC, PET and PE greenhouses controlled by different environment control systems on the growth of green pepper. Light transmittance of 64.7% in the glass greenhouse was the highest among different green-houses. Air temperature was the highest in the glass greenhouse when ventilators were closed, and was the highest in the PE greenhouse when ventilators were open. Air relative humidity was the highest in the PE greenhouse during 24 hours. The amount of solar energy accumulated in soil was the greatest in the glass greenhouse and this energy released during the night escaped through covering materials. Latent heat and solar energy affected air temperature increased in greenhouses. The air temperature of glass greenhouse was 27.5$^{\circ}C$ at 11 O clock, which was the highest air temperature among the all greenhouse types. Clear differences were observed in leaf area and plant height at 30 days after transplanting. Days to first flowering was the shortest in the glass greenhouse with 72.7 days. Flower shedding was the greatest in the PE greenhouse with 12.6%. Days to fruit harvesting was the shortest in the glass greenhouse with 14.3 days. Fruit quality, such as fruit length, fruit diameter, fruit flesh thickness, and vitamin C content, was the best in the glass greenhouse. Percent marketable fruits was the highest with 95.3% when the pepper was grown hydroponically in the glass greenhouse.

  • PDF

태양에너지 하베스팅을 위한 자가발전 아두이노 시스템의 설계 및 동작 (Design and Operation of Self-Powered Arduino System for Solar Energy Harvesting)

  • 윤일평;조승명;안지용;오석진;민경식
    • 전기전자학회논문지
    • /
    • 제26권3호
    • /
    • pp.483-487
    • /
    • 2022
  • 본 논문에서는 태양에너지 하베스팅을 위한 자가발전 아두이노 시스템을 설계하고 이의 동작을 설명한다. 이를 위해서 아두이노 시스템이 시시각각 변하는 태양에너지의 양을 센싱하고 이에 따라서 active mode와 sleep mode의 동작 시간의 비율을 스스로 조정해서 주어진 태양 빛의 세기에 대해서 최적으로 동작할 수 있는 동작 조건을 스스로 찾아가는 방법을 설명하고 이의 동작을 검증한다. 본 논문에서 개발한 active mode와 sleep mode의 동작 시간의 비율의 자가 조절을 통해서 태양 빛의 세기가 충분히 강할 경우에는 아두이노 시스템이 active mode로 지속적으로 구동되고, 태양광으로부터 전력을 충분히 공급받을 수 없는 경우 sleep mode를 사용하여 전력 소모를 최소화한다. 그 결과 active mode를 지속적으로 구동하는 것에 비해 sleep mode를 사용하는 경우 전력 소모를 최대 81.7% 줄여 에너지 소비를 최소화할 수 있다는 것을 알 수 있다. 또한 빛의 세기가 중간 수준일 때에는 active mode와 sleep mode의 비율을 빛의 세기에 맞게 적정하게 배분하여 동작하게 한다. 본 논문에서 제안한, 스스로 active mode와 sleep mode의 동작 시간 비율을 조절하는 방법은 특히 높은 전력 소비 효율 특성이 필요한 웨어러블 및 바이오-헬스용 자가발전 시스템을 에너지 효율적으로 동작시킬 때에 도움이 될 것으로 생각된다.

에너지 하베스팅을 위한 쿼드로터의 퍼칭 메커니즘 연구 (A Perching Mechanism of a Quadrotor for Energy Harvesting)

  • 최홍철;신내호
    • 로봇학회논문지
    • /
    • 제13권3호
    • /
    • pp.198-204
    • /
    • 2018
  • Quadrotor with limited flight time due to battery level can have the extended mission life by applying energy harvesting technology. Bio-inspiration from the birds' locomotion of flight and perch-and-stare can make energy consumption efficient, and energy harvesting technology can generate energy. In order to charge the battery with solar power, the drones are required to be in a position without shade. In the mountainous terrain, a novel mechanism is required in order to be located stably at the top of the tree or the inclined rock. In this study, we propose an analysis of the origami structure and the concept design of the perching mechanism with two stable equilibrium states. The origami structure composed of compliant material can be applied to the perching mechanism that can be locked passively. Moreover, the experimental results of the trajectory and perching test are discussed.

Photoelectrochemical Properties of $TiO_2$ Electrodes Prepared Using Chemical Functionalized Binders

  • 송용환;김상기;양재창;박준호;김명수;구할본;박경희
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 한국신재생에너지학회 2010년도 추계학술대회 초록집
    • /
    • pp.60.1-60.1
    • /
    • 2010
  • Chemically functionalized plant oils such as acrylated epoxidized soybean oil (AESO) and maleinized acrylated epoxidized soybean oil (MAESO) were used as new bio-based binders for $TiO_2$ electrodes of dye-sensitized solar cells (DSSC). More porous networks and larger porosities were fabricated on the $TiO_2$ films using plant oil binders due to the larger number of functionalities, in comparison with the film using polyethylene glycol (PEG). The charge-transfer resistance in the $TiO_2$ films was considerably shrunk due to the reduced impurity states. The short circuit photocurrent (Isc) and the open circuit photovoltage (Voc) of the cell using plant oil binders increased and the conversion efficiency improved significantly.

