• 제목/요약/키워드: Bio-reduction

검색결과 756건 처리시간 0.021초

폴리우레탄 디아크릴레이트의 미세다공성 UV코팅에 의한 PET 직물의 투습방수가공 (Breathable Waterproof Finish of PET Fabrics via Microporous UV Coating of Polyurethane Diacrylate)

  • 구광회;장진호
    • 한국염색가공학회지
    • /
    • 제22권3호
    • /
    • pp.239-245
    • /
    • 2010
  • Breathable waterproof PET fabrics were prepared by the UV coating of UV-curable polyurethaneacrylate(PUA) formulation mixed with polyethyleneglycol(PEG) as a water soluble pore former. The dispersed PEG in the UV-cured coating was extracted by warm water, which can generate individual circular pores uniformly distributed all over the coating instead of pore channels. Accordingly the moisture permeability of the microporously coated fabrics increased substantially with increasing PEG addition without significant reduction of hydrostatic pressure. Also the silicone diacrylate addition in the formulation was beneficial in increasing the hydrostatic pressure. The UV-based microporous coating can be an alternative to conventional thermal curing of solventborne polyurethane coating owing to the enhanced environment friendliness and energy saving.

다양한 유기성 폐자원을 적용한 바이오 수소 생성 연구 (Feasibility of batch anaerobic bio-hydrogen production from different organic wastes)

  • 황재훈;최정아;;전병훈
    • 신재생에너지
    • /
    • 제5권4호
    • /
    • pp.80-85
    • /
    • 2009
  • The effects of various organic wastes on anaerobic fermentative hydrogen production were studied using enriched mixed microflora in batch tests. Rotten fruit, corn powder and organic wastewater enriched with sulfate (up to 1,000 mg/L) were used for experiments. Maximum hydrogen production (547.1 mL) was observed from rotten apple with initial substrate concentration of 132.2 g COD/L. The experimental result on sulfate enriched organic wastewater indicated that hydrogen production is not adversely influenced by relatively high sulfate concentration. Residual sulfate content remained at 96-98 % after 75 hours of reaction, which showed that no major sulfate reduction was occurred at pH 5.3-5.5 in the reactor. The volatile fatty acid (VFA) fractions produced during the reaction was in the order of butyrate > acetate > propionate in all experiments. The results of this study would be useful for controlling the conditions on fermentative hydrogen production using different feedstocks.

  • PDF

Electrochemical Study of [Ni63-Se)2μ4-Se)3(dppf)3] Cluster and Its Catalytic Activity towards the Electrochemical Reduction of Carbon Dioxide

  • Park, Deog-Su;Jabbar, Md. Abdul;Park, Hyun;Lee, Hak-Myoung;Shin, Sung-Chul;Shim, Yoon-Bo
    • Bulletin of the Korean Chemical Society
    • /
    • 제28권11호
    • /
    • pp.1996-2002
    • /
    • 2007
  • The redox behavior of a [Ni6(μ3-Se)2(μ4-Se)3(Fe(η 5-C5H4P-Ph2)2)3] (= [Ni-Se-dppf], dppf = 1,1-bis(diphenylphosphino) ferrocene) cluster was studied using platinum (Pt) and glassy carbon electrodes (GCE) in nonaqueous media. The cluster showed electrochemical activity at the potential range between +1.6 and ?1.6 V. In the negative region (0 to ?1.6 V), the cluster exhibited two-step reductions. The first step was one-electron reversible, while the second step was a five-electron quasi-reversible process. On the other hand, in the positive region (0 to +1.6 V), the first step involved one-electron quasi-reversible process. The applicability of the cluster was found towards the electrocatalytic reduction of CO2 and was evaluated by experiments using rotating ring disc electrode (RRDE). RRDE experiments demonstrated that two electrons were involved in the electrocatalytic reduction of CO2 to CO at the Se-Ni-dppf-modified electrode.

중질유 연소시 유용성 유기금속화합물 연소촉진제의 Dust 저감특성 (A Study on the Reduction of Particulate Emission Using Oil Soluble Organometallic Compounds as Combustion Improver for Heavy Fuel Oil)

  • 김동찬;노남선;우제경;김진훈;이영서
    • 한국대기환경학회지
    • /
    • 제24권1호
    • /
    • pp.55-62
    • /
    • 2008
  • This study is aimed at substantially reducing the particulate matter (dust) emission during the combustion of heavy fuel in boilers by addition of combustion improver. The combustion improver used were the oil-soluble organometallic compounds that were found to be more effective than the dispersing agents that are generally used for reducing the particulate emission. The dust reduction effect was found to depend on the active materials (metals) as well as on the organic ligand part of organometallic compounds. Acetylacetonoate and naphthenate of Fe and Ca were found to be most effective for dust reduction. Addition of Fe and Ca organometallic compounds as combustion improver in concentration of 30 ppm (metal basis) to heavy fuel oil, caused dust reduction by 50 wt% to 80 wt%.

