• Title/Summary/Keyword: Bio-fuel

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Comparison of Environmental Conditions and Insulation Effect between Air Inflated and Conventional Double Layer Greenhouse (공기주입 및 관행 이중피복온실의 재배환경 및 단열성능 비교)

  • Jayasekara, Shanika N.;Na, Wook H.;Owolabi, Abdulhameed B.;Lee, Jong W.;Rasheed, Adnan;Kim, Hyeon T.;Lee, Hyun W.
    • Journal of Bio-Environment Control
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    • v.27 no.1
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    • pp.46-53
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    • 2018
  • This study was conducted to determine which greenhouse provided good environmental conditions for strawberry production, and performed better at conserving energy. Temperature, RH, VPD, $CO_2$, solar radiation, yield, and fuel consumption were the parameters analyzed. The temperatures of both greenhouses were well controlled in order to provide optimal day and night temperatures for strawberry production. The air inflated double layer greenhouse had higher RH values (more than 90% at night), which led to higher disease occurrence, in comparison to the conventional double layer greenhouse. Furthermore, the air inflated double layer greenhouse had lower VPD values than the conventional double layer greenhouse. Therefore, better RH and VPD were observed in the conventional double layer greenhouse. Higher $CO_2$ concentration was observed in the air inflated double layer greenhouse while the conventional double layer greenhouse ventilated better than the air inflated greenhouse, because of its side ventilators. Moreover, higher solar radiation in the conventional double layer greenhouse resulted in higher yield, in comparison to the air inflated double layer greenhouse. Thus, we can conclude that the conventional double layer greenhouse provided a better environment for crop growth, in comparison to the air inflated double layer greenhouse. Regarding fuel consumption, the air inflated double layer greenhouse had lower fuel consumption than the conventional double layer greenhouse. Therefore, from an energy consumption point of view, we can conclude that the air inflated double layer greenhouse performed better than the conventional double layer greenhouse.

Effects of reaction conditions on composition of the organic liquid product during the deoxygenation process of palm oil (팜유(Plam Oil)의 탈산소 공정 중 운전 조건이 생성물의 조성에 미치는 영향)

  • Kim, Sungtak;Jang, Jeong Hee;Ahn, Minhwei;Kwak, Yeonsu;Han, Gi Bo;Jeong, Byung Hun;Han, Jeong Sik;Kim, Jae-Kon
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.3
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    • pp.865-875
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    • 2018
  • Selection of optimum reaction conditions during deoxygenation process of palm oil is essential factor to obtain the maximum yield of bio-jet fuel. In this context, the deoxygenation of palm oil was carried out in a fixed bed reactor with an internal diameter of 1 inch loaded with a 1 wt.% $Pt/Al_2O_3$ catalyst. The composition of the organic liquid product(OLP), which can be utilized as a transportation fuel through the upgrading process, was analyzed by a gas chromatography method. The palm oil/hydrogen ratio and hydrogen pressure in the feed affected the decarboxylation(DCB) and hydrodeoxygenation(HDO) reactions, resulting in a change in the composition of the OLP. As the reaction temperature increased, the continuous cracking reaction of the deoxygenation product was promoted and the product composition in the $C_5{\sim}C_{14}$ region was increased. Thus, the results can help to understand the characteristics of deoxidation reaction of palm oil as well as the subsequent process, hydro-upgrading, to obtain the maximum yield of bio-jet fuel.

Catalytic Fast Pyrolysis of Tulip Tree (Liriodendron) for Upgrading Bio-oil in a Bubbling Fluidized Bed Reactor

  • Ly, Hoang Vu;Kim, Jinsoo;Kim, Seung-Soo;Woo, Hee Chul;Choi, Suk Soon
    • Clean Technology
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    • v.26 no.1
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    • pp.79-87
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    • 2020
  • The bio-oil produced from the fast pyrolysis of lignocellulosic biomass contains a high amount of oxygenates, causing variation in the properties of bio-oil, such as instability, high acidity, and low heating value, reducing the quality of the bio-oil. Consequently, an upgrading process should be recommended ensuring that these bio-oils are widely used as fuel sources. Catalytic fast pyrolysis has attracted a great deal of attention as a promising method for producing upgraded bio-oil from biomass feedstock. In this study, the fast pyrolysis of tulip tree was performed in a bubbling fluidized-bed reactor under different reaction temperatures, with and without catalysts, to investigate the effects of pyrolysis temperature and catalysts on product yield and bio-oil quality. The system used silica sand, ferric oxides (Fe2O3 and Fe3O4), and H-ZSM-5 as the fluidized-bed material and nitrogen as the fluidizing medium. The liquid yield reached the highest value of 49.96 wt% at 450 ℃, using Fe2O3 catalyst, compared to 48.45 wt% for H-ZSM-5, 47.57 wt% for Fe3O4 and 49.03 wt% with sand. Catalysts rejected oxygen mostly as water and produced a lower amount of CO and CO2, but a higher amount of H2 and hydrocarbon gases. The catalytic fast pyrolysis showed a high ratio of H2/CO than sand as a bed material.

