• Journal of Plant Biotechnology
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• v.36 no.2
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• pp.97-105
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• 2009

Seed storage lipids of plants, essential for seed germination as energy supplier, have been used for humankind and animal as nutrition sources. Fatty acids of vegetable oils have the characters appropriate for industry based on their chain length, the position and the number of double bonds. So they are used as raw materials for lubricants, cosmetics, soaps, paints and plastics or as energy source such as bio-diesel. However, there is a limit that applies vegetable oils from typical oil crops for industrial uses, mainly because of the mixture of five common fatty acids. Therefore, identification of unusual fatty acids for industrial uses from diverse plant resources and metabolic engineering to produce unusual fatty acids have been carried out in Arabidopsis as a model for the study of oilseed biology. Here, we discuss the unusual fatty acids for industrial uses, the genes synthesizing them in lipid metabolism, and the current limits in production of transgenic plants accumulating unusual fatty acid in their seeds. In addition, we describe our work on metabolic engineering of Brassica napus for the production of the unusual fatty acid ricinoleic acid in the seed, because of its industrial uses.

• Journal of Biosystems Engineering
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• v.34 no.3
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• pp.147-154
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• 2009

Suitable rapeseed cultivation techniques of domestic agriculture are essential for stable security, supply and demand of rapeseed. This research developed a rapeseed seeder for bio-diesel and analyzed the seeding performance improving an existent granule fertilizer applicator. The relational expression of metering groove size and discharge rate per time displayed high correlation with a coefficient of determination of 0.988. Also, the scattering types were analyzed by forwarding speed and discharge rate. Validity application width was decided as 7.0 m by analyzing application uniformity at application widths of 7.6 m, 6.6 m, 5.6 m. All average coefficients of variation values were less than 20%. The best application uniformity was obtained in the condition of a work speed of 1.3 m/s and a sowing rate of 19.0 g/s. It was better average coefficient of variation values under 10% at superposition application of rapeseed seeder. Also, scattering amount rates of right and left were within 0.89${\sim}$1.0.

• Journal of Biosystems Engineering
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• v.34 no.1
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• pp.15-20
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• 2009

This study was conducted to develop a moisture sensor for rapeseed, a bio-diesel material. A typical rapeseed, SUNMANG, was used as a raw material. The rapeseed moisture content sensor consists of three components, such as upper and bottom electrodes, a test material dish, and a fixing housing. To evaluate the performance, a data acquisition system was equipped with the rapeseed moisture sensor, computer, printer, and main board. The findings of this study were: 1) the rapeseed moisture content was inversely proportional to electric resistance, and 2) values of electric resistance were recorded in a range of $10{\sim}100\;M{\Omega}$, depending upon a change of the moisture content. The determination of coefficient ($R^2$) and standard error between rapeseed moisture content and electric resistance were 0.9921 and ${\pm}0.289$, which indicated a highly correlative relationship. The response of rapeseed moisture sensor to temperature change was also observed for further performance test. Satisfying results were obtained, such as the determination of coefficient ($R^2$) of 0.9918, predicted standard error of ${\pm}0.373%$, deviation of 0.103%, measurement error of $0.14{\sim}0.48%$, standard deviation of $0.01{\sim}0.22%$, and measurement time of 28.3 s per point, respectively.

• Journal of Biosystems Engineering
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• v.34 no.1
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• pp.21-29
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• 2009

A rapeseed reaping equipment attachable to a conventional combine was developed in order to harvest rapeseed for bio-diesel materials. This study was carried out to measure the harvest feasibility of a prototype combine in rapeseed fields. Grain, stem and pod flow rate, grain qualities (whole kernel, damaged kernel, unhulled kernel, material-other-than-grain) and grain loss rates (header, threshing, separation) were investigated in each field test. As the result of the fold test, the average grain flow rates of SUNMANG and MS varieties showed 1,430 kg/h and 2,038 kg/h, respectively. The average stem and pod flow rates showed 3,443 kg/h and 6,596 kg/h, respectively. In each working speed, the average whole kernel rate and the material-other-than-grain showed 99.9% and below 0.08%, respectively. In the average grain loss, the rates showed 5.66% in case of SUNMANG and 5.94% in MS. Header loss was higher than other parts for SUNMANG. However, threshing loss was relatively higher than other parts for MS. Header loss rate due to side cutter knifes, however, was not so high when compared with a grain loss due to the cutter bar. Effective field capacity and field efficiency of the prototype combine showed 0.389 ha/h and 44%, respectively. Comparison of customary combine with the prototype combine through field test demonstrated that the header loss was reduced by 69.3% when the prototype combine was used.

• Clean Technology
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• v.18 no.1
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• pp.102-110
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• 2012

In this study, the production of bio-diesel from animal oil by esterification and trans-esterification was investigated. There were three different extraction methods for oil extraction from raw animal fat. Heterogeneous catalysts such as Amberlyst-15 and Amberlyst BD-20 and a homogeneous catalyst such as sulfuric acid were used for esterification. Among three catalysts, the removal efficiency of Free Fatty Acid (FFA) was the highest in sulfuric acid. Response surface method was carried out to find the optimal esterification condition of sulfuric acid and methanol. After the esterification under the optimal condition, this animal fat was used for the trans-esterification. Animal oil used for trans-esterification was below 1% of FFA content and 0.09% of water content. The catalysts for trans-esterification were KOH, NaOH and $NaOCH_3$. To investigate the effects of catalyst type and amount on trans-esterification, The amount of catalyst were changed with 0.3, 0.6 and 0.9 wt%. The molar ratio of methanol/oil was changed with 4, 6, 9 and 12. The amount of catalyst was fixed to 0.8 wt%. The KOH catalyst showed the highest FAME conversion for trans- esterification, and the optimal methanol/oil weight ratio was 6. In the experiments of various catalysts and methanol molar ratios, the highest content of FAME is 96%. However, this FAME content was below Korean bio-diesel standard which is 96.5% of FAME content. After distillation, FAME content increased to 98%.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.1
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• pp.8-13
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• 2008