Yield Prediction of Chinese Cabbage (Brassicaceae) Using Broadband Multispectral Imagery Mounted Unmanned Aerial System in the Air and Narrowband Hyperspectral Imagery on the Ground

  • Kang, Ye Seong;Ryu, Chan Seok;Kim, Seong Heon;Jun, Sae Rom;Jang, Si Hyeong;Park, Jun Woo;Sarkar, Tapash Kumar;Song, Hye young
    • Journal of Biosystems Engineering
    • /
    • 제43권2호
    • /
    • pp.138-147
    • /
    • 2018
  • Purpose: A narrowband hyperspectral imaging sensor of high-dimensional spectral bands is advantageous for identifying the reflectance by selecting the significant spectral bands for predicting crop yield over the broadband multispectral imaging sensor for each wavelength range of the crop canopy. The images acquired by each imaging sensor were used to develop the models for predicting the Chinese cabbage yield. Methods: The models for predicting the Chinese cabbage (Brassica campestris L.) yield, with multispectral images based on unmanned aerial vehicle (UAV), were developed by simple linear regression (SLR) using vegetation indices, and forward stepwise multiple linear regression (MLR) using four spectral bands. The model with hyperspectral images based on the ground were developed using forward stepwise MLR from the significant spectral bands selected by dimension reduction methods based on a partial least squares regression (PLSR) model of high precision and accuracy. Results: The SLR model by the multispectral image cannot predict the yield well because of its low sensitivity in high fresh weight. Despite improved sensitivity in high fresh weight of the MLR model, its precision and accuracy was unsuitable for predicting the yield as its $R^2$ is 0.697, root-mean-square error (RMSE) is 1170 g/plant, relative error (RE) is 67.1%. When selecting the significant spectral bands for predicting the yield using hyperspectral images, the MLR model using four spectral bands show high precision and accuracy, with 0.891 for $R^2$, 616 g/plant for the RMSE, and 35.3% for the RE. Conclusions: Little difference was observed in the precision and accuracy of the PLSR model of 0.896 for $R^2$, 576.7 g/plant for the RMSE, and 33.1% for the RE, compared with the MLR model. If the multispectral imaging sensor composed of the significant spectral bands is produced, the crop yield of a wide area can be predicted using a UAV.

Effect of γ-Aminobutyric Acid (GABA) Producing Bacteria on In vitro Rumen Fermentation, Biogenic Amine Production and Anti-oxidation Using Corn Meal as Substrate

  • Ku, Bum Seung;Mamuad, Lovelia L.;Kim, Seon-Ho;Jeong, Chang Dae;Soriano, Alvin P.;Lee, Ho-Il;Nam, Ki-Chang;Ha, Jong K.;Lee, Sang Suk
    • Asian-Australasian Journal of Animal Sciences
    • /
    • 제26권6호
    • /
    • pp.804-811
    • /
    • 2013
  • The effects and significance of ${\gamma}$-amino butyric acid (GABA) producing bacteria (GPB) on in vitro rumen fermentation and reduction of biogenic amines (histamine, methylamine, ethylamine, and tyramine) using corn meal as a substrate were determined. Ruminal samples collected from ruminally fistulated Holstein cows served as inoculum and corn was used as substrate at 2% dry matter (DM). Different inclusion rates of GPB and GABA were evaluated. After incubation, addition of GPB had no significant effect on in vitro fermentation pH and total gas production, but significantly increased the ammonia nitrogen ($NH_3$-N) concentration and reduced the total biogenic amines production (p<0.05). Furthermore, antioxidation activity was improved as indicated by the significantly higher concentration of superoxide dismutase (SOD) and glutathione peroxidase (GSH-Px) among treated samples when compared to the control (p<0.05). Additionally, 0.2% GPB was established as the optimum inclusion level. Taken together, these results suggest the potential of utilizing GPB as feed additives to improve growth performance in ruminants by reducing biogenic amines and increasing anti-oxidation.

전기응집 분리 막 생물반응기의 막 오염 저감 (Membrane fouling reduction using electro-coagulation aided membrane bio-reactor)