Synthesis and Lubricating Properties of Dimer Acid Derivatives Based on Used Vegetable Oil (폐식물유 기반 다이머산 유도체의 합성 및 경유의 윤활성능)

  • Lee, Sang Jun;Kim, Young-Wun;Yoo, Seung-Hyun;Kim, Nam-Kyun;Shin, Ji Hoon;Yoon, Byung-Tae
    • Applied Chemistry for Engineering
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    • v.24 no.5
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    • pp.530-536
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    • 2013
  • Vegetable oil-based dimer acid derivatives were prepared through a two-step procedure and their lubricating properties for diesel fuel were evaluated using high frequency reciprocating ring (HFRR) method to investigate wear scar diameter (WSD). Diels-Alder reaction at an elevated temperature transformed fatty acid to dimer acid, subsequently converted into dimer acid derivatives by esterification with methanol. It should be noted that the derivatives were dissolved well in diesel oil up to 1 wt%. After adding 120 ppm of the derivatives to pure diesel, the WSD significantly decreased to $300{\sim}05{\mu}m$, compared to $552{\mu}m$ of WSD in pure diesel. Dimer acid derivatives having carboxylic acid show superb in lubricating property which does not depend on the alkyl group in the derivatives.

Preparation and Characterization of the Impregnation to Porous Membranes with PVA/PSSA-MA/THS-PSA for Fuel Cell Applications (연료전지 응용을 위한 다공성막에 가교된 PVA/PSSA-MA/THS-PSA의 함침을 통한 고내구성 이온교환막의 제조 및 특성 연구)

  • Kim, Il-Hyoung;Kim, Sung-Pyo;Lee, Hak-Min;Park, Chan-Jong;Rhim, Ji-Won;Cheong, Seong-Ihl
    • Membrane Journal
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    • v.21 no.3
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    • pp.299-305
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    • 2011
  • This study deals with the preparation of polymeric electrolyte membranes having high durability for the application of fuel cells. The membranes under investigation were prepared the impregnation to porous polyethylene membranes with poly(vinyl alcohol)(PVA), poly(styrene sulfonic acid-co-maleic acid), and (PSSA-MA)3-(trihydroxysilyl)-1-propanesulfonic acid (THS-PSA). To characterize the resulting membranes, the water contents, the contact angles, FT-IR, the proton conductivity and the the modulus were measured. The proton conductivity of 30% content of THS-PSA at $55^{\circ}C$ gave excellent $1.27{\times}10^{-1}S/cm$ and the mechanical strength was improved 7 times higher up to the THS-PSA content 15%, as a result, the durability was elevated extensively.

A Study on the Reduction of Particulate Emission Using Oil Soluble Organometallic Compounds as Combustion Improver for Heavy Fuel Oil (중질유 연소시 유용성 유기금속화합물 연소촉진제의 Dust 저감특성)

  • Kim, Dong-Chan;Nho, Nam-Sun;Woo, Je-Kyung;Kim, Jin-Hoon;Lee, Young-Sea
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.1
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    • pp.55-62
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    • 2008
  • This study is aimed at substantially reducing the particulate matter (dust) emission during the combustion of heavy fuel in boilers by addition of combustion improver. The combustion improver used were the oil-soluble organometallic compounds that were found to be more effective than the dispersing agents that are generally used for reducing the particulate emission. The dust reduction effect was found to depend on the active materials (metals) as well as on the organic ligand part of organometallic compounds. Acetylacetonoate and naphthenate of Fe and Ca were found to be most effective for dust reduction. Addition of Fe and Ca organometallic compounds as combustion improver in concentration of 30 ppm (metal basis) to heavy fuel oil, caused dust reduction by 50 wt% to 80 wt%.

