• Title/Summary/Keyword: Bio-carbon

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Adsorption of Selenium in Industrial Wastewater Using Anion Exchange Resin and Activated Carbon (음이온교환수지와 활성탄을 이용한 산업 폐수 중 셀레늄의 흡착)

  • Han, Sang-Uk;Park, Jin-Do;Lee, Hak-Sung
    • Journal of Environmental Science International
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    • v.18 no.12
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    • pp.1411-1416
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    • 2009
  • Several adsorbents were tried to remove the selenium ions from industrial wastewater and the following ascending order of the adsorption performance for the selenium at pH 9 was observed: cation exchange resin < chelate resin < zeolite < brown marine algae < granular activated carbon < anion exchange resin. Initial concentration of selenium(146 mg/L) in industrial wastewater was reduced to 63 mg/L of selenium at pH 9 by neutralization process. The maximum uptake of Se calculated from the Langmuir isotherm with anion exchange resin was 0.091 mmol/g at pH 10 and that with granular activated carbon was 0.083 mmol/g at pH 6. The affinity coefficients of Se ion towards anion exchange resin and granular activated carbon were 3.263 L/mmol at pH 10 and 0.873 L/mmol at pH 6, respectively. The sorption performance of anion exchange resin at the low concentration of Se, namely, was much better than that of granular activated carbon. The Se ions from industrial wastewater throughout neutralization process and two steps of adsorption using anion exchange resin was removed to 97.7%.

An Analysis of Local Quantity of Carbon Absorption, Fixation and Emission by Using GIS

  • Kim, Hyeon-Tae;Moon, Byeong-Eun;Choi, Eun-Gyu;Kim, Chi-Ho;Ryou, Young-Sun;Kim, Jong-Goo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.1
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    • pp.40-48
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    • 2014
  • Due to increasing greenhouse gas emissions, global warming and abnormal weather phenomena it has become important on a national level to keep a count of greenhouse gases being emitted. We want to take advantage of any selected area, as the basic data for the calculation of greenhouse gas emissions, Forest and Grassland, Paddy fields, and Fields(crops), Greenhouse(crops), Pig farm, Cattle farm, Farm household(populations, agricultural machinery) and Vehicle, the basic building blocks shots with a small amount of per-unit basis, the statistics calculated based on regional carbon emissions through the literature and experimental. Carbon absorption 772,960 ton C/year, amount of fixation 487,477 ton C/year, amount of emission 1,112,607 ton C/year were noted in Gimje-si, and amount of carbon absorption 55,559 ton C/year, amount of fixation 25,864 ton C/year, amount of emissions 58,355 ton C/year in Gongdeok-myeon, respectively. The carbon absorption at Hwangsan-ri is 25,107 ton C/year, fixation 4,301 ton C/year, and emission 20,330 ton C/year respectively. We were able to estimate the amount of carbon according to the specific characteristics of each unit village, then expanding it to a large-scale and comparative analysis, therefore we were able to obtain basic data on the national levels of carbon absorption.

A Complete, Reductive Depolymerization of Concentrated Sulfuric Acid Hydrolysis Lignin into a High Calorific Bio-oil using Supercritical Ethanol

  • Riaz, Asim;Kim, Jaehoon
    • KEPCO Journal on Electric Power and Energy
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    • v.2 no.3
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    • pp.447-452
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    • 2016
  • It is imperative to develop an effective pathway to depolymerize lignin into liquid fuel that can be used as a bioheavy oil. Lignin can be converted into liquid products either by a solvent-free thermal cracking in the absence air, or thermo-chemical degradation in the presence of suitable solvents and chemicals. Here we show that the solvent-assisted liquefaction has produced promising results in the presence of metal-based catalysts. The supercritical ethanol is an efficient liquefaction solvent, which not only provides better solubility to lignin, but also scavenges the intermediate species. The concentrated sulfuric acid hydrolysis lignin (CSAHL) was completely liquefied in the presence of solid catalysts (Ni, Pd and Ru) with no char formation. The effective deoxy-liquefaction nature associated with scEtOH with aid hydrodeoxygenation catalysts, resulted in significant reduction in oxygen-to-carbon (O/C) molar ratio up to 61%. The decrease in oxygen content and increase in carbon and hydrogen contents increased the calorific value bio-oil, with higher heating value (HHV) of $34.6MJ{\cdot}Kg^{-1}$. The overall process is energetically efficient with 129.8% energy recovery (ER) and 70.8% energy efficiency (EE). The GC-TOF/MS analysis of bio-oil shows that the bio-oil mainly consists of monomeric species such as phenols, esters, furans, alcohols, and traces of aliphatic hydrocarbons. The bio-oil produced has better flow properties, low molecular weight, and high aromaticity.

Cloning and Expression Analysis of a Chitinase Gene Crchi1 from the Mycoparasitic Fungus Clonostachys rosea (syn. Gliocladium roseum)

  • Gan, Zhongwei;Yang, Jinkui;Tao, Nan;Yu, Zefen;Zhang, Ke-Qin
    • Journal of Microbiology
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    • v.45 no.5
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    • pp.422-430
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    • 2007
  • Clonostachys rosea (syn. Gliocladium roseum) is a well-known biocontrol agent and widely distributed around the world. In this study, an endochitinase gene Crchi1 was isolated from the mycoparasitic fungus C. rosea using the DNA walking strategy. The Crchi1 ORF is 1,746 bp long and interrupted by three introns. The cloned gene Crchi1 encodes 426 amino acid residues and shares a high degree of similarity with other chitinases from entomopathogenic and mycoparasitic fungi. Several putative binding sites for transcriptional regulation of Crchi1 in response to carbon (5'-SYGGRG-3') and nitrogen (5'-GATA-3') were identified in the upstream of Crchi1. Expression of Crchi1 gene in different carbon sources was analyzed using real-time PCR (RT-PCR). We found that the Crchi1 expression was suppressed by glucose but strongly stimulated by chitin or solubilized components of the cell wall from Rhizoctonia solani. Phylogenetic analysis of chitinases from entomopathogenic and mycoparasitic fungi suggests that these chitinases have probably evolved from a common ancestor.

Cystocin, a Novel Antibiotic, Produced by Streptomyces sp. GCA0001: Production and Characterization of Cystocin

  • Sohng, Jae-Kyung;Lee, Hei-Chan;Liou, Kwang-Kyoung;Lee, Eui-Bok;Kang, Sun-Yub;Woo, Jin-Suk
    • Journal of Microbiology and Biotechnology
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    • v.13 no.4
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    • pp.483-486
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    • 2003
  • 3'-[S-Methyl-cysteinyl]-3'-amino-3'-deoxy-N,N- dimethyl adenosine, cystocin, is a biosynthesized antibiotic material newly identified from Streptomyces sp. GCA0001. Its structure was found to be similar to puromycin, where the terminal tyrosine is replaced by a methyl cysteine. NMR data prove that the 3-ammo ribose is connected to dimethylaminopurine through the anomeric carbon at 1'-carbon. The methyl cysteinyl unit is connected to the amino unit of ribose by peptide bond. The verification of the structure was performed by comparing the puromycin nucleosides resulted from the hydrolysis of cystocin and puromycin, respectively. Antibiotic activity of cystocin against Streptococcus was found to be two times more potent than that of puromycin.

Involvement of Cytochrome P450 in (-)-(4R)-Isopiperitenone Oxidation by Cell Suspension Cultures of Mentha piperita

  • Park, Si-Hyung;Chang, Yung-Jin;Kim, Kyung-Hyun;Kim, Soo-Un
    • Journal of Microbiology and Biotechnology
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    • v.9 no.2
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    • pp.147-149
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    • 1999
  • Biotransformation of exogenous (-)-(4R)-isopiperitenone in cell suspension cultures of Mentha piperita resulted in oxidized products, with (-)-7-hydroxyisopiperitenone being the major compound. The mass of products obtained $unde^{18}O_2$, atmosphere was two units higher than that under normal atmosphere. The biotransformation was inhibited by several cytochrome P450-specific inhibitors as well as by carbon monoxide. Carbon monooxide inhibition was substantially overcome by irradiation of cells with blue light including light at 450nm wavelength. These results suggested that a cytochrome P450-type monooxygenase was involved in the biotransformation.

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Shear performance of green timber wall panels (그린팀버월 패널의 전단성능)

  • Kim, Yun-Hui;Shin, Il-Joong;Jang, Sang-Sik
    • Korean Journal of Agricultural Science
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    • v.38 no.3
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    • pp.541-547
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    • 2011
  • Korean building industry was developed by concrete and steel construction. However, concrete and steel have some problems which low carbon storage capability and difficulty of recycling. According to many studies, timber has high carbon storage capability, high recycling capability and sustainable supporting capability. Focus on this factors of timber, make new wall structure as Green Timber Wall panels and check the shear performance to use wall system in housing construction such as light-weight timber construction and nondearing wall on other construction. In the results, B-4-B and B-4-S show similar modulus of shear stiffness on the table. GH-4-GH has slip shape failure mode between Green Timber Wall boards. GH-4-GV has most stable characteristic curve than other specimens.

Effect of Black Charcoal and Activated Carbon for Reduction of Radon Radioactivity that Emitted from Building Materials (건축재료로부터 방출되는 라돈방사능 감소를 위한 흑탄과 활성탄 효과)

  • Cho, Yun-Min;Lee, Hwa-Hyung
    • Journal of the Korea Furniture Society
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    • v.22 no.1
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    • pp.13-17
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    • 2011
  • Recently, interest in indoor air quality is increasing. Especially, radon radioactivity among the indoor air is a well-known risk factor for lung cancer because of ionizing radiation in the form of ${\alpha}$-particles. This study was carried out to investigate effect of black charcoal and activated carbon for reduction of radon radiation that emitted from building materials. Black charcoal and activated carbon were used as a barrier which was against the infiltration of radon. The source of radon was gypsum board. Two types of charcoal barrier were powder- and board-type with 5 mm, 10 mm thickness respectively. The method for this determination is evaluated radon concentration in chamber. The measurements were performed with radon detector, SARAD3120. Results of this study are as following: Black charcoal and activated carbon confirmed the highly efficient barrier. Radon concentration was reduced from 72% to 85% as compared the control chamber. Radon reduction capability, however, was no difference as barrier's types. Results obtained in ventilation condition, radon concentration shows 5.93 pCi/L on average in the closed condition and shows 2.69 pCi/L in the opened condition.

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Beyond Net Zero - SOM's Urban Sequoia Building Concept and Technologies for Future, Regenerative Cities

  • Mina Hasman;Jiejing Zhou;Alice Guarisco;Nicholas Chan;Alessandro Beghini;Zhaofan Li;Michael Cascio;Yasemin Kologlu
    • International Journal of High-Rise Buildings
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    • v.12 no.2
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    • pp.121-128
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    • 2023
  • Cities cover only 3% of the planet's surface, yet they are responsible for more than 75% of the global emissions. Given the projected urban built area will double by 2060, the carbon emitted from cities will further increase. SOM proposes the Urban Sequoia concept, for buildings that go beyond 'net zero' and absorb carbon from the atmosphere. This concept combines multiple strategies, including the use of an optimised building form with a highly efficient structural system, modularized prefabrication techniques, holistic integration of facade, MEP and interiors' components, bio-based materials, and Direct Air Capture (DAC) technology, to reduce a 40-storey building's whole life cycle carbon emissions by more than 300% over a 100-year lifespan. Calculations of embodied carbon emissions are performed with SOM's in-house Environmental Analysis (EA) Tool to demonstrate the effectiveness of employing Urban Sequoia's design strategies in the design of new buildings using current technologies.

Phase Behavior of Simvastatin Drug in Mixtures of Dimethyl Ether and Supercritical Carbon Dioxide (디메틸에베르와 초임계이산화탄소의 혼합물에서 Simvastatin 약물의 상거동)

  • Shin, Eun-Kyoung;Oh, Dong-Joon;Lee, Byung-Chul
    • Clean Technology
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    • v.13 no.4
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    • pp.237-243
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    • 2007
  • Phase behavior of the ternary systems of water-insoluble simvastatin drug, which is well known to be effective drugs for hypercholesterolemia therapy, in solvent mixtures of dimethyl ether (DME) and supercritical carbon dioxide was investigated to present a guideline of establishing operating conditions in the particle formation of the drugs by a supercritical anti-solvent recrystallization process utilizing DME as a solvent and carbon dioxide as an anti-solvent. The solubilities of simvastatin in the mixtures of DME and carbon dioxide were determined as functions of temperature, pressure and solvent composition by measuring the cloud points of the ternary mixtures at various conditions using a high-pressure phase equilibrium apparatus equipped with a variable-volume view cell. The solubility of the drug increased as the DME composition in solution and the system pressure increases at a fixed temperature. A lower solubility of the drug was obtained at a higher temperature.

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