  • 김완규;홍성준;장인성
    • 한국산학기술학회논문지
    • /
    • 제19권8호
    • /
    • pp.105-114
    • /
    • 2018
  • 전기응집 (Electro-coagulation)을 활용한 분리 막 생물반응기 (Membrane Bio-Reactor) 공정의 막 오염 저감 현상을 확인하고 이를 해석하고자 하였다. 전기응집의 주요 운전 인자인 전류밀도와 접촉시간 변화가 활성슬러지 혼합액의 막 여과에 미치는 영향을 관찰하고 전기응집 과정에서 발생하는 수산화금속염이 막 오염에 미치는 역할에 대해 연구하였다. 전류밀도를 $10A/m^2$으로 높게 유지한 경우에는 전기응집 시간이 증가하여도 막 오염 감소 효과가 크지 않은 반면 $2.5A/m^2$의 낮은 전류밀도 하에서는 전기응집 시간이 증가하면 추가적인 막 오염 감소가 관찰되었다. 즉, 막 오염을 감소시키는 전류밀도와 접촉시간의 곱이 전체 막 오염 저감 정도를 지배하고 있음을 확인하였다. 또한 주어진 전류밀도와 인가시간에서 입도분포는 크게 변화하지 않은 것으로 나타나 콜로이드 입자와 막 오염 저감과는 큰 관련성이 없는 것으로 판단되었다. 그러나 전기응집을 통해 생성된 수산화알루미늄 (인산알루미늄)이 막 여과 과정에서 동적 막 (Dynamic Membrane)을 형성하여 막 오염 현상을 완화하는 것으로 확인되었다. 전기응집에서 발생한 수산화금속염이 막 표면에 동적 막을 형성하고 이로 인해 유입수의 입자성분이 직접 막 표면과 내부에 침적되는 것을 방해하고 동적 막에 주로 쌓이게 함으로써 막 오염이 감소된 것이다. 본 연구에서 밝힌 수산화금속염에 의한 동적 막의 역할은 전기응집을 활용한 MBR 공정의 후 막 오염 감소 메커니즘을 해석하는데 중요한 역할을 한다고 결론지을 수 있다.

반포화 순환 여과식 인공습지에 의한 도로 강우유출수의 실증처리 연구 (Demonstration Study of Half-Saturated Bio-filter Wetland with Recirculation Pump for Road Stormwater)

  • 박기수;김영철
    • 한국습지학회지
    • /
    • 제19권3호
    • /
    • pp.259-270
    • /
    • 2017
  • 본 연구는 실증규모의 반포화 순환식 인공습지에서 도로 강우유출수를 처리하여 습지의 성능분석, LID 기능 및 다른 LID-BMP 시설과의 처리효율을 비교하였다. 강우시 모니터링을 바탕으로 연구대상 습지의 저감효율을 산정한 결과 TSS 저감효율은 평균 92%, COD, TN, TP는 각각 평균 63%, 36%, 75%로 분석되었으며 다른 시설과 직접적인 비교는 불가능하지만 SA/CA 비율에 따른 오염물질 저감효율을 분석한 결과 연구대상 시설의 SA/CA 비율이 낮았음에도 불구하고 유사한 수준의 효율을 보였다. 또한, 전체 강우유출수의 18%만을 처리하여 약 70%의 오염물질을 저감할 수 있는 시설의 성능을 보였다. 연구대상 습지(합성섬유 충진)와 동일한 형태로 제작되어 직접적인 비교가 가능했던 유기성 여재를 충진한 습지와의 비교 결과 TSS, TP는 유사한 처리성능을 보였으며, COD는 유기성 여재에서 용출되는 유기물질의 영향으로 연구대상 습지에서 높은 효율을 보였으나 TN은 유기성 여재에서 자체 공급되는 유기탄소의 영향으로 유기성 여재를 충진한 습지에서 높은 효율을 나타내었다. 한편 초기 강우유출수 포착장치를 갖춘 본 연구대상 습지에서 그렇지 않은 침투도랑 습지의 성능을 비교분석한 결과 훨씬 안정적인 처리성능을 얻을 수 있었다.

SWAT모형을 이용한 RCP 기후변화 시나리오에 따른 고랭지농업유역의 최적관리기법 평가 (Assessment of Climate Change Impact on Best Management Practices of Highland Agricultural Watershed under RCP Scenarios using SWAT)

  • 장선숙;김성준
    • 한국농공학회논문집
    • /
    • 제60권4호
    • /
    • pp.123-132
    • /
    • 2018
  • The purpose of this study was to evaluate the reduction effect of non point source (NPS) pollution in Haean highland agricultural catchment ($62.8km^2$) for 13 BMP scenarios under RCP (Representative Concentration Pathway) 4.5 and 8.5 scenarios. Under the present climate condition, the BMP (best management practices) reduction efficiency of SS (suspended solid), T-N (total nitrogen), and T-P (total phosphorus) showed +25.7%, +4.2%, and +16.1% for VFS (vegetative filter strip), +0.1%, +15.6%, and +5.7% for FC (fertilizer control), and +6.3%, -2.9%, and +3.9% for RSM (rice straw mulching) respectively. In general, effective was the best for SS and T-P reductions, and the FC was the best for T-N reduction. The negative effect of T-N on RSM was induced by increase in infiltration and solute transport to baseflow. Under the future climate change scenarios, the SS, T-N, and T-P reduction efficiency showed the range of +1.9~+11.6%, -1.9~+0.2%, and +5.3~+11.9% respectively. The 3 BMPs (VFS, FC, and RSM) application in the future showed negative and little differences (-0.5~+1.6%) for SS and T-N reduction efficiencies while T-P reduction efficiency showed +0.3~+7.6% comparing with the baseline period. To achieve an increase in the reduction efficiency of future SS and T-N by +2~+10%, the combined application of more than two BMPs is necessary.