Emissions from automobiles have long been considered a prime source of pollutants involved in smog formation and ozone production. Especially VOCs are associated with serious environmental problems such as photo-chemical smog as well as human health effects. Since motor vehicles are a major source of VOCs, estimating of emission from mobile source is the most important factor to control VOCs. VOCs are emitted from various pollution like motor vehicles, mobile and stationary source that has characteristics of toxicity, cancer-causing, bio-accumulation, durability in air and diffusion can exert a bad influence upon human health and environment. However we don't have any standard or regulation about VOCs emissions. This study is summarized as VOCs emission characteristics from in-use light-duty diesel and LPG fueled vehicles. The vehicle exhaust-gas test mode is CVS cycle and nier-10 cycles that developed on EPA and National Institute of Environmental Research. TO-14 method (Toxic Organic) was chosen for VOCs analysis from EPA in USA. This study results will be useful when make a emission factor and rule making of emission standard about domestic VOCs emission for the improve to air condition.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.795-796
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• 2010

Interest has been increasing worldwide in Fischer-Tropsch synthesis (F-T) as a method of producing synthetic liquid fuels from biomass. Hydroisomerization of $C_7-C_{15}$ paraffins applies to production of diesel fuel with high cetane number and improved cold flow properties, such as viscosity, pour point and freezing point. The commercial products such as fuel jet produced from F-T synthesis should have low freezing and pour points. In this study, our major aim is to develop a catalyst for hydroisomerization of synthesis-oil for bio-jet fuel. Effects of zeolites and platinum loading on hydroisomerization of dodecane were investigated as a model reaction in a batch reactor.

• Tribology and Lubricants
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• v.31 no.6
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• pp.251-257
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• 2015

Heavy oil production is receiving significant attention because of increased demands for thermal power generation systems of the diesel engine and boilers. However, asphaltene, which is a heavy oil components (6-8 wt%), reduces the heat efficiency of the fuels owing to its agglomerated sludge of asphaltene during the burning process. Therefore, for hassle-free operation, we should develop asphaltene dispersants to suppress the formation of the sludge. We prepare variable salt-type polymeric dispersants using poly(isobutenyl succinic anhydride) and poly(amine) through both condensation esterification and acid-base neutralization reactions, which we subsequently evaluate for dispersing performance, using Turbiscan measurement. Total acid number (TAN) and total base number (TBN) of 75Lec-25SynDis.2 composed of lecithin and the prepared polymeric salt having the ratio of 3 : 1 are 18.9 and 33.7 mg KOH/g, respectively, which are comparable to those of the commercial dispersants (15.8 and 26.5 mg KOH/g). We determine the initial turbidity observed for 15 min of the polymeric dispersant was determined with transmittance (%), which can be calculated to separability number (SN). The SN value of 75Lec-25SynDis.2 is close to zero, which is superior to that of commercial dispersants and lecithin (0.015 and 0.017).

• Journal of Environmental Science International
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• v.19 no.3
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• pp.313-321
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• 2010

This study was carried out to investigate the emissions of the air pollutants from the automobile in Suwon city. To estimate emissions due to by automobile the data of express highway and the national road used an observation traffic volume, and the other roads used a method by Vehicle kilometer traveled(VKT). In the emissions due to by automobile from Suwon city, CO was highest 36,290.4 ton/year, NOx at 19,392.1 tons, HC 5,095.4 tons and PM 2,788.7 tons was highly order. SOx emissions in the whole Suwon city by fuel types was investigated with 178ton/year from the Diesel motorcar, 26.9 ton/year and 6.2 ton/year from the gasolines and LPG automobiles, respectively. VOC emissions from the automobile was investigated with 366.4 ton/year (29.22%) from Gwonseon-gu, 329.2 ton/year (26.25%) Yeongtong-gu, 319.9 ton/year (25.51%) Jangan-gu, 238.6 ton/year (19.03%) Paldal-gu.

• Clean Technology
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• v.19 no.3
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• pp.313-319
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• 2013

To produce biodiesel efficiently from fish oil containing 4% free fatty acid, esterification and trans-esterification were carried out with Vietnam catfish oil, which was kindly provided from GS-bio company. Heterogeneous solid acid catalysts such as Amberlyst-15 and Amberlyst BD-20 and sulfuric acid as homogeneous acid catalyst were used for the esterification of free fatty acids in the fish oil. Sulfuric acid showed the highest removal efficiency of free fatty acid and the shortest reaction time among three acid catalysts. The base catalysts for trans-esterification such as KOH, $NaOCH_3$ and NaOH were compared with each other and KOH was determined to be the best transesterification catalyst. Some solid material, which assumed to be saponified product from glycerol and biodiesel, were observed to form in the fish oil biodiesel when using $NaOCH_3$ and NaOH as the transesterification catalyst. The initial acid value of fish oil was proven to have a negative effect on biodiesel conversion. Of the three catalysts, KOH catalyst transesterification was shown to have high content of FAME and the optimal ratio of methanol/oil ratio was identified to be 9:1.