The Overall Performance Improvement of Microbial Fuel Cells Connected in Series with Dairy Wastewater Treatment

  • Choudhury, Payel;Bhunia, Biswanath;Bandyopadhyay, Tarun Kanti;Ray, Rup Narayan
    • Journal of Electrochemical Science and Technology
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    • v.12 no.1
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    • pp.101-111
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    • 2021
  • To improve the potential of single chamber microbial fuel cells (SCMFCs) as an applicable technology, the main challenge is a practical application for larger scales bioenergy production from potent exoelectrogenic microorganism with real dairy wastewater. To increase power generation, three individual MFCs were together operated in series best under the fed batch condition for 15 days. The volume of MFC 1 and MFC 2 is "300 mL" and MFC 3 is "500 mL" respectively. The individual MFCs 1, MFC 2 and MFC 3 gives an open circuit voltage of 0.60 V, 0.66 V and 0.55 V and result in total working voltage when connected in series of 1.745V, which lead an LED to glow. The maximum power densities obtained from MFC 1, MFC 2 and MFC 3 are 62 mW/㎡, 50 mW/㎡ and 45 mW/㎡ (normalized to the surface area of the anodic electrode, which was 50 ㎠ for all three MFCs), and corresponding to current densities of 141 mA/㎡, 155 mA/㎡ and 123 mA/㎡, respectively. Therefore this work suggests the cheapest way to connect microbial fuel cells in series to gain power with the lowest operating cost and chemical oxygen demand (COD) removal.

Feasibility Study of Using Wood Pyrolysis Oil in a Diesel Engine (목질 열분해유의 디젤 엔진 적용성 연구)

  • Lee, Seok-Hwan;Park, Jun-Hyuk;Lim, Gi-Hun;Choi, Young;Woo, Se-Jong;Kang, Kern-Yong
    • Journal of ILASS-Korea
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    • v.16 no.3
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    • pp.152-158
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    • 2011
  • Fast pyrolysis of biomass is one of the most promising technologies for converting biomass to liquid fuels. The pyrolysis oil, also known as the bio crude oil (BCO), have been regarded as an alternative fuel for petroleum fuels to be used in diesel engine. However, the use of BCO in diesel engine requires modifications due to low energy density, high water contents, low acidity, and high viscosity of the BCO. One of the easiest way to adopt BCO to diesel engine without modifications is the use of BCO/diesel emulsions. In this study, a diesel engine operated with diesel, bio diesel (BD), and BCO/diesel emulsion was experimentally investigated. Performance and emission characteristics of a diesel engine fuelled by BCO/diesel emulsion were examined. Results showed that stable engine operation was possible with emulsion and engine output power was comparable to diesel and bio diesel operation. Long term validation of adopting BCO in diesel engine is still needed because the oil is acid, with consequent problems of corrosion especially in the injection system.

A Study on the Evaluation of Surface Dose Rate of New Disposal Containers Though the Activation Evaluation of Bio-Shield Concrete Waste From Kori Unit 1

  • Kang, Gi-Woong;Kim, Rin-Ah;Do, Ho-Seok;Kim, Tae-Man;Cho, Chun-Hyung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.1
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    • pp.133-140
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    • 2021
  • This study evaluates the radioactivity of concrete waste that occurs due to large amounts of decommissioned nuclear wastes and then determines the surface dose rate when the waste is packaged in a disposal container. The radiation assessment was conducted under the presumption that impurities included in the bio-shielded concrete contain the highest amount of radioactivity among all the concrete wastes. Neutron flux was applied using the simplified model approach in a sample containing the most Co and Eu impurities, and a maximum of 9.8×104 Bq·g-1 60Co and 2.63×105 Bq·g-1 152Eu was determined. Subsequently, the surface dose rate of the container was measured assuming that the bio-shield concrete waste would be packaged in a newly developed disposal container. Results showed that most of the concrete wastes with a depth of 20 cm or higher from the concrete surface was found to have less than 1.8 mSv·hr-1 in the surface dose of the new-type disposal container. Hence, when bio-shielded concrete wastes, having the highest radioactivity, is disposed in the new disposal container, it satisfies the limit of the surface dose rate (i.e., 2 mSv·hr-1) as per global standards.

Growth Characteristics of Polyporales Mushrooms for the Mycelial Mat Formation

  • Bae, Bin;Kim, Minseek;Kim, Sinil;Ro, Hyeon-Su
    • Mycobiology
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    • v.49 no.3
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    • pp.280-284
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    • 2021
  • Mushroom strains of Polyporales from the genera Coriolus, Trametes, Pycnoporus, Ganoderma, and Formitella were explored in terms of mycelial growth characteristics for the application of mushroom mycelia as alternative sources of materials replacing fossil fuel-based materials. Among the 64 strains of Polyporales, G. lucidum LBS5496GL was selected as the best candidate because it showed fast mycelial growth with high mycelial strength in both the sawdust-based solid medium and the potato dextrose liquid plate medium. Some of the Polyporales in this study have shown good mycelial growth, however, they mostly formed mycelial mat of weak physical strength. The higher physical strength of mycelial mat by G. lucidum LBS5496GL was attributed to its thick hyphae with the diameter of 13 mm as revealed by scanning electron microscopic analysis whereas the hyphae of others exhibited less than 2 mm. Glycerol and skim milk supported the best mycelial growth of LBS5496GL as a carbon and a nitrogen source, respectively.