  • PDF

시설원예용 태양열 시스템의 효율적 이용과 자동화 장치 개발(3) -지중가온 방법에 따른 가온관수와 지중가온의 생육 효과- (A Development of Automation system and a way to use Solar Energy System Efficiently in. Greenhouse(3) - Effects of growth of soil heating and heating irrigation by methods of soil heating -)

  • 김진현;구건효;김태욱
    • 한국생물환경조절학회:학술대회논문집
    • /
    • 한국생물환경조절학회 1998년도 임시총회 및 학술논문발표요지
    • /
    • pp.11-18
    • /
    • 1998
  • 우리나라의 산업구조는 1970년 이후에 에너지 과다 소비형인 중공업, 석유화학 공업, 제철공업, 조선, 자동차 등이 집중 육성되었다. 그 결과로 지구 온난화의 주범인 $CO_2$는 1990년-2000년 사이에 128%의 증가(세계 1위)가 예상되어 세계 2위인 스페인에 비하여 무려 5배나 $CO_2$ 발생량을 많이 배출하고 있다. 1997년 제 3차 세계기후협약 이후에 선진국들은 한국을 강력히 규제할 것으로 보여진다. (중략)

  • PDF

태양열을 이용한 시설재배 지중변온가온의 토양 온도특성 연구(3) - 지중변온가온의 재배실용화 실증시험 - (Study on Temperature Variation by Greenhouse Soil Warming System Using Solar Thermal Energy (3) - Verification Experiment on Commercialization of Cultivation -)

  • 김진현;김태욱;송재관;나규동;하유신;김태수;김은태
    • Journal of Biosystems Engineering
    • /
    • 제36권3호
    • /
    • pp.211-216
    • /
    • 2011
  • According to the result of the first report and the second report of this study, it was expected that soil heating in a protected cultivation in winter season would affect the initial growth and development of fruit. Based on the result of previous study, we compared height, leaf number, leaf area, fruit weight, crop growth rate (CGR), features and quantity of cucumber for 3 months after planting between the soil heating group and the non-heating group. The result were summarized as follows: The height, leaf number, leaf area and fruit weight of cucumber in the soil heating group were 12.5%, 14.6%, 21.4% and 22.8% higher, respectively, compared to those of cucumber in the non-heating group. Although both the soil heating group and the non-heating group similarly showed an increasing pattern in CGR after transplanting, the soil heating group showed the increased CGR by 12.1% compared to that of the non-heating group. The quantity of cucumber in the soil heating group was about 26% higher than that of the non-heating group. It is assumed that the activation of initial growth and development of fruit in the heating group resulted in the increase of quantity.

온실 내 토양소독을 위한 지중난방시스템의 지중 열전달 특성 (Underground Heat Transfer Characteristics of the Underground Heating System for Soil Sterilization in Greenhouse)

  • 박경규;하유신;홍동혁;장승호;김진현
    • Journal of Biosystems Engineering
    • /
    • 제35권2호
    • /
    • pp.108-115
    • /
    • 2010
  • This study was conducted to estimate the optimum temperature and required time for soil sterilization when heated water was circulated through underground heating pipes in the greenhouse which solar heat was influenced to the temperature of soil during the summer day. Two different types of heating pipes were used for the experiment. One was a polyethylene pipe(XL) and the other was a corrugated ring shaped stainless steel pipe(STS). The results of the studies were summarized as follows; By measuring the thermal characteristics of the XL and STS, it was examined that the average temperature differences of the inlet and outlet were $8.5^{\circ}C$ and $13.3^{\circ}C$, the average flowrates were 15.3 L/min and 5.6 L/min, and the average radiation powers were 9.1 kW and 4.1 kW, respectively. As results of the regression analysis of underground temperatures, when average soil temperature was$35^{\circ}C$, an average water temperature was $80^{\circ}C$, and XL was used, it was estimated that the possible heat transfer distance, the required time for heat transfer and heat flux to reach the underground temperature of $60^{\circ}C$ were 300 mm, 230 hours, and $7.57kW/m^2$, respectively.

A Method for Absolute Determination of the Surface Areal Density of Functional Groups in Organic Thin Films

  • Min, Hyegeun;Son, Jin Gyeong;Kim, Jeong Won;Yu, Hyunung;Lee, Tae Geol;Moon, Dae Won
    • Bulletin of the Korean Chemical Society
    • /
    • 제35권3호
    • /
    • pp.793-797
    • /
    • 2014
  • To develop a methodology for absolute determination of the surface areal density of functional groups on organic and bio thin films, medium energy ion scattering (MEIS) spectroscopy was utilized to provide references for calibration of X-ray photoelectron spectroscopy (XPS) or Fourier transformation-infrared (FT-IR) intensities. By using the MEIS, XPS, and FT-IR techniques, we were able to analyze the organic thin film of a Ru dye compound ($C_{58}H_{86}O_8N_8S_2Ru$), which consists of one Ru atom and various stoichiometric functional groups. From the MEIS analysis, the absolute surface areal density of Ru atoms (or Ru dye molecules) was determined. The surface areal densities of stoichiometric functional groups in the Ru dye compound were used as references for the calibration of XPS and FT-IR intensities for each functional group. The complementary use of MEIS, XPS, and FT-IR to determine the absolute surface areal density of functional groups on organic and bio thin films will be useful for more reliable development of applications based on organic thin films in areas such as flexible displays, solar cells, organic sensors, biomaterials, and